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Materials Science, Surfaces, Coatings & Films; atomic behavior; hard coating; expansion and contraction; force-energy behaviors; surface and interface
Online: 17 August 2018 (03:18:21 CEST)
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Coatings of suitable materials having thickness of few atoms to several microns on the viable substrates are the basic need of society and they attend the regular attention of scientific community working in various fields of science and technology. Decorative and protective coatings, transparent and insulating coatings, coatings of medical implants and surgical instruments, coatings for drug delivery and security purposes, ultra-precision machine coatings and coatings of miscellaneous uses are in the routine demand of research and commercial objectives. Different hard coatings develop with significant composition of differently natured atoms where their force-energy behaviors under recovering of certain transition state provide the provision for electrons (of outer ring) belonging to gas atoms to undertake another clamp of energy knot, in each case, clamping to unfilled states (of outer ring) belonging to solid atoms. Set process conditions switch force-energy behaviors of differently natured atoms as per at the ground surface where they nearly worked oppositely to the original state behaviors. Different natured atoms develop structure in the form of hard coating by locating the ground point between original points where gas atoms increase potential energy under the decreasing levitational force exerting at electron levels while the solid atoms decrease potential energy under the decreasing gravitational force exerting at electron levels. Ti-atom to Ti-atom binding is through the difference of expansion of their lattices when one atom is just landing on the landed atom where the position of nitrogen atoms (dealing double clamping of their electrons) becomes nearly in their interstitial sites. Under suitable set parameters, different nature atoms deposit in the form of coating at substrate surface positioned in the deposition chamber. In random arc-based vapor deposition system, depositing different nature atoms at substrate surface depends on the input power where involved non-conserved energies engaged the non-conservative forces to keep them adhered. Different properties and characteristics of hard coatings emerged as per engaged forces under the set conditions of involved energy. The present study sets new trends not only in the field of films and coatings but also in the diversified class of materials, wherever, atoms recall their roles.
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Materials Science, Surfaces, Coatings & Films; X-ray tomography; cold spray; porosity; stainless steel; three-dimensional imaging
Online: 24 July 2018 (07:50:30 CEST)
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Cold gas-dynamic spray (cold spray) is an evolving coating deposition and restoration technology in which particles are deposited above the sonic speed. This paper presents the non-destructive three-dimensional characterization of cold sprayed stainless steel coating. The visualization of coating morphology and volumetric porosity, and the analyses of porosity size and spatial distributions confirmed that dense stainless steel coating with non-connected, micron-sized gradient porosity is successfully produced by cold spray. The suitability of X-ray tomography for characterizing cold sprayed coatings is assessed.
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Materials Science, Surfaces, Coatings & Films; wearables; human motion monitoring; SWCNT; textiles; machine learning algorithm
Online: 13 July 2018 (10:36:00 CEST)
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Wearable sensors for human physiological monitoring have attracted tremendous interest from researchers in recent years. However, most of the research was only done in simple trials without any significant analytical algorithms. This study provides a way of recognizing human motion by combining textile stretch sensors based on single-walled carbon nanotubes (SWCNTs) and spandex fabric (PET/SP) and machine learning algorithms in a realistic applications. In the study, the performance of the system will be evaluated by identification rate and accuracy of the motion standardized. This research aims to provide a realistic motion sensing wearable products without unnecessary heavy and uncomfortable electronic devices.
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Materials Science, Surfaces, Coatings & Films; Synthesis, Crystal growth, Optical band gap, electrical susceptibility.
Online: 12 July 2018 (15:56:11 CEST)
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A good optical quality crystal of 2-aminopyridine (2AP) metal complex crystals was grown by slow evaporation technique at room temperature. The transparent and defect less bulk size of 2-aminopyridine potassium dihydrogen orthophosphate metal complex crystals have been grown by solution growth method. The molecular structure and morphology of grown crystals was drawn and planes are indexed using WINXMORPH software. A optical absorption spectrum, the UV cut-off wavelength, Band gap (Eg), Reflectance (R), Refractive Index (n), Extinction coefficient (K) and Electrical susceptibility (χc) are calculated for 2AP metal complex crystals.
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Materials Science, Surfaces, Coatings & Films; bionic composites; thin films; mechanical properties
Online: 11 July 2018 (13:10:32 CEST)
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Regenerated silk (RS) is a protein-based “biopolymer” that enables the design of new materials; here, we called “bionic” the process of regenerated silk production by a fermentation-assisted method. Based on yeast’s fermentation, here we produced a living hybrid composite made of regenerated silk nanofibrils and a single-cell fungi, the Saccharomyces cerevisiae yeast extract, by fermentation of such microorganisms at room temperature in a dissolution bath of silkworm silk fibers. The fermentation-based processing enhances the beta-sheet content of the RS, corresponding to a reduction in water permeability and CO2 diffusion through RS/yeast thin films enabling the fabrication of a mechanically robust film that enhances food storage durability. Finally, a transfer print method, which consists of transferring RS and RS/yeast film layers onto a self-adherent paraffin substrate, was used for the realization of heat-responsive wrinkles by exploiting the high thermal expansion of the paraffin substrate that regulates the applied strain, resulting in a switchable coating morphology from the wrinkle-free state to a wrinkled state if the food temperature overcomes a designed threshold. We envision that such efficient and smart coatings can be applied for the realization of smart packaging that, through such a temperature-sensing mechanism, can be used to control food storage conditions.
