The integration of metal nanoparticles and solid carriers can achieve ideal stability, high load and good conductivity. In this work, copper nanoparticles (Cu NPs) were sequentially deposited on a cobalt metal-organic framework (Co-MOF) by bonding with exposed imino groups, followed by a reduction reaction to prepare a new Cu@Co-MOF composite. Cu@Co-MOF acts as a non-enzymatic electrochemical sensor to detect glucose (Glu) in an alkaline medium. The composite working electrode of Cu@Co-MOF/GCE (GCE = glassy carbon electrode) improves the electrocatalytic activity for Glu oxidation. Cu@Co-MOF/GCE shows excellent electrocatalytic performances in Glu concentration ranging 0.005~1.8 mmol∙L⁻¹ (mM): the sensitivities are 282.89 μA∙mM⁻¹∙cm⁻² in 0.005-0.4 mM Glu and 113.15 μA∙mM⁻¹∙cm⁻² in 0.4-1.8 mM Glu respectively with low detection limit of 1.6 μM (S/N = 3) and high selectivity and stability.

Cobalt, like other critical elements, is gaining in importance today. The great technological advances and the deep knowledge of the physical and chemical properties of this element have allowed to enhance its applications in various fields, such as: catalysts, paints, alloys for the mechanical and aerospace industries, as well as the medical sector and in recent times, its use within the rechargeable battery industry. The main exploitable deposits are in the Democratic Republic of the Congo, which have economic potential due to a strong influence on their mineralization processes. However, the growing demand for cobalt and the search for less dependence on African deposits leads to targeting other regions, so it is necessary to carry out exhaustive exploration to find out the potential of its reserves for a subsequent benefit of the mineral. Generally, cobalt comes as a by-product of the extraction of other metallic minerals, mainly from Cu-Co, Ni-Co, Ni-Cu-Co deposits. From the above, a first review is carried out on the differences that exist in the geochemical, mineralogical and forecast properties that exist within the different deposits that harbor cobalt. As a second review topic, it delves into efficient processing for cobalt recovery, which is generally carried out by flotation, acid leaching, in addition to its recovery from secondary sources, such as batteries and metallurgical waste. However, generally speaking there is still a vast lack of fundamental knowledge about the processability of cobalt. Said processing has been affected from the point of view of mineralogy, that is, understanding and knowing the cobalt-bearing minerals, as well as gangue mineralogy, these aspects exercise significant control during their processing and selection of the most appropriate route. suitable for cobalt extraction (leaching and/or flotation). In this context, the document concludes with a vision of the challenges that the mining industry must implement to enter circular economy models, mainly in the creation of sustainable processes from secondary sources.

Co/TiO2 catalysts with different cobalt loadings (3.8, 7.5 and 15 wt%) were prepared by impreg-nation method of Co(NO3)2 .6H2O over titania. Samples containing Co(NO3)2 .6H2O and TiO2 in stoichiometric proportions in order to obtain CoTiO3 and Co2 TiO4 phases were also synthesized. The effect of the calcination treatment at two different temperatures, 550 and 1150 °C was investigated. Characterizations by several techniques, such as XRD UV-vis-NIR, DRS, Raman and XPS were carried out. XRD showed the coexistence of three phases: CoTiO3; Co2TiO4 and Co3O4 after calci-nation at 550°C, while the calcination at high temperature (1150°C) leads to single-phase systems (CoTiO3 or Co2TiO4). Diffuse reflection and XPS spectroscopy showed that divalent cobalt occupies octahedral sites in the ilmenite phase and both tetrahedral and octahedral sites in the spinel phase. The catalytic performances of the prepared catalysts, calcined at the two different temperatures, were evaluated in the oxidative dehydrogenation reaction (ODH) of ethane to ethylene. The con-version values were almost comparable for all the samples, calcined at 550 °C, and comparable the ethylene selectivity were recorded, slightly higher only in the case of CoTiO3. The calcination at 1150°C did not modify the overall activity (ethane conversion values around 20%), however, the production of COx becomes more significant. The study examined the influence of the reaction mixture composition, specifically the presence of water, and reveals a slight increase in the yield of ethylene accompanied by a decrease in the overall catalyst activity. This behavior is likely attributed to an increase in the surface concentration of hydroxyl species (OH), resulting in heightened surface acidity.

This work focuses on the support effect on the performances of Co-based catalysts for the acetic acid steam reforming. SBA-15, a well ordered hexagonal mesoporous silica structure, and CeO2 have been selected as the supports, with the impact of chromium addition also being investigated. Better acetic acid steam reforming performances have been recorded for CeO2 compared to SBA-15 supported catalysts and, in particular, the 7Co/CeO2 catalyst showed the highest values of acetic acid conversions with enhanced H2 yields below 480°C, in comparison to the other investigated catalytic formulations. In addition, more pronounced coke depositions and acetone concentrations have been obtained with CeO2 supported catalysts, due to the tendency of ceria to catalyse the ketonization reaction. Chromium addition to Co/SBA-15 catalysts led to an enhancement in the activity towards acetic acid steam reforming, while on CeO2 supported catalysts no improvement in the catalysts activity was observed; however, on both SBA-15 and CeO2 supported catalysts, Cr addition reduced the amount of coke deposited on the catalysts surface.

In this work, cobalt doped ZnO nanorod arrays with anticorrosion function were successfully prepared on FTO substrate by a simple aqueous solution method. XRD and EDS results indicate the doped Co2+ has successfully incorporated into the ZnO crystal lattice. Photocurrent density and open circuit potential (OCP) results indicate the photocathodic protection performance for 316 stainless steel (316 SS) and Q235 carbon steel in 3.5 wt.% NaCl solution under 300 W Xe lamp enhanced with the increase of cobalt concentration, and the photoanode with 15% Co/Zn ratio has the optimal photocathodic protection effect. The mechanism of enhancement may be result from the narrowed band gap, the lower recombination rate of photogenerated electron-holes, the intermediate impurity level and the split of the hypo-outer shell of cobalt ions.

In this paper, a new anode environmentally friendly for hydrogen production was developed based on 430 stainless steel with an electrodeposited cobalt layer. The novelty of this work is the cobalt source once the electrodeposition bath was obtained from recycling of spent Li-ion batteries cathode with composition LiCoO₂. The electrodeposited cobalt behaves as supercapacitor in KOH 1M. In the linear voltammetry in KOH 1M, when the overpotential reaches 370 mV, the anodic density current for 430 SS/Co is 19 mA cm⁻². Thus, the anode developed in this paper achieves the double of density current with half of production cost if compared with 316SS. Moreover the anode construction described in this paper is an excellent option for Li- ion battery recycling.

Crystalline β-cobalt hydroxide (β-Co(OH)₂) of different morphologies have been successfully synthesized with the addition of sodium hydroxide to cobalt nitrate solution and aging in the mother liquor. The rate of NaOH addition, ranging from 0.1 mL/min to 10 mL/min, influences the surface morphology with the obtained storage capability of the respective electrode. Characterization of the β-Co(OH)₂ was fully developed, including X-ray diffraction, scanning and transmission electron microscopy, and BET analyses. At a lower rate of NaOH addition, particles are like platelets, while for a higher rate (≥2 mL/min) grains are fused together forming a larger crystallite size. This result is supported by the X-ray diffraction structural analysis, where the phase evolution of (002) plane becomes distinct for the higher rate of NaOH addition. Lithium cobalt oxide (LiCoO₂) was synthesized through oxidation from the as-prepared β-Co(OH)₂ and LiOH. The electrochemical performance of as obtained LiCoO₂ is investigated using charge-discharge and cyclic voltammetric studies. The precursor β-Co(OH)₂ prepared at a lower rate of 0.1 mL/min in LiCoO₂ demonstrated the best electrochemical performance of 155 mAh/g. After 50 cycles, the capacity retention rate was 67% compared with the first cycle. Finally, we have attempted to correlate the amount of the available OH^- ions with the formation of platelets and the discharge capacity. This work has developed a methodology for the synthesis of LiCoO₂ using β-Co(OH)₂ in a facile chemical solution process.

This study investigates the magnetization of Cobalt (Co) nanoparticles with two different crystal structures: a centered cubic (fcc) and an hexagonal close packed (hcp), under the magnetic field of the Earth. For that reason, the hysteresis loops of the two material samples are exported and compared with the corresponding value by experimental procedure in the laboratory under the Earth’s magnetization. For both samples, the nanoparticle number variation and the nearest neighbor distance effect, in the Co hysteresis loop are investigated, structural information that is useful for the sample preparation. For the simulations the Finite Element Method (FEM) was used, while experiments are conducted using a measurement set-up based on fluxgate magnetometers. From the simulation, it is proven that, for both samples, the nanoparticle number effect does not change the hysteresis loop. In contrast, when the distance between the nanoparticles increases, the magnetization obtains smaller value. This study aims to build a novel, simple and economical measurement arrangement enabling in situ magnetic measurements for ferromagnetic nano-material characterization. As the need for continuous knowledge of the condition and the phase of ferromagnetic nanoparticles that is crucial in many applications, like catalytic processes, this work aims to introduce an alternative approach that will add another dimension to conventional chemical reaction engineering this of the magnetic state of the material resolved in time and space and to contribute in the field of the monitoring and the early fault diagnosis of nanoparticle materials.

Urea, a prevalent component found in wastewater, shows great promise as an alternative substrate to water for energy-efficient hydrogen production by electrolysis. However, the sluggish kinetics of the anodic urea oxidation reaction (UOR) significantly hampers the overall reaction rate. To address this challenge, this article presents a comprehensive study focusing on the controlled fabrication of hierarchically structured nanomaterials as potential catalysts for UOR. The prepared MnO2@NiCo-LDH hybrid catalyst demonstrates remarkable improvements in reaction kinetics, benefiting from synergistic enhancements in charge transfer and efficient mass transport facilitated by its unique three-dimensional architecture. Notably, the catalyst exhibits an exceptionally low onset potential of 1.228 V and requires only 1.326 V to achieve an impressive current density of 100 mA cm-2, representing a state-of-the-art performance in UOR. These findings highlight the tremendous potential of this innovative material-designing strategy to drive advancements in electrocatalytic processes.

The reaction of [Co2(CO)8] with an equimolar amount of P(OPh)3] in toluene solution yields in situ generated [Co2(CO)7{P(OPh)3}] 1. Subsequent heating of 1 provides in a condensation reaction an alternative synthetic access to the tetranuclear cluster [{Co4(μ2-CO)3(CO)8{P(OPh)3}] 2. Compound 2 has been characterized by IR and 31P NMR spectroscopy, the tetranuclear cluster framework has be ascertained by a single-crystal X-ray diffraction study performed at 100 K.

The effect of dentin pretreatment with desensitizing paste containing 8% arginine and calcium carbonate on the retention of laser-sintered cobalt-chromium (Co-Cr)-based crowns was examined. Forty molars were prepared using a standardized protocol. The Co-Cr crowns were produced using selective laser melting. The teeth were either pretreated with the desensitizing paste or not pretreated. After one week, each group was cemented with glass ionomer cement (GIC) or zinc phosphate cement (ZPC). Surface areas of the teeth were measured before cementation. After aging, the cemented crown-tooth assemblies were tested for retentive strength using a universal testing machine. The debonded surfaces of the teeth and crowns were examined at 2.7× magnification. Pretreating the dentin surfaces with the desensitizing paste before cementation with GIC or ZPC did not affect the retention of the Co-Cr crowns. The retention of the GIC group (6.04±1.10 MPa) was significantly higher than that of the ZPC group (2.75±1.25 MPa). The predominant failure mode for the ZPC and for the nontreated group of the GIC was adhesive cement-dentin; for the GIC-treated group, it was adhesive cement-crown. The desensitizing paste can be safely used to reduce postcementation sensitivity without reducing the retentive strength of Co-Cr crowns cemented with GIC or ZPC.

Starting 1994, the debate for regulating organic agriculture in Brazil was officially recognized in May 1999. Still, only in 2003, when the law # 10,831 was instituted, the country reached an effective milestone on organic production, both internally and externally. Since the industry regulation, the legislation underwent many modifications, constantly reviewing and adjusting. The current study examined the institutionalization of organic production in Brazil and what the current regulations can be used as a reference for those interested in this sector. The most recent update of Organic legislation and its implication on practice were also discussed. A case study on production of strawberry in organic system is presented and discussed.

Two interesting compounds such as quaternary ammonium lignin(QAL) and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester (P507) were synthesized as ionic liquids(QP-ILs) for the extraction of metal ions. The extraction behavior of Co(II) and Ni(II) from chloride solution was compared between QP-ILs and P507. The results showed that the extraction rates of Co(II) and Ni(II) in the two solutions varied with the extraction conditions, but QP-ILs has stronger extractability for cobalt than P507, while Ni is on the contrary. Under the same conditions, the Co/Ni separation performance(βCo/Ni) in QP-ILs is superior to that in p507. At pH4.0, 55℃, concentration of 20%, extraction time of 10 minutes, the βCo/Ni of QP-ILs reached to 2703, while that of P507 was only 164. In conclusion, QP-ILs was more efficient than P507 for separating Co from mixed solutions.

