Due to the imbalance between the supply and demand of oxygen, the oxygen system of iron- and steel-making enterprises in China has problems with high oxygen emission and high pressure in the pipelines, resulting in the energy consumption of oxygen production being high. To relieve this problem, using a large-scale iron- and steel-making mill as a case study, the research on demand forecasting and optimal scheduling of the oxygen system was carried out. The ARIMA model and the GABP model are employed to forecast oxygen demand. Based on the forecast results, an optimal scheduling model for the oxygen system was developed to conduct optimal scheduling. The case study shows that based on the oxygen demand forecast and the optimal scheduling, the oxygen emission and the pipeline pressure in the studied iron- and steel-making enterprise can be significantly reduced, thereby achieving considerable energy-saving effects and economic benefits. Specifically, the following conclusions are obtained: (1) For the oxygen demand forecast, the prediction accuracy of the GABP model is better than that of the ARIMA model. The average MAPE of the 12 sets of data of the ARIMA and GABP models are 23.8% and 20.2%, respectively. (2) By comparing the scheduling results and the field data, it is found that after the scheduling, the amount of oxygen emission has decreased by 6.32%, the pipeline pressure has decreased by 0.61%, and the energy consumption of oxygen compression has decreased by 1.6%. Considering both the oxygen emission loss and the energy consumption of oxygen compression, the total power consumption of the oxygen system is reduced by 1.38%, which saves the electricity cost of about 9.03 million RMB per year.

Upon the implementation of the European Union Carbon Border Adjustment Mechanism (CBAM), substantial challenges are anticipated to impact the international trade of Chinese steel products. To safeguard the competitiveness of Chinese steel products on the global stage, this paper establishes a tripartite evolutionary game model, involving large steel enterprises, small and medium-sized steel enterprises, and the government. The model integrates collaborative emission reduction and free-riding benefits among enterprises, along with the government's dynamic subsidies and penalties. The paper analyzes the evolutionary trends and stable states of the three parties during different stages of CBAM, including a sensitivity analysis of key parameters. The findings indicate that large enterprises demonstrate a heightened sensitivity to CBAM, while small and medium-sized enterprises are more significantly influenced by free-riding benefits. Government intervention should be strategically timed and incline towards passive management during the strengthening phase of CBAM. Additionally, the refinement of the Chinese carbon market emerges as an effective means to counter CBAM. This paper provides theoretical support for how steel enterprises and the government can respond to CBAM, aiding stakeholders in selecting optimal strategies during different implementation stages and mitigating the impacts of CBAM to the maximum extent possible.

TiC–high Mn steel-bonded carbide with a cellular structure was designed and fabricated by powder metallurgy techniques using coarse and fine TiC particles as the hard phase. This preparation process was carefully investigated and optimized. The microstructure of the TiC steel-bonded carbide was observed using a scanning electron microscope. Results showed that there are two types of microstructures in the TiC steel-bonded carbide: the coarse-grained TiC and fine-grained TiC. The transverse rupture strength and impact toughness of the alloy reach maximum values 2231 MPa and 12.87 J/cm2, respectively when the starting weight ratio of MP-A (containing coarse TiC particles) to MP-B (containing fine TiC particles) is 60:40. Hence, this study serves as a feasible example of how to prepare a high-strength and high-toughness TiC–high Mn steel-bonded carbide.

Experimental quantification of retention factors related to post-fire strength as well as post-fire ductility of intentionally selected stainless steel grades applied in construction is the objective of research presented here. These steel grades are characterized by a two-phase austenitic-ferritic microstructure of the duplex type. In this context two mutually corresponding chromium-nickel-molybdenum steel grades have been subjected to analysis, namely X2CrNiMoN22-5-3 steel belonging to the standard duplex group (DSS 22% Cr) and X2CrMnNiN21-5-1 steel belonging to the lean duplex group (LDSS). The similarities and differences in the mechanical properties exhibited by these steel grades after effective cooling, following more or less prolonged simulated fire action conforming to several development scenarios, have been identified and indicated. The resistance of given steel grade to permanent structural changes induced by the heating program proved to be the critical factor determining these properties and resulting in many cases in increased susceptibility to brittle fracture.

Raindrop erosion is a significant materials limiting issue. It can affect materials for transportation and renewable energy converters such as wind turbines as well as all external structures used in the construction industries. In such cases, the raindrop effects can occur over a wide range of impact velocities and particles sizes. In understanding tribological variable effects, it is useful to study using reference materials. This is because the reference material is well characterized, from previous knowledge of the tribological and corrosion patterns. Further, the well established chemical composition and stochiometry of the corrosion products provide some background understanding of how effectively, during tribological action, the surface scale adheres to the substrate. In this study, a carbon steel was used as a reference to study the effects of velocity and drop diameter in a whirling arm erosion test rig. The results were used to establish the conditions where corrosion was accelerated and the environments where aerodynamic effects may have resulted in droplets being deflected the surfaces. Erosion maps were generated to illustrate such mechanisms based on the results.

In order to tackle the issue of severe rocking phenomenon under seismic conditions in structures equipped with steel spring isolation bearings, this paper investigates a novel type of anti-rocking bearing. Firstly, the structural configuration and working principle of the novel anti-rocking bearing are introduced, and a design method for bearing parameters is proposed. Secondly, a finite element analysis model is established using SAP2000 software to conduct nonlinear dynamic time history analysis under seismic loading. The analysis results show that the structural arrangement of the novel anti-rocking bearing reduces both the vertical displacement difference and the rocking angle of the isolation layer. The bearing exhibits a certain level of anti-rocking effect, but it may cause significant tensile forces in some bearings, necessitating the installation of anti-tensile reinforcement. The effectiveness of the anti-rocking effect improves as the stiffness of the steel tension rod in the bearing increases; however, it also leads to higher maximum tension in individual bearings as well as the total tension in all bearings. For structures equipped with the novel anti-rocking bearing, the acceleration amplifies under most cases, with amplification coefficients ranging from 0.82 to 1.55. The performance of the novel anti-rocking bearing varies significantly for different seismic waves. The stiffness of the steel tension rod should be determined considering the reference pressure of the bearing and the maximum designed tension of the bearing. Through the finite element simulation of the bearing, the mechanical properties of the bearing are basically the same as the theoretical analysis results. For the cylinder and the joint bearing, certain structural measures need to be taken to ensure its strength and stiffness.

In this paper, through high-temperature tensile tests of 55NiCrMoV7 steel, the high-temperature fracture behavior, microstructure evolution and carbide distribution characteristics of both thermal-mechanical coupling zone (fracture zone) and thermal stress zone (clamping zone) at different temperatures were studied. Intrinsic relationship between high temperature fracture and carbides types, distribution and size were revealed and evolution mechanism of microstructure near cracks in 55NiCrMoV7 hot-working die steel during high temperature deformation was clarified. Samples were stretched at different temperatures from 25 °C to 700 °C, and microscopic examinations were carried out by using SEM and TEM. The results showed that: With the increase of temperature, tensile strength and yield strength decreased, elongation and reduction of area increased, and fracture mode changed from brittle fracture to ductile fracture by transition temperature at about 400℃. During high temperature deformation, the grain dislocation density decreased, the tempered martensite decomposed, recovered, recrystallized, and then grain grew. M7C3 and M23C6 carbides precipitated and grew along the grain boundary, and a small amount of fine granular MC carbides were dispersed in the grain. The work done by the external force on the deformation zone would cause the temperature of it to be higher than tensile temperature, which provides thermodynamic conditions for the re-dissolution of small carbides near the fracture zone and the grain growth of large carbides, resulting in the decrease of small carbides and increase of large carbides in thermal-mechanical coupling zone.

Corrosion is considered as one of the main factors in the structural performance deterioration of steel members. In this study, experimental and numerical methods were used to assess the reduction in compressive strength of short tubular steel columns with local corrosion damage. The corrosion damage was varied with different depths (0, 1.5, 2, 3, 4, 4.5, and 6 mm), height (0, 20, 40, 60, 80, 100, 120, 140, 160, and 180 mm), circumference (0, 90, 180, 270, and 360°), and location along the column. A parametric numerical study was performed to establish a correlation between the residual compressive strength and the severity of corrosion damage. The results showed that as the corrosion depth, height and circumference increased, the compressive strength decreased linearly. As for the corrosion height, the residual compressive strength became constant after decreasing linearly when the corrosion height was greater than the half-wavelength of buckling of the short columns. An equation is presented to evaluate the residual compressive strength of short columns with local corrosion wherein the volume of the corrosion damage was used as a reduction factor in calculating the compressive strength. The percentage error using the presented equation was found to be within 11.4%.

The article presents results of research consisting in an attempt to assess the influence of temperature, heating time and cooling method on microstructure and residual strength properties of steel previously tempered during the production process. Simulated environmental conditions to which high-strength bolts, commonly used in steel construction, were subjected, were intended to reflect conditions of a natural fire that may occur in public facilities where the obligation to ensure safety of users and rescue teams is of key importance, also required by law. Furthermore, the tests carried out also comprised a simulated effect of a rescue and firefighting operation using shock, rapid cooling of some of the heated bolts. Samples cut out from the tested bolts, after they were properly prepared, were subjected to microstructural tests using light microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), phase analysis with the use of an X-ray diffractometer (XRD) and quantitative analysis of the microstructure involving, inter alia, measuring the surface area of grains, their equivalent diameter and mean diameter. As a result of the tests, considerable microstructure changes were identified occurring in the bolt material as a result of exposing it to fire conditions, leading to a change in key, from the point of view of structural safety, mechanical properties. The results of the microstructure tests were compared with the results of previous strength tests, including hardness of the material after the heat treatment and the residual tensile strength of the material Rm. A conducted comparative analysis showed a significant effect of all such factors as the temperature level of the simulated fire, its duration and the fire-fighting method on the mechanical properties of bolts. Results obtained were provided with required comments and the concept of using the microstructure for the post-fire assessment of steel structures was referred to.

To weaken the harm of Al-Si coating and increase the strength of welded joint, variable thickness of Ni foil (Ni, an austenitic formation element) was added into the lap laser welding Al-Si coated 22MnB5 hot stamping steel/galvanized steel joints. The joints' weld appearance, microstructure, and mechanical properties were explored. The weld altered from X-shape to Y-shape with the increased thickness of Ni foil. During welding, Al-Si coating was melted and diluted into the welding pool, forming δ-ferrite (a rich-Al phase with low toughness and strength) in FZ and FB. This phase deteriorated the strength of the joints. After adding Ni, the amount and size of the δ-ferrite phase decreased. With a significant thickness of Ni foil, δ-ferrite would disappear. However, a new phase (FM, rich-Ni phase) probably formed except PM(a no or negligible Ni phase). The heat-affected zone (HAZ) on the side of 22MnB5 comprised a coarse martensite zone, refined martensite zone, martensite+ferrite zone, and tempered martensite zone from the FZ to the basic material. HAZ on the side of galvanized steel mainly contained ferrite and pearlite. After adding Ni foil, the strength of the joint was more than that without Ni. The maximum strength of the joint can be up to 679MPa because of the disappearance of δ-ferrite. Meanwhile, the toughness of the joint increased. The fracture mode was from three mixed fractures(cleavage, quasi-cleavage, and dimple) to one fracture(dimple).

CO₂ emissions have been identified as the main driver for climate change, with devastating consequences for the global natural environment. The steel industry is responsible for ca. 8%-11% of global CO₂ emissions, due to high fossil-fuel and energy consumption. The onus is therefore on industry to remedy the environmental damage caused and to decarbonise production. This desk research report follows a two-tiered route: 1) exploring the Bio Steel Cycle; 2) proposing a seven-step strategy to overcome the challenges within the iron and steel industry. The true levels of CO₂ emissions in the steelmaking process, during the blast-furnace/basic-oxygen-furnace operation, will be detailed first, at 4.61t of CO₂ emissions/t of steel produced. The manuscript proposes a solution for reduced carbon emissions steelmaking with the Bio Steel Cycle components and detail on how to reach net-zero carbon emissions steel production. The 7-step-implementation-strategy as a potential solution to achieve net and true zero carbon emissions steel production in the short to medium-term. The findings of this are pointing towards the conclusion that CO₂ emissions seem to have been under-reported and under-estimated in the past, but the emission can be addressed if the correct scenarios for net-zero steel manufacturing are implemented by 2050.