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Materials Science, Surfaces, Coatings & Films; acetylated nanofibrillated cellulose; acrylic resins ABPE-10; composite films; flexible organic light-emitting device substrate; interpenetrating polymer network
Online: 10 July 2018 (12:38:16 CEST)
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The ANFC/ABPE-10 composite film was prepared by ABPE-10 impregnating into ANFC films under negative pressure. And the composite film had meted high performance FOLED substrate requirement even when ANFC dosage was high for approximately 70%, which was consistent with for low cost efficiency, recyclability, and environmentally friendly. The enhanced properties of ANFC films were mainly because of the nature of ABPE-10 itself and the IPN structure formed between ABPE-10 and ANFC film. The transparency of composite films with different ANFC dosage was significantly increased from 67% to 88% by UV-Vis analysis. The composite film inherited the properties of AFNC, obtaining low CTE characteristics and ductile compact structure. The contact angles of ANFC films increased by 102% from 49.2° to 102.9°after dipping ABPE-10. Additionally, the composite films had outstanding mechanical properties such as tensile strength 173.72 MPa, Young’s modulus 4.06 GPa, and elongation at break 5.81%.
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Materials Science, Surfaces, Coatings & Films; magnetron sputtering; TiN/TiCN/TiC film; Cp-Ti; Ti6Al4V; adhesion; scratch; nanoindentation
Online: 9 July 2018 (10:41:21 CEST)
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Enhancement of mechanical properties by using TiN/TiCN/TiC multilayer thin films deposited on commercially pure cast Titanium (CP-Ti), Ti6Al4V and silicon (Si) substrates via magnetron sputtering technique was investigated in this study. The structural, chemical and mechanical properties of the coatings were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), nanoindentation and scratch test. Results of the XRD analysis showed reflections corresponded to FCC (1 1 1) cubic and polycrystalline structure for TiN/TiCN/TiC films. XPS analysis revealed formation of titanium nitride, titanium carbonitride and titanium carbide in the coatings. According to SEM images, the coatings demonstrated dense cross-sectional morphology and columnar structure as well as good adhesion to the substrate with a thickness of 1.77 μm deposited on silicon (1 0 0). Scratch and nanoindentation test results showed the best mechanical behavior for the coated Ti6Al4V substrate material with the 19.96 GPa hardness and 25 N critical load values, because of its higher hardness and toughness of substrate in compared to Cp-Ti substrate.
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Materials Science, Surfaces, Coatings & Films; membrane distillation; polyvinylidene fluoride; copper oxide nanoparticles; membrane morphology
Online: 6 July 2018 (09:03:09 CEST)
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Membrane distillation techniques appear as one of the most promise alternative to guarantee the availability of potable water in time of scarce of this essential resource. For membrane preparation, polyvinylidene fluoride (PVDF) is preferred due to the easier synthesis procedures with respect to other fluorine based polymers. In this work, copper oxide nanoparticles (CuONPs) at different weight percent (wt.%), embedded in PVDF membranes supported on non-woven polyester fabric (NWPET) were prepared by the phase-inversion method, and characterized by spectroscopy (ATR-FTIR, Raman) and electron microscopy techniques (SEM). The PVDF deposited onto the NWPET was highly composed by its polar -phase (F()= 53 %) which was determined from the ATR-FTIR spectrum. The F() value was kept constant, in the whole range of CuONPs studied (2-10 wt.%) as was determined from the ATR-FTIR spectrum. The absence of signals corresponding to CuONPs in the ATR-FTIR spectra and the appearance of peaks at 297, 360 and 630 cm-1 in the Raman spectra of the membranes suggested that the CuONPs are preferably located in the inner of the membrane but not on its surface. The membrane morphologies were characterized by SEM. From the obtained SEM micrographs, a decrease and increase in the amount of micropores and nanopores, respectively, near to the surface and intercalated in the finger-like layer were observed. As result of the CuONPs addition, the nanopores in the sponge-like layer decrease in size. The values of water contact angle (WCA) measurements showed a trend to decrease from 94° to 80° upon the addition of CuONPs (2-10 wt.%) indicating a diminish in the hydrophobicity degree of the membranes. Apparently, the increase in the amount of nanopores near to the surface decreased the membrane roughness becoming less hydrophobic.
