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Thermochemical Transformation and Valorization of Fresh Açaí (Euterpe oleracea, Mart.) Seeds: Waste-to-Energy, Green Gaso-Line, Bio-Adsorbents Characterization, Adsorption of Organic Acids
Douglas Alberto Rocha de Castro
,Simone Patrícia Aranha Da Paz
,Andréia de Andrade Mancio Mota
,Nilton Pereira da Silva
,Renan Marcelo Pereira Silva
,Neyson Martins Mendonça
,Jhuliana da Silva Santana
,Sílvio Alex Pereira da Mota
,Marcelo Costa Santos
,Erika Milene Pinto de Sousa
+6 authors
Posted: 15 July 2026
Process Analysis by Pyrolysis of Fresh Açaí Seeds (Euterpe oleracea, Mart.): Reaction Products Yields, Physicochemical Properties and Chemical Composition
Douglas Alberto Rocha de Castro
,Simone Patrícia Aranha da Paz
,Andréia de Andrade Mâncio Mota
,Nilton Pereira da Silva
,Renan Marcelo Pereira Silva
,Neyson Martins Mendonça
,Williane Azevedo da Silva
,Sílvio Alex Pereira da Mota
,Marcelo Costa Santos
,Erika Milene Pinto de Sousa
+5 authors
In this work, the influence of temperature on the yield of reaction products (bio-oil, gas, H2O, and coke), physicochemical properties (acid value, density, and kinematic viscosity) and chemical composition (hydrocarbons and oxygenates) of bio-oil obtained by pyrolysis of fresh Açaí (Euterpe oleracea Mart.) seeds, a rich lignin-cellulose residue, has been systematically investigated in technical scale. The pyrolysis reaction carried out in a reactor of 143 L, operating in batch mode at 350, 400, and 450 ºC, 1.0 atmosphere. The distillation of bio-oil carried out in a laboratory scale (Vigreux) column according to the boiling temperature range of fossil fuels. The bio-oil and distillation fractions were physical-chemistry characterized for density, kinematic viscosity, acid value and refractive index. The chemical composition and qualitative analysis of chemical functions and/or groups present in bio-oils were determined by GC-MS and FT-IR. The yields of bio-oil, H2O and gas varied between 2.0 and 4.39% (wt.), 26.58 and 29.39% (wt.), and 18.76 and 30.56% (wt.), respectively, increasing with process temperature, while that of solid phase (coke) varied between 35.67 and 52.67% (wt.), decreasing with temperature. The distillation of bio-oil yielded gasoline, light kerosene, and kerosene-like fuel fractions of 16.16, 19.56, and 41.89% (wt.), respectively. The bio-oil densities and kinematic viscosities ranged between 1.0236 and 1.0468 g/cm3, and 57.22 and 68.34 mm²/s, respectively, increasing with temperature, while bio-oil acid values varied between 70.26 and 92.87 mg KOH/g, decreasing with temperature. The densities of gasoline, light kerosene, and kerosene-like fuel fractions were 0.9146, 0.9191, and 0.9816 g/cm3, respectively, while the kinematic viscosities were 1.457, 3.106, and 4.040 mm²/s, respectively, with acid values of 14.94, 61.08, and 64.78 mg KOH/g, increasing with boiling range temperature. The FT-IR analysis identified in bio-oil chemical functions characteristics of hydrocarbons (alkanes, alkenes, and aromatics) and oxygenates (phenols, cresols, ketones, esters, carboxylic acids, aldehydes, and furans). The GC-MS analysis identified hydrocarbons and oxygenates as major chemical compounds in bio-oil, with chemical composition strongly dependent on pyrolysis temperature. The concentration of hydrocarbons in bio-oil varied between 13.505 and 21.542% (area.), increasing with temperature, while that of oxygenates varied between 78.458 and 86.495% (area.), decreasing with pyrolysis temperature. The composition of alkanes, alkenes, and aromatics increase with temperature, showing that higher temperatures favor the formation of hydrocarbons.