The cold-formed steel sections are becoming popular for different steel structures because it has a high resistance against the different straining actions with minimum weight compared with hard steel sections. Recently, the perforated cold-formed steel (PCFS) sections are used in many applications such as storage perforated uprights racks. Experimental research into the behaviour of steel storage rack uprights subjected to axial compression is presented in this paper. The material qualities of cold-formed steel uprights were determined by tensile tests. The seventeen perforated specimens were examined under axial compression, with five different cross-sections, three different web heights and thicknesses, and varying lengths. The study's goals are to find out how perforations affect the performance and failure mode of steel storage rack uprights, discuss the interaction of distortional and global buckling, and verify the accuracy of using the Direct Strength Method (DSM) for predicting the ultimate strength of uprights failing in buckling interactions for perforated uprights. It is found that the failure modes of perforated specimens with stiffeners generally cannot be well predicted by the Direct Strength Method. But when the modifications proposed by Xianzhong Zhao etc. al. are used, their accuracy is acceptable.

The purpose of this study is to propose a consecutive manufacturing process system to secure the productivity of excellent STKN540B steel tube in the respect of economy and safety as the supporting material for mega structures such as building, bridge and ship. The components of consecutive manufacturing are press-bending, orbital auto welding and steel tube correction. By using STKN540B a high-strength steel material with low yield point that requires a special manufacturing process unlike other steel materials, an actual tube manufacturing is carried out at each stage in this experimental study. With this, the quality of steel tube and the efficiency of the manufacturing process are analyzed to draw out some points to improve in the future.

Metal corrosion poses a significant challenge for industries by decreasing the lifespan of materials and escalat-ing maintenance and replacement costs. This study is critically important as it assesses the corrosion resistance properties of annealed steel wire electrodes coated with manganese, employing chronoamperometry and linear voltammetry techniques. The electrodes were immersed in an electrolyte solution and subjected to chronoam-perometry at various voltages (-0.55 V, -0.60 V, and -0.70 V) and durations (60 seconds and 1800 seconds). Sub-sequently, linear voltammetry was performed over a potential range from -0.8 V to 0.8 V to generate Tafel plots. The Butler-Volmer equation was applied to the data obtained to determine the corrosion current density. The re-sults indicate that the optimal conditions for forming a highly effective protective manganese layer occur at a potential of -0.70 V for 1800 seconds. Under these conditions, the electrodes exhibited superior corrosion re-sistance. The study also revealed that shorter durations and less negative potentials led to less effective manga-nese coatings, with higher corrosion rates and reduced stability. These findings are significant for developing ef-ficient corrosion protection methods in industrial and research applications, providing clear parameters for op-timizing the manganese electrodeposition process on annealed steel.

JIS SUJ2 is most widely used in bearing steels. The advantages are good hardenability, excellent fatigue, wear resistance and comprehensive mechanical properties. For wear resistance and fatigue resistance of the steel are getting more and more attention, the residual stress state and its distribution on the surface of the heat affect zone are critical factors affecting the fatigue life and wear resistance of the parts. In this study, using the SUJ2 as the material to talk about the surface residual stress and retained austenite distribution. Doing the quenching and tempering treatment to obtain different microstructures, using the induction method to re-quench the case region. After the heat treatment, measuring the residual stress and retained austenite volume on the surface by X-ray diffraction, observing the microstructure and comparing the hardness. The results show that the microstructure after heat treatment contains unsolidified carbides, tempered martensite and retained austenite. The residual stress on the surface is the tensile state. In the re-hardened area after induction quenching, the residual stress is all compressive, and the values are more than -800 MPa. In conclusion, in the same output power condition can be observed that the microstructure of the specimens before induction hardening has a significant impact on the effective case depth. The surface residual stress has changed from a tensile to a compressive state. In the re-hardened area, the maximum of the residual compressive stress increased with the austenitized temperature increase.

Energy market price volatility and an upward trajectory of prices per unit of electricity have sent all industrial sectors and many economies to the brink of recession. Alongside the urgent need for decarbonisation of all industries, achieving a higher level of energy independence across all sectors seems imperative. A multi-disciplinary approach with a proposed system of CO₂ emissions reduction and capture technologies has the potential for short-term emissions reduction to near-zero in absolute terms. The findings of this research showed CO₂ emissions reduction of ~30% from 977t of CO_2e to 684t in one single blast furnace production cycle, by switching the energy provider generating energy exclusively from renewable sources. Replacing coal with biomass (BECCS), resulted in an additional reduction of ~30%, to CO_2e to 479t CO_2e. Installing solar PV panels for energy generation on site resulted in a further ~30% reduction, to 335 tonnes CO_2e. Finally, the installation of CO₂ filters reduced the CO₂ emissions to near-zero. Simultaneously, energy-saving and process improvement measures implementation (up to 60% efficiency increase), excess heat recovery (<30% of energy savings), and retrofitting renewable energy technology resulted in an energy independence of 88%. Short-term engineering solutions, partly subsidised in the UK, are readily available.

In this study, the Bohler K 190 steel was used. The steel was manufactured by the powder metallurgy (PM) process. The boronizing process was carried out in the range of 1173 to 1323 K, for 1-10 h. The samples were boronized in solid medium, called the Durborid powder mixture. For the microstructural observations, the scanning electron microscopy was utilized for determining the morphology of interfaces and measuring the layers’ thicknesses. The phase composition of boride layers was also determined with X-ray diffraction analysis. To investigate the redistribution of chemical elements redistribution during the boronizing process, the EDS mapping and EDS point analysis were used. The boride layers were constituted by FeB and Fe2B phases except for 1173 K for 1 h. The values of Vickers microhardness of Fe2B, FeB and transition zone were estimated. Finally, to assess the boron activation energies in FeB and Fe2B, the so-called integral method was applied and the results in terms of activation energies were confronted with the literature data.

: The effect that the microstructure exerts on the TRIP phenomenon and on the mechanical properties in a multiphase steel was studied. Samples of an initially cold-rolled ferrite-pearlite steel underwent different intercritical annealing treatments at 750 °C until an equal fractions of austenite/ferrite was reached; the intercritical treatment was followed by isothermal bainitic treatments before cooling the samples to room temperature. Samples in the first treatment were heated directly to the intercritical temperature, whereas other samples were heated to either 900 or 1100 °C to obtain a fully homogenized, single phase austenitic microstructure prior to the conducting the intercritical treatment. The high temperature homogenization of austenite resulted in the decrease in its stability, so a considerable austenite fraction transformed into martensite by cooling to room temperature after the bainitic heat treatment. Most of the retained austenite transformed during the tensile tests, and as a consequence, the previously homogenized steels showed the highest UTS. In turn, the steel with a ferritic-pearlitic initial microstructure, exhibited higher ductility than the other steels and texture components that favor forming processes.

Enhancement in the strength of austenitic steels with a small content of carbon can be achieved by a limited number of methods, among which is the ultrafine-grained (UFG) structure formation, especially efficient with the use of severe plastic deformation (SPD) processing that enables increasing significantly the contribution of grain-boundary strengthening, and also involves a combination of other strengthening factors (work hardening, twins, etc.). In this paper, we demonstrate that the use of SPD processing combined with conventional methods of deformation treatment of metals, such as rolling, may lead to an additional strengthening of UFG steel. Analysis of the results of the study on the change of the microstructure and mechanical properties of the Cr-Ni stainless austenitic steel after a combined deformation reveals a substantial increase in the strength properties of this steel, resulting from a consecutive application of SPD processing via equal-channel angular pressing and rolling at a temperature of 400 С, yielding a strength more than 1.5 times higher that that produced by any of these two methods used separately.

A proposed low-temperature forging method aims to enhance stainless steel bearings by creating a martensitic subsurface layer, significantly boosting bearing fatigue life due to increased surface hardness. This technique induces beneficial residual stresses, particularly in axial bearings, streamlining their construction and improving machine elements. Challenges persist, especially with radial bearings, but simplicity in axial bearing forging promotes compact, resource-efficient facility construction. Future research will focus on applying this technique to axial bearing washers, potentially replicating success in other bearing components. Despite the energy ex-penditure for cooling during forging, the substantial increase in bearing fatigue life offsets this, enhancing overall longevity and reliability of critical machine components. Integration of this forging technique into bearing fabrication appears seamless, offering a promising trade-off be-tween energy use and enhanced performance.

The effect of current density of electrodeposition on the morphology, hardness, and corrosion resistance of the Ni coatings and Ni-Al2O3 coatings on Q345 steels were investigated. The surface of Ni coatings exhibited the cellular structure, while the surface of Ni-Al2O3 composite coatings showed the finer protrusions structure. The thickness of all coatings increased as the current density of electrodeposition increased from 1.5 A/dm2 to 3.0 A/dm2. After coating, the hardness and corrosion resistance of the Q345 steels were significantly enhanced. Furthermore, for the Ni coatings and Ni-Al2O3 coatings, the highest hardness and best anticorrosion property were obtained at 2.5 A/dm2 of electrodeposition current density. Compared with the Ni coatings, the co-deposition of Al2O3 nanoparticles improved the hardness of Ni-Al2O3 coating due to the second phase strengthen, but reduced the thickness and corrosion resistance due to more defects caused by the coelectrodeposition of the Al2O3 particles.

The forming mechanism of clinch joints, for various materials arrangement, using a punch and a rigid die, is well known. The basic technological parameter of the process is the parameter X – the minimal thickness of the embossment. Usually, the lower the X parameter, the greater the joint interlock. This paper presents the possibility of forming a pressed joint for two 1.5 [mm] thick sheets made of HX340 steel. The joint was formed using an additional deformable steel rivet with a hardness of 400HV1. Different values of rivet pressing below the initial surface of the upper sheet were chosen: 0, 0.15, 0.30, 0.45 and 0.60 (in [mm]). The punch positioning accuracy was 0.01 [mm]. For the mentioned rivet pressing distances, forming tests were performed using an ‘‘SKB’’ die with three die depths: 1.45, 1.60 and 1.75 (in [mm]). Observations and measurements of the characteristic geometric dimensions of the interlock were made. Furthermore, the strength of the clinch-riveted joints was analysed. The greater the rivet pressing distance, the larger the interlock parameters. Furthermore, depending on the size of the rivet pressing distance, different failure mechanisms of the lap joint were observed in the tensile shear tests.

To investigate the structural behavior of simply supported concrete beams with steel and polypropylene fiber under low velocity impact loading. In all twenty-four beams (150X200X1800 mm) with simply supported boundary condition were modeled and analyzed using ABAQUS software. Steel and polypropylene fibers of aspect ratio of 60 and 231 respectively are used. The total volumes of fibers are maintained at 1% by volume of specimen. A 100 kg hammer with tip diameter 16 mm (hemispherical contact area = 201 mm2) with four different velocities (3.13 m/s, 4.42 m/s, 5.43 m/s and 6.11 m/s) were used in the analysis. It is observed that with the addition of hybrid fibers the deflection in beams was reduced. The beams with 1% PP and 0% steel fiber shows the maximum deflection values due to low modulus of elasticity. Beams with 0.9% steel and 0.1% polypropylene fibers was less affected in terms of deflection as compared to all other beams, it is due to presence of high tensile strength fibers.

This paper describes the formulations for viscoplasticity of metals based on the Chaboche and Delobelle model. The implementations of the viscoplastic models were detailed herein and then implemented via user subroutines for material models (UMAT) in ABAQUS. Two typical metals, i.e., 316 Stainless Steel and Zircaloy-4, were chosen as examples and their viscoplastic behaviors were captured. Numerical simulations are compared to reported experiments to validate the models and the UMAT codes. Typical viscoplastic behaviors of both metals, such as stress relaxation and creep, were captured well against available experiments. We publicize all the data and codes via: https://github.com/XJTU-Zhou-group/ABAQUS_UMAT_316ss_Zr4.

In this work a solution-annealed AISI 316H grade austenitic stainless steel was studied in terms of investigating the electrolytic hydrogen charging effects on the resulting Charpy impact toughness and dry sliding tribological behavior. Conventional Charpy impact bending tests were employed to study the mechanical response of the investigated material to dynamic loading conditions, whereas dry linear sliding tribological tests were used to study the material friction and wear behavior. The obtained mechanical and tribological properties were correlated with corresponding fracture and tribological mechanisms determined from morphological observations of fracture surfaces and tribological tracks. The applied testing procedures were individually carried out for the non-hydrogenated, hydrogen-charged, and dehydrogenated material conditions. The observed changes of individual properties due to applied hydrogen charging were rather small which indicated good resistance of the solution-annealed AISI 316H steel against material degradation in currently used electrolytic hydrogenation conditions.