The usage of biotechnological molecules and processes is an indispensable part of the resource technology research. The development of novel biomolecules therefore needs to be adapted to the existing applicational conditions and biological processes are to be examined. Novel biosorbents may not only contribute to future applications but can be of further used, e.g. to better understand the interaction of known metal- and metalloid-interacting biological molecules and materials. This review highlights biotechnological approaches published so far for bioremediation as well as metal recovery with a special spotlight on cobalt, nickel and arsenic.

The exploitation of the metallacarboranes’ potential in various fields of research and practical ap-plications requires the availability of convenient and versatile methods for their functionalization with various functional moieties and/or linkers of different types and lengths. Herein we report a study on cobalt bis(1,2-dicarbollide) functionalization at 8,8’-boron atoms with different het-ero-bifunctional moieties containing protected hydroxyl function allowing further modification after deprotection. Moreover, an approach to the synthesis of three and four functionalized metallacarboranes, at boron and carbon atoms simultaneously, via additional functionalization at carbon to obtain derivatives carrying three or four rationally oriented and distinct reactive surfaces, is described

Streptococcus suis is a zoonotic pathogen causing serious infections in both swine and humans. Although metals are essential for life, excess amounts of metals they are toxic to bacteria. when accumulated in excess amounts. Except for zinc, Transcriptome-level data of the mechanisms for resistance to metal-induced toxicity in S. suis are available for no metals other than zinc. have not been investigated from the transcriptome level in S. suis. Herein, we explored the transcriptome-level changes of in S. suis in response to ferrous iron and cobalt toxicity by RNA sequencing. Many A lot of genes were differentially expressed in the presence of excess ferrous iron and cobalt. Most of the genes in response to cobalt toxicity showed the same expression trends as those were expressed in the same trend in response to ferrous iron toxicity. qRT-PCR analysis of the selected genes confirmed the accuracy of RNA sequencing results. Bioinformatics analysis of the differentially expressed genes indicated that ferrous iron and cobalt have similar impacts effects on the cellular processes of S. suis. Treatment with ferrous Ferrous iron treatment resulted in down-regulation of several oxidative stress tolerance-related genes involved in oxidative stress tolerance and up-regulation of the genes in an amino acid ABC transporter operon. Expression of the several genes in the arginine deiminase system was down-regulated in the presence of after ferrous iron and cobalt treatment. Collectively, our results suggested that S. suis alters the expression of a lot of multiple genes to respond to ferrous iron and cobalt toxicity.

A comprehensive kinetic model of the Fischer-Tropsch synthesis (FTS) is developed in a fixed bed reactor under operating conditions (temperature, 230–235°C, pressure, 20–25 bar, gas hourly space velocity, 4000–5000 cm³(STP)/h/g_catalyst ,H₂/CO feed molar ratio, 2.1) over a Co based catalyst. Reaction rate equations based on Eley-Rideal (ER) type model for initiation step and Langmuir-Hinshelwood-Hougen-Watson (LHHW) type model for propagation and termination steps of the FTS reactions have been considered and the readsorption of olefins were taken into account. The model that was reported in the literature was modified in order to explain many significant deviations from the ASF distribution. Optimum parameters have been obtained by Genetic Algorithms (GA). The calculated activation energies to produce n-paraffins and 1-olefins were in the range of 82.24 to 90.68 kJ/mol and 100.66 to 105.24 kJ/mol, respectively. The hydrocarbon distribution in FTS reactions was satisfactorily predicted particularly for paraffins.

Cobalt (Co) is a transition metal and is classified as a beneficial metal for plants, but its benefits for plants remain obscure. Cobalt has been reported to negatively affect plant physiochemical processes both at higher (toxic) and lower (deficient) applied levels. High concentrations of cobalt in plant organs cause irreversible changes to the plant cells, mainly via enhanced production of reactive radicals. Moreover, Co and its compound play an essential role in humans as they are the central atoms of cobalamin, a co-enzyme precursor whose absence causes anemia. Hence, the optimum Co supply to plants is critical for customary plant metabolic workings. Henceforth, monitoring Co behavior in the soil-plant-human system is highly imperative. This review highlighted the latest literature on (i) Co in soil and plants; (ii) its mobility and phyto-availability in soil; (iii) phytouptake and translocation towards shoot tissues; (iv) toxic and deficient effects of Co on plants; (v) plant detoxification mechanisms under increased Co levels inside plants; and (v) its role in the human body. For this purpose, 1026 plant observations from literature data were analyzed related to Co biogeochemical behavior in the soil-plant system. The data analysis revealed an overall increase in 567 observations and a decrease in 381 observations. However, these general trends in plant responses vary significantly for different types of plant species and physiological attributes. Overall, the current review delineates an updated and critical representation of the biogeochemical behavior of Co in the soil-plant-human system, supported by up-to-date 9 main tables, 14 supporting tables, and 3 figures. The authors believe that the literature presented here can be of great interest to scientists, researchers, policymakers, and graduate-level students.

The very slow anodic oxygen evolution reaction (OER) greatly limits the development of large-scale hydrogen production via water electrolysis. By replacing OER with easier urea oxidation reaction (UOR), developing a HER/UOR coupling electrolysis system for hydrogen production can significantly save energy and costs. Al doped cobalt ferrocyanide (Al-Co2Fe(CN)6) nanocube array was in-situ grown on nickel foam (Al-Co2Fe(CN)6/NF). Due to the unique nanocube array structure and regulated electronic structure of Al-Co2Fe(CN)6, the as-prepared Al-Co2Fe(CN)6/NF electrode exhibited outstanding catalytic activities and long-term stability to both UOR and HER. The Al-Co2Fe(CN)6/NF electrode needed potentials of 0.169 V and 1.118 V (vs. reversible hydrogen electrode) to drive 10 mA cm−2 for HER and UOR, respectively, in alkaline condition. Applying the Al-Co2Fe(CN)6/NF to a whole urea electrolysis system, 10 mA cm−2 was achieved at a cell voltage of 1.357 V, which saved 60% electricity energy comparing to that of tranditional water splitting. Density functional theory calculations demonstrated that the boosted UOR activity comes from Co sites with Al doped electronic environments. This promoted and balanced the adsorption/desorption of main intermediates in UOR process. This work indicates that Co based materials as efficient catalysts have great prospects for application in urea electrolysis systems, and are expected to achieve low-cost and energy-saving H2 production.

This study presents a tri-layer broadband metamaterial absorber which operates in the GHz range. The absorber was composed of a polyhedral iron-cobalt alloy/graphite nanosheet material arranged in a flat sheet with two punched-in rings for the top layer, a continuous FR-4 layer at the middle, and a continuous copper layer at the bottom. For the normal incidence of electromagnetic wave, the proposed absorber demonstrated an exceptional broadband absorption in a frequency range of 7.9-14.6 GHz, revealing an absorption exceeding 90%. The absorption magnitude remains to be above 90% in a frequency range of 8-11.1 GHz for transverse-electric-polarized waves at incident angles up to 55°. For both transverse-magnetic- and electric-polarized waves, the absorption exceeds 90% in a frequency range of 9.5-14.6 GHz. The physical mechanism behind the absorption properties is analyzed thoroughly through the electric- and magnetic-field distributions. The obtained results could contribute potentially to the development of microwave applications based on metamaterial absorbers, such as radar-stealth technology, electromagnetic shielding for health safety and reduced electromagnetic interferences for high-performance communications and electronic devices.

The development and improvement of methods for the synthesis of environmentally friendly catalysts based on base metals is currently an urgent and promising task of modern catalysis. Catalysts based on nanoscale magnetite and maghemite have fast adsorption-desorption kinetics and high chemical activity. The purpose of this work was to obtain magnetic composites, determine their physicochemical characteristics and verify their activity in the process of liquid-phase oxidation of phenol with oxygen. Magnetic nanocomposites were obtained by chemical co-deposition of salts of ferrous and trivalent iron. The synthesized magnetic composites were studied by X-ray diffractometry, energy dispersive X-ray fluorescence and Mössbauer spectroscopy, IR-Fourier spectroscopy, elemental analysis. To increase the catalytic activity in oxidative processes, the magnetite surfaces were modified using cobalt nitrate salt. Further, CoFe2O4 was stabilized by adding polyethylenimine (PEI) as a surfactant. Preliminary studies of the oxidation of phenol with oxygen, as the most typical environmental pollutant were carried out on the obtained Fe3O4, CuFe2O4, CoFe2O4/PEI catalysts. The spectrum of the reaction product shows the presence of CH in the aromatic ring and double C=C bonds, stretching vibrations of the C=O groups of carbonyl compounds; the band at 3059 cm–1 corresponds to the presence of double C=C bonds, the band at 3424 cm–1 hydroquinone compounds. The band at 1678 cm–1 and the intense band at 1646 cm–1 refer to vibrations of the С=О bonds of the carbonyl group of benzoquinone. Peaks at 1366 cm–1 and 1310 cm–1 can be related to the vibrations of C–H and C–C bonds of the quinone ring. Thus it was demonstrated that produced magnetic composites based on iron oxide are quite effective in the oxidation of phenol with oxygen.

CoCr2O4 and doped lithium Co1-xLixCr2O4 chromate powder and nanoparticles were prepared by modified by sol-gel method. The morphological and structural properties of nano chromates were investigated by x-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy and Photoluminescence (PL). Nanoparticles of doped lithium were synthesized by adding appropriate amount of cobalt nitrate, chromium nitrate, lithium nitrate and 1,2 Ethanediol as a complexing agent. The sample were heated at 105 ˚C for ten hours in oven to obtain dry gel. Calcination temperature for these samples was 700˚C for 3 hours in a furnace. The particle size of parent compound ranges from 4.4 nm to 11 nm, determined by SEM. The tendency of particles to form the aggregates with the increased annealing temperature was observed. The SEM and optical characterization of this compound has shown the sol gel derived material may be successfully used as an effective doped lithium cobalt ceramic pigment with controlled variation in structural and optical properties. SEM images showed that spherical like doped particle have diameter 33nm. From PL spectra Nano structure shows band gap 2.5ev and when we doped Lithium in it band gap decreases and become 1.19ev, which is associated to band gap transition.

Polymer-based piezoelectric biomaterials have already proven their relevance for tissue engineering applications. Further, the morphology of the scaffolds plays also an important role in cell proliferation and differentiation. The present work reports on poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV), a biocompatible, biodegradable and piezoelectric biopolymer that has been processed in different morphologies, including films, fibres, microspheres and 3D scaffolds. Further, the corresponding magnetically active PHBV-based composites were also produced. The effect of the morphology on physico-chemical, thermal, magnetic and mechanical properties of pristine and composites samples was evaluated, as well as their cytotoxicity. It was observed that the morphology does not strongly affect the properties of the pristine samples but the introduction of cobalt ferrites induces changes in the degree of crystallinity that could affect the applicability of prepared biomaterials. Young modulus is dependent of the morphology and also increases with the addition of cobalt ferrites. Both, pristine and PHBV/cobalt ferrite composite samples are no cytotoxic, indicating their suitability for tissue engineering applications.

We revisit the argument that link the efficiency of a solar cell to its reverse operation as a LED, in the case where the material is organic. In organic cells, exciton transport is an intermediate process between sunlight absorption and the generation of electric current. We show that quenching exciton radiation can be beneficial to cell efficiency, without contradicting the general rule prevailing for semiconductor cells. Our treatment allows us to discuss both bulk heterojunction and planar junctions.

Additive Manufacturing and nanotechnology have been used as basic tools for the manufacture of nanostructured parts with magnetic properties to expand the variety of applications in additive processes by tank photopolymerization. Magnetic cobalt ferrite (CoFe2O4) and barium ferrite (BaFe12O19) nanoparticles with the size distribution of average value DTEM of 12 ± 2.95 nm and 37 ± 12.78 nm, respectively were generat-ed by hydroxide precipitation method. The dispersion of the nanoparticles on commercial resins (Anycubic Green and IRIX White resin) was obtained by mechanochemical reactions carried out in an agate mortar for 20 minutes, at room temperature and with limited exposure to light. The product of each reaction was placed in amber vials, also being kept in a box, to avoid contact with light. The photopolymerization process was carried out only at low concentrations (w/w % nanoparticles/resin) since, at high concentrations, there is no for-mation of pieces due to the high refractive index of ferrites. Raman shift spectroscopy of the final pieces showed that they contain the magnetic nanoparticles, with no apparent chemical changes. The EPR results of the pieces maintain the magnetic properties and apparently, they are not modified during the photopolymer-ization. Although significant differences were found in the dispersion process of the nanoparticles in each piece, we determined that the photopolymerization did not influence the structure and superparamagnetic behavior of ferrite nanoparticles during processing, and the magnetic properties were successfully transferred to the final 3D-printed magnetic obtained piece.

The development of gamma rays mutant rice lines would be a solution for introducing variability in already farmer using varieties. In vitro gamma (60Co) mutagenesis reduces chimeras and allows a faster selection of desired traits but requires laboratory process optimization. The objective of the present work was the in vitro establishment of a recalcitrant rice embryogenic calli, the determination of its sensitivity to gamma radiation (Co-60), sequencing MATK and Rubisco for identification purposes, as well as generation optimization. The radiosensitivity of embryogenic calli resulted in an LD50 of 110Gy, while the 20% lethal dose was 64Gy. All sequenced genes matched perfectly with already reported MATK and Rubisco O. sativa genes with a clear SNP that identifies the local variety related to the southeast Asia Region. Callus induction improves with an MS with 2mg/L 2,4D, and the regeneration was achieved with an MS medium with 3mg/L BAP and 0,5mg/L NAA. The optimized radiation condition was 60Gy with an 83% regeneration in a semisolid medium, allowing a balance between mutation and regeneration. When increased to 80Gy, the regeneration rate falls to 29%. An immersion system (RITA®) of either 60 or 120 seconds every 8hours allowed a systematic and homogeneous total regeneration of the recalcitrant line, in contrast with the semisolid medium that resulted in positive but irregular regeneration. Other well-known recalcitrant cultivars, CR1821, CR1113 also had an improving regeneration in the immersion system, demonstrating its potential use for recalcitrant materials. To our knowledge, this is the first report on using an immersion system to allow regeneration of gamma-ray mutants from recalcitrant rice materials.