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Materials Science, Surfaces, Coatings & Films; Corrosion Resistance; TIG; Hardness; Wear Resistance; SS 304
Online: 5 July 2018 (16:30:30 CEST)
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The aim of this work is evaluation of corrosion behavior of SS 304 coated through TIG process. In this work, Ti tube cored with graphite powder was applied. Experimental processes were shown that the optimum parameters for coating procedure are voltage of 15V, current density of 120A and the speed of 2.1mm/s. Investigations on corrosion resistance of coating are shown that not only this composite coating can improve the tribological behavior of this type of stainless steel, but also there is an improvement in its deteriorative property. Moreover, it is observed that mass reduction in coating is 5 times lower than the base metal.
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Materials Science, Surfaces, Coatings & Films; Electroplating; Semiconductors; Large area electronics; Characterisation; Solar cells
Online: 26 June 2018 (16:18:18 CEST)
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The attributes of electroplating as a low-cost, simple, scalable and manufacturable semiconductor deposition technique for the fabrication of large-area and nanotechnology-based device applications are discussed. These strengths of electrodeposition are buttressed experimentally using techniques such as X-ray diffraction, Ultraviolet-visible spectroscopy, Scanning electron microscopy, Atomic force microscopy, Energy-dispersive X-ray spectroscopy and photoelectrochemical cell studies. Based on the structural, morphological, compositional optical, and electronic properties evaluated results, it is evident that electroplating possesses the capabilities of producing high-quality semiconductors usable in producing excellent devices. In this paper, we will describe the progress of electroplating technique mainly for the deposition of semiconductor thin film materials, their treatment processes and fabrication of solar cells.
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Materials Science, Surfaces, Coatings & Films; laser cladding; powder flow; 316L stainless steel
Online: 15 June 2018 (11:50:29 CEST)
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Laser Cladding is one of the leading processes within Additive Manufacturing technologies, a fact which has concentrated an important amount of effort on its development. In regard to the latter, the current study aims to summarize the influence of the most relevant process parameters in the laser cladding processing of single and compound volumes (solid forms) made from AISI 316L stainless steel powders and using a coaxial nozzle for deposition. Process speed, applied laser power and powder flow are considered to be the main variables affecting laser cladding in single clads, meanwhile overlap percentage and overlapping strategy become also relevant when dealing with multiple clads. By means of setting appropriate values of each process parameter, the main goal of this paper is to develop a processing window in which a good metallurgical bond between the delivered powder and substrate is obtained, trying simultaneously to maintain processing times in their lowest value possible. Conventional metallography techniques were performed on the cross sections of the laser tracks to measure the effective dimensions of clads for dilution analysis, height and width for the values of overlap between contiguous clads and layers, and also to analyze them for physical defects such as porosity and cracks. The resulting solid piece was 8 mm high at 800 mm/min.
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Materials Science, Surfaces, Coatings & Films; surface removal; nanoscale process; copper thin film; ultrathin water film
Online: 12 June 2018 (06:11:36 CEST)
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The surface planarity and asperity removal behaviors of atomic scale under the ultrathin water environment was studied for the nanoscale process by molecular dynamics simulation. The monolayer atomic removal was achieved under the noncontact and monoatomic layer contact conditions with different water film thickness, and the newly formed surface is relatively smooth and no deformed layer and plastic defects exist. The nanoscale processing is governed by the interatomic adhering action during which the water film transmits the loading forces to Cu surface and thereby result in the migration and removal of surface atoms. With scratching depth ≥ 0.5 nm, the abrasive particle squeezed out the water film from scratching region and scratched Cu surface directly, leading to the surface quality deterioration mainly governed by the plowing action. This study brings the goals of “0 nm planarity, 0 residual defects and 0 polishing pressure” closer to us in the nanoscale process for the development of ultra-precision manufacture technology.
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Materials Science, Surfaces, Coatings & Films; crystallization of thin films; ambient crystallization; room temperature crystallization; magnet induce crystallization; sparking discharge
Online: 7 June 2018 (11:32:14 CEST)
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Grazing incidence X-Ray Diffraction spectroscopy was employed to characterize crystallinity of Iron, Nickel, Copper and Tungsten, prepared by sparking discharge process in presence of 0.4 T magnetic field at ambient temperature 25 °C. Iron thin film preserved crystallinity even after one year of ageing. Nickel exhibit higher crystallinity when sparked in nitrogen gas flow from the one sparked in oxygen. Tungsten was successfully crystalized after just 40 minutes of sparking inside of magnetic field.
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Materials Science, Surfaces, Coatings & Films; cermet coating; aluminia-titania; thermal spraying; cavitation erosion; microstructure; wear model.