Cold gas dynamic spray (CS) is a unique technique to deposit material using high strain rate solid state deformation. A major challenge for this technique is its dependence on the powder properties and lack of standards to assess them between lots and manufacturers. The motivation of this research was to understand the variability in powder atomization techniques for stainless steel powders and their subsequent properties for their corresponding impact on CS. A drastic difference (~30%) was observed in deposition efficiencies (DE) of unaltered, spherical, and similar sized stainless steel (316) powders produced using centrifugal (C.A) and traditional gas atomization (G.A) techniques. The study highlights more on differences on precursor level. Using recent advancements in large scale statistical measurements like laser diffraction shape analysis, µCT scanning, traditional methods like EBSD, nano-indentation, an attempt is made to understand the powder property. Insights on powder size and shape are documented. Significant differences were observed between C.A and G.A powders in terms of grain size, fraction of higher angle grain boundaries (HAGB) and nano hardness. The outcomes of this study would be helpful to understand the commercialization of the cold-spray process for bulk manufacturing of powder precursors

As the coproduct of steelmaking, steelmaking slag, volumetrically expansive-prone without treatment, has been satisfactorily used as an aggregate base course material in highway construction. Although numerous technical reports and papers have revealed that steel slag aggreged using in rigid matrixes, the end product, paving block, non-structural concrete, for example, possesses superb strength and durability properties, the application of steel slag aggregate as a concrete aggregate is currently prohibited in highway construction. Naturally, researchers explore the practicality of use of steel slag, how to connect the laboratory experiment results to the end-product behavior, and further convert the research results into real construction? For all nontraditional or secondary materials utilization, the procedure of laboratory material examination, lab and field trial test are critical. To generalize the utilization, usability criteria establishment is necessary. This paper tries to use step-by-step method and plain language to explain how the volumetrically expansion can be simulated in lab testing apparatus, and based on the model, the mathematical deduction can result in a numerical usability criterion for steel slag use as a coarse aggregate in concrete (a rigid material). Therefore the paper is composed four main parts, laboratory test methods to examine the expansion force resulted from steel slag; converting the measured expansion force in a given volume of mass aggregate to the expansion (body) force of a single particle; modeling of slag and end material disruption; and a usability criterion from numerical deduction for the use of expansive-prone coarse slag in concrete or other rigid matrices. The paper provides the solutions to answer the above questions. Through the mathematical and mechanical modeling, provides the potential criteria that could result in specifications and guidance establishment for broad volumetric expansive-prone slags.

The study presents the effect of annealing process parameters on the microstructure, hardness and strain hardening coefficients i.e., the strength coefficient c and the strain hardening exponent n, of 42CrMo4 steel. Seven selected annealing time-temperature schemes are examined for superior steel formability in cold metal forming conditions. The c and n coefficients are first determined in experimental upsetting of annealed samples and then used in FEM simulations of the upsetting process. The results demonstrate that the strain hardening coefficients (c and n) depend on the employed annealing scheme. Compared to the as-received sample, the annealing process reduces the true stress and effectively decrease the hardness of 42CrMo4 steel, improves microstructural spheroidization and, consequently, facilitates deformability of this material. The annealing schemes relying on heating the material to 750 °C and its subsequent slow cooling lead to the highest decrease in hardness ranging from 162 to 168HV. Results obtained with the SEM-EDS, LOM and XRD methods lead to the conclusion that the employed heat treatment schemes cause the initial ferritic-pearlitic microstructure to develop granular and semi-lamellar precipitation of cementite enriched with Mo and Cr in the ferrite matrix. In addition, the annealing process affects the growth of α-Fe grains. The highest cold hardening rate, and thus formability, is obtained for the annealing scheme producing the lowest hardness. The results of FEM simulations are positively validated by experimental results. Obtained results are crucial for further numerical simulations and experimental research connected with developing new cold metal forming methods for producing parts made of 42CrMo4 steel.

In this investigation steel P355NH has been successfully cladded with Inconel 625 through the method of explosive welding. Explosively welded bimetal clad-plate was subjected to the two separated post weld heat treatment processes: stress relief annealing (at 620oC for 90 minutes) and normalizing (at 910oC for 30 minutes). In order to analyze the microstructure of the joint in the as-welded state and to investigate the influence of the post weld heat treatment on it, the light and scanning electron microscope observations and microhardness analysis have been performed. The examination of the diffusion zone microstructure has been performed by using the scanning transmission electron microscope. It was stated that obtained joint has characteristic wavy-shape geometry with the presence of the melted zones and severe deformed grains of both joined materials. Strain hardening of the materials in joint zone was established with microhardness analysis. In both of the heat treatments the changes in the grain structure have been observed. The normalizing heat treatment has the most significant impact on the microstructure of the joint as well as the concentration of the chemical elements in the joint zone. It was reported that due to normalizing the diffusion zone has been formed together with precipitates in the joint zone. The analysis of the diffusion zone images leads to the conclusion that the diffusion of alloying elements from Inconel 625 to steel P355NH takes place along the grain boundaries with additional formation of the voids in this area. The precipitates in Inconel 625 in the joint zone are two type of carbides – chromium-rich and molybdenum-rich. Scanning transmission electron microscope observation of the grain microstructure in the diffusion zone shows that this area consists of equiaxed grains (from the side of Inconel 625 alloy) and columnar grains (from the side of steel P355NH).

The fatigue strength of the hot work steel depends on various factors, including the mechanical, properties and behavior and bulk and the surface under layer, the microstructural features as well as heat treatments. The influence of a series of heat treatments on the fatigue strength of H13 hot work steel was investigated. Different preheating, quenching and tempering treatments were applied to four sets of specimens and fatigue tests were conducted at room temperature using a rotating bending test machine. All heat treatments resulted in a certain improvement of the fatigue strength. Highest fatigue strength obtained by applying a double tempering heat treatment (first tempering at 550 °C for two hours and second tempering at 610 °C for two hours) after initial preheating and quenching. One tempering treatment (550 °C for two hours after preheating and quenching) did not significantly improve the fatigue strength.

Additive manufacturing (AM) is today’s buzzword—and not only in commercial production. One of the AM techniques produces 3D objects with complex geometry using a laser beam. The relationship between the morphology of individual powder particles and the printing process has not been adequately documented yet. This article presents a detailed microscopic analysis of virgin and reused powder particles of maraging steel. Metallographic observation was performed using a scanning electron microscope (SEM). Detailed analyses of individual particles were carried out using SEM with a focused ion beam (FIB) milling capability. Analyses of elemental distribution and phase distribution were performed using EDS and EBSD, respectively. The findings have led to a better understanding and prediction of defects in additive-manufactured products.

Construction involves the use of significant quantities of raw materials and entails high-energy consumption. For the sake of choosing the most appropriate solution that considers environmental and sustainable concepts, tools such as the integrated value model for sustainable assessment (Modelo Integrado de Valor para una Evaluación Sostenible, MIVES) used in Spain, plays a key role in obtaining the best solution. MIVES is a multi-criteria decision-making method based on the value function concept and the seminars delivered by experts. Such tools, in order to show how they may work, require application to case studies. In this paper, two concrete slabs manufactured with differing reinforcement during the construction of the La Canda Tunnels are compared by means of MIVES. The two concrete slabs were reinforced with a conventional steel-mesh and with polyolefin fibres. The results showed that from the point of view of sustainability, the use of polyolefin fibres provided a significant advantage mainly due to the lower maintenance required.

Laser Cladding is one of the leading processes within Additive Manufacturing technologies, a fact which has concentrated an important amount of effort on its development. In regard to the latter, the current study aims to summarize the influence of the most relevant process parameters in the laser cladding processing of single and compound volumes (solid forms) made from AISI 316L stainless steel powders and using a coaxial nozzle for deposition. Process speed, applied laser power and powder flow are considered to be the main variables affecting laser cladding in single clads, meanwhile overlap percentage and overlapping strategy become also relevant when dealing with multiple clads. By means of setting appropriate values of each process parameter, the main goal of this paper is to develop a processing window in which a good metallurgical bond between the delivered powder and substrate is obtained, trying simultaneously to maintain processing times in their lowest value possible. Conventional metallography techniques were performed on the cross sections of the laser tracks to measure the effective dimensions of clads for dilution analysis, height and width for the values of overlap between contiguous clads and layers, and also to analyze them for physical defects such as porosity and cracks. The resulting solid piece was 8 mm high at 800 mm/min.

The article presents tests aimed to verify the possibility of making T-joints in TMCP steel using laser. The tests involved the use of 10 mm thick high yield point steel S700MC obtained in an industrial manufacturing process. The joints made in the tests were single and double-sided. Subsequent non-destructive tests revealed that the joints obtained in the tests represented quality level B in accordance with PN-EN ISO 13919-1. Single-sided welding performed using the laser beam having a power of 11 kW enabled the obtainment of 8 mm deep penetration without visibly deforming the web of the joint. The double-sided welded joints were characterised by proper geometry and the presence of gas pores in the welds not compromising the requirements of quality level B (strict requirements). The weld structure was bainitic-ferritic. The weld hardness was by approximately 60 HV1 higher than that of the base material (280 HV1). The HAZ area was slightly softer than the base material. The tests of thin foils performed using a high-resolution scanning transmission electron microscope revealed that, during welding, an increase in the content of the base material in the weld was accompanied by an increase in contents of alloying microagents Ti and Nb, particularly near the fusion line. The above-named alloying microagents, in the form of fine-dispersive (Ti,Nb)(C,N) type precipitates, could reduce plastic properties of joints.

The precipitate phases often play an important influence on the corrosion resistance of 2205 Duplex stainless steel (DSS). In the presented paper, the microstructure and corrosion resistance in the hot-rolled and cold-rolled 2205 DSS aging for different time at 850 °C was investigated by XRD, SEM and potentiodynamic polarization. It has been found that the Chi(χ) phase and Sigm(σ) phase were precipitated in turn after aging treatment of hot-rolled and cold-rolled materials, but the precipitate amount in cold-rolled material is much more than that of hot-rolled samples. The corrosion resistance of the solution-annealed cold-rolled material is similar to the hot-rolled material, but the corrosion resistance of cold-rolled material with precipitate is weaker than that of hot-rolled material after aging treatment. Pitting initiates preferentially in the Cr-depleted region from σ phase in aged hot-rolled 2205, and severe selective corrosion occurs on sigma/ferrite interfaces aged for a long aged lime. However, the initiation of pitting corrosion may take place at the phase boundary, defect and martensite in the aged cold-rolled 2205. The σ phase is further selectively dissolved by electrochemical method to investigate the difference of microstructure and corrosion behavior in hot-rolled and cold-rolled 2205 duplex stainless steel.

Laser powder bed fusion (LPBF) is an additive manufacturing process employed in many industries, for example for aerospace, automotive and medical applications. In these sectors, mainly nickel-, aluminum- and titanium-based alloys are used. In contrast, the mechanical engineering industry is interested in more wear-resistant steel alloys with higher hardness, both of which can be achieved with a higher carbon content, like in high-speed steels. Since these steels are susceptible to cracking, preheating needs to be applied during processing by LPBF. In a previous study, we applied a base plate preheating temperature of 500 °C for HS6-5-3-8 with 1.3 % carbon content. We were able to manufacture dense (p > 99.9 %) and crack-free parts from HS6-5-3-8 with a hardness > 62 HRC (as built) by LPBF. In this study, we investigate the influence of preheating temperatures up to 600 °C on hardness and microstructure dependent on part height for HS6-5-3-8. The microstructure was studied by light optical microscopy (LOM), scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). The analysis of hardness and microstructure at different part heights is necessary because state-of-the-art preheating systems induce heat only into the base plate. Consequently, parts are subjected to temperature gradients and different heat treatment effects depending on part height during the LPBF process.

A new lateral force-resisting wall panel is presented for applications in mid-rise prefabricated lightweight steel construction in seismic prone regions. This panelised system is composed of a hot-rolled frame and cold-formed studs and tracks, which works as a lateral force resisting system in lightweight steel framing. The proposed hybrid panel system exhibits proper ductility and energy dissipation behaviour. The hysteretic responses of full-scale panel experiments demonstrate that the system can safely resist high cyclic loads. The hot-rolled steel part, on the other hand, can significantly improve the initial lateral stiffness of the total system that will control the maximum allowable drift of multi-story buildings. Finally, in a case study, by applying the proposed system to the design of a mid-rise building in a high seismic area, the performance of the hybrid panels, are compared with those of fully hot-rolled systems (moment resisting frames) and fully cold formed systems. The findings indicate that applying hybrid panels will result in lower weights and better performance in seismic prone regions.