In this work, the influence of temperature on the yield of reaction products (bio-oil, gas, H2O, and coke), physicochemical properties (acid value, density, and kinematic viscosity) and chemical composition (hydrocarbons and oxygenates) of bio-oil obtained by pyrolysis of fresh Açaí (Euterpe oleracea Mart.) seeds, a rich lignin-cellulose residue, has been systematically investigated in technical scale. The pyrolysis reaction carried out in a reactor of 143 L, operating in batch mode at 350, 400, and 450 ºC, 1.0 atmosphere. The distillation of bio-oil carried out in a laboratory scale (Vigreux) column according to the boiling temperature range of fossil fuels. The bio-oil and distillation fractions were physical-chemistry characterized for density, kinematic viscosity, acid value and refractive index. The chemical composition and qualitative analysis of chemical functions and/or groups present in bio-oils were determined by GC-MS and FT-IR. The yields of bio-oil, H2O and gas varied between 2.0 and 4.39% (wt.), 26.58 and 29.39% (wt.), and 18.76 and 30.56% (wt.), respectively, increasing with process temperature, while that of solid phase (coke) varied between 35.67 and 52.67% (wt.), decreasing with temperature. The distillation of bio-oil yielded gasoline, light kerosene, and kerosene-like fuel fractions of 16.16, 19.56, and 41.89% (wt.), respectively. The bio-oil densities and kinematic viscosities ranged between 1.0236 and 1.0468 g/cm3, and 57.22 and 68.34 mm²/s, respectively, increasing with temperature, while bio-oil acid values varied between 70.26 and 92.87 mg KOH/g, decreasing with temperature. The densities of gasoline, light kerosene, and kerosene-like fuel fractions were 0.9146, 0.9191, and 0.9816 g/cm3, respectively, while the kinematic viscosities were 1.457, 3.106, and 4.040 mm²/s, respectively, with acid values of 14.94, 61.08, and 64.78 mg KOH/g, increasing with boiling range temperature. The FT-IR analysis identified in bio-oil chemical functions characteristics of hydrocarbons (alkanes, alkenes, and aromatics) and oxygenates (phenols, cresols, ketones, esters, carboxylic acids, aldehydes, and furans). The GC-MS analysis identified hydrocarbons and oxygenates as major chemical compounds in bio-oil, with chemical composition strongly dependent on pyrolysis temperature. The concentration of hydrocarbons in bio-oil varied between 13.505 and 21.542% (area.), increasing with temperature, while that of oxygenates varied between 78.458 and 86.495% (area.), decreasing with pyrolysis temperature. The composition of alkanes, alkenes, and aromatics increase with temperature, showing that higher temperatures favor the formation of hydrocarbons.
Posted: 14 July 2026
Techno-Economic Assessment of a Hybrid Offshore Wind–Tidal System for Green Hydrogen Production and Maritime Export in Morocco
Oumaima El Farnini
,Mourad Trihi
Posted: 14 July 2026
A Dynamic Graph Fusion Model for Ultra-Short-Term Wind Farm Turbine-Level Wind Power Forecasting
Mingyong Cui
,Peiyan Jiang
Posted: 10 July 2026
Experimental Analysis of an Off-Grid Solar PV Cooking Solution for Households in Sub-Saharan Africa
Experimental Analysis of an Off-Grid Solar PV Cooking Solution for Households in Sub-Saharan Africa
Karidewa Nyeinga
,Jimmy Chaciga
,Denis Okello
,Ole Jorgen Nydal
