Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

Directional Crystallization of Conjugated Molecules during Coating Processes

Version 1 : Received: 12 June 2023 / Approved: 13 June 2023 / Online: 13 June 2023 (07:56:31 CEST)

A peer-reviewed article of this Preprint also exists.

Smilgies, D.-M.; Li, R. Directional Crystallization of Conjugated Molecules during Coating Processes. Molecules 2023, 28, 5371. Smilgies, D.-M.; Li, R. Directional Crystallization of Conjugated Molecules during Coating Processes. Molecules 2023, 28, 5371.

Abstract

Coating of organic molecules from the solution phase can result in directional crystal growth under certain conditions, even on a smooth isotropic surface and without the need of any kind of graphoexpitaxial preparation of the substrate. Based on reviewing the results from a variety of coating techniques and conditions, we identify the condition that the coating speed should equal the growth speed of the fastest growing crystal plane as crucial for achieving a high degree of directional crystallization.

Keywords

organic electronics; conjugated molecules; blade coating

Subject

Chemistry and Materials Science, Electronic, Optical and Magnetic Materials

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