The behavior of concrete beams reinforced with steel and Glass Fiber Reinforced Polymer (GFRP) rebars, without shear reinforcement is investigated in the current study. This study includes testing experimentally of twenty-four steel and GFRP Reinforced Concrete (RC) beams cast with different percentage of fibers. The beams were split into two types, steel and GFRP RC beams. Beams of different fiber ratios (0, 0.5, 1.5 and 2.5%) were developed and tested, in two groups, each consists of twelve specimens, steel and GFRP reinforced RC beams. Both steel and GFRP RC beams were cast as singly reinforced with 10 mm diameter longitudinal bars at the bottom. In order to ensure that the beam to fail under shear, the top reinforcement and stirrups are removed. The concrete cover was kept as 30 mm. Three concrete grades (M30, M60 and M80) were examined for different dosage of fibers for both steel and GFRP RC beams. The size of the beam samples was kept as 150 ×200×1500 mm. The key parameters were the form of reinforcement material (steel and GFRP), compressive strength of concrete and fiber percentage. Failure mode, ultimate load carrying capacity, mid-span deflection, strain in concrete and reinforcement (steel and GFRP) of the beams have been reported. It is found that the effect of using fibers and higher grade of concrete is more pronounced in improving stiffness of GFRP RC beams compared to steel RC beams. Hence it can be concluded that GFRP rebars can be used as an efficient type of reinforcement in RC beams.

This study investigates the microstructural evolution and mechanical properties of high-nickel shipbuilding steel during thermal processing using High Temperature Confocal Laser Scanning Microscopy (HTCLSM). The in-situ observation of the heating and holding processes reveals critical insights into phase transformations, grain growth behavior, and the formation of precipitates. The experimental results demonstrate that austenitization begins at approximately 700°C, with significant grain boundary nucleation. At 900°C, the formation of black precipitates was observed, and their persistence up to temperatures exceeding 1000°C was confirmed. Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) analyses identified these precipitates as chromium carbides (Cr7C3), which significantly contribute to the material's strength. The comprehensive analysis using Transmission Electron Microscopy (TEM) confirmed the presence and distribution of Cr7C3 within the grains and along grain boundaries. These findings provide a deeper understanding of the microstructural dynamics in high-nickel steels, guiding the optimization of heat treatment processes to enhance mechanical properties for maritime applications.

Brittle fracture of iron and steel above twinning temperatures are caused by cementite grain boundary wall cracks. These were revealed by an Atomic Force Microscope. At temperatures below the Ductile-Brittle Transition, cracks must propagate longitudinally within the cementite walls until the stress is sufficient high for the cracks to propagate across ferrite grains. Calculations using these concepts correctly predict the stress and temperature at the Ductile-Brittle Transition required for fracture to occur. At temperatures above the Ductile-Brittle Transition for hypoeutectoid ferritic steels, dislocations must fracture these walls transversely for plastic deformation to continue. This is responsible for the upper yield point at the elastic limit in these steels followed by a large drop in stress to the lower yield point. Here the walls surround completely all of the grains. Where the walls are segmented such as in iron, dislocations can pass around the walls resulting in a gradual change from elastic to plastic deformation. The Cottrell atmosphere theory of yielding is not supported experimentally. It was the best available until later experiments including those using the Atomic Force Microscope were obtained. Methods are presented here giving yield strength versus temperature and also the parameters for the Hall-Petch and Griffith equations.

As a new type of high-performance material, gradient structural steel is widely used in engineering fields due to its unique microstructure and excellent mechanical properties. For the prevalent fatigue failure problem, the rate of change of the local grain size gradients along the structure (referred to as the gradient rate) is a key parameter in the design of gradient structures, which significantly affects the fatigue performance of gradient structural steel. In this work, a method of ‘Voronoi primary + secondary modeling’ is adopted to successfully establish three typical high-strength steel models corresponding to the convex, linear, and concave type gradient rates for gradient structures, focusing on the stress-strain response and crack propagation in structural steel with different gradient rates under cyclic loading. It is found that the concave gradient rate structural model is dominated by finer grains with larger volume fraction, which is conducive to hindering fatigue crack propagation and has the longest fatigue life; the linear structure is the second one, and the convex structure is the shortest one. The simulation results in this work are consistent with the relevant experimental phenomena. Therefore, when regulating the gradient rate, priority should be given to increasing the volume fraction of fine grains and designing a gradient rate structure dominated by fine grains to improve the fatigue life of the material.

Steel slag and GBFS are wastes generated during the steel and iron smelting process, characterized by their considerable production rates and extensive storage capacities. After grinding, they are often used as supplementary cementitious materials. However, the intrinsic slow hydration kinetics of steel slag-GBFS cementitious material (SGM) when exposed to a pure water environment result in prolonged setting times and diminished early-age strength development. The incorporation of modifiers such as gypsum, clinker, or alkaline activators can effectively improve the various properties of SGM. This comprehensive review delves into existing research on the utilization of SGM, examining their hydration mechanisms, workability, setting time, mechanical strengths, durability, and shrinkage. Critical parameters including the performance of base materials (water-to-cement ratio, fineness, and composition) and modifiers (type, alkali content, and dosage) are scrutinized to understand their influence on the final properties of the cementitious materials. The improvement mechanisms of various modifiers on properties are discussed. This the promotes resource utilization of industrial solid wastes and provides theoretical and technical support for the application of SGM.

The microstructure evolution of SCM435 cold heading steel at different cooling rates was investigated by means of scanning electron microscopy, TEM, XRD, and electron backscatter diffraction. The results show that the cooling rate has a significant effect on the microstructure of the experimental steel. With an acceleration of the cooling, the microstructure of the steel gradually changed from ferrite and pearlite to ferrite, pearlite, and granular bainite; finally, the pearlite disappeared, and the microstructure changed to acicular ferrite, bainite, and martensite. With an increase in the cooling rate, the morphology of the carbide underwent an evolution from sheet carbide to short-rod carbide, granular carbide, and ultimately thin-strip carbide. With the acceleration of cooling, the proportion of large-angle grain boundaries gradually decreased, and the area of small-angle grain boundaries gradually increased. When the cooling rate was 0.1℃/s, the proportion of large-angle grain boundaries was as high as 52.8%, and the dislocation density was only 1.91 × 1012 cm−2. When the cooling rate was 2.0℃/s, the proportion of large-angle grain boundaries was only 27.1%, and dislocation density increased to 5.38 × 1012 cm−2. With the increase in the cooling rate, the depth of the decarbonization layer and the thickness of the scale oxide gradually decreased, the proportion of FeO phase in the scale phase gradually decreased, and the proportion of Fe3O4 phase and Fe2O3 phase gradually increased. The tensile strength increased monotonously with the increase in cooling rate, whereas the elongation and shrinkage first decreased, then increased, and then decreased. When the cooling rate was 1.0 m/s, the short rod and granular bainite in the material structure endowed the SCM435 steel with excellent strength and toughness matching, and the tensile strength and elongation of the steel reached 895 MPa and 24%, respectively.

The guided ultrasonic wave (GUW) is extensively employed in non-destructive testing (NDT) for the purpose of detecting defects in aerospace vehicles, oil pipelines and mechanical equipment. The filtration of GUW signals, which often contain substantial environmental noise, is a crucial procedure in signal processing. This paper presents a novel denoising approach that combines Variational Mode Decomposition (VMD) with an enhanced Singular Value Decomposition (SVD). The VMD method is employed to preprocess the initial signal, thereby segregating the signal component from the noise component. Subsequently, the SampEn-SVD (Sample Entropy-SVD) method is utilized to extract the effective component from the VMD-preprocessed noise component. Finally, the VMD-preprocessed signal component and the SampEn-SVD-processed effective component are combined to yield the resultant signal, which effectively filters out the noise. The efficacy of this integrated denoising approach is substantiated through the examination of experimental signals. Furthermore, a comparative analysis is conducted to evaluate the efficacy of this method in relation to other denoising techniques. The results indicate that the SampEn-SVD method yields a superior signal-to-noise ratio (SNR) when processing the GUW signal transmitted through the steel strand. Moreover, the denoising procedure significantly reduces the discretization of characteristic parameters in the signal waveform, thereby addressing the issue of inadequate reproducibility in testing outcomes. Consequently, the denoised signal exhibits high fidelity and demonstrates a strong correlation between its combined eigenvector and strand stress.

Shape Memory Alloy (SMA) have emerged as a revolutionary material that holds the potential to change the design and construction methods of buildings and other structures. One of the most promising applications of SMAs in civil engineering is their use as reinforcements for steel structures. This paper presents the latest research progress, opportunities and challenges of SMA in the field of steel structural reinforcement, both in terms of basic components and applications. In terms of components, the construction forms and working mechanisms of Fe-SMA strips, SMA/CFRP composite patches and SMA dampers are introduced. On this basis, the application of SMA in steel structures reinforcement is introduced, and its effect is analyzed from three aspects: crack restoration, seismic retrofitting and structural strengthening. Finally, the results of the current research are summarized and the shortcomings are analyzed, hoping to provide a reference for the research of SMA in the field of steel structures reinforcement.

This study deals with two different aspects of the high-strength low-alloyed 1100 MC steel. The first is associated with the remarkable heterogeneity in the surface state produced during sheet rolling with respect to the sheet width. The variable-thickness surface layer exhibits a microstructure different from that of the deeper bulk. Variation of the thickness of the thermally softened near-surface region strongly affects Barkhausen noise, as well. This technique can be considered a reliable tool for monitoring the aforementioned heterogeneity. It can also be reported that the opposite sides of the sheet are different with respect to the surface state, heterogeneity distribution, and corresponding Barkhausen noise. These aspects indicate the different conditions during hot rolling followed by rapid quenching on the upper and lower rollers. The second aspect is related to the remarkable asymmetry of Barkhausen noise emission with respect to two consecutive bursts. This asymmetry is due to the presence of remnant magnetisation in the sheet produced during manufacturing. The remnant magnetisation is coupled to the magnetic field produced by the excitation coil of the Barkhausen noise sensor and strongly contributes to the aforementioned asymmetry. As soon as sufficient removal of this remnant magnetisation is carried out in the vanishing magnetic field (demagnetisation), the aforementioned remarkable asymmetry is fully lost.

We present functionalization of AISI 316L surfaces by nanosecond Nd:YAG laser texturing in order to modify the surface morphology with crosshatch and dimple patterns. We performed tribological analysis under lubrication with sunflower and jojoba oil with and without addition of solid lubricant, MoS2 nanotubes. In connection to friction/wear response we analysed laser-textured surface wettability, oil spreadability and oil retention capacity. We have shown, that the crosshatch pattern generally exhibited lower friction than the dimples pattern, with the addition of MoS2 nanotubes not having any significant effect on the coefficient of friction under the investigated contact conditions. This was additionally with better oil spreadability and oil retention capacity results of crosshatch textured surface. Furthermore, texturing reduced wear of the stainless steel surfaces but led to approximately one order of magnitude larger wear rate of the steel counter-body, primarily due to the presence of hard bulges around the textured patterns. Overall, the crosshatch pattern showed better oil retention capacity and lower friction in combination with different vegetable oils, thus making it a promising choice for improving tribological performance in various environmentally friendly applications.

Nitriding has long been used to engineer the surfaces of engineering steels to improve their surface and subsurface properties. The role of the surface compound layer (’-Fe4N and/or -Fe2-3N) in improving the tribological and corrosion resistant properties of nitrided steels has been established. However, there have been very few studies on the response of the compound layer to tribocorrosion in corrosive environments. In this work, the tribocorrosion behaviour of a 5 m thick ’-Fe4N nitride layer produced on mild steel (MS) by plasma nitriding has been studied in a NaCl containing solution under various electrochemical conditions. The results show that at a cathodic potential, where mechanical wear is predominant, the total material removal (TMR) from the ’-Fe4N layer is 37% smaller than that from the untreated MS, and at open circuit potential, TMR from the layer is 35% smaller than that from the untreated MS, while at an anodic potential, the ’-Fe4N layer can reduce TMR from mild steel by 87%. The beneficial effect of the ’-Fe4N nitride layer in improving the tribocorrosion behaviour of mild steel is derived from its high hardness and good corrosion resistance in the test solution and its ability to resist both mechanical wear and chemical wear.