Online: 6 June 2018 (12:07:17 CEST)
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This manuscript deals with the cavitation erosion resistance of low-velocity oxy-flame (LVOF) sprayed Al2O3–40%TiO2/NiMoAl cermet coatings, a new functional application of cermet coatings. The aim of the study was to investigate the cavitation erosion mechanism and determine the effect of feedstock powder ratio (Al2O3–TiO2/NiMoAl) of LOVF cermet coatings on their cavitation erosion resistance. As-sprayed coatings were investigated for roughness, porosity, hardness, Young’s modulus. Microstructural characteristics of the cross-section and the surface of as-sprayed coatings were examined by light optical microscopy (LOM) and scanning electron microscopy (SEM) equipped with the EDS and XRD methods. Coatings cavitation tests were conducted in accordance with the ASTM G32 standard with usage of reference samples made from steel, copper and aluminum alloys. Cavitation erosion resistance was measured by weight and volume loss, and normalised cavitation erosion resistance was calculated. Surface eroded due to cavitation was examined in successive time intervals by LOM and SEM-EDS. On the basis of coating properties and cavitation investigations, a phenomenological model of the cavitation erosion of Al2O3–40%TiO2/NiMoAl cermet coatings was elaborated. General relationships between their properties, microstructure and cavitation wear resistance were established. The Al2O3–40%TiO2/NiAlMo composite coating containing 80% of ceramic powder has a higher cavitation erosion resistance than the reference aluminium alloy.
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Materials Science, Surfaces, Coatings & Films; silicon; nanostructures; percolated networks; nanocomposites; thin films; laser processing; phase separation; liquid phase crystallization
Online: 4 June 2018 (08:10:30 CEST)
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Three-dimensional nanocomposite networks consisting of percolated Si nanowires in a SiO2 matrix, Si:SiO2, were studied. The structures were obtained by reactive ion beam sputter deposition of SiOx (x ≈ 0.6) thin films at 450 °C and subsequent crystallization using conventional oven as well as millisecond line focus laser annealing. Rutherford backscattering spectrometry, Raman spectroscopy, X-ray diffraction, cross-sectional and energy-filtered transmission electron microscopy were applied for sample characterization. While oven annealing resulted in a mean Si wire diameter of 10 nm and a crystallinity of 72 % within the Si volume, almost single-domain Si structures with 30 nm in diameter and almost free of amorphous Si were obtained by millisecond laser application. The structural differences are attributed to the different crystallization processes: Conventional oven tempering proceeds via solid state, millisecond laser application via liquid phase crystallization of Si. The 5 orders of magnitude larger diffusion constant in the liquid phase is responsible for the three times larger Si nanostructure diameter. In conclusion, laser annealing offers not only significantly shorter process times but moreover a superior structural order of nano-Si compared to conventional heating.
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Materials Science, Surfaces, Coatings & Films; electron microscopy; energy dispersive X-ray spectroscopy (EDX); electron energy loss spectroscopy (EELS); worn surface analysis; tribofilms
Online: 31 May 2018 (11:27:10 CEST)
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Friction and wear take place on two solid surfaces in sliding contact as a result of the mechanical, thermal and chemical interactions with the participation of environmental species. Electron microscopy and the associated spectroscopic analyses are powerful in probing these mechanisms in spatial resolutions from micro to atomic scale. This article provides a review of the author’s work in the wear and friction mechanisms of PVD hard coatings in which various SEM- and TEM-based microscopic and spectroscopic techniques were employed. Understanding on the failure mechanisms and the origin of self-adaptive friction has been improved to nano-scale. Other related issues are also discussed, such as sample preparation techniques for cross-sectional electron microscopy, energy dispersive X-ray spectroscopy and electron energy loss spectroscopy.
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Materials Science, Surfaces, Coatings & Films; graphene synthesis; silicon carbide; thin film; high-power impulse magnetron sputtering; thermal decomposition, electronic devices
Online: 30 May 2018 (08:22:05 CEST)
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This article reports a novel and efficient method to synthesize graphene by thermal decomposition process. In this method, silicon carbide (SiC) thin films grown on Si(100) wafers with an AlN buffer layer were used as substrates. A CO2 laser beam heating without vacuum or controlled atmosphere was applied for SiC thermal decomposition. The physical, chemical, morphological, and electrical properties of the laser-produced graphene were investigated for different laser energy densities. The results demonstrate that graphene was produced in form of small islands with quality, density and properties depending on the applied laser energy density. Furthermore, the produced graphene exhibits a sheet resistance characteristic similar to graphene grown on mono-crystalline SiC wafer, which indicates its potential for electronic device applications.
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Materials Science, Surfaces, Coatings & Films; direct surface activation; low-temperature vacuum carburization; expanded austenite; supersaturation; acetylene
Online: 30 May 2018 (06:23:47 CEST)
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The effect of the acetylene and hydrogen gases mixture ratios in direct low-temperature vacuum carburization was investigated. The gas ratio is an important parameter for producing the free radicals in the carburization. The free radicals can remove the natural oxide film by the strong reaction of the hydrocarbons, and then thermodynamically activity can be increased. When the gas ratio was below 1, the supersaturation expanded austenite layers were formed on the surface of the AISI 316L stainless steel, which had the maximum carbon solubility up to 11.5 at.% at 743 K, were formed. On the other hand, when the gas ratio was above 1, the carbon concentration of them remained low even if the process time was enough increased to reach the maximum carbon solubility. As a result, the carbon concentration underneath the surface was determined to be highly dependent on the gas mixture ratio of acetylene and hydrogen. In conclusion, it is necessary to restrict the ratio of acetylene and hydrogen gases to total mixture gases to form the expanded austenite layer with the high carbon concentration in the direct low-temperature vacuum carburization.