This paper seeks to examine how the Mn-Co spinel interconnect coating microstructure can in-fluence the Cr contamination in an oxygen electrode of intermediate temperature Solid Oxide Cells at the operating temperature of 750 °C. A Mn-Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition and subsequently sintered following both the one-step and two-step sintering, in order to obtain significantly different densification levels. The electrochemical characterization is performed on anode supported cells with a LSCF cathode. The cells were aged prior to the electrochemical characterization in contact with the spinel coated Crofer 22 APU at 750 °C for 250 hours. Current-voltage and impedance spectra of the cells were measured after the exposure with the interconnect. Post-mortem analysis of the interconnect and the cell was carried out in order to assess the Cr retention capability of coatings with different microstructures.

Cobalt ferrite nanoparticles (NPs) doped with rare earth (RE) metals with general formula CoFe_2-xRE_xO₄ (RE=Yb, Dy, Gd; x = 0.0 - 0.3) were synthesized by the co-precipitation method followed by post thermal treatment. The influence of RE doping on structural, magnetic and thermal properties and potential biomedical applications like magnetic hyperthermia has been investigated. In the as-prepared samples RE cations enter the spinel lattice as detected by X-ray diffraction. Thermal treatment leads to thermodynamically stable and relaxed single-phase spinel structures only for lower RE content, x = 0.01-0.05. However, annealed samples present higher mass magnetization values (M_S), up to 83 Am²/kg. RE content also affects M_S, especially in the case of annealed samples where it decreases linearly with x from about 80 Am²/kg (x = 0.01) to about 60 Am²/kg (x = 0.30). Thermal treatment induces a reduction in coercivity from 60-100 mT for as-prepared samples to 18-33 mT for annealed samples, in a nonlinear manner with respect to RE content. Heating efficiency, i.e., Specific Loss Power (SLP), of all samples has been studied using both magnetometric and calorimetric method to deeper examine the energy loss mechanisms involved.

We report on the effects of the film morphology on the fluorescence spectra for a thin film including a quinoxaline-based co-polymer (TQ1) and a fullerene derivative (PC₇₀BM). The ratio between the polymer and the fullerene derivative, as well as the processing solvent were varied. Beside the main emission peak at 700 nm in the fluorescence spectra of thin films of this phase-separated blend, a broad emission band is observed with a maximum at 520 - 550 nm. The intensity of this emission band decreases with an increasing degree of mixing in the film and becomes most prominent in thicker films, films with high PC₇₀BM content, and films that were spin-coated from solvents with lower PC₇₀BM solubility. We assign this emission band to aggregated PC₇₀BM.

The objectives of this study are threefold. First, we evaluate the applicability of the information–motivation–behavioral skills (IMB) model for predicting organic food purchase intention (OFPI) in adults with chronic conditions. Second, we examine the indirect effects of organic food knowledge, attitudes toward organic food purchase, and subjective norms on OFPI through self-efficacy. Third, we examine whether these indirect effects are moderated by gender and educational attainment. Data were collected from Indian adults with chronic conditions using a self-administered questionnaire. The results show significant indirect effects of organic food knowledge, attitude toward organic food purchase, and subjective norm on OFPI through self-efficacy. Moreover, the mediating effect of knowledge was moderated by gender and education attainment, with the effect being stronger for females and among individuals with a lower level of education. Organic food marketers, social marketers, and public health agencies promoting organic food consumption to people with chronic conditions should aim to increase their confidence in comprehending organic food. This study contributes to the literature by assessing the applicability of Fisher and Fisher’s (1992) IMB model in understanding behavioral intention toward organic food.

The removal of sulfur from fossil fuels is one of the most important processes in modern refineries. It is accomplished via hydrodesulfurization (HDS) of the sulfur organic compounds in presence of heterogeneous catalysts. In the current work, heterogeneous catalysts containing cobalt and mo-lybdenum supported on mesoporous materials type SBA-15 and AlSBA-15 were synthesized for application in the HDS reactions of thiophene in n-heptane stream. The mesoporous materials were synthesized by hydrothermal method starting from TEOS, pseudobohemite, hydrochloric ac-id and water. Pluronic P123 was used as template. The best calcination conditions for removal of the organic template were optimized by thermogravimetry analysis (TG/DTG). The calcined SBA-15 and AlSBA-15 supports were submitted to co-impregnation with solutions of cobalt nitrate and ammonium heptamolybdate, aiming the production of 15% in mass of metal loading with atomic ratio of [Co/(Co+Mo)]=0.45. The obtained materials were dried and calcined for obtaining the mesoporous catalysts in the form of CoMo/SBA-15 and CoMo/AlSBA-15. The catalysts were char-acterized by XRD, TG/DTG, SEM and nitrogen adsorption. From XRD analysis, it was verified that after decomposition of the cobalt and molybdenun salts, were formed MoO3, Co3O4 and Co-MoO4 oxides on the supports, being attributed to these chemical species the activity for the HDS reactions. The activity of the obtained catalysts was evaluated in a continuously flowing tubular fixed-bed microreactor coupled on-line to a gas chromatograph, using n-heptane stream contain-ing 12070 ppm of thiophene (ca. 5100 ppm of sulfur) as a model compound. From the catalytic tests it was verified that the synthesized catalysts presented good activity for the reaction, and the main obtained products were cis- and trans-2-butene, 1-butene, n-butane and low amounts of iso-butane. The presence of 1,3-butadiene and tetrahydrothiophene (THT) were not detected. A mechanism of the primary and secondary reactions and subsequent formation of the olefins and paraffins, in the CoMo/SBA-15 and CoMo/AlSBA-15 mesoporous catalysts were proposed, con-sidering steps of desulfurization, hydrogenation, dehydrogenation, THT decyclization and isomerization.

Cobalt-doped alumina catalysts were prepared by different methods, applying either the conventional wet impregnation (WI) and/or the advanced spray impregnation (SI), and evaluated as novel oxidation catalysts for CO and MeOH oxidation. The spray impregnation technique aims towards the synthesis of core-shell catalytic nanostructures to secure chemical/thermal stability of the active sites on the catalyst carrier. The catalysts were further promoted with low Pd content (0.5 wt.%) applying either incipient wetness impregnation (DI) or spray impregnation. The results revealed the superior performance of spray impregnated catalysts (Co/γ-Al2O3-SI) for both reactions. The deposition of Co oxide on the outer surface of the alumina particle (SEM images) and the availability of the active Co phase, resulted in the enhancement of Co/γ-Al2O3 catalysts oxidation activity. Pd incorporation increased catalysts reducibility (TPR-H2) and improved the catalysts performance for both reactions. However, Pd incorporation method affected the catalytic performance; as with the SI method the active phase of Co3O4 was probably covered from PdO and was not available for the oxidation reactions. On the contrary, the incorporation of Pd with the DI method resulted in better dispersion of PdO all over the Co/Al catalyst surface, maintaining available Co active sites and better Pd-Co interaction. MeOH desorption studies revealed the methanol oxidation mechanism; Co/Al catalysts promote partial oxidation of MeOH to formaldehyde (HCHO) and dehydration to dimethyl ether (DME), while Pd-based Co/Al catalysts enhance the complete oxidation of methanol to CO2 and H2O.

The use of cobalt-iron (VaCoFe) core is investigated as an alternative to silicon-iron (FeSi) on the design of interior permanent magnet synchronous motors (IPMSM). A spoke-type IPMSM geometry is optimized considering FeSi and VaCoFe cores for a torque range up to 40 N.m, providing a general comparative analysis between materials, considering the application of a 4-motor competition vehicle’s powertrain. A genetic optimization algorithm is applied over a hybrid analytical/finite-element model of the motor to provide sufficiently accurate electromagnetic and thermal results within a feasible time. VaCoFe can result in an estimated increase of up to 5 % in efficiency for the same torque, or up to 64 % torque increase for the same efficiency level. After optimization, and using a detailed time-dependent model, a potential 3.2 % increase in efficiency, a core weight reduction of 4.1 %, and a decrease of 9.6 % in the motor’s core volume was found for the VaCoFe at 20 Nm. In addition, for the same motor volume, the VaCoFe allows an increase of 51.9 % of torque with an increase of 1.1 % of efficiency, when compared with FeSi.

At present, the drilling rig for deep seabed shallow strata is widely used in the exploration of ocean cobalt-rich crust resources and other fields, which not only can obtain solid core samples at a specific station, but the operation process is relatively safe. This paper mainly presents the structure and mechanism of mobile drilling rig in acquiring the seafloor cores (up to 1.5 m long). Based on the function of the AMESim software, the hydraulic propulsion system model of mobile drilling rig is established, which is the basis and core part of the mobile drilling rig. Moreover, the control methods of closed-loop and PID are respectively used to control the hydraulic propulsion system for simulation analysis. Through the comparison of simulation results, it is found that the PID control method is more convincing in verifying the design rationality of hydraulic propulsion system. In the simulation of the PID-controlled hydraulic propulsion system, the co-simulation technology of AMESim and Matlab/Simulink not only establishes the hydraulic model and control model, but also determines the relevant simulation parameters, which is helpful to improve the system simulation efficiency. In its verification deployment in the South China Sea, the mobile drilling rig has been operated for many times at different depths, and some cores have been successfully obtained. Furthermore, the mobile drilling rig has been used during the 55th Voyage of China Oceanic Scientific Expedition supported by China Ocean Mineral Resources R&D Association. Several sites were explored and a large number of cobalt-rich crust cores were obtained. The powerful theory and sea trails are provided to support for the further research on survey of the abyssal resource.

This review delves into the pivotal role of green manure in advancing agricultural sustainability and enhancing soil fertility. It emphasizes the wide-ranging ecological benefits of green manure practices, particularly in tropical regions, where it fosters multiple biological processes such as nitrogen fixation and nutrient cycling. The text provides an in-depth exploration of specific green manure species, their characteristics, practical considerations, and the physical, biological, and chemical effects they have on soil. It also discusses the practical implementation of green manure techniques, including cropping, intercropping, and strip or alley cultivation. The study emphasizes the critical need for species selection and effective green manure management, shedding light on their profound impact on crop productivity and environmental sustainability. With comprehensive details on various species and their practical implications, the study offers a comprehensive understanding of green manure's potential as an alternative source to mineral fertilizers in tropical agriculture.

Research indicates that farmers’ demographic characteristics and production practices have safety and health implications. However, current systems do not identify organic farmers independently from conventional farmers, and literature on how organic and conventional farmers compare is very limited. We conducted a secondary analysis of 2012 Census of Agriculture data to compare organic and non-organic farms and principal operators (POs) in New Mexico (NM). Organic farms were smaller in size, and POs of farms with organic sales were significantly younger (55.8±9.5 vs. 60.5±5.5 years) and less experienced (19.5±6.8 vs. 25.2±6.8 years). Significant differences were also found in POs ethnicity, race, and primary occupation. More farms with organic sales had a female PO compared to farms with non-organic sales (27% vs. 19%). Other significant differences related to work arrangements, household income, living conditions, and access to Internet. National surveys and regional studies may not accurately typify and describe the local organic producer, which is essential in order to advance policy, develop health interventions, and properly address occupational safety and risk among organic farmers. This study makes a unique contribution to understanding the importance of surveillance and collecting place-based data that are specific to the organic producer.

Organic farming products are fast gaining acceptance from consumers all over the world due to the perceived belief that they are safe for human consumption. In recent years, there has been an increase in the levels of persistent organic and inorganic pollutants in the environment. These pollutants may be found in materials such as sewage sludge, treated wastewater, farmyard manure (human and animal feaces and urine) that are used for organic farming. The present review examined through literature the presence of these emerging pollutants in crops that are cultivated from farming activities practicing organic farming. The review highlighted and documented various pollutants that may be found in crops due to non-compliance with legislation establishing organic farming. The need to develop a robust method for identifying safe products from organic farming was highlighted. The impact of non-compliance and lack of proper education on the peasant farmers practicing backyard farming was also enumerated.

Biochars are often proposed as a strategy for long-term carbon sequestration. Nevertheless, application of pyrolysed feedstock, particularly along with exogenous organic matter, may affect carbon dynamics in soil through introduction of labile carbon pools and stimulation of extracellular enzymes activity. The main aim of this research was to evaluate the influence of biochars and unprocessed organic amendments addition in two agricultural soils on the dissolved organic carbon (DOC) content and activity of three enzymes involved in carbon turnover. In the incubation experiment, activity of dehydrogenase, β-glucosidase, cellulase and DOC content were measured on day 30, 60, 90, 180 and 360. Addition of biochars stimulated the activity of dehydrogenase and β-glucosidase, while cellulase was suppressed. Fresh biomass amendment enhanced activity of the enzymes through priming effect. DOC content tended to be the highest in treatments with high enzyme activity, suggesting that DOC introduced with amendments acted as a source of energy for microbes. Our findings support the hypothesis that biochar properties and presence of exogenous organic matter affect microbial response in soil, what might be crucial for carbon sequestration potential of biochar. However, long-term studies are recommended to fully understand the mechanisms that determine response of soil biota to biochar addition.