A large amount of steel slag (SS) and CO2 are generated in the steelmaking process. The indirect CO2 capture using SS is a promising way for co-treatment of the wastes. Ammonium salt solution is widely used to extract Ca2+ from the SS since it is recyclable. Several works have focus on improving the carbonation rate by adjusting various parameters (e.g., temperature and pH). However, there is little detail information about the associating behaviors and interaction strength between the various ions in the ammonia solution during the carbonation process. In this work, the Ca2+–CO32-–NH4+–Cl-–H2O system was established by using Material studio software. The effects of temperature and concentration of CO32- on CaCO3 growth were explored at the atomic scale by calculating the binding energy, mean square displacement, and diffusion coefficient between particles. Furthermore, the microstructure, bonding characteristics, and occurrence behavior of each particle were studied though molecular dynamics simulation methods. The results showed that with the increase of temperature (20–80 ℃), the binding ability and diffusion coefficients of Ca2+ and CO32- increase in the system, which is beneficial to the formation of CaCO3 clusters. With the increase of the concentration of CO32- (15–25 vol.%), the binding ability and diffusion coefficient of Ca2+ and CO32- in the system are enhanced, which is beneficial to the formation of CaCO3 clusters.

Steel slag is a co-product of the steelmaking industry, this material is rarely used as a binder due to its low cementitious properties. Thus, it´s believed that the alkaline activation of steel slag can enable its use as a cementitious material. This work has the objective of making a systematic bibliographic review on the theme "slag melt as a precursor in activated alkali binders". To this end, the ProKnow-C method was used for the selection and analysis of relevant research on the topic. The portfolio resulted in 71 texts, mostly journals paper. Bibliometrics showed that the country with the most publications is China and the journal with the most publications is Construction and Building Materials. The critical analysis concluded that the XRD, XRF, and compressive strength tests are the most used for the characterization of the material. It is possible to establish that there are some knowledge gaps on the subject, such as better mechanical characterization and greater production of works with dosing by the one-part method.

This study is follow-up of the steel shot transformation under the influence of environmental factors research (Lisin et al., 2022) and is the initial stage of investigating the iron behavior in soils during steel shot corrosion under a number of factors: the metallic lead in soils, atmospheric precipitation, excess organic matter. The results obtained show that corrosion of steel ammunition is a continuous process, including the formation of a poorly soluble rust crust on the surface of the steel and the mineralization of the metal until it is destroyed. As a result, the metal transformed into rust form, is a constant source of iron ions and dispersed rust particles migrating in soil waters and accumulating in soils. In addition, the aggregation of corrosion products of steel ammunition is the cause of a change in physical and mechanical properties of soils, which leads to a violation of the air and water migration regime of soils and an increase in surface runoff from the territories of shooting activity. The highest environmental risks are observed when steel ammunition is used on shooting areas where metallic lead intensifies steel shot corrosion rate, while the deposited steel shot activates the deterioration of previously encapsulated metal and — if steel and lead ammunition are used at the same time — slows down the encapsulation of newly deposited metallic lead, which catalyses the accumulation and migration of lead in environmental components.

The article presents a modified finite element (FE) based algorithm for nonlinear analysis of 2D beam structures, which takes into account the influence of the shear forces. The method proposed enables using complex materials with nonlinearities without the need of implementing advanced constitutive models in FE routines. It can be directly integrated with commonly available FE software for linear analysis of beam structures, so its functionality can be easily extended also with material nonlinearities. The presented approach adopts the generalized constitutive law algorithm to iteratively modify the stiffness of beam element. To address an influence of a shear stiffness, a Timoshenko beam element was used. The methodology was implemented and its performance was verified on several numerical examples. For validation, the displacements and the ultimate loads were compared with the values from a commercial FE software. The results shown a good correlation between the reference model and the method proposed.

A phosphate/molybdate and cerium-modified phosphate/molybdate conversion coatings were deposited on a carbon steel surface and their protective and self-healing abilities were evaluated. Surface morphology and inner structure of the coatings were examined using FE-SEM-FIB and TEM techniques, chemical composition and element distribution depth profiles in conversion layers were determined using EDX measurements, whereas XPS was applied for the analysis of Mo and Ce oxidation states. Voltammetric measurements and EIS were performed to assess the corrosion behavior of the samples. The higher protective and stronger self-healing abilities were found for phosphate/molybdate/cerium conversion coating deposited in a sulphate-containing solution. This was attributed to higher values of both: total cerium and Ce(IV) content in the conversion layer as well as to lower number of structural defects in the coating. It was demonstrated that the micro-structural characteristics of protective coatings are also important in determining self-healing abilities.

Metal 3D printing technology is a promising manufacturing method, especially in the case of complex shapes. The quality of the printed product is still a challenging issue for mechanical applications. The anisotropy of the microstructure, imperfections, and residual stress are some of the issues that diminish the mechanical properties of the printed sample. The simulation could be used to investigate some technical details, and this research has tried to computationally study the metal 3D printing of austenitic stainless steel to address austenite microstructure and local yield strength. Two computational codes were developed in Visual basics 2015 to simulate the local heating/cooling curve and subsequent austenite microstructure. A stochastic computational code was developed to simulate austenite grain morphology based on calculated thermal history. Then Hall-Pitch equation was used to estimate the yield strength of the printed sample. These codes were used to simulate the effect of temperature of the printer’s chamber on microstructure and subsequent yield strength. The austenite grain topology is more columnar at a lower temperature. The percentage of the equiaxed zone will be increased at a higher chamber’s temperature. Almost a fully equiaxed austenite microstructure will be achieved at 800 C chamber’s temperature, but the last printed layer, which is columnar and can be removed by cutting then. The estimated local austenite grain size and the local yield strength in the equiaxed regions are in the range of 15 to 30 μm and 270 to 330 MPa at 800 C temperature of printer’s chamber, respectively.

This paper analyses the evolution of the internal damage in two types of steel that show different fracture behaviours, with one of them being the initial material used for manufacturing prestressing steel wires, which shows a flat fracture surface perpendicular to the loading direction, and the other one being a standard steel used in reinforced concrete structures, which shows the typical cup-cone surface. 3mm-diameter cylindrical specimens are tested with a tensile test carried out in several loading stages and, after each of them, unloaded and analysed with X-ray tomography, which allows detection of internal damage throughout the tensile test. In the steel used for reinforcement, damage is developed progressively in the whole specimen, as predicted by Gurson-type models, while in the steel used for manufacturing prestressing steel-wire damage is developed only in the very last part of the test. In addition to the experimental study, a numerical analysis is carried out by means of the finite element method by using a Gurson model to reproduce the material behaviour.

Transient liquid phase (TLP) bonding of Al-6063 and UNS S32304 was performed using copper foil as an interlayer between the base metals. A compression load was applied normal to the specimens. Metallurgical examination of the produced joints showed three distinct regions including a reaction zone, diffusion affected zone and the base metals. The diffusion of copper into aluminum resulted in an Al-Cu eutectic structure. However, the oxide layer on the aluminum surface controlled the dissolution behavior of copper and the extent of its wettability with the base metals. Although voids and intermetallic compounds were detected at the interfaces of the processed joints, a defect free joint was produced at 570°C. In addition, the results from corrosion tests showed that the use of copper as an interlayer decreased the corrosion resistance of the joints. However, increase in thickness of the joining reaction zone with increasing bonding temperature was observed to increase corrosion resistance.

Carbon fiber reinforced polymer (CFRP) has been used widely in strengthening of steel structures. Steel/CFRP systems subjected to elevated temperatures is realistic in a summer climate event in many countries where the temperature in steel may approach 50 °C or even higher, which will lead to the degradation of the bond performance between CFRP and steel. Therefore, predicting the bond behavior of the CFRP/steel system under elevated temperature is critical. This paper investigated the mechanical performance of CFRP/steel adhesively-bonded double strap joints at elevated temperatures. Thirty CFRP-steel double strap joints were tested to failure under temperatures between 10 °C and 90 °C. It was found that the joint failure mode changed from adherend failure to debonding failure as the temperature approached T_g. In addition, the ultimate load and joint stiffness decreased significantly at temperatures near to and greater than T_g. Based on the experimental results, a model is proposed to predict the bond stress of the CFRP/steel at different temperatures.

1-[(4-ethyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl)methyl]-4-phenyl-1H-1,2,3-triazole (Ph4) and1-[(4-ethyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl)methyl]-5-phenyl-1H-1,2,3-triazole (Ph5) are new isomers of the triazole derivative family, were synthesized and tested on the corrosion of mild steel in molar hydrochloric acid molar media using weight loss, electrochemical polarization and impedance spectroscopy. Then the experimental results were confirmed by quantum chemical calculations using DFT at B3LYP /6-31G (d,p). The compound Ph4 is the best inhibitor and its inhibitory efficiency increased with increasing concentration and reaching 95% at 10⁻³ M. Polarization curves studies show that both compounds tested are mixed-type inhibitors. Nyquist curves presented a single capacitive loop, their diameter increases progressively with both inhibitors concentration. The change of the substitution phenyl from position 5 to position 4 in the triazole ring increases the inhibitory effect of the triazole compounds. The effect of temperature on the corrosion behavior of iron indicates that the inhibitory efficiency of the two inhibitors decreases with increasing temperature in the range of 308 to 338K. DFT study is in good correlationwith the experimental results.

Medium-carbon steel is commonly used for the rail, wire ropes, tire cord, cold heading, forging steels, cold finished steel bars, machinable steel and so on. Its fatigue behavior analysis and fatigue life estimation play an important role in the machinery industry. In this paper, the estimation of fatigue life of medium-carbon steel with different surface roughness using established S-N and P-S-N curves is presented. To estimate the fatigue life, the effect of the average surface roughness on the fatigue life of medium-carbon steel has been investigated using 75 fatigue tests in three groups with average surface roughness (Ra): 0.4μm, 0.8μm, and 1.6μm respectively. S-N curves and P-S-N curves have been established based on the fatigue tests. The fatigue life of medium-carbon steel is then estimated based on Tanaka-Mura crack initiation life model, the crack propagation life model using Paris law, and material constants of the S-N curves. 6 more fatigue tests have been conducted to validate the presented fatigue life estimation formulation. The experimental results have shown that the presented model could estimate well the mean fatigue life of medium-carbon steel with different surface roughness

Epoxy asphalt (EA) concrete is widely used in constructing long-span steel bridge pavements (SBDPs). This study aims to derive a fatigue damage evolution law, conducting an experimental investigation of SBDP. First, a general theoretical form of the fatigue damage evolution law of materials is established based on the thermal motion of atoms. Then, fatigue experiments demonstrate that this evolution law well represents the known damage–life relationships of SBDP. Taking into account the experimental relationships between damage and fatigue life under symmetrical cyclic loadings with different overload amplitudes and temperature variations, a detailed damage evolution law is deduced. Finally, the role of damage accumulation is discussed on the basis of the proposed damage evolution law for the extreme situation of heavy overload and severe environments. The results show that both heavy loading and falling temperatures increase the fatigue damage of SBDP considerably; therefore, SBDP should avoid heavy loading combined with winter temperatures. EA shows a fatigue life two to three times longer than that of modified matrix asphalt (SMA) or guss asphalt (GA). For the same thickness, EA pavement is demonstrated to be more suitable for an anti-fatigue design of large-span SBDP under high traffic flows and low temperatures.

China is facing the development requirements of the dual carbon goal and the construction needs of resilient cities. Currently, high-strength composite structural systems are a feasible solution, but their research and application in the construction field are insufficient, especially for the combination forms of concrete above C100 and steel above Q550. In response to this issue, this paper proposes a new high-performance structural system, namely the composite frame - high-strength steel plate wall core tube resilient structure system, which includes high-strength steel plate (Q550) - ultra-high strength concrete (C100) shear walls, replaceable energy dissipation coupling beams, and composite frames. Taking a 200 meter building as an example, this paper designs and establishes calculation models for a conventional reinforced concrete frame-core tube structure and a high-performance structure based on PKPM software, and establishes elastoplastic analysis models for both based on SAUSAGE software, and then conducts dynamic elastoplastic time history analysis and seismic resilience assessment of structures under design basis earthquakes (DBEs), maximum considered earthquake (MCEs) and extremely rare earthquakes (EREs). Research has shown that compared to conventional structures, new high-performance structures can effectively reduce the size of shear walls, reduce the self-weight of the structure, and enhance the space for building use; The story drift ratio has higher redundancy than specification limits, lower plastic damage and overall stiffness degradation of the structure, and better seismic performance; The seismic resilience has significantly improved, especially in the case of casualties, which can better ensure the safety of people's lives and property.