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Materials Science, Surfaces, Coatings & Films; stone; nanocomposite; protective coating; electrokinetic characterization; Zeta potential; isoelectric point; alkyl alkoxysilane; contact angle; water absorption; surface modification
Online: 8 May 2018 (10:01:28 CEST)
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The characterization of protective coatings applied on natural stones is often a complex task due to the difficulty of identifying and quantifying the various factors contributing to the overall behaviour of the coating-stone system. In particular, linking information about the coating-stone interaction to macroscopic effects in terms of physical behaviour of treated stones can be especially arduous owing to the inherent structural complexity of stone substrates. Electrokinetic analysis based on streaming current measurements, having already proved the ability to sense even minor changes in the chemical composition of different materials surfaces upon treatment, may provide useful insights in view of better understanding the extent of stone surface modification. In particular, involving the interaction of stones with a water-based solution, the streaming current technique could extend the characterization of stone surface to the outermost part of the pore network, which is part of every treatment-induced modification of surface properties. In this work, the effectiveness of streaming current measurements as analytical tool for the characterization of coatings applied on natural stones is assessed by considering different lithotypes and coatings and trying to correlate the results of electrokinetic analysis with the physical behaviour of treated stones, with specific regard to wettability and capillary water absorption.
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Materials Science, Surfaces, Coatings & Films; Centella asiatica extract; gelatin; carboxymethyl cellulose (CMC); antioxidant; functionality properties
Online: 1 May 2018 (11:10:24 CEST)
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This study aimed to characterize the antioxidant, mechanical and physical properties of chicken skin gelatin/CMC/Centella asiatica blended film. The influence of Centella asiatica at 0.3% and 0.7% on antioxidant activities; mechanical properties and physical properties of chicken skin gelatin/CMC/Centella asiatica film were investigated. Characterization of the blended films with 0.7% Centella asiatica extract shows higher antioxidant activities with a total phenolic content of 0.36 mg/g of GAE, DPPH of 89.26%, and reducing power of 0.80 nm compared to 0.3% Centella asiatica extract. The addition of 0.3% of Centella extract provide higher value in tensile strength (5.0 × 10−2 MPa), elongation at break (281%), melting point (131.31 °C), transparency (0.86) but lower UV-light penetration. While the addition of 0.7% Centella extract contribute to higher value in WVP (1.13 × 10−4 g m−1s−1Pa−1) and puncture test (0.06 N). There are no significant differences between functional groups obtained from this blended film as evaluated by FTIR analysis (p > 0.05). Furthermore, XRD analysis showed the addition of extract decrease the crystallinity of film. In conclusion, the incorporation of Centella asiatica extracts on film greatly increased antioxidant levels and improved some of the mechanical and physical properties of the film blends.
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Materials Science, Surfaces, Coatings & Films; Cemented carbides, cermets, iron binders, oxide coating, radiation shielding, nanoindentation, passivation, silicides.
Online: 1 May 2018 (11:04:54 CEST)
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An oxidation resistant coating on cemented tungsten carbides is characterised in this work. Cemented tungsten carbides (cWCs) are routinely used in mining and manufacturing but are also candidate materials for compact radiation shielding in fusion power generation. In both environments, cWCs will suffer significant degradation due to oxidation at relatively low temperatures. In a recent study, a Si-deposition coating method was demonstrated to improve the oxidation resistance of cWCs by up to a factor of 1,000. This work focusses on the growth kinetics, phase composition, and mechanical properties of these coatings. By combining quantitative X-ray diffraction, electron microscopy and nanoindentation, we show that the coating layer has a 20 % higher hardness than the substrate, which was explained on the basis of a previously-unknown presence of a fine distribution of very hard SiC laths. To interpret the coating stability, a coating growth map is developed. The map shows the structure is stable under a broad range of processing temperatures and composite compositions, demonstrating the potential application of these coatings in a variety of nuclear shielding cWCs.
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Materials Science, Surfaces, Coatings & Films; hemp bast fibre; hydrothermal processing; KOH activation; activated carbon
Online: 28 April 2018 (12:29:14 CEST)
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Synthesis of activated carbon from waste biomass is of current interest towards sustainability. The properties of biomass derived activated carbon largely depends on the carbonization process. This study reports preparing extremel high surface area mesoporous activated carbon from hemp bast fibre using hydrothermal processing. Processing in hot water (390-500oC), then activation using KOH and NaOH was investigated at different loading ratios. The described approach was found to enhance the mesoporosity (centered at 3.0 to 4.5 nm) of the hemp derived activated carbon (HAC) from activation (confirmed by BJH pore size distribution and TEM imaging). BET results showed that the product has an extremely high surface area (2425 m2/g) while the surface functional groups (-OH, COOH, C=C/C-C) were confirmed and quantified by XPS and FTIR results. Increasing KOH concentration was found to enhance the surface area with an optimum biochar to KOH ratio of 1:3. The crystallite domain size of HAC was determined using Raman spectroscopy of different wavelengths. The procedure described in this study is an environmentally friendly scalable route for the mass production of activated carbon using hemp fiber.