Shutdown for just six days enables land plants to entirely fix CO₂ excess of +4 Gt C per yr. Rebuilding soil organic carbon (SOC) in worm-worked humus is the only practical carbon capture and storage (CCS) capable of freely offsetting annual anthropogenic emissions. A case is made to redirect all available resources towards proven, earthworm-based, organic husbandry. Priority is to safely combat mounting global threats due to irreversible species extinction, perilous climate change and deteriorating human wellbeing (mental/physical health). All three interlinked risks are underpinned by a relentless, yet largely ignored, critical loss of precious topsoil. A first step to topsoil recovery is vermi-composting all vegetable and animal ‘wastes’ for return to the field.

The magnetic properties of RCo3B2 compounds, with heavy rare earths, are investigated by using magnetic measurements and electronic structure calculations. The cobalt sublattice magnetizations are very small and antiparallel oriented to rare earths moments. Contributions of cobalt moments to the Curie constants were also shown. The cobalt magnetic behavior has been analyzed in spin fluctuations model. The presence of short-range order above the Curie temperatures in RCo3B2 compounds with R=Tb, Dy, and Ho has been attributed to reminiscent R5d-Co3d interactions.

Cardiovascular diseases (CVDs) constitute the first cause of death among the population of developing and developed countries. Atherosclerosis, which is a disorder with multifactorial etiopathogenesis, underlies most CVDs. The available literature includes ample research studies on the influence of classic cardiovascular (CV) risk factors. However, environmental exposure to heavy metals, among other substances, is still an unappreciated risk factor of CVDs. This study aimed to assess the concentration of some heavy metals (copper (Cu), zinc (Zn), manganese (Mn), cobalt (Co), and iron (Fe)) in the blood serum of postmyocardial infarction (post-MI) patients and patients free from myocardial infarction (MI) as well as estimate the relationship between the occurrence of MI and increased concentration of heavy metals. The concentration of heavy metals (Cu, Zn, Mn, Co, and Fe) was assessed using the inductively coupled plasma mass spectrometry technique in a group of 146 respondents divided into two groups: post-MI group (study group (SG), n = 74) and group without cardiovascular event (CVE) having a low CV risk (control group (CG), n = 72). The concentration of the analyzed heavy metals was higher in SG. All the heavy metals showed a significant diagnostic value (p < 0.001). The highest value of area under the curve (AUC) was observed for manganese (Mn) (0.955; 95% confidence interval (CI) = 0.922–0.988), while the lowest value was found for zinc (Zn) (0.691; 95% CI = 0.599–0.782). In one-dimensional models, high concentrations of each of the analyzed heavy metals significantly increased the chances of having MI from 7-fold (Cu) to 128-fold (Mn). All the models containing a particular metal showed a significant and high discrimination value for MI occurrence (AUC 0.72–0.92). Higher concentrations of Cu, Zn, Mn, Co, and Fe were found to considerably increase the chances of having MI. Considering the increasingly higher environmental exposure to heavy metals in recent times, their concentrations can be distinguished as a potential risk factor of CVDs.

Photoelectrochemical water splitting is a promising field for sustainable energy production using hydrogen. Development of efficient catalysts is essential for resourceful hydrogen production. The most efficient catalysts reported to date have been extremely precious rare-earth metals. One of the biggest hurdles in this research area is the difficulty of developing highly efficient catalysts comparable to the noble metal catalysts. Here, we report that non-noble metal dichalcogenide (Co₃Se₄) catalysts made using a facile one-pot electrodeposition method, showed highly efficient photoelectrochemical activity on a Si photocathode. To enhance light collection and enlarge its surface area even further, we implemented surface nano-structuring on the Si surface. The nano-structured Si photoelectrode has an effective area greater than that of planar silicon and a wider absorption spectrum. Consequently, this approach exhibits reduced overvoltage as well as increased photo-catalytic activity. Such results show the importance of controlling the optimized interface between the surface structure of the photoelectrode and the electrodeposited co-catalyst on it to improve catalytic activity. This should enable other electrochemical reactions in a variety of energy conversion systems.

The long-term use of fertilizers and pesticides in conventional cultivation has resulted in a decrease in soil productivity and vegetable yields in greenhouses. However, only a limited number of studies have explored the impacts of organic cultivation on greenhouse soil. Specifically, there is a scarcity of research examining the alterations in soil aggregate mediated organic carbon and microbial communities, which are known to enhance soil productivity. This study investigated the properties of soil aggregates, including the levels of organic carbon fractions, microbial community, and enzyme activity with the three aggregate classes microaggregates (&lt;0.25 mm), small macroaggregates (2-0.25 mm) and large macroaggregates (&gt;2 mm). These investigations were conducted under three different cultivation methods in a greenhouse: conventional cultivation (CC), integrated cultivation (IC), and organic cultivation (OC) in greenhouse. The results showed that (1) OC and IC promoted the formation of small macro-aggregates and enhanced aggregate stability compared to CC, (2) SOC in the three size fractions of OC increased by 98.99%-92.06% compared to CC; EOC increased by 98.47%-117.59%; POC increased by 138.59%-208.70%; MBC increased by 104.71%-230.61%; DOC increased by 21.93%-40.90%, respectively; (3) Organic cultivation significantly increased enzyme activity in all three particle size aggregates and increased the relative abundance of bacteria in micro-aggregates as well as the relative abundance of fungi in small macro-aggregates. Structural equation model (SEM) analysis revealed that organic farming practices fostered the development of smaller macro-aggregates, elevated microbial and enzyme activities within soil aggregates, and facilitated the conversion of soil nutrients and carbon sequestration. consequently, this led to an increase in soil organic carbon content and improved vegetable yield in greenhouse environments. In conclusion, the soil carbon content and vegetable yield are enhanced through long-term organic cultivation in greenhouses, primarily by increasing the proportion of small macro-aggregates.

Organic-rich shale deposits of the Paleocene-Eocene Palana Formation in western Rajasthan, India were systematically analyzed based on the elemental composition and organic geochemistry combined with microscopic examinations to evaluate the sedimentary paleoenvironmental conations and volcanic activity and their impact on the high organic carbon accumulation. The Palana shales are categorized by high OM and sulfur contents with total values up to 36.23 wt. % and 2.24 wt. %, respectively, suggesting marine setting and anoxic environmental conditions during the Paleocene-Eocene period. The richness of phytoplankton algae (i.e., telalginite and lamalginite) together with redox-sensitive trace elements further suggests anoxic environmental conditions. The significant low oxygen conditions may contributes to enhance preservation of organic matter during deposition. The mineralogical and inorganic geochemical indicators demonstrate that the Palana organic-rich shale facies was accumulated in warm and humid climate and low salinity stratification conditions of the water columns, thereby contributing to high bioproductivity of the phytoplankton algae blooms within the photic zone. The presence of the high concentrations of Fe-rich silica minerals such as olivine in most of the Palana organic-rich shales facility volcanic origin and supports hydrothermal activities during the Paleocene-Eocene period. These volcanic activities in this case are considered influx of large masses of nutrients into the photic zone due to the ash accumulation. Therefore, high bio-productivity associated with effective OM preservation contributed to the organic carbon accumulation in the Palana Formation during the Paleocene-Eocene.

In recent years, organic agriculture has gained more popularity, yet its approach to food production and its potential impact on consumers’ health and various environmental aspects remain to be fully discovered. The goal of organic farming practices is to maintain soil health, sustain ecological systems, maintain fairness in its relationship with the environment and protect the environment in its entirety. Various health benefits have been associated with higher consumption of organic foods. This review identified some of these health benefits including a reduction in obesity and body mass index (BMI), improvements in blood nutrient composition as well as a reduction in maternal obesity and pregnancy-associated preeclampsia risk. Furthermore, organic food consumption can reduce the development of non-Hodgkin lymphoma and colorectal cancers. Upon reviewing existing literature regarding the nutritional value of organic foods, it was found that organic food contained higher levels of iron, magnesium, and vitamin C. However, the evidence available to draw definitive generalizations remains limited. In this review, we provided essential insights to support sustainable organic farming and highlighted the potential of organic food consumption that could play a pivotal role in positively impacting human health.

The effect of organic matter (OM) on soil P-sorption is controversial and needs to be more investigated. The dissolved organic matter (DOM) may be regarded as an influential component on P sorption in natural soils. However, despite the great need for renewable sources of available P and OM in agricultural soils, little is known about interaction between P and DOM in natural soil systems. To uncover if and how soil saturation with DOM derived from different types of abundant agricultural wastes (cattle manure, horse manure, biogas digestate, compost) affects the phosphate sorption, we examined P sorption process in control and DOM-saturated sandy soils. The results indicated that organic matter introduced with agricultural wastes did not always reduce P sorption, but certainly had an effect on impairing P fixation and thus may result in potentially greater P mobility in the soil, including P availability. Up to now, we cannot recommend any of the tested organic amendments to directly overcome the P fixation in arable soils.

Today, more disciplines are intercepting each other, giving rise to “cross-disciplinary” research. Technological advancements in material science and device structure and production have paved the way towards development of new classes of multi-purpose sensory devices. Organic phototransistors (OPTs) are photo-activated sensors based on organic field-effect transistors that convert incident light signals into electrical signals. The organic semiconductor (OSC) layer and three-electrode structure of an OPT offer great advantages for light detection compared to conventional photodetectors and photodiodes, due to their signal amplification and noise reduction characteristics. Solution processing of the active layer enables mass production of OPT devices at significantly reduced cost. The chemical structure of OSCs can be modified accordingly to fulfil detection at various wavelengths for different purposes. Organic phototransistors have attracted substantial interest in a variety of fields, namely biomedical, medical diagnostics, healthcare, energy, security, and environmental monitoring. Lightweight and mechanically flexible and wearable OPTs are suitable alternatives not only at clinical levels but also for point-of-care and home-assisted usage. In this review, we aim to explain different types, working mechanism and figures of merit of organic phototransistors and highlight the recent advances from the literature on development and implementation of OPTs for a broad range of research and real-life applications.

Bimetallic colloidal CoPt nanoalloys, with a very low platinum content, were successfully synthesized following a modified polyol approach. Powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and Transmission Electron Microscopy studies were performed to estimate the crystal structure, morphology and surface functionalization of the colloids respectively, while the room temperature magnetic properties were measured using Vibrating Sample Magnetometer. The particles exhibit excellent uniformity, with a narrow size distribution, and display strong room temperature hysteretic ferromagnetic behavior even in the as-made form. Upon annealing at elevated temperatures, progressive formation and co-existence of exchange coupled both chemically ordered and disordered phases, significantly enhance the room temperature coercivity.

This study presents the synthesis of graphitic carbon nitride (g−C3N4) and its nanostructures with cobalt ferrite oxide (CoFe2O4) and silver nanocubes (Ag) using the combined pyrolysis of melamine and polyol method. The resulted nanostructures were tested as electrocatalysts for hydrogen and oxygen evolution reactions in alkaline media. It was found that the Ag/CoFe2O4/g−C3N4 shows the highest current density and gives the lowest overpotential of −259 mV for HER to reach a current density of 10 mA cm−2 in 1 M KOH. Overpotentials to reach the current density of 10 mA·cm−2 for OER are 370.2 mV and 382.7 mV for Ag/CoFe2O4/g−C3N4 and CoFe2O4/g−C3N4, respectively. The above results demonstrate that CoFe2O4/g−C3N4 and Ag/CoFe2O4/g−C3N4 materials could act as a bifunctional catalyst due to the notable performance towards HER and OER and for total water splitting in practical applications is a promising alternative to noble metal-based electrocatalysts.

A new approach to preparing a series of Co/Sm2O3 catalysts for hydrogen production by dry re-forming of methane (DRM) is developed. The catalysts precursors are synthesized by a simple method, including evaporation of aqueous solutions of cobalt and samarium nitrates, followed by a short-term calcination of the resulting material. The as-prepared and spent catalysts are characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), temperature-programmed reduction (H2-TPR), and thermogravimetric analysis (TGA). It is shown that the content of cobalt in the synthesized materials affects their phase composition and carbonization resistance in the DRM reaction. It is demonstrated that preheating under N2 affords catalysts providing stable hydrogen and CO yields of 94-98 % for at least 50 h at 900°C. These yields are among the highest ones currently available for DRM catalysts derived from Co-Sm complex oxides. It is found that reduction in the amount of cobalt in the catalyst and its preheating to an operating temperature of 900°C in a nitrogen flow con-tribute to preventing catalyst carbonization and metal particles sintering.