This study explores the effects of tempering on the precipitation behavior and impact toughness of high-nickel steel. The specimens underwent double quenching at 870°C and 770°C, followed by tempering at various temperatures. Advanced characterization techniques including optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to elucidate precipitation phenomena. Additionally, electron backscatter diffraction (EBSD) was employed to assess the misorientation distribution after tempering. Charpy impact tests were performed on specimens tempered at different temperatures to evaluate their toughness. The findings reveal that with increasing tempering temperature, the fraction of low-angle grain boundaries decreases, which correlates positively with enhanced impact toughness. The impact toughness peaks at 580°C and then diminishes with further temperature increases.

Longitudinal cutting is a most common process in steel structure manufacturing, and the man-hours of the process provide an important basis for enterprises to generate production schedules.However, currently the man-hours in factories are mainly estimated by experts, and the accuracy of this method is relatively low.In this study,we propose a system that predicts man-hours with history data in the manufacturing process and that can be applied in practical structural steel fabrication.The system addresses the data inconsistency problem by one-hot encoding and data normalization techniques,Pearson correlation coefficient for feature selection,and the Random Forest Regression(RFR) for prediction.Compared with the other three Machine Learning(ML) algorithms, the Random Forest algorithm has the best performance.The results demonstrate that the proposed system outperforms the conventional approach and has better forecast accuracy, so that it is suitable for man-hours prediction.

The corrosion inhibition behavior of cetyl pyridinium chloride (CPC) on mild steel (MS) in 0.5 M H₂SO₄ solution was examined using the weight loss method and potentiodynamic polarization method. The experimented MS surface was characterized by Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and Atomic Force Microscopy (AFM). Corrosion rate and corrosion efficiency was calsulated via weight loss and potentiodynamic polarization methods where the corrosion rate in 0.5 M H₂SO₄ , 0.000192 M, and 0.0077 M of CPC solution was 12.09×10^-3, 8.23×10^-3, 6.63×10^-5 (mm/Year), respectively and the inhibition efficiency of 94.42% and 98.54%. FESEM studies demonstrated the corrosion attack on MS surface. Also, the EDX showed the presence of nitrogen of CPC. Thus, CPC acts as an important corrosion inhibitor.

This study aims to investigate a friction stir welded joint between steel and aluminum alloy. Friction stir welding is nowadays one of the most interesting joining technique due to the possibility to connect materials and thicknesses that are difficult or impossible to weld with traditional techniques. The main advantage is that Materials are not affected by thermal cycle problems during solidification and cooling and the absence of fumes and pollution during the process favors the quality of the welded joint. The life of metal joints could be greatly reduced in a corrosive environment, since the less noble material will tend to increase its corrosion rate while the nobler one will reduce its electrochemical dissolution. Accelerated ageing tests (i.e. salt fog test) are used to estimate the lifetime of metal joints in highly aggressive environments. The aim of the present work is to evaluate the durability at long ageing time in salt spray test (according to ASTM B117) of carbon steel/aluminum alloy joints, obtained by FSW. In this first part, mechanical tests results are reported. A deep metallographic and chemical investigation are going to be reported in the part 2.

The investigation aims to analyze the effect of homogenization heat treatment on the quantity, distribution, morphology, and chemical composition of δ ferrite and sigma phase in the 316L austenitic stainless steel cast billet. Microstructures of the cast billet at different locations, center, 0.5 R, R, and the subsequent 2/6-hour homogenization heat treatment at 1240 oC were examined. The microstructure at the radius R was much more uniform and expected a better performance in the following hot/cold forging processes due to the highest cooling rate compared with those at 0.5R and center. The δ ferrite often accompanies the generation of the sigma phase, and the transformation of δ ferrite into the sigma/(austenite) and retained δ ferrite is strongly related to the cooling rate after homogenization heat treatment. The sigma phase is hard and detrimental to the subsequent hot/cold forgings. It must be removed from the homogenization heat treatment before forging. Fast air cooling from 850 oC to room temperature after homogenization heat treatment cannot prohibit the sigma phase formation. Rapid cooling between 850 and 1240 oC after homogenization treatment is required to avoid the sigma phase formation in the 316L stainless steel cast billet.

The effect of plasma electrolytic nitrocarburizing on the wear resistance of carbon tool steel in friction couples with hardened steel and lead-tin bronze is considered. The microgeometry of friction tracks and its change with increasing duration of friction tests are analyzed. The equilibrium roughness is determined, which is optimal for the friction couple and ensures minimal wear. The type and mechanism of wear of carbon tool steel after plasma electrolytic nitrocarburizing has been determined. The optimal values of the plasma electrolytic nitrocarburizing parameters, which provide the lowest values of the friction coefficient and weight wear, have been determined. The phase and elemental composition of the surface layer was studied using X-ray diffraction analysis and EDX analysis. The relationship of the microstructure of the nitrocarburized layer of tool steel with the friction coefficient and weight wear is established.

In the current industrial revolution, advanced technologies and methods can be effectively utilized for the detection and verification of defects in high-speed steel filament production. This paper introduces an innovative methodology for the precise detection and verification of micro surface defects found in steel filaments through the application of the Eddy current principle. Permanent magnets are employed to generates a magnetic field with high frequency surrounding a coil of sensor positioned at the filament's output end. The sensor's capacity to detect defects is validated through a meticulous rewinding process, followed by a thorough analysis involving scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). Artificial defects were intentionally introduced into a sample, and their amplitudes were monitored to establish a threshold value. The amplitude signal of these created defect was identified at approximately 10% FSH, which corresponds to a crack depth of about 20 µm. In the experimental production of 182 samples covering 38 km, the defect ratio was notably high, standing at 26.37%. These defects appeared randomly along the length of the samples. The verification results underscore the exceptional precision achieved in the detection of micro surface defects within steel filaments. These defects were primarily characterized by longitudinal scratches and inclusions containing physical tungsten carbide.

Transmission electron microscopy methods were used to analyze the cementite substructure in the head of special-purpose long rails of DT400IK category made of hypereutectoid steel after long-term operation on an experimental track on the Russian Railways ring (the passed tonnage is 187 million tonnes). It is noted that the study of various aspects of cementite – its structure, morphology, chemical composition, crystal lattice defects is relevant. The steel structure is represented by three morphological components at a distance of 10 mm from the sample surface: lamellar perlite, fractured and fragmented perlite. The volume fraction of lamellar perlite in the material is 65%. It is shown that after operation, the cementite plates are bent and separated by ferrite bridges. In the plates of ferrite and cementite, a dislocation substructure is formed which is of chaotically distributed and network type in ferrite and of ordered type in cementite. An increased density of dislocations at ferrite-cementite interfaces compared to the volume of ferrite plates was noted. Two possible mechanisms of deformation transformation of lamellar perlite grains are indicated: fracture of cementite plates and carbon pulling out from the lattice of the carbide phase. It is indicated that in the dissolution of cementite plates, the interfacial boundaries “α-phase-cementite” play an important role. The removal of carbon from cementite plates occurs most intensively near defects in ferrite and cementite. The formed nanosized particles of tertiary cementite are unevenly distributed in the ferrite plates, most of them are observed at the locations of ferrite subgrains and interfacial boundaries. This results in non-uniform diffraction contrast in dark-field images of cementite plates. Nanosized particles of cementite can be taken out into the interlamellar space of pearlite colonies in the process of dislocation slip, or they are formed as a result of deformation decomposition, which is less likely. Fragmentation of ferrite and cementite plates is revealed and azimuthal components of total misorientation angles are estimated. The mechanisms of mass transfer of carbon atoms over interstitial sites, deformation vacancies, dislocation tubes, grain boundaries and fragments are considered. According to all the established patterns of the cementite substructure transformation, a comparison with the results for rails made of hypoeutectoid steel was performed.

This paper mainly used database technology, machine learning, thermodynamic calculation, experimental verification, etc., on integrated computational materials engineering. The interaction between different alloying elements and the strengthening effect of precipitated phases are investigated mainly for martensitic ageing steels. Modelling and parameter optimization were performed by machine learning, and the highest prediction accuracy was 98.58%. Investigated the influence of composition fluctuation on performance and correlation tests to analyze the influence of elements from multiple perspectives. Furthermore, screen out the three-component composition process parameters with composition and performance with high contrast. Thermodynamic calculations studied the effect of alloying element content on the nano-precipitation phase, Laves phase, and austenite in the material. The heat treatment process parameters of the new steel grade were also developed based on the phase diagram. A new type of martensitic ageing steel was prepared by selected vacuum arc melting. The sample with the highest overall mechanical properties had a yield strength of 1887 MPa, a tensile strength of 1907 MPa, and a hardness of 58 HRC. The sample with the highest plasticity had an elongation of 7.8%. The machine learning process for the accelerated design of new ultra-high tensile steels was found to be generalizable and reliable.

In this study, we investigated the inhibiting effect of Dioscorea spp leaf extracts on the corrosion of mild steel in selected media using the weight loss method. The mild steel samples were pre-weighed and immersed in NaOH, NaCl and H₂SO₄ solutions respectively containing the leaf extracts, with the control samples immersed in solutions of the media containing no extract. The samples were allowed to stand for 672 hours, with a set of samples from each environment withdrawn at intervals of 168 hours for corrosion characterization. The results obtained from all the environments indicate that the corrosion rate increased as concentrations of Dioscorea spp increased. Results also confirmed that the extract was an effective and excellent inhibitor in the alkaline, salt, and acidic media. Conclusively it was proven that the higher concentration of Dioscorea spp leaf extracts in the media had the best inhibition characteristic on the mild steel in the selected environments. The results show good potential for application in manufacturing industries. The microstructure analysis of the various test coupons in the test media should be carried out to reveal the influence of adding the leaf extracts to the stimulated media on the grain structure distribution of the mild steel.

Martensitic steels are used at a wide range of strength levels in environments which expose them to hydrogen or water vapor over a large range of partial pressures and temperatures. Hydrogen can cause catastrophic failures under many seemingly benign conditions. The effect of hydrogen on the dimension stability of high strength martensitic steels under such conditions has been poorly understood, and existing models do not seem to adequately account for it. Experiments were conducted to measure the variation in volume due to the uptake of hydrogen of such steels under near-ambient conditions, and the results were compared to theoretical estimates derived from the density of defects acting as hydrogen traps. Based on these results a new model for hydrogen embrittlement was developed. The hydrogen lattice dilation (HLD) model isolates volume expansion as a primary driver of hydrogen embrittlement. It provides and distinguishes two modes of failure acceleration: the fast, brittle, stress-intensity independent cracking under higher static crack loading, and a slower, highly stress-intensity dependent tearing mode at lower stress intensity. The relationship between the two is explained, as is how hydrogen absorption by defects accounts for the crack threshold and crack velocity of each.

The paper contains the results of the 100-hour test campaign of the Additive Manufactured (AM) spare part (retainer – slipper) dedicated for an exact axial piston pump. The material of the retainer-slipper has been identified by using energy dispersive spectroscopy and replaced by other – with similar material properties as the original one. The obtained spare part had been subjected to only one postprocessing type (sandblasting) to analyze the influence of the rough part after the AM process. The whole test campaign has been divided into stages, where after each stage microscopic measurements have been made. During microscopical investigation roughness and geometrical measurements were conducted. The results revealed that it is possible to replace parts in hydraulic pumps with the use of AM. 100-hour test campaign caused about 500% increase in the surface roughness of the pump’s original part which was cooperated with the AM spare retainer-slipper, without any damages to the test system.

This article deals primarily with the problem of determining the cutting force when machining hardened steels. Secondary issues are focused on the evaluation of surface quality on machined samples and the recommendation of cutting conditions. A wide variety of components are used in engineering, the final heat treatment of which is hardening. These components are usually critical in a particular product. The quality of these components determines the correct functioning of the entire technical equipment and ultimately its service life. In our case, these are the core parts of thrust bearings, specifically the rolling elements. The subject of the experiment is machining these components in the hardened state with cubic boron nitride tools and continuous measurement of the cutting force using a dynamometer. The following evaluation assesses the surface quality by both touch and non-touch methods. A structural equation with appropriate constant and exponents was then constructed from the data obtained using the dynamometer.

This article discusses the issue of hardened steel machining. Many components in the engineering industry use hardening as the final heat treatment. These components usually occupy a significant position in a given assembly unit. They guarantee the correct operation of the entire technical equipment in total cooperation with other components. The quality of these components depends on the integrity of their surface. The production of these parts is usually carried out by traditional technological procedures. An example of such a technology is clearly grinding. However, this article discusses the application of other finishing technologies using tool material made of cubic boron nitride (CBN). The technology used is finishing turning with subsequent tumbling technology. The subject of the evaluation is the integrity of the surface. In this part of the experiments, there are mainly individual parameters of surface roughness. Compared components are bearing rings, in this case the inner surface of the housing ring.