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Materials Science, Surfaces, Coatings & Films; Cu/Al laminated composites; deformation behavior; interface; microstructure; constitutive equation
Online: 9 April 2018 (07:55:59 CEST)
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In order to understand the hot deformation behavior of novel Cu/Al laminated composites, isothermal hot compression tests were conducted by Gleeble-1500D thermo-mechanical simulator. And the effect of bonding interface, deformation temperature and strain rate on the deformation behavior was analyzed. Results show that under the interface constraint effect, soft Al layer trends to flow synchronously with hard Cu layer. And further microstructure examinations indicate the cooperative deformation capability of Cu/Al composites increases with increasing stain rate and decreasing deformation temperature. Strain hardening exponent, calculated based on the true stress-true strain data, also proves the effect of deformation temperature and strain rate on the cooperative deformation behavior. Meanwhile, unique composites structure allows the Al matrix to exhibit the characteristic of dynamic recrystallization during the hot deformation process. Lastly, strain compensated Arrhenius-type constitutive equation was employed to describe the coupling effect of temperature, strain rate and strain on the flow stress.
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Materials Science, Surfaces, Coatings & Films; volatile renewable resources; microbial infection; secondary plant metabolites; antimicrobial essential oils; biologically-active polymers; plasma-assisted technique
Online: 5 April 2018 (03:32:08 CEST)
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The persistent issue of bacterial and fungal colonization of artificial implantable materials and decreasing efficacy of conventional systemic antibiotics used to treat implant-associated infections has led to the development of a wide range of antifouling and antibacterial strategies. This article reviews one such strategy where inherently biologically active renewable resources, i.e. secondary plant metabolites (SPMs) and their naturally occurring combinations (i.e. essential oils) are used for surface functionalization and synthesis of polymer thin films. With a distinct mode of antibacterial activity, broad spectrum of action and diversity of available chemistries, secondary plant metabolites present an attractive alternative to conventional antibiotics. However, their conversion from liquid to solid phase without significant loss of activity is not trivial. Using select examples, this article shows how plasma techniques provide a sufficiently flexible and chemically reactive environment to enable the synthesis of biologically-active polymer-coatings from volatile renewable resources.
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Materials Science, Surfaces, Coatings & Films; lubricant additives; boundary lubrication; ab initio molecular dynamics; tribochemistry; organophosphorus additives
Online: 30 March 2018 (09:57:07 CEST)
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We performed for the first time to our knowledge fully ab initio molecular dynamics simulations of additive tribochemistry in boundary lubrication conditions. We consider an organophosphourus additive that has been experimentally shown to reduce friction in steel-on-steel sliding contacts thanks to the tribologically-induced formation of an iron phosphide tribofilm. The simulations allow us to observe in real time the molecular dissociation at the sliding iron interface under pressure and to understand the mechanism of iron phosphide formation. We discuss the role played by the mechanical stress by comparing the activation times for molecular dissociation observed in the tribological simulations at different applied loads with that expected on the basis of the dissociation barrier.
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Materials Science, Surfaces, Coatings & Films; accelerated weathering test; color change; poplar OSB; wettability
Online: 29 March 2018 (04:38:44 CEST)
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Oriented strand board (OSB) panels are widely marketed for several applications, from building to packaging. The manufacturing of poplar OSB started recently in Northern Italy representing a relevant innovation in the sector since this product is usually made of coniferous wood. The thermal treatment is widely used for reducing the hygroscopicity of wood-based products, nonetheless it influences the mechanical behavior and degrades the main components of wood, which can affect their finishing. Therefore, it is important to know the properties of the treated surfaces. To this purpose, in this study a lot of OSB panels, made of poplar wood, 15 mm thick and with a density of 590 kg/m3, were thermally treated under vacuum conditions at 190 °C for 2 h and then subjected to accelerated weathering. The changes in color and in wettability due to treatment and accelerated weathering were studied. The thermal treatment determined a significant darkening of the color; the accelerated weathering darkened the untreated surfaces and, on the opposite, lightened the thermo-treated surfaces. The wettability decreased after thermal treatment and increased after weathering, more evidently in treated panels. Overall, this study improves the knowledge about the behavior of the surface of thermo-treated poplar OSB, which is relevant for the industrial coating of this product.