In pursuit of carbon neutrality, the demand for metals that are necessary for the development of clean energy technologies is rapidly increasing. Metallurgical waste, such as slag, presents a promising secondary source of these key metals. This research aims to develop an eco-friendly hydrometallurgical process to recover Cu, Ni, and Co from discarded copper/nickel slag. The high-pressure acid leaching (HPAL) was used to selectively leach Ni, Cu, and Co from the fayalite slag, yielding high leaching efficiencies of 99.9%, 89.4%, and 99.9%, respectively, with low Fe and Si tenors to the pregnant leach solution (PLS). The solvent extraction (SX) technique utilizing LIX 984N was used to selectively extract and enrich copper from the dilute PLS to about 23 g/L Cu with a very low Fe concentration of 0.05 g/L. Potassium amyl xanthate (PAX) solution was used to form Ni and Co xanthate complexes from the raffinate solution. Nickel was selectively recovered using ammonia solution, while cobalt xanthate complex was thermally decomposed and recovered as cobalt oxide solids of about 25 wt.% Co. A comprehensive process flowsheet is presented, furthermore, to realize the real application of the developed slag cleaning process, a preliminary economic evaluation was performed.

Compared with precious metal catalysts, non-platinum catalysts have the advantages of low cost and high performance. Among them, the activated carbon (AC) with a large specific surface area (SSA) can be used as a carrier or as a carbon source of nonprecious metal/carbon system catalyst at the same time. Therefore, this paper uses cheap pine peel bio-based materials to prepare large surface area activated carbon and then compound with cobalt phthalocyanine (CoPc) to obtain a high-performance cobalt/nitrogen/carbon catalyst. The merits include AC@CoPc composite catalysts are prepared by precisely controlling the composite proportion of AC and CoPc, the atomically dispersed Co nanoparticles form and synergistically with N promote the exposure of CoNx active sites, and the Eonset of the catalyst treated with a composite proportion of AC and CoPc of 1 to 2 at 800 °C (AC@CoPc-800-1-2) is 1.01 V, which is higher than Pt/C (20 wt%) catalyst. Apart from this, the stability is 87.8% in 0.1 M KOH after 20000 s testing in compared with other AC@CoPc series catalysts and Pt/C (20 wt%) catalyst. Considering from the performance and price of the catalyst in practical application, these composite catalysts combine biomass carbon materials with phthalocyanine series, which will be widely used in the area of nonprecious metal catalysts.

The limitations of investment casting of cobalt-based alloys are claimed to be less problematic with significant improvements in metal additive manufacturing by selective laser melting (SLM). Despite these advantages, the metallic devices are likely to display mechanical anisotropy in relation to build orientations, which could consequently affect their performance ‘in vivo’. In addition, there are inconclusive evidence concerning the requisite composition and post-processing steps (e.g. heat-treatment to relieve stress) that must be completed prior to the devices being used. In the current paper, we evaluate the microstructure of ternary cobalt-chromium-molybdenum (Co-Cr-Mo) and cobalt-chromium-tungsten (Co-Cr-W) alloys built with Direct Metal Printing and LaserCUSING SLM systems respectively at 0°, 30°, 60° and 90° inclinations (Φ) in as-built (AB) and heat-treated (HT) conditions. The study also examines the tensile properties (Young's modulus, E; yield strength, R_P0.2; elongation at failure, A_t and ultimate tensile strength, R_m), relative density (RD), and micro-hardness (HV5) and macro-hardness (HV20) as relevant physico-mechanical properties of the alloys. Data obtained indicate improved tensile properties and HV values after short and cost-effective heat-treatment cycle of Co-Cr-Mo alloy; however, the process did not homogenize the microstructure of the alloy. Annealing heat-treatment of Co-Cr-W led to significant isotropic characteristics with increased E and A_t (except for Φ = 90º) in contrast to decreased R_P0.2, R_m and HV values, compared to the AB form. Similarly, the interlaced weld-bead structures in AB Co-Cr-W were removed during heat-treatment, which led to a complete recrystallization in the microstructure. Both alloys exhibited defect-free microstructures with RD exceeding 99.5%.

: This study was conducted to evaluate the behavior of nitrate, moisture and organic matter in a soil with low agronomic input. The test was conducted on silty-sandy soil, a temporal variability of the variables in the different seasons was observed in the three theses. The theses were observed in parallel twice a week. Nitrates showed an increase during the summer-autumn season with higher values ​​in the thesis containing organic matter, “bare soil” followed by the thesis “fallow” and finally by the “cultivated” (see below in experimental set up). The humidity was higher in the “bare soil” thesis followed by “fallow” and “cultivated” one during the summer, in winter the “cultivated” showed the lowest humidity compared to the other two theses. The organic matter does not show great variability in the seasons but is higher in the “fallow” thesis followed by “bare soil” and “cultivated” one. The Montecarlo test informed us that organic matter and humidity were autocorrelated within 5-7.5 m of distance (10-15 lag) while nitrates even if they seemed to be not autocorrelated with each other and have a cyclical pattern.

Dissolved organic matter (DOM) derived from organic fertilizers may increase soil phosphorus (P) availability. However, the frequently observed correlation between soil P availability and dissolved organic carbon (DOC) content has led to an excessive focus on DOC content at the expense of DOM properties. The present study investigated the influence of DOM characteristics on soil P availability by using a 6-year field experiment and microcosms of P sorption in paddy soil. Our results showed that partial replacement of chemical P fertilizer with manure or crop straw increased P fertilizer-use efficiency, even when decreasing chemical P input by 34 %, compared to normal chemical fertilization. The microcosm experiment demonstrated that DOM properties, rather than total DOC content, determine soil P sorption capacity, despite the significant correlation between DOC content and P availability observed in the field experiment. Manure-DOM exerted stronger inhibitory effects on P sorption than straw-DOM, and high molecular weight (HMW)-fractionated DOM exerted stronger inhibitory effects on P sorption than low-molecular-weight-fractionated DOM by 16-20%. The mechanism was rooted in the HMW DOM with unique characteristics (e.g., strong aromaticity, hydrophobicity, abundant humic-like components, carboxyl groups, and benzene ring structures) competing for soil P sorption sites (e.g., reduction in specific surface area and micropore volume), decreasing the soil surface charge (e.g., zeta potential), and thereby suppressing P sorption in paddy soil. Our study points out a promising avenue for regulating organic matter properties with organic fertilization to improve P use efficiency in agricultural soils.

Chemical versatility of organic semiconductors provides nearly unlimited opportunities for tuning their electronic properties. However, despite decades of research, relationship between molecular structure, molecular packing and charge mobility in these materials remains poorly understood. This reduces the search for high-mobility organic semiconductors to the inefficient trial-and-error approach. For clarifying the abovementioned relationship, investigations of the effect of small changes in the chemical structure on OSs properties are particularly important. In this study, we address computationally the impact of substitution of C-H atom pairs by nitrogen atoms (N-substitution) on molecular properties, molecular packing and charge mobility of crystalline oligoacenes. Besides of decreasing frontier molecular orbital levels, N-substitution dramatically alters molecular electrostatic potential yielding pronounced electron-rich and electron-deficient areas. These changes in the molecular electrostatic potential strengthen face-to-face and edge-to-edge interactions in the corresponding crystals and result in the crossover from the herringbone packing motif to π-stacking. When the electron-rich and electron-deficient areas are large, sharply defined and, probably, have certain symmetry, charge mobility increases up to 3-4 cm2V-1s-1. The results obtained highlight the potential of azaacenes for application in organic electronic devices and are expected to facilitate rational design of organic semiconductors for steady improvement of organic electronics.

Soil organic carbon (SOC) mineralization is closely related to carbon source or sink of terrestrial ecosystem. Understanding soil organic carbon (SOC) mineralization under plum plantation is essential for improving our understanding of SOC responses to land-use change in karst rocky desertification ecosystem. In this study, 2-y, 5-y and 20-y plum plantations and adjacent woodland were sampled and a 90-day incubation experiment was conducted to investigate the effect of plum plantation with different years on SOC mineralization in subtropical China. Results showed that: (1) there was no significant difference in SOC content between different planting years, but there were significant differences in accumulative SOC mineralization (C_t) and potential SOC mineralization (C₀); (2) the dynamics of the SOC mineralization was a good fit to a first-order kinetic model. Both C₀ and C_t in calcareous soil of this study was several to ten folds lower than that in other soils, indicating that SOC in karst region has higher stability. (3) Correlation analysis revealed that both C_t and C₀ was significantly correlated with soil calcium (Ca) and C/N, indicating the important role of Ca and C/N in SOC mineralization in karst rocky desertification area.

Soil amendments with composted organic materials are recommended to increase soil organic matter (SOM), promote soil fertility, and the Circular Economy. Growing areas of hedged olive groves in southern Iberia peninsula generate huge amounts of olive leaves whose potential as soil organic amendment is not fully studied. An experimental field trial in a hedged olive grove (cv. “Cobrançosa”) was set up near Portalegre, Portugal, to test a compost of olive leaves plus sheep manure (2:1) applied in the row, at soil surface. Three nominal rates (0 or control, 2.5 and 5.0 kg m-2) were used, in a complete randomized block setup (3 treatments, 3 replicas, 9 plots) and soil chemical properties of layers 0-5, 5-15, and 15-30 cm deep were annually monitored. Results (mainly in layer 0-5 cm) showed increases in total N, carbon of the particulate organic matter (POM-C), permanganate oxidizable carbon (POX-C), extractable phosphorus, and zinc, after one year, and increases in soil organic carbon (SOC), C-stock, pHKCl, extractable phosphorus, and zinc, after two years. POX-C was the most sensitive SOM-related indicator, showing increases up to 30 cm deep after one year. This compost improved soil fertility, but should be monitored over longer periods of time, namely for SOC and extractable zinc content.

Tillage has been reported to induce seasonal changes of organic carbon (Сmicro) and nitrogen (Nmicro) in biomass of microorganisms. Soil microorganisms execute such ecosystem functions as: it is an immediate sink of labile biophil elements; it is an agent of a conversion, catalysis and synthesis of humus substances; it transforms soil contaminants into non-hazardous wastes; it participates in soil aggregation and pedogenesis as a whole. However, the seasonal turnover of microorganisms on arable lands in temperate ecosystems has not been investigated on a relevant level. Hence, we aimed to study the dynamics of such soil microbial biomass patterns as: Сmicro, Nmicro, microbial index (MI = (Сmicro/CTOC)·100, %) and CO2-C emission on the background of 9 years of tillage and 22 years of abandoned (Ab) and fallow (F) usage. Our study was conducted on a long-term experimental site on a Mollisol in the northeast China. The maximum Сmicro and Nmicro content was found: at the beginning of the growing season – in 0-10-; in mid-July – in 20-40 cm layers, while the minimum – in August-October. The Сmicro content ranged from 577.79- and 381.79 mg-1 kg-1 under Ab in spring to 229.53- and 272.86 mg-1 kg-1 in autumn under CT (conventional tillage) and F in 0-10- and 10-20 cm layers, respectively. The amplitude of Nmicro content changes was several times lower comparatively to Сmicro. The smallest quartile range (IQR0.25-0.75) of such changes was under: no-till (NT) and Ab in 0-10-, NT and F – in 10-20- and CT - in 20-40 cm layers. The widest Сmicro : Nmicro ratio was found at F and CT – in 0-20- and CT and rotational tillage (Rot) – in 20-40 cm layers. MI dynamics resembled the trends of Сmicro and Nmicro and changed from 0.72  0.168- tо 2.00  0,030 %. The highest part of Сmicro in CTOC was at Ab (1.82  1.85 %) and NT (1.66  1.52 %) – in 0-10-; Ab (1.23  1.27 %) and NT (1.29  1.32 %) – in 10-20- and – Ab (1.19  1.09 %) and F (1.11  1.077 %) – in 20-40 cm layers, correspondingly. The Pearson’s correlation coefficient between Сmicro and CTOC increased from the upper 0-10- to the lower 20-40 cm layer, it was "strong" and "high" between Сmicro and CTOC. Different use of Mollisol affected the amplitude of Сmicro and Nmicro seasonal changes, but it didn’t change their trend. Our results suggest the key role of Ab and NT technologies in Сmicro accumulation in total organic carbon (TOC).

This study concerns calculation and comparison of Fe, Co, Ni and Cu deposition rates in tungsten codeposition process based on electrodeposition of numerous tungsten alloys. 8 different tungsten alloys containing from 2 to 5 metals were electrodeposited in constant conditions in order to compare exact reduction rates. Calculated rates enabled control of the alloy composition precise enough to obtain a high-entropy WFeCoNiCu alloy with well-balanced composition. Introduction of copper to form the quinternary alloy was found to catalyze the whole process, increasing deposition rates of all components of the high-entropy alloy.