The effect of rare earth Pr6O11 on the microstructure and mechanical properties of high-strength steel weld metal was investigated by optical microscopy, scanning electron microscopy and mechanical testing. Three different contents of Pr6O11 were added to the flux-cored wires. The results showed that the addition of 1% Pr6O11 can promote the refinement and spheroidization of inclusions, refine the grains, form acicular ferrites, and significantly improve the toughness of weld metal. The addition of Pr6O11 promoted the formation of rare earth composite inclusions and acicular ferrites in the weld metal, refined the lath microstructure, inhibited the formation of martensite and bainite. The crack formation mode changed from the boundary cracking of the bainite clusters caused by the surface shear stress to the surface shear stress-induced decohesion of inclusion. However, excessive addition of Pr6O11 will reduce the number of inclusion nucleation and deteriorate the mechanical properties. The wire No.2 with 1% Pr6O11 had the good comprehensive mechanical properties, and the corresponding values were 835MPa of tensile strength and 72 J of impact toughness. These findings suggest that the control of Pr6O11 can be an effective way to improve the impact toughness of weld metal.

The effect of Pr6O11 on the microstructure and mechanical properties of high-strength steel weld metal was investigated by optical microscopy, scanning electron microscopy and mechanical testing. Three different contents of Pr6O11 were added to the flux-cored wires. The results demonstrate that the addition of 1% Pr6O11 can promote the refinement and spheroidization of inclusions, refine the grains, form acicular ferrites in the weld metal, and significantly improve the toughness. The addition of Pr6O11 promoted the formation of rare earth composite inclusions and acicular ferrites in the weld metal, refined the lath microstructure, inhibited the formation of martensite and bainite. The crack formation mode changed from the boundary cracking of the bainite clusters caused by the surface shear stress to the surface shear stress-induced decohesion of inclusion. Excessive addition of Pr6O11 will reduce the number of inclusion nucleation and deteriorate the mechanical properties. The wire No.2 with 1% Pr6O11 had the good comprehensive mechanical properties.

This research evaluates the inhibitory effect of L-amino acids (AAs) with different side chain lengths on Fe surface implementing Monte Carlo (MC) simulation. A quantitative and qualitative description of the adsorption behavior of AAs on the iron surface has been carried out. Calculations have shown that the absolute values of the adsorption energy of L-amino acids increase with side chain prolongation; they are also determined by the presence of heteroatoms. AAs from nonpolar and basic groups have the best adsorption ability to the iron surface, which indicates their highest inhibitory efficiency according to the results of MC simulation.

Abstract: This study was aimed to determine the influence of the volume fraction of steel fibers and on fracture parameters of concrete. Fifty notched steel fiber reinforced concrete (SFRC) beams and ordinary concrete beams with dimensions of 100mm×100mm×515mm were cast and tested via three-point bending test. Among them, the type of steel fiber is milling type (MF), and the volume fraction of steel fiber added is 0%, 0.5%, 0.5%, 1.5%, 1.5%, 2%, respectively. The effects of the steel fiber volume fraction (VF) on the critical stress intensity factor (KIC), fracture energy (GF), the deflection at failure(δ0), the critical crack mouth opening displacement (CMODC) and the critical crack tip opening displacement (CTODC)were studied. Through the analysis of test phenomena and test data such as load-deflection (P-δ) curve, load-crack mouth opening displacement (P-CMOD) curve and load-crack tip opening displacement (P-CTOD) curve following conclusions are drawn: With the increase of steel fiber volume fraction, some fracture parameters increase gradually and maintain a certain linear growth. The gain ratio of fracture parameters increases significantly, and the gain effect is obvious. Through this law of growth, the experimental statistical formulas of fracture energy and critical stress intensity factor are summarized.

The effects of build orientation and heat treatment on the crack growth behavior of 316L stainless steel (SS) fabricated via a selective laser melting (SLM) additive manufacturing process were investigated. Significant growth of available research results of additively manufactured metallic parts still needs to be improved. The most important issue connected with properties after additive manufacturing is properties high anisotropy, especially from the fatigue point of view. The research included crack growth behavior of additively manufactured 316L in comparison to conventionally made reference material. Both groups of samples were obtained using precipitation heat treatment. Different build orientation in additively manufactured samples and rolling direction in reference samples were taken into account as well. Precipitation heat treatment of additively manufactured parts allowed to reach similar microstructure and tensile properties to elements conventionally made. The heat treatment positively affected fatigue properties. Additionally, precipitation heat treatment of additively manufactured elements significantly affected the reduction of fatigue cracking velocity and changed the fatigue cracking mechanism.

Background: The main factors to influence on the stroking performance of club head are alloy and spring-like effect. Design the structure of new club face to create the fairway wood which can show best stroking feeling and let driving distance become longer. Purpose: The club face of fairway wood is processed through the iron alloy heating procedure and CNC to innovate the club head with high spring-like effect (characteristic time). Method: (1) Use 455 stainless steel processed by heating and aging treatment, to do the analysis on microstructure and mechanical properties. (2) Through CNC to design seven different patterns for the back of club face, each pattern for three club head. The total amount is twenty-one. (3) Make finished product be test the characteristic time and the ability of strike by the practical measurement. (4) To analyze after the compare between three-way ANOVA and LSD. Results: After 455 stainless steel was heated in procedure S850℃-A550℃, mechanical properties became superior and had the better malleability, it is suitable for developing the club face of high spring-like effect. Before and after grinding among three-way ANOVA (pattern*thickness*place), did not achieve the significant level on the figure of characteristic time. Through two-way ANOVA (pattern*place and thickness*place), showed the significant deviation before and after grinding. After doing the crash test by 45m/s, all the results can reach the higher limited standard. Summary: 455 stainless steel was designed with the different club face’s thicknesses of fairway wood can make spring-like effect achieve high characteristic time. The much thinner club face let the characteristic time perform highly. But there was no obvious effects from the patterns of the back club face.

Plasma Electrolytic Oxidation (PEO) is a surface treatment, similar to anodizing, that produces thick oxide films on the surface of metals. In the present work, PEO coatings were obtained on zinc-aluminized (ZA) carbon steel using as electrolyte a solution containing sodium silicate and potassium hydroxide, and working with high current densities and short treatment times in DC mode. The surface morphology resulted the typical one of PEO layers, with the presence of a lot of pores and micro-cracks. Considering the cross section, the thickness of the coating was strongly influenced by the process parameters, with different dissolution grades of the ZA layer depending on the current density and treatment time. The PEO layer resulted mainly composed by aluminum and zinc oxides and silicates. The corrosion resistance was remarkable increased in the samples with the PEO coating.

Mortarless refractory masonry structures are widely used in the steel industry for the linings of many high-temperature industrial applications including steel ladle. The design and the optimization of these components require accurate numerical models that consider the presence of joints as well as joints closure and opening due to cyclic heating and cooling. The present work reports on the formulation, numerical implementation, validation, and application of homogenized numerical models for simulation of refractory masonry structures with dry joints. The validated constitutive model has been used to simulate a steel ladle and to analyze its transient thermomechanical behavior during a typical thermal cycle of steel ladle. 3D solution domain, enhanced thermal and mechanical boundary conditions have been used. Parametric studies to investigate the impact of joints thickness on the thermomechanical response of the ladle have been carried out. The results clearly demonstrate that the thermomechanical behavior of mortarless masonry is orthotropic nonlinear due to gradual closure and reopening of joints with the increase and decrease of temperature. Also, resulting thermal stresses increase with the increase of temperature and decrease with the increase of joints thickness.

This paper studies the use of zinc oxide nanoparticles (ZnO-NPs) synthesized using an extract of convolvulus leaves and expired ZnCl₂, as an efficient inhibitor for carbon steel corrosion in 1M HCl solution. ZnO-NPs are characterized by Fourier-transform infrared spectrophotometer (FTIR) and UV–Vis analysis. The technique of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) has also been used to investigate the prevention of carbon steel corrosion in 1M HCl. The results showed that the efficiency of restraint increased when the concentration of ZnO-NPs was raised to 91% and that the inhibition efficiency is still high despite its decrease at high temperature, and it acts as a mixed-type inhibitor A sample of carbon steel with the protective inhibitor layer on top was immersed for 20 hours and observed; an increase in the charge transfer resistance (Rct) and stability of the inhibitor was noticed after 6 hours. Adsorption isotherm models demonstrated that the inhibitor adsorption mechanism on the carbon steel surface followed Langmuir, more than Freundlich and Temkin, behavior. The thermodynamic parameters showed that the adsorption process is a mixed adsorption, spontaneous, and exothermic. The results illustrated that the acid medium was a strong inhibitor of carbon steel corrosion. Scanning electron microscope (SEM) showed that the ZnO-NPs formed a good protective film on the carbon steel surface.

Adding steel fibers to concrete improves the capacity in tension-driven failure modes. An example is the shear capacity in steel fiber reinforced concrete (SFRC) beams with longitudinal reinforcement and without shear reinforcement. Since no mechanical models exist that can fully describe the behavior of SFRC beams without shear reinforcement failing in shear, a number of empirical equations have been suggested in the past. This paper compiles the existing empirical equations and code provisions for the prediction of the shear capacity of SFRC beams failing in shear as well as a database of 487 experiments reported in the literature. The experimental shear capacities from the database are then compared to the prediction equations. This comparison shows a large scatter on the ratio of experimental to predicted values. The practice of defining the tensile strength of SFRC based on different experiments internationally makes the comparison difficult. For design purposes, the code prediction methods based on the Eurocode shear expression provide reasonable results (with coefficients of variation on the ratio of tested to predicted results of 27% - 29%). None of the currently available methods properly describe the behavior of SFRC beams failing in shear. As such, this work shows the need for studies that address the different shear-carrying mechanisms in SFRC and its crack kinematics.

The acoustic emission (AE) technique was applied to monitor the pitting corrosion of carbon steel in NaHCO₃ + NaCl solutions. The open circuit potential (OCP) measurement and the corrosion morphology in-situ capturing using optical microscope were conducted during AE monitoring. The corrosion micromorphology was characterized with scanning electron microscope (SEM). The propagation behavior and AE features of natural pitting on carbon steel were investigated. After the performing of signal processing including pre-treatment, shape preserving interpolation and denoising for raw AE waveforms, three types of AE signals can be classified in the correlation diagrams of new waveform parameters. Finally, a 2D pattern recognition method was established to calculate the similarity of different continuous AE graphics, which is quite effective to distinguish the localized corrosion from uniform corrosion.

The aim of this study was to determine the correlation between the external friction angle of cereal kernels and the roughness of a steel friction plate. The experiment was performed on the kernels of five principal cereals: wheat, rye, barley, oats and triticale. Flat seed units composed of three spaced kernels joined by adhesive tape were analyzed in each experimental variant. The external friction angle of flat seed units was determined on 9 steel friction plates with different roughness. Measurements were performed in 3 replications with a photosensor device which registered the external friction angle of cereal kernels. On friction plates with surface roughness Ra=0.36 to Ra=6.72, the average values of the angle of external friction ranged from 17.56° in rye kernels to 34.01° in oat kernels. The greatest similarities in the angle of external friction were observed between wheat and triticale kernels, whereas the greatest differences were noted between barley and oat kernels and between barley and triticale kernels. Friction plates made of ST3S steel should be characterized by the lowest surface roughness to minimize energy consumption during grain processing. The optimal surface roughness of steel friction plates was determined at Ra=0.9.

The aim of this study was to determine the correlation between the external friction angle of cereal kernels and the roughness of a steel friction plate. The experiment was performed on the kernels of five principal cereals: wheat, rye, barley, oats and triticale. Flat seed units composed of three spaced kernels joined by adhesive tape were analyzed in each experimental variant. The external friction angle of flat seed units was determined on 9 steel friction plates with different roughness. Measurements were performed in 3 replications with a photosensor device which registered the external friction angle of cereal kernels. On friction plates with surface roughness Ra=0.36 to Ra=6.72, the average values of the angle of external friction ranged from 17.56° in rye kernels to 34.01° in oat kernels. The greatest similarities in the angle of external friction were observed between wheat and triticale kernels, whereas the greatest differences were noted between barley and oat kernels and between barley and triticale kernels. Friction plates made of ST3S steel should be characterized by the lowest surface roughness to minimize energy consumption during grain processing. The optimal surface roughness of steel friction plates was determined at Ra=0.9.