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Materials Science, Surfaces, Coatings & Films; Plasma Electrolytic Oxidation (PEO); Micro Arc Oxidation (MAO); Titanium
Online: 23 March 2018 (15:16:33 CET)
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In the paper, the effect of voltage increasing (from 500 VDC up to 650 VDC) on the structure and chemical composition of porous coating on titanium made by Plasma Electrolytic Oxidation, is presented. In the present paper, phosphates based coatings enriched with calcium, magnesium, zinc and copper in electrolyte based on 1 L of 85% concentrated H3PO4 with additions of Ca(NO3)2·4H2O, and Mg(NO3)2∙6H2O, and Zn(NO3)2∙6H2O, and Cu(NO3)2∙3H2O, are described. The morphology, chemical and phase composition, are evaluated using SEM, EDS, XRD, XPS, GDOES. Based on all the analyses, it was found out that the PEO coatings are porous and enriched with calcium, magnesium, zinc and copper. They consist mainly of the amorphous phase, which is more visible for higher voltages, and it is correlated with the increasing of the total PEO coating thickness (the higher the voltage, the thicker the PEO coating). However, for 650 VDC an amorphous phase and titanium substrate was also recorded with a signal from Ti2P2O7 crystalline, that was not observed for lower voltages. It was also found out that all the obtained coatings may be divided in three sub-layers, i.e. porous, semiporous, and transition one.
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Materials Science, Surfaces, Coatings & Films; laser surface glazing; Ti6Al4V alloy; FEA; thermal model; biomedical application; heating and cooling rates; depth of modified zone; hardness; wear resistance
Online: 19 March 2018 (06:42:48 CET)
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Ti64 alloy plays a significant role in the biomedical applications such as bioimplants for its excellent biocompatibility. Its usage can be further extended by improving the surface hardness and wear resistance. In this respect, laser surface glazing (LSG), an advanced surface modification technique, is very useful which can produce thin hardened surface layer and strong metallurgical bonding. Investigation of temporal and spatial temperature distributions of laser glazed surface of materials are essential because temperature plays significant role in achieving required surface properties. Therefore, in this study, a 3D Finite element analysis has been developed to perform transient thermal analysis of LSG for Ti64 alloy. The model investigated temperature distribution, depth of modified zone and heating and cooling. The results show that the peak temperature is attained 2095 K for 300 W laser power, 0.2 mm beam width and 0.15 ms residence time. Since this temperature is above the melting point (1933 K) of Ti64 alloy, the melt depth is calculated 22.5 μm. Furthermore, from the simulation results, the average heating and cooling rates are estimated 1.19×107 Ks-1 and 2.71×106 Ks-1 respectively which indicate the presence of hard phases in the modified zone.
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Materials Science, Surfaces, Coatings & Films; MCrAlX coatings; Ruthenium; Cerium; Oxidation; Simulation
Online: 14 March 2018 (13:44:22 CET)
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MCrAlX (M: Ni or Co or both, X: minor elements) coatings have been widely used to protect hot components in gas turbines against oxidation and hot corrosion at high temperatures. Understanding the influence of the X-elements on oxidation behaviour is important in the design of durable MCrAlX coatings. In this study, NiCoCrAlX coatings doped with Y+Ru and Ce, respectively, were deposited on Inconel-792 substrate by HVOF. The samples were subjected to isothermal oxidation test in laboratory air at 9000, 1000, 1100 ºC and cyclic oxidation test between 100 ºC and 1100 ºC with 1 hour dwell time at 1100 ºC. It was observed that the coating with Ce shows a much higher oxidation rate than the coating with Y+Ru under both isothermal and cyclic oxidation tests. Besides, β-depletion due to interdiffusion between coating and substrate was significantly lower with Ru addition. Simulations results using both a moving phase boundary model and an established oxidation-diffusion model show that Ru stabilize β grains which reduces β-depletion of coating due to substrate interdiffusion. This paper presents a comprehensive study of the influence of Ce and Ru on oxidation behaviour including investigation of the microstructure evolution influenced by oxidation time at coating surface and coating-substrate interface combining experiment and simulation results.
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Materials Science, Surfaces, Coatings & Films; remanufacture ; laser cladding forming ; stress ; ultrasonic testing ; complex factors coupling
Online: 8 January 2018 (18:42:42 CET)
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Stess in laser cladding coating is an important factor affecting the safe operation of remanufacturing components. Ultrasonic testing has become a hot direction in nondestructive evaluation of stress, because it has the advantages of safety, non-destructive and on-line detection. This paper provides a review of ultrasonic testing for stress in remanufacturing laser cladding coating. It summarizes the recent research outcomes on ultrasonic testing for stress, analyzes mechanism of ultrasonic testing for stress. Remanufacturing laser cladding coating shows typical anisotropic behaviors, the ultrasonic testing signal in laser cladding coating is influenced by many complex factors, such as microstructure, defect, temperature and surface roughness, etc. At present, ultrasonic testing for stress in laser cladding coating can only be done roughly. The paper discusses active mechanism of micro / macro factors to the reliability of stress measurement and the impact of stress measurement to the quality and safety of remanufacturing components. Base on the discussion, the paper proposes strategies for acquisition of nondestructive, rapid and accurate measurement of stress in remanufacturing laser cladding coating.