Iron-containing nickel sulfides, selenides, and sulfoselenides were synthesized via a simple two-step hydrothermal reaction (temperature 160 °C) for their application as electrocatalysts in the oxygen evolution reaction (OER) in an alkaline solution (1 mol L–1 KOH). The study demonstrated that iron-containing nickel cobalt sulfides and selenides exhibit superior OER performance with lower overpotentials compared to iron-free nickel cobalt sulfide and selenide, which highlights the significant role of iron in enhancing OER nickel cobalt electrocatalysts: Fe0.1Ni1.4Co2.9(S0.87O0.13)4, η50 = 318 mV; Fe0.2Ni1.5Co2.8(S0.9O0.1)4, η50 = 310 mV; Fe0.3Ni1.2Co2.5(S0.9O0.1)4, η50 = 294 mV; Fe0.6Ni1.2Co2.5(S0.83O0.17)4, η50 = 294 mV, Fe0.4Ni0.7Co1.6(Se0.81O0.19)4, η50 = 306 mV compared to Ni1.0Co2.1(S0.9O0.1)4, η50 = 346 mV and Ni0.7Co1.4(Se0.85O0.15)4, η50 = 355 mV (all values at current densities η50 of 50 mA cm–2). Furthermore, the iron-containing nickel cobalt sulfoselenide Fe0.5Ni1.0Co2.0(S0.57Se0.25O0.18)4 displayed exceptional OER performance with η50 = 277 mV, surpassing the benchmark RuO2 electrode with η50 = 299 mV. The superior performance of the sulfoselenide was attributed to its low charge transfer resistance (Rct) of 0.8 Ω at 1.5 V vs. the reversible hydrogen electrode (RHE). Moreover, the sulfoselenide demonstrated remarkable stability, with only a minimal increase in overpotential (η50) from 277 mV to 279 mV after a 20 h chronopotentiometry test. These findings suggest that trimetallic iron, nickel and cobalt sulfide, selenide and especially sulfoselenide materials hold promise as high-performance, cost-effective, and durable electrocatalysts for sustainable OER reactions. This study provides a valuable approach for the development of efficient electrocatalytic materials, contributing to the advancement of renewable energy technologies.

Lithium-ion (Li-ion) batteries are becoming more common in portable electronic devices due to their high energy density, lack of memory effect, and high charge and discharge rate capabilities. Li-ion batteries are a relatively new technology, first marketed in the early 1990s, and research and development work are ongoing to improve safety and increase capacity, charge/discharge rate, and lifetime [1]. In this paper, we review the types and characteristics of Li-ion batteries and summarize charging methods and safety considerations. Following, we design and fabricate Li-ion battery and highlight the steps of fabrication that ensure fast charge/discharge rates that give the battery more reliability and high energy density

The aim of this paper was to determine the soil phosphorus release risk from drained and re-wetted peatlands under different landcovers. The study was carried out at 10 soil profiles (organic soils, frequently with mursh in the topsoil, developed from low peat with various degrees of decomposition, on mineral subsoil or gyttja) located south-west of Lake Kośno nature reserve in northern-central Europe (north-eastern Poland). The soil samples were collected from the depths of 0-30 cm, 50-80 cm and 100-130 cm during spring, summer and autumn (in April, July, and October). In the laboratory, the following soil properties were determined: ash content, soil reaction, content of total organic carbon, total nitrogen, total and plant-available phosphorus. Gyttja formations and hemic peats had the highest total P content (6.77 g∙kg-1 and 2.29 g∙kg-1, respectively). Murshes contained twice less P (1.18 g∙kg-1). In spring, more plant-available phosphorus (AP sp) was released in murshes (0.29 g∙kg-1) than in peats (0.07-0.14 g∙kg-1). In the summer, higher amounts of plant-available P were stated in fiber peats (0.37 g∙kg-1) than in murshes (0.26 g∙kg-1), whereas in autumn, the amounts of P in murshes (0.22 g∙kg-1) and peats (0.21-0.23 g∙kg-1) did not vary. Generally, average contents of AP were the highest in murshes (0.26 g∙kg-1) and fiber peats (0.25 g∙kg-1), and the lowest in sapric peats (0.15 g∙kg-1). The release of phosphorus from organic compounds or binding of P by organic matter (immobilization) depends on the C:P ratio in plant residues and soil. If it is wide (&gt;300), P is bound, if it is narrower (150–200), P is released. In the tested soil formations, the C:P ratio was frequently above 300. Only in some murshes and gyttjas the C:P ratio was below 150, which may indicate a risk of phosphorus release to groundwaters.

In the era of disruption, to achieve food sustainability and the SDGs, Indonesia is faced with changes in the values, attitudes, and behavior of the community to be adaptive to environmental and technological changes. This study aims to analyze the factors that influence social transformation in peri-urban communities and their impact on food sustainability and the achievement of SDGs. The research method is a qualitative approach, triangulated by conducting in-depth interviews, field observations, and focus group discussion (FGD) in two districts. The results showed that factors influencing social transformation in peri-urban communities include: strengthening public awareness of the importance of food sustainability, access to information and technology, collaborative synergetic of government, companies, academics, and community participation in decision-making on empowerment programs. This social transformation leads to increased food production and poverty reduction. Private facilitators through CSR programs play a role in achieving food sustainability and achieving several SDG indicators related to poverty. The occurrence of collaborative synergetic between community participation, extension workers, village government, media utilization, academics, and companies contributes significantly to transforming the values, attitudes, and behavior of people managing community resources.

This study investigated the factors that influence consumer acceptance of fungus-resistant grape varieties (FRGV) in Germany. The qualitative research methodology involved conducting semi-structured interviews including sensory evaluation test with focus groups consisting of 48 consumers, and the data were evaluated using content analysis. The findings revealed that the attractiveness of a grape variety is determined by four distinct attributes. Furthermore, FRGV can be made more attractive to consumers by using denominations based on established grape varieties or by using and associating them with their sensory patterns. The sensory acceptance of FRGV varies significantly across consumer segments and vinification methods. Providing relevant information about the benefits of resistant grape varieties has a positive impact on consumer acceptance, and the level of interest and relevance varies by the target group. The study suggests that it is possible to enhance consumer acceptance by offering attractive grape varieties, targeting group-specific sensory profiles and engaging in storytelling campaigns that educate consumers about the advantages of resistant grapes.

Interest in organic foods is increasing at a moment when humanity is facing a range of health challenges including the concern that some conventionally produced foods may pose possible adverse effects on human and livestock health. With the increasing human population, intensive production is increasingly trending towards high-input systems that aim to close yield gaps, increase crop yields, and develop new crop varieties with higher yield potential and tolerance to biotic and abiotic stresses, all within the context of incorporating specific traits to satisfy consumer demand. Potato (Solanum tuberosum L.) is one of the most consumed foods under different cultural diets, however its production faces some challenges related to soilborne diseases, marketable yield and quality, sugars and dry matter content of the produced tubers, tuber content in terms of nitrate, minerals, vitamins, bioactive compounds and antioxidants, and consumer appreciation regarding the sensory characteristics of tubers and processed products. Different studies have been investigating some of these challenges, with sometimes straightforward and sometimes connflicting results. This variability in research results indicates the general non-transferability of the results from one location to another under the same management practices in addition to differences in plant material. This review compares some characteristics of raw or boiled potato and processed products from potato tubers grown organically and conventionally. Ideally, such information may be of benefit in decision making by consumers in their dietary choices, by potato growers in their selection of crop management practices, and by scientists looking at potential areas for future research on potatoes.

We develop an optimized force-field for poly(3-hexylthiophene) (P3HT) and demonstrate its utility for predicting thermodynamic self-assembly. In particular, we consider short oligomer chains, model electrostatics and solvent implicitly, and coarsely model solvent evaporation. We quantify the performance of our model to determine what the optimal system sizes are for exploring self-assembly at combinations of state variables. We perform molecular dynamics simulations to predict the self-assembly of P3HT at ~350 combinations of temperature and solvent quality. Our structural calculations predict that the highest degrees of order are obtained with good solvents just below the melting temperature. We find our model produces the most accurate structural predictions to date, as measured by agreement with grazing incident X-ray scattering experiments.

Honey is a sweet substance extensively consumed in the world for its nutritional and healthy properties. However, residues of pesticides and environmental contaminants can compromise its quality. For this reason, the physicochemical parameters, and the organic contamination of monofloral and multifloral honeys from three regions of Algeria (Tiaret, Laghouat and Tindouf) were monitored to evaluate the quality of honey and the safety for consumers. In general, the results obtained from the physicochemical analyses were in line with the EU standards. In terms of contamination, pesticides authorised and used in Algerian agriculture (matalaxyl-M and cyromazine), as well as banned pesticide (carbaryl), were found in almost all the samples. However, only the concentration of cyromazine was higher than the relative EU maximum residue levels. PCB 180, PCB 189, anthracene, fluorene and phenanthrene were mainly detected. All the honeys show traces of DiBP, DBP, DEHP and DEHT, but no traces of bisphenols were found. Moreover, the dietary exposure assessment shows that a small amount of Algerian honey can be safely consumed. Overall, data from this study should motivate the Algerian government to enhance their monitoring activities in beekeeping and to find solutions for implementing more sustainable agricultural practices harmonizing with the international legislation.

We investigated and quantified soil organic carbon (SOC) stock at the mangrove forest (Magyi, That Bot Khan and Wette) of Shwe Thaung Yan coastal region in Myanmar and estimated the SOC stock changes in Magyi mangrove forest over six years using repeated field measurements. The study sites were characterized by different mangrove vegetation, soil types, and sediment deposition from different water sources. Results showed that the mangrove preservation and restoration efforts had a significant effect on soil C storage, with soil carbon stocks in 2021 (1954.43 ± 33.24 ton/ha) being 2.7 times higher than the estimated carbon stock in 2015 (732.26 ± 6.99 ton/ha). The results also revealed slight differences in SOC between Magyi and the Tha-Bot-Khan and Wette areas, as the mangrove plants in the latter areas have an additional source of nutrients from Pho-Thoung-Gyi, a deep-sea bay near the forest. Our research findings are beneficial in understanding the role of Myanmar’s mangrove ecosystems in carbon sequestration and climate change mitigation efforts.

Lead-free ferroelectric perovskite N-methyl-N'-diazabicyclo[2.2.2]octonium)–ammonium triio-dide, MDABCO-NH₄I₃, nanocrystals are embedded in three different polymer fibers fabricated by the electrospinning technique. The nanofibers, which are very flexible and have a high Young modulus, behave as active piezoelectric energy harvesting sources that produce a piezoelectric voltage coefficient up to geff = 3.6 VmN-1 and show a blue intense luminescence band at 325 nm. In this work, the pyroelectric coefficient is reported for the MDABCO-NH₄I₃ perovskite inserted in electrospun fibers. At the ferroelectric-paraelectric phase transition, the embedded nanocrystals display a pyroelectric coefficient as high as 194×10-6 Cm-2k-1, within the same order of magnitude as that reported for the state-of-the-art bulk ferroelectric triglycine sulfate (TGS). The perovskite nanocrystals embedded into the polymer fibers remain stable, and no degradation is caused by oxidation.

The interest in the Spark Plasma Sintering (SPS) technique has continuously increased over the last few years. This article shows the possibility of the development of a SPS device used for material processing and synthesis both in both scientific and industrial applications. This work presents an example of processing Arc-Meleted (half-Heusler, cobalt triantimonide) and SHS-synthesized semiconductors (bismuth telluride) materials with SPS device. The system functionalities expansion is presented, showing the possible way of increasing the information amount obtained about SPS processes and using the SPS apparatus for conducting synthesis of materials and increasing reproducibility and accuracy of process parameters control.

In this work, electrochemical deposition (galvanostatic and potentiostatic) techniques were used to obtain of new composite polymer: 3-methylpyrrole - sodium dodecyl sulfate/poly 2-methythiophene (P3MPY-SDS/P2MT) coatings on cobalt -based alloy sample for anticorrosion protection. The sodium dodecyl sulfate as a dopant ion used in electropolymerization practice can have a relevant effect at the anticorrosion protection of the composite polymer layer by blocking the entry of aggressive ions. The cobalt -based alloy substrate had an important influence on the electrochemical performance of the composite coating and this together with the presence of the polymeric layer was achieved by simultaneously formation of a complex oxides film and polymeric layers. The polymeric coatings were analyzed by cyclic voltammetry, Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM) methods. The corrosion protection of P3MPY-SDS/P2MT coated cobalt based alloy has been explored by potentiostatic and potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) procedures in1 M HCl medium. The corrosion establishment of P3MPY-SDS/P2MT covered cobalt based alloy was observed to be ~10 times less than that uncoated specimen and the effectiveness of these composite layers of this coating is above than 90%. The superior efficacy is achieved by the electrochemical polymerization of P3MPY-SDS/P2MT obtained at 0.5 mA/cm2 and 1mA/cm2 current densities and at 0.9V and 1.0V potential applied and in molar ratio 5:1. Corrosion tests result indicated that P3MPY-SDS/P2MT coatings provide good corrosion protection of cobalt -based alloy in aggressive environments.

From the wide range of engineering materials traditional Stellite 6 alloy exhibits excellent cavitation erosion (CE) resistance. In this work, the effect of nitrogen ion implantation of HIPed Stellite 6 on the improvement of CE resistance and both cobalt-rich matrix phase transformation due to nitrogen implantation and CE were stated. The CE resistance of stellites ion-implanted by 120 keV N+ ions two fluences: 5x1016 cm-2 and 1x1017 cm-2 were comparatively analysed with the unimplanted stellite and AISI 304 stainless steel. CE tests were conducted according to ASTM G32 with stationary specimen method. Erosion rate curves and mean depth of erosion confirm that the nitrogen implanted HIPed Stellite 6 two times exceeds the resistance to CE than unimplanted stellite, and has almost 10 times higher CE reference than stainless steel. The X-ray diffraction (XRD) confirms that HIPed Stellite 6 nitrogen ion implantation favours transformation of the ɛ(hcp) to γ(fcc) structure. Unimplanted stellite ɛ-rich matirx is less prone to plastic deformation than γ and consequently, increase of γ phase effectively holds carbides in cobalt matrix and prevents Cr7C3 debonding. This phenomenon elongates three times the CE incubation stage, slows erosion rate and mitigates the material loss. Metastable γ structure formed by ion implantation consumes the cavitation load for work-hardening and γ → ɛ martensitic transformation. In further CE stages, phases transform as for unimplanted alloy namely, the cavitation-inducted recovery process, removal of strain, dislocations resulting in increase of fcc phase. The CE mechanism was investigated using a surface profilometer, atomic force microscopy, SEM-EDS and XRD. HIPed Stellite 6 wear behaviour relies on the plastic deformation of cobalt matrix, starting at Cr7C3/matrix interfaces. Once the Cr7C3 losing their restrain, are debonding and removed. Carbides detachment creates cavitation pits which initiate cracks propagation through cobalt matrix, the loss of matrix phase and CE proceeds with a detachment of massive chunk of materials.