Concrete-filled steel columns have been extensively used in the world due to having all suitable characteristics of concrete and steel, more ductility, increasing concrete confinement using steel wall, large energy-absorption capacity and appropriate fire behavior. In present paper, concrete-filled steel square columns have been simulated under the influence of blast load using ABAQUS software. These responses will be compared for scaled distances based on the distance to source and weight of explosive material. As result, it can be seen that although concrete deformation has been restricted using steel tube, but inner layer of concrete has been seriously damaged and column displacement will be decreased by increasing scaled distance. We also concluded that concrete-filled steel columns have high ductility and blast resistance.

This study investigates the fabrication and characterization of large-sized ceramic-reinforced TWIP (Twinning-Induced Plasticity) steel matrix composites using the lost foam casting technique. Various ceramic shapes and sizes, including blocky, flaky, rod-like, and granular forms, were evaluated for their suitability as reinforcement materials. The study found that rod-like and granular ceramics exhibited superior structural integrity and formed strong interfacial bonds with the TWIP steel matrix, compared to blocky and flaky ceramics, which suffered from cracking and fragmentation. Detailed microstructural analysis using scanning electron microscopy (SEM) and industrial computerized tomography (CT) revealed the mechanisms influencing the composite formation. The results demonstrated that rod-like and granular ceramics are optimal for reinforcing TWIP steel composites, providing excellent mechanical stability and enhanced performance. This work contributes to the development of advanced composite materials with potential applications in industries requiring high-strength and durable materials.

One of the major sources of catastrophic failures and deterioration of the mechanical properties of metals such as ductility, toughness, and strength, of various engineering components during application is hydrogen embrittlement (HE). It occurs as a result of adsorption, diffusion, and interaction of hydrogen with various metal defects like dislocations, voids, grain boundaries and oxide/matrix interfaces due to its small atomic size. Over the years, extensive effort has been dedicated to understanding hydrogen embrittlement sources, effects, and mechanisms. This research aimed at assessing the tensile properties; toughness, ductility, and susceptibility to hydrogen embrittlement, of cold-finished mild steel. Steel coupons were subjected to electrochemical hydrogen charging in a carefully chosen alkaline solution over a particular time and at various charging current densities. Tensile property tests were conducted immediately post the charging process, and the results were compared with those of uncharged steel. The findings revealed a clear drop in toughness and ductility with increasing hydrogen content. Fracture surfaces were examined to determine failure mechanisms. This evaluation has enabled the prediction of the steel's ability to withstand environments with elevated hydrogen concentrations during practical applications.

Concrete being one of the most frequently used construction materials in the field of construction. The use of concrete has increased with the passage of time as the more and more construction activities are taking place around the globe. Different materials have been added in to the concrete mix to provide the concrete more strength and make it more durable and long lasting. This paper looks into a detailed comparison of concrete strength when casted with in the presence of carbon fibers, steel fibers and glass fibers. The compressive strength for cubes and cylinder with carbon fibers is the highest as compare to steel fibers as well as glass fibers. The compressive strength of concrete is measured on 3 day, 7 day, 14 day and 28 day strength. The compressive strength of cube on 28th day strength is 37.52 MPa for carbon fiber steel, for steel fiber it is 34.22 MPa and with glass fiber the strength is 29.335 MPa whereas the compressive strength of cylinder with carbon fibers the 34.88 MPa, with steel fiber it is 34.22 MPa and with glass fiber the strength is 27.447 MPa. For the cubes the maximum difference between different fibers inducted concrete sample is 28% approximately and for cylinder it is 27%, respectively. On the other hand, the tensile strength of concrete was also gained with the carbon fiber. It was determined that carbon fiber provided about 16% and 12.8% tensile strength higher than glass and steel fibers respectively.

The article presents a new method called slide roller burnishing (SRB) for cold working of cylindrical surfaces on machine tools, implemented with a novel multi-functional device. The machined material was chromium–nickel austenitic stainless steel. The deforming element is a toroidal roller whose axis crosses that of the workpiece. As a result, a relative sliding velocity occurs in the contact zone between the roller and the machined surface. The sliding velocity vector is set using the burnishing device. The theoretical background of SRB is presented. When the two axes are parallel, the well-known roller burnishing (RB) method is implemented. Thus, RB is a special case of SRB. Both processes are realized using the multi-functional burnishing device. The RB process was studied experimentally and optimized according to three criteria, based on the relationship between the surface integrity and operating behavio of the respective component, to achieve three processes: smoothing, hardening and mixed burnishing. Using the optimal RB parameters obtained, the dependence of the results of SRB on the crossing angle was investigated and optimized. A comparative analysis was performed between the optimized RB and SRB processes (respectively for their three variants: smoothing, hardening and mixed) based on geometrical and physical–mechanical characteristics of the surface integrity. The main advantage of the SRB is that it provides smaller height roughness parameters and a higher surface microhardness than RB.

As part of a comprehensive research on eco-friendly processing techniques, the influence of heat treatment environment on the case-hardening of AISI 1018 steel using pulverized cassava leaf was studied. The process was carried out at two different temperatures (850˚C and 950˚C) and under three environmental conditions: (Process 1) the control experiment, was carried out in air only, (Process 2) the medium comprised of pulverized cassava leaves, and (Process 3) the combination of pulverized cassava leaves plus barium carbonate (BaCO3) as an energizer (CBC mixture). Vickers microhardness testing and scanning electron microscopy were used to evaluate the effect of processing environment on case hardening of the steel. As expected, regardless of the processing temperature, Process 1 resulted in little or no hardening of the steel surface. However, notable case hardening occurred when steel specimens were subjected to either Process 2 or Process 3. Furthermore, the inclusion of barium carbonate in Process 3 significantly enhanced the case hardening effectiveness of the cassava leaf as it pertains to rate and maximum hardness achieved. Maximum enhancement was observed at 950oC. After 1 hour, the increase in hardness were 160% and 280%, for Process 2 and Process 3, respectively. Upon increasing the processing time to 5 hours, the increase in hardness due to Process 2 was raised to 254%, while that of Process 3 remained at approximately 280%. Diffusivity of AISI 1018 was calculated using the microhardness data. Diffusivity was highest in Process 2 samples with values of 1.568 x 10-9 m2/s at 850°C and 1.893 x 10-9 m2/s at 950 °C.

Temper embrittlement is a major challenge encountered during the heat treatment of high-performance steels for large forgings. This study investigates the microstructural evolution and mechanical properties of Cr-Ni-Mo-V thick-walled steel, designed for new large forgings with a tensile strength of 1500 MPa, under different tempering cooling rates. Optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD) were employed to analyze the microstructural features. The results demonstrate that the embrittlement occurring during air cooling after tempering is attributed to the concentration of impurities near Fe3C at the grain boundaries. The low-temperature impact toughness at -40°C after water quenching reaches 29 J due to the accelerated cooling rate during tempering, which slows down the diffusion of impurity elements towards the grain boundaries, resulting in reduced concentration and dislocation density, and increased stability of the grain boundaries, thereby enhancing toughness. the bainite content decreases and the interface between martensite and bainite undergoes changes after water quenching during tempering. These alterations influence the crack propagation direction within the two-phase microstructure, further modifying the toughness. These findings contribute to the understanding of temper embrittlement and provide valuable guidance for optimizing heat treatment processes to enhance the performance of high-performance steels in large forgings.

The aim of the paper is to analyze the experimental results of the influence of elevated temperatures and strain rate on the mechanical and structural properties of steel 42CrMo4. The experiments were based on uniaxial tension and compression tests at high temperatures between 700 °C and 1000 °C and strain rates range 0.0018 - 0.1 s^-1. The influence of temperature and strain rate on yield stress, strain to fracture, hardness, structural changes, and fracture characteristics were analyzed. Due to the dynamic recrystallization phenomenon present during the hot tensile tests, an increase in the flow stress is observed at the beginning of the deformation, after which it decreases until the fracture. By increasing the deformation temperature from 700 °C to 1000 °C, the tensile stress decreases significantly for all strain rates. The increase in the strain rate leads to the increase in the tensile stress. In compression tests by increasing the strain rate, the true strain is slightly increasing, but this depends on the temperature. The non-uniformity of deformations obtained at different values of the strain rate and temperature were also analyzed. Analysis by scanning electron microscopy showed the ductile behavior of the material. The degree of damage of the material caused by the presence of cavities increases by increasing the deformation temperature. For all the presented deformation conditions, the presence of the fracture through the ductile fracture mechanism was produced by the localized of necking and the coalescence of microvoids. By increasing the deformation temperature and reducing the strain rate, the fracture behavior of 42CrMo4 steel can be improved.

During the 16th and 17th centuries, Latin American cities adopted earthen construction techniques from European colonizers. As a result, rammed earth (RE) buildings now occupy an important place in Latin America's cultural heritage. However, earthquakes around the world have shown that unreinforced earthen constructions are highly vulnerable. For several years, researchers in northern South America have been proposing a technique that consists of installing confining steel plates (or wooden elements) on both sides of the RE walls forming a grid. This system has shown excellent performance in controlling seismic damage and increasing strength and ductility capacity. Although researchers have tested full-scale one- and two-story earthen walls under pseudo-static loading in the laboratory, and one- and two-story earthen walls at 1:1 and 1:2 scale on uniaxial and biaxial shaking tables, the behavior of a complete reinforced module (one- or two-story) on a shaking table has never been assessed. The present study presents the results of shaking table tests performed on two-story RE modules at 1:4 scale. The experimental data indicate that the retrofit system with confining steel strips was effective in reducing the seismic damage of earthen constructions. In addition, the comparison of the results of the 1:4 scale tests with the 1:2 and 1:1 scale tests previously conducted by the researchers, shows that the acceleration levels of the equivalent prototypes are in the same order of magnitude for the three scales.

Computational Fluid Dynamics (CFD)-based simulation has been the traditional way to model complex industrial systems and processes. One very large and complex industrial system that has benefited from CFD-based simulations is the steel blast furnace. The problem with the CFD-based simulation approach is that it tends to be very slow to generate data. The CFD-only approach may not be fast enough for use in real-time decision-making. To address this issue, in this work, the authors propose the use of machine learning techniques to train and test models based on data generated via CFD simulation. Regression models based on neural networks are compared to tree boosting models. In particular, several areas (tuyere, raceway, and shaft) of the blast furnace are modeled using these approaches. The results of the model training and testing are presented and discussed. The obtained R2 metrics are, in general, very high. The results look promising and may help to improve the efficiency of operator and process engineer decision-making when running a blast furnace.

This study investigated the mechanical properties and fatigue behavior of FH36 steel plate rolled in different directions. By adopting a sequential rolling process in the rolling direction (RD) and transverse direction (TD), the differences in properties between RD and TD were eliminated, resulting in nearly identical tensile properties. The steel plate exhibited a yield strength of approximately 420 MPa, a tensile strength of approximately 506 MPa, and an elongation of approximately 25%. Fatigue tests conducted at room temperature and -60℃ showed a fatigue limit of the maximum stress of 488 MPa at room temperature and 500 MPa at -60℃, indicating improved low-temperature fatigue performance. The fracture surfaces displayed distinct characteristics, such as oblique shearing fractures for high-cycle fatigue and cup-cone shape fractures for low-cycle fatigue. The fatigue source zone were both on the surface of the specimens. As the maximum stress increased, the area of the crack propagation zone for high-cycle fatigue decreased, while the area of the final fracture zone, the number of dimples and the proportion of the LAGBs increased.

Currently, the design of the concrete mix is an important part of the environmental problem. In front of this question, engineers face a major challenge that is addressed in two ways. On one hand, how do they use its component materials to improve its mechanical properties, on the other hand how do they use less polluting materials? Hence, in an environmental and economical view, laboratory tests were carried out on samples of concrete reinforced with smooth steel fiber extracted from the waste tires, in order to assess its impact and to prove its mechanical feasibility for these purposes. Consequently, laboratory results have shown satisfactory improvement in the behavior of concrete under compression loads in the elastic stage and an increase in ductility and toughness of the matrix in the plastic stage. Besides, taking into account the discontinuity and the structural disturbances observed during the loading of samples in the post-elastic state, a method has been proposed to calculate "the effective toughness and toughness Index of fiber concrete; on the other hand, this method has helped to better optimize length and slenderness of fibers for better use of this recycled material