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Materials Science, Surfaces, Coatings & Films; ion plasma treatment; fatigue loading; fracture; polyurethane; surface morphology
Online: 8 January 2018 (09:48:51 CET)
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Plasma treatment of soft polymers is the promising technique to improve biomedical properties. The response to the deformation of such materials is not yet clear. Soft elastic polyurethane treated with plasma immersion ion implantation is subjected to fatigue uniaxial loading (50000 cycles, frequency – 1 Hz, strain amplitude – 10, 20, 40%). The influence of the strain amplitude and the plasma treatment regime on damage character is discussed. Surface defects are studied in unloaded and stretched states of the material. As a result of fatigue loading, transverse cracks (with closed overlapping edges as well as with open edges deeply propagating into the polymer) and longitudinal folds which are break and bend inward, appear on the surface. Hard edges of cracks cut the soft polymer which is squeezed from the bulk to the surface.
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Materials Science, Surfaces, Coatings & Films; 1,10-Phenanthroline-5,6-diamine; corrosion inhibitor; weight loss method
Online: 8 January 2018 (09:08:46 CET)
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The inhibition impacts of 1,10-Phenanthroline-5,6-diamine (PTDA) on mild steel in 1 M HCl solution were investigated through weight loss method. The inhibition efficiencies of PTDA increase with increase in PTDA concentration at the temperature 303. Weight loss method indicate that PTDA is an excellent inhibitor the inhibition efficiency of 81.5% at the maximum PTDA concentration of 0.5 g/L at the temperature 303K.
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Materials Science, Surfaces, Coatings & Films; polylactic acid; ion implantation; surface property modification
Online: 20 November 2017 (10:11:55 CET)
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We describe our investigations of the surface physicochemical and biological properties of polylactic acid modified by silver, argon and carbon ion implantation to doses of 1 × 1014, 1 × 1015 and 1 × 1016 ion/cm2 at energies of 20 keV (for C and Ar) and 40 keV (for Ag). X-ray analysis shows enhancement of coherent scattering regions and lattice constant increase after ion implantation. Secondary electron mass-spectrometry indicates that Ag concentration in the subsurface layer is less than 80%, but at a depth of 500 nm does not exceed 1–2%. The silver forms metal particles in the subsurface layer rather than making additional chemical bonds with polymer atoms. Atomic force microscopy reveals that the higher the irradiation dose the larger the surface roughness of the samples. Ag-irradiated samples implanted to a dose of 1 × 1016 ions/cm2 have the highest roughness, 190 nm. Our investigation of the cytotoxicity of two individual donor macrophages shows that Ag-implanted polylactic acid has no negative impact on immune system cells and could be a promising material for biomedical application.
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Materials Science, Surfaces, Coatings & Films; PVDF membrane; coagulation bath temperature; polymer molecular weight
Online: 14 November 2017 (10:48:54 CET)
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The global polyvinyldene flouride market is estimated to reach $937,278.5 thousand by 2019, therefore to develop new membranes and gain pioneering ideas, which could create innovative business opportunities, a fundamental knowledge about membrane properties fabricated from recent commercially available PVDF polymers is highly mandatory. In this study, we successfully prepared nine non-woven supported PVDF membranes using a phase inversion precipitation method starting from a 15 wt% PVDF solution in N-methyl-2-pyrrolidone. Various membrane morphologies were obtained by using (1) PVDF polymers with diverse molecular weight in a range from 300.000 Da to 700.000 Da and (2) different temperatures of the coagulation bath (20, 40, and 60 ±2°C) used for the films precipitation. Environmental Scanning Electron Microscope (ESEM) was used for surface and cross-section morphologies characterization. Atomic Force Microscope (AFM) was employed to investigate surface roughness, while Contact Angle (CA) instrument was used for membranes wettability studies. Fourier Transform Infrared Spectroscopy (FTIR) results show that the fabricated membranes are formed by a mixture of TGTG’ chains in α phase crystalline domains and all-TTTT trans planar zigzag chains characteristic to β phase. Moreover, generated results indicate that the phases content and membrane morphologies depend on the polymer molecular weight and conditions used for the membranes preparation. The diversity of fabricated membranes could be applied by the End User Industries for different applications.
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Materials Science, Surfaces, Coatings & Films; expired drug; corrosion inhibitor; potentiodynamic polarization; electrochemical impedance spectroscopy; AFM
Online: 17 October 2017 (04:18:30 CEST)
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Our study aims to implement a strategy to reduce the carbon steel corrosion rate in sulfuric acid solution, using an expired drug with adsorption affinity on the metal surface. To investigate the corrosion protection efficiency of an environmental friendly inhibitor, namely neomycin sulfate (NMS), the electrochemical measurements were applied on carbon steel immersed in 1.0 M H2SO4 solution with and without NMS. The protective layer formed on the steel surface was studied by atomic force microscopy (AFM). The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) showed that the presence of the neomycin sulfate in acid solution leads to the decrease in corrosion current density (icorr) and the increase of polarization resistance (Rp). The mixed mechanism between physical and chemical adsorption of NMS molecules on the steel surface was proposed according to the Langmuir adsorption isotherm. The