Śmiałkowski, K.; Sardo, C.; Leśnikowski, Z.J. Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands. Molecules2023, 28, 4118.
Śmiałkowski, K.; Sardo, C.; Leśnikowski, Z.J. Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands. Molecules 2023, 28, 4118.
Śmiałkowski, K.; Sardo, C.; Leśnikowski, Z.J. Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands. Molecules2023, 28, 4118.
Śmiałkowski, K.; Sardo, C.; Leśnikowski, Z.J. Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands. Molecules 2023, 28, 4118.
Abstract
The exploitation of the metallacarboranes’ potential in various fields of research and practical ap-plications requires the availability of convenient and versatile methods for their functionalization with various functional moieties and/or linkers of different types and lengths. Herein we report a study on cobalt bis(1,2-dicarbollide) functionalization at 8,8’-boron atoms with different het-ero-bifunctional moieties containing protected hydroxyl function allowing further modification after deprotection. Moreover, an approach to the synthesis of three and four functionalized metallacarboranes, at boron and carbon atoms simultaneously, via additional functionalization at carbon to obtain derivatives carrying three or four rationally oriented and distinct reactive surfaces, is described
Chemistry and Materials Science, Medicinal Chemistry
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