Low-frequency electron paramagnetic resonance (EPR) is used to extract the EPR parameter A-mid and support the approximate X-band value of g-mid for Ba(Co_yZn_1/3-yTa_2/3)O₃. Although cobalt hyperfine structure for the [+/−1/2> state is often unresolved at X-band or S-band, it is resolved in measurements on this compound. This allows for detailed analysis of the molecular orbital for the [+/−1/2> state, which is often the ground state. Moreover, this work shows that the EPR parameters for Co substituted into Zn compounds gives important insight into the properties of zinc binding sites.

Oil and petroleum are strategic resources of great importance to national security. Petroleum and hydrothermal gold deposits may form together, with similar evolutionary trends in their formation, migration, and enrichment. Petroleum reservoirs and gold deposits are closely coupled under certain geological conditions. The solubility of gold in crude oil and its forms of occurrence are important in determining the mechanisms of interaction between gold and petroleum and in facilitating the recovery of gold from gold-bearing petroleum. In this study, the occurrence of gold in crude oil from the Linnan Depression in the Bohai Bay Basin, China, was studied using inductively coupled plasma–mass spectrometry and X-ray photoelectron spectroscopy. Concentrations of gold in crude oil from the Linpan and Shanghe oilfields averaged 44.5 ppb, which is well above the minimum concentration required for hydrothermal gold mineralization. Gold has an affinity with carbon, oxygen, and sulfur, and its concentration in crude oil is positively correlated with total acid and sulfur contents. We speculate that gold may exist in crude oil as complexes with organic acids or thiols, with crude oil thus being a transport medium for gold.

Life Cycle Cost Analysis is a method used to assess long-term economic efficiency among equivalent competing processes or products. The purpose of the paper is to investigate the nature and level of costs for an organic orchard located in Southern Romania, using a complex approach covering the entire chain of production, through the life span. The research results, based on a dynamic analysis and an integrated evaluation of the orchard's performance, have been ranked on investment and operational costs, broken down on three categories (establishment and production, post-harvest and transport costs). The highest cost, representing 151726 euros/ha/20 years, about 52.72% of the total operational costs and 50.4% of the total farm costs/ha/20 years, was recorded in exploitation stage. The scenarios for the sensitivity analysis considered different levels of average yield (40, and, respectively 60 tons/ha) with different rate of sold production (85%, optimistic scenario; 70%, pessimistic scenario). The hotpoints identified at the production stage were use of agricultural machinery, several pesticides, the costs of seedlings, anti-hail net, plastic boxes and labor cost, while at the post-harvest stage, were those related to labor and energy consumption. The transport stage has had important costs with tractor operation and the track.

Organic fertilizers are fertilizers made from organic materials which are partly or wholly derived from waste materials, the function of these fertilizers is to improve the physical, biological, and chemical properties of the soil, these fertilizers are processed through the composting process, these fertilizers are very much needed because they are difficult to obtain at a high price. expensive. This study aims to obtain data on the growth and yield of sweet corn, due to the use of agricultural waste as organic fertilizer. The research method was experimentally consisting of 5 treatments and 5 replications; ie P0 = Without organic fertilizer (control) P1 = Dosage of organic fertilizer 2.5 tons/ha, P2 = Dosage of organic fertilizer 5 tons/ha P3 = Dosage of organic fertilizer 7.5 tons/ha, P4 = Dosage of organic fertilizer 10 tons /ha using a Randomized Block Design (RBD) The results showed that organic fertilizer had a significant effect on plant height aged 30, 40 and 50 DAP, had a very significant effect on cob length at a dose of 10 t.ha-1 and, had no significant effect on cob weight, will still have a high weight of 350 g.cob-1 From this description it can be concluded that organic compost can be used as a substitute for chemical fertilizers which provides an increase in the growth and production of sweet corn plants at the use of 10 tons/ha.

Coating of organic molecules from the solution phase can result in directional crystal growth under certain conditions, even on a smooth isotropic surface and without the need of any kind of graphoexpitaxial preparation of the substrate. Based on reviewing the results from a variety of coating techniques and conditions, we identify the condition that the coating speed should equal the growth speed of the fastest growing crystal plane as crucial for achieving a high degree of directional crystallization.

Composting is one of the most economical and environmentally safe methods of recycling organic waste. Soil microorganisms play a significant role in decomposition and the availability of plant nutrients. This study was designed to prepare a suitable microbial inoculum and its evaluation on composting heap to decrease the time of waste degradation. The bacteria were isolated and molecular characterized from the soil near composting area by using 16S ribotyping technique. The identified strains of bacillus cereus used as an inoculum gives better results to expedite the degradation of organic waste. The prepared bacterial inoculum with molasses was also compared with commercial inoculum by optimizing physical and chemical parameters (temperature, oxygen, C: N, pH, and moisture content) of composting heap. Monthly reading of these parameters was taken from experimental and control treatments. The highest decomposition rate of organic waste was recorded in treatment A (experimental heap) where molasses and bacterial inoculum were added and less decomposition was observed in treatment D (experimental heap) where no inoculum and molasses were added. It was concluded from the studies that the prepared bacterial inoculum with two strains of Bacillus was effective and prepared mature compost in 2.5 months by increasing decomposition efficiency of organic waste. Furthermore, the prepared compost was also sustainable in its physical and chemical characteristic.

Even in the first quarter of XXI century, the presence of organic dyes in wastewaters is a normal occurrence in a series of countries, and being these compounds toxics, their removal from these waters is of a necessity. Among the separation technologies, adsorption processing appeared as one of the most widely used to reach this goal. The present work reviewed the most recent approaches (first half of 2021 year) about the use of a variety of adsorbents on the removal of, also, a variety of organic dyes of different nature.

This review analyzes the preparation and characterization of metal organic frameworks (MOFs) and their application as photocatalysts for water purification. The study begins by highlighting the problem of water scarcity and the different solutions for purification, including photocatalysis with semiconductors such as MOFs. It also describes the different methodologies that can be used for the synthesis of MOFs, paying attention to the purification and activation steps. The characterization of MOFs and the different approaches that can be followed to learn on the photocatalytic processes are also detailed. Finally, the work reviews literature focused on the degradation of contaminants from water using MOF-based photocatalysts under light irradiation.

The main aim of the study was to analyze/determine how international modern retailers’ chains can achieve a competitive advantage by introducing private labels (PLs) in the organic category and in turn stimulate consumption of food produced with respect of sustainability principles. Following a review of the relevant literature data collection process involved two steps. First, to select retailers with organic private labels (OPLs) and producers delivering products under OPLs, there were conducted in-depth semi-structured interviews with the representatives of the management board of 17 enterprises. A group of 6 enterprises was selected, including 3 retailers having OPLs, 2 producers delivering products under OPLs and one enterprise that was categorized as producer and distributor. Based on the results of the interviews, six sources of the competitive advantage of the OPLs were identified and further discussed. Second, to analyze more in depth assortment-based competitive advantage of the OPLs, 8 enterprises (5 retailers having OPLs, 2 producers delivering products under OPLs and one enterprise categorized as a producer and distributor) were approached for the interviews. To explore price-related competitive advantage three products offered under the premium PLs, the economy PLs, the organic PLs, the producer brands and the imported brands were selected for the subsequent analysis. Increasing competition in the food retailing sector pose many challenges on the retailers and stimulate them to develop the PLs that is in line with global trends. In case of the OPLs, the more popular strategy while introducing them is to differentiate the PLs with quality and image related attributes comparable to leading producer brands. Retail chains introducing the OPLs achieve the competitive advantage related to six sources: price, range of assortment, type of PLs, image of retailer, sustainability and specific process and product related attributes of organic food. Additionally the retailers use their reputation and image of retailers’ brand to guarantee the quality of new organic products introduced under the PLs. To achieve or maintain the competitive advantage, retailers tend to introduce the OPLs positioned as value added PLs. They perceive the OPLs as a way to influence the consumers' decision to buy and increase their loyalty towards store brands. The strategies of the retailers evolve and the largest retailers decided to create the premium OPLs, the others focus on introduction of the international OPLs or aim at development of new PLs based on the analysis of consumers' preferences. There are several factors behind the decision to introduce or extend the premium OPLs i.e. to expand the assortment of organic products and green products line, to increase category margins and to enhance retailer’s image among customers. Other large retailers create the OPLs with special product line design focusing on health- and environmental related attributes and high quality guaranteed by the organic regulations and the certification. The process of the introducing the premium PLs should be influenced by the inherent characteristic of organic food and its production methods that respect the principles of the sustainable development.

A recent breakthrough in preparation of immobilized enzyme based biocatalysts achieving highly enhanced enzymatic activities and stabilities has become a great alternative to conventional immobilization techniques. The functional hybrid nanobiocatalysts (FHNs) fabricated in this immobilization composed of organic components (amino acid, peptide, protein, enzyme and plant extract) and inorganic components (various metal ions) give flower-like morphology with narrow size distribution and porous structure. The enzyme incorporated FHNs exhibite greatly enhanced catalytic activities and stabilities compared to free and conventionally immobilized enzymes under various experimental conditions. In addition to that, the FHNs consisting of other organic components act as Fenton-like reagents and show peroxidase-like activity owing to presence of metal ions and porous structure in the FHNs. This report basically focuses on preparation, characterization, and bioanalytical applications of the FHNs and explain mechanism of the FHNs formation and thier enhanced activities and stabilities.

In the past decade, under the background of the carbon peaking and carbon neutrality era, the rapid development of new energy vehicles has put forward higher requirements for the performance of strike forces such as battery cycle life, energy density and cost. Lithium-ion batteries have gradually become the mainstream of electric vehicle power batteries due to their excellent energy density, rate performance and cycle life. At present, the most widely used cathode materials for power batteries are lithium iron phosphate (LFP) and ternary nickel-cobalt-manganese (NCM). However, these materials exhibit the bottlenecks that limit the improvement and promotion of power battery performance. In this review, the performance characteristics, cycle life attenuation mechanism (including structural damage, gas generation and active lithium loss, etc.) and improvement methods (including surface coating and element-doping modification) of LFP and NCM batteries are reviewed. Finally, the development prospects of this field are proposed.

Rising organic charge in northern freshwaters is attributed to increasing levels of Dissolved Natural Organic Matter (DNOM) and shifts in water chemistry. Organic charge concentration may be determined by charge balance calculations (Org.-) or modelled (OAN-) using the conceptual Oliver and Hruška models based on the density of weak acid functional sites (SD) present in DNOM. The charge density (CD) is governed by the SD and protonation and complexation reactions on the functional groups. The models use this SD as a key parameter in empirically fitting the model to Org.-. Utilizing extensive datasets of water chemistry, this study shows that spatial and temporal differences in SD and CD are influenced by variations in the humic-to-fulvic ratio of DNOM and the organic aluminum (Al) complexation, as well as the mole fraction of CD to SD governed by the acidity. Site median SD obtained for 44 long-term monitored acid-sensitive lakes was 11.1 and 13.9 µEq/mg C for the Oliver and the Hruška model, respectively. During the 34 years of monitoring the CD increased by 70%, likely due to rising pH and declining Al complexation with DNOM. Present-day median SD values for the Oliver and Hruška models in 16 low-order streams are 13.8 and 15.8 µEq/mg C, respectively, and 10.8 and 12.5 µEq/mg C, respectively, in 10 high order rivers.

SOC stock (SOCS) changes caused by land use changes are still unclear, and understanding this response is essential for many environmental policies and land management practices. In this study, we investigated the temporal-spatial and vertical distribution characteristics of SOCS on the Western Sichuan Plateau (WSP) using the sparrow search algorithm-random forest regression (SSA-RFR) models with excellent model applicability and accuracy. The temporal-spatial varia-tions in the SOCS were modeled using 1080 soil samples and a set of nine environmental covariates. We analyzed the effect of land use changes on the SOCS on the WSP. The total SOCS increased by 18.03 Tg C from 1990 to 2020. The results of this study confirmed that the SOCS in the study area has increased significantly since 2010, with an increase of 27.88 Tg C compared to the total SOCS in 2010. We found that the spatial distribution of the SOCS increased from southeast to northwest, and the vertical distribution of the SOCS in the study area decreased with increasing soil depth. Forest and grassland are the main sources of SOCS, the total SOCS in the forest and grassland accounted for 37.53 and 59.39% of the total SOC pool in 2020, respectively. Expansion of the wetlands, forest, and grassland areas could increase SOCS in the study area.

This article explores the geothermal resources of Kazakhstan's Zharkent Basin, with a specific focus on the high-temperature geothermal sources in the Almaty region of Southern Kazakhstan. The research aims to analyze the energy characteristics of the Organic Rankine Cycle (ORC) for harnessing low-enthalpy geothermal energy for small-scale electricity generation. A detailed thermodynamic model was developed, employing R134a as the working fluid. An in-depth analysis of the Zharkunak field (Zharkent, Almaty region) revealed that well 5539, with its notably high temperatures, offers the highest potential for geothermal electricity production, achieving an annual output of approximately 10,371 MWh. The total electric power output from the studied wells in the region is estimated at 20,111 MWh annually, representing a significant contribution towards sustainable energy production and reducing reliance on traditional coal-fired power plants. The study concludes that the Organic Rankine Cycle is not only a viable and efficient technology for utilizing low-enthalpy geothermal resources to generate electricity on a small scale, but also a key player in enhancing energy independence. By leveraging local geothermal energy, the Almaty region can significantly reduce its reliance on external energy sources, thereby fostering sustainable development and reducing environmental impacts.

Anaerobic digestion of waste material to biogas, with the remaining digestate slurry used as agricultural biofertilizer, is already a route of sustainable fuel production and its uptake will grow further. However, the foam layer that forms on top of the reacting mixture impedes the process and leads to liquid and solid material contaminating the gas product. Ideally, any effective foam repression should be low-cost, and react fast. Therefore, methods of optimizing anaerobic digestion need foam repression as one of the parameters in increasing gas yield. Foam can be repressed by pre-treating substrate which destroys filamentous bacteria and adding trace elements. The drawback to this method is the high cost of pre-treatment, the trace elements not being biodegradable and being toxic at high concentration; this method does not completely repress foam and is only effective under moderate organic loading

Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) exist in the atmosphere in the vapor and particulate phases, as well as in the solubilized form in fog/rain/cloud waters. They are abundant pollutants and are known for their acute and chronic toxicity. In the current paper, fogwater samples are collected during 42 events between 2015 and 2021 at four sites (Strasbourg, Geispolsheim, Erstein, Cronenbourg) in the Alsace region with different topological characteristics. PAHs and PCBs are extracted using the liquid-liquid extraction (LLE) supported on a solid cartridge (XTR Chromabond), and then analyzed by gas-chromatography tandem mass spectrometry (GC-MS/MS). Total PAHs and PCBs concentration in fog samples varied between 0.58 and 6.7 µg L-1 (average of 2.70 µg L-1), and 0.14 and 15.5 µg L-1 (average of 2.75 µg L-1). Low molecular weight (LMW) predominant and highly detectable over high molecular weight PAHs by at least 1.6 times, while pentachloro-biphenyls are the dominant PCB congener accounting for at least 50% of the total fraction. PAHs and PCBs concentrations have increased over sampling years at all sites, except a slight decrease in PCBs level at Geispolsheim. Diagnostic ratio analysis suggested that diesel and fossil fuel combustion are the dominant contributors to PAHs in Alsace

Cacao (Theobroma cacao L.) is an important woody species for production in Ecuador. Woody species have the potential to incorporate soil organic carbon (SOC) into the soil. The province of Manabí is known for its cocoa plantations and several cocoa species, which generates interest in their analysis. This study aimed to determine the concentration and accumulation of SOC in three cocoa species (EET95, EET103 and EET116) 15 years old, both under the tree and in the rows, at different depths 0-5, 5-10, 10-20 and 20-30 (cm). The results showed that soil SOC concentration was higher in the row for EET116 (2.51%) and significantly different under the tree for EET103 (1.57%) at 0-5 cm. No significant differences were found in the other sections. In the whole profile analyzed (0-30 cm), the EET116 species accumulated 41 t ha-1 and 54 t ha-1 under the tree and in the row, respectively. The species EET103 in the row presented 47 t ha-1 with no significant differences. Species EET95 and EET103 had the lowest values, but without significant differences between sampling locations, with 36 t ha-1, 37 t ha-1, and 47 t ha-1 under the tree and in the windrow, respectively. In conclusion, the species EET116 accumulated more organic carbon due to several factors, possibly a higher decomposing biomass, not only from the tree but also from other trees in the area, which contributes to the incorporation of organic matter throughout the soil profile.

This paper evaluates the global sustainable competitiveness of three blocks of power (US, China and EU) based on OGT (Organic Growth Theory) structure. In addition, a sensitivity analysis of COVID-19 on three measures of global sustainable competitiveness, economy, environment and social is also presented. OGT is a well-thought-through and standard framework for evaluation of any type of organiza-tion in their pathway to experience truly sustainable growth. GDP (Gross Domestic Product) is used as an economic measure; total carbon emissions equivalent is used as an environmental measure and HMI (Human Development Index) as a social measure. It is concluded that the pandemic has paused the evolution of countries to be truly world centric countries. However, the recovery plans seem to be highly aligned with the OGT scores and it is expected that the scores to improve dramatically.

The influence of the ligands in coupled organic-inorganic nanostructures (COINs) on the performance of optoelectronic devices is investigated. We fabricated photodiodes based on pentacene and PbS nanocrystals coupled to organic ligands like 1,2-ethanedithiol (EDT) and tetrabutylammonium iodide (TBAI) and a combination of both, EDT and TBAI, as a heterostructure. These ligands were first separately used to fabricate single ligand-type of organic-inorganic devices and later compared with a heterostructure of PbS-EDT and PbS-TBAI. To tune the optical energy gap of COINs to align with the triplet level of pentacene, it was necessary to choose a suitable particle size. For this purpose, ultraviolet photo-emission spectroscopy (UPS) was used to determine the energy of the highest occupied molecular orbital (HOMO) and the work function of COINs, while the energy of the lowest unoccupied molecular orbital (LUMO) of COINs was estimated subsequently by adding the exciton binding energy and the optical band gap to the measured HOMO energy. Devices with heterostructure COINs achieve a higher short circuit current than COINs with a single type of the ligands. Finally, even if the requirements of proper energy level alignment are satisfied, the photodiodes' performance was affected by the morphology of COINs. This finding has been demonstrated by atomic force microscopy (AFM) and transmission electron microscopy (TEM). Incident photon to current efficiency (IPCE) shows a shift for the excitonic absorption peaks in the visible range at opposite applied voltages. The IPCE signal for the double heterostructure device is higher than the single type device.

Organic electrochemical transistors (OECTs) based on conducting polymers have attracted significant attention in the field of biosensors. PEDOT:PSS and polyaniline (PANI) are representative conducting polymers used for OECTs. While there are many studies on PEDOT:PSS, there are not so many reports on PANI-based OECTs, and a detailed study to compare these two polymers has been desired. In this study, we investigated the fabrication conditions to produce the best performance in the OECTs using the above-mentioned two types of conducting polymers. Two main parameters were film thickness and film surface roughness. For PEDOT:PSS, the optimal conditions for fabricating thin films were a spin-coating rate of 3000 rpm and DI water immersion time of 18 hours. For PANI, the optimal conditions were a spin-coating rate of 3000 rpm and DI water immersion time of 5 seconds, and adding dodecylbenzenesulfonic acid (DBSA) was found to provide better OECT performances. The OECT performances based on PEDOT:PSS were superior to those based on PANI in terms of conductivity and transconductance, but PANI showed excellence in terms of film thickness and surface smoothness, leading to the good reproducibility of OECT performances.

Results of profile loss measurements, including trailing edge flow details, are presented for the flow of an organic vapor through a linear turbine cascade. The so-called VKI-I blade profile from the open literature was chosen for the cascade, and the working fluid was NOVEC 649. Pitot probes and hot wire anemometry were employed to measure the flow field up and downstream of the cascade. Details of the unsteady flow caused by the trailing edge of the blades and the turbulent spectrum were investigated using hot-wire anemometry. The new organic vapor flow results were compared with literature data obtained for air and with the prediction of conventional literature loss models. It was found that under certain thermodynamic conditions, specific traditional loss models can reasonably predict organic Rankine cycle (ORC) turbines' profile loss. Still, significant deviations between the loss models and the experimental data can also occur.

Compared with the traditional bundle pricing strategy with fixed products, this paper proposes a more flexible interactive bundle pricing strategy (IBPS) for agricultural e-retailers. Since more and more consumers tend to buy more environmentally friendly and healthy organic agricultural products, we consider consumers' organic preferences and build a mixed bundle pricing model for organic and inorganic agricultural products. A free shipping strategy is introduced to maximize retailer profit and optimize consumer surplus. Through numerical analysis, we find: (1) Compared with the traditional online retailing method, IBPS can effectively stimulate consumption and higher retailer profit; (2) As the free shipping threshold increases, the total profit shows a trend of first increasing and then decreasing, indicating that a suitable free shipping threshold can optimize the retailer profit; (3) As the consumer green preference increases, the total sales of agricultural products decrease, but the organic sales improve, while total profit rises; (4) The higher the level of consumption, the higher the sales volume of organic products and there is an upward trend in the profits of e-retailers.

Coagulant lectin from Moringa oleifera seeds (cMoL) was characterized by potentiometry and scanning electron microscopy (SEM) using MOF, Metal-Organic Frameworks of [Cu3(BTC)2.H2O)3]n, to immobilize cMoL and construct biosensors. Developed aluminum-air batteries degraded indigo carmine dye formulated similar to a textile effluent; biosensors investigated cMoL interaction with specific galactose and monitored residual dye. SEM revealed components of electrode assembly steps. Oxide reduction reactions of batteries generated Al(OH)3 promoting dye electrocoagulation. Cyclic voltammetry showed differentiated redox peaks related to dye residue quantification by cMoL. Electrochemical systems evaluated cMoL interaction with ligand and efficiently degraded dye; biosensors could be used for lectin characterization and monitoring dye residues in environmental textile effluents.

Agriculture is the mainstay of the Ethiopian and a key sector of its economy. However, Lack of productive and environmentally friendly technology is not widely applicable elsewhere. Likewise, the vermicomposting technology is a recently emerging science which not effectively transferred to the users across the country. Thus, this review is aimed to shine the importance, unexploited opportunities and the challenges hindered for further expansions in Ethiopian context. Vermicompost is among the powerful organic fertilizers which enhance soil Fertility and productivity. As agrarian society; there are plenty of raw byproducts and weed species which are not center of focus (i.e cattle waste, crop residues and invasive weeds like P.Juliflora, P.hysterophorus and E.crassipes respectively). However, there are many constraints there like policy issue, handling problems and sensitivity of the worms for different environmental factors which hindered to invest on a wide range. Generally, the number and weight of vermiculture as well as amount of produced casts are promised and every possible ways were recommended to entertain on the large scale.

A The present investigation was undertaken in foothill regions of Uttarakhand from July-2016 up to December-2018. A total of thirty four different sites ranging from the roadside areas, grasslands to forests were studied and Mushroom fruiting bodies were collected. A total of One Hundred sixty six fruiting counts were obtained and 68 mushroom genera belonging to 15 orders and 43 families were identified. During collection visits mushroom were apparent from organic debris of diversified habitats ranging from humid soil; grassland; leaf litter; living tree trunk; dead wood log of forest zone. Maximum fruiting bodies (75%) were obtained between July to September and minimum i.e. 6% between November – February. Among the collected mushroom Stereum rugosum, Crepidotus variabilis, Laccaria laccata, Schizophyllum commune, Ganoderma applantum, Cantharellus cibarius were more prevalent. Out of all collected mushroom sample the frequency of Mushroom belonging to order Agaricales was 45.18% followed by Polyporales i.e., 27.7%. The collected mushroom were cultured on PDA medium and their mycelial forms were preserved for further studies.

Air pollution is a serious global issue, responsible for approximately one in every nine deaths each year, ranking it among the greatest environmental hazards to human health. It is of particular concern in urban areas, where elevated pollutant concentrations and potential sufferers converge. Over one half of the world’s population presently lives in urban areas, and the urban population ratio is expected to reach 68% by 2050. Common air pollutants include particulate matter (PM), sulphur dioxide (SO2), ground-level ozone (O3), nitrogen oxide (NOx) and carbon monoxide (CO). While elevated rates of air pollution pose serious health risks for humans, outdoor plants can help reduce the harmful effects of air pollution by filtering and purifying the air around us.In this project Common Ivy, Aster and Miniature Andromeda plants were evaluated for air pollutant mitigation. In this study we developed a vegetation barrier model with the plant located in the middle of the greenhouse box, and air pollutant was sprayed on one side of the plant. Dispersion patterns of sprayed pollutants were tested with and without vegetation barrier. Measurements of carbon dioxide (CO2), Formaldehyde (HCHO), Total Volatile Organic Compounds (TVOC), and Particulate Matter (PM2.5/PM10) were taken before spraying, then at 0 and 30 minutes after spraying, using both monitors.The results show mitigation rates (in 177 ft3 of air after 30 min): for TVOC the minimum reduction is 5 mg/m3; for HCHO, 1 mg/m3; for CO2, 2000 ppm; for PM2.5, 2000 ug/m3; and for PM10 it was 1000 ug/m3.

In the last 10 years, carbon dots (CDs) synthesized from renewable organic resources have been gathered a considerable amount of attention in different fields for their peculiar photoluminescent properties. Moreover, the synthesis of CDs fully responds to the principles of the circular chemistry and the concept of safe-by-design. This review will focus on the different strategies for the incorporation of CDs in organic light-emitting devices (OLEDs) and on the study of the impact of CDs properties on the OLEDs performance. The main current research outcomes and highlights are summarized to guide users towards the fully exploitation of use these materials in optoelectronic applications.