Posted: 10 July 2026
Beyond Net Metering: Design and Performance of a Hybrid Solar Strategy for Cost Efficiency and Security of Supply in Intermittent Urban Grids
Jose David Esquicha-Tejada
,Elias David Esquicha-Larico
,Victor Ricardo Esquicha-Tejada
,Ivan Edgardo Reaño-Soto
,Elizabeth Susan Mamani-Machaca
Posted: 09 July 2026
GAF-CNN Characterization of Interwell Fluid-Flow Connectivity Zones in Fractured Reservoirs
Margarita Mayoral-Villa
,Lizeth Torres
,Estela Mayoral-Villa
,Jaime Klapp
,Enrique Guzmán
Posted: 09 July 2026
A New Concept of Cooling Air in Ship Cogeneration Engines
Hanna Koshlak
,Wen Huabing
,Roman Radchenko
,Andrii Andreev
,Artem Andreev
,Sergii Serogin
,Valerii Pozdieiev
Posted: 08 July 2026
Stage-Dependent Production Behavior and Adaptive Strategy Optimization for Horizontal Wells in Shale Oil Reservoirs, Longdong Area, NW China
Shuwei Ma
,Youan He
,Qinchuan Yang
,Tianjing Huang
,Wenlian Xiao
,Bo Wang
,Shunyan Feng
Posted: 08 July 2026
Investigation of Transient Thermo‐Fluid‐Mass Coupling in a Hydrogen Knudsen Compressor Under Different Thermal Non Equilibrium Processes
Shuhan Chen
,Qianhao Xiao
,Biyuan Tan
,Muyan Cao
Posted: 08 July 2026
Two-Phase Flow Simulation of Multi-Droplets Motion Relevant for Polymer Electrolyte Fuel Cell Gas Channel Using the Volume of Fluid Approach
Dunke Liu
,Dieter Froning
,Ralf Peters
Posted: 08 July 2026
Rethinking Energy in Displacement Contexts
Tim Ronan Britton
,Boris Heinz
Posted: 07 July 2026
Agrivoltaics in Desert Regions: A Focused Review Through the Water-Energy-Food Nexus
Onne A. Iping
,Maja S.L. Lamminga
,Annik Riise
,Rebecca Saive
Posted: 07 July 2026
Energy Analysis of an ICE and Electrolyzer-Based Poly-Generative System with Renewable Energy Storage Supporting the Green Mobility and Building Loads
Giuseppe De Lorenzo
,Piero Bevilacqua
,Roberto Bruno
,Pietropaolo Morrone
,Nicola Briguglio
Posted: 06 July 2026
Vessel-Type Electrical Load Forecasting for Cold Ironing Berths: A Data-Driven Approach
Kypros Tillyros
,Michael Komodromos
,Muhammad Ahmed Qureshi
,Marios Lestas
,Stelios Ioannou
,Zunaib Ali
,Nicholas Christofides
Posted: 06 July 2026
Underground Gas Storage as a Resilience Factor for European Energy Systems During Energy Crises
Tomasz Włodek
,Szymon Kuczyński
,Adam Szurlej
,Mariusz Łaciak
Posted: 06 July 2026
Impact of Scrap and Hydrogen-Based Direct Reduced Iron Ratios on Energy Demand, Emissions, and Oxygen Management in Green Steelmaking
Florentin Eckl
,Ana Moita
,Tânia Sousa
,Rui Costa Neto
Posted: 02 July 2026
Mass Production and Application of 17O-Enriched Water Using Low-Energy Nuclear Reactions
Mou-Yung Liao
,Sih-Li Chen
,Li Xu
,Yu-Hsiang Pan
,Xin-Yuan Wu
,Po-Hsien Wu
,Jong-Fu Yeh
,Yu-Yuan Hsien
,Kuan-Che Lan
,Yi-Tung Chen
+4 authors
Posted: 02 July 2026
EVENT: A Modular, Semi-Automated Methodology for Anomaly Detection and Event Characterization in Thermal Power Plant Operational Data with an Explicit Separation of the Analyst and Expert Roles
Michal Ježek
,Kamil Staněk
,Michaela Veselá
,Jiří Šťastný
Posted: 01 July 2026
Multi-Parameter Coupling of Seismic, Drilling and Logging Data for Fine Prediction of Cambrian Gypsum-Salt Sequences
Yuanyin Zhang
,Zhongkai Bai
,Dayong Li
,Xintao Wang
Posted: 30 June 2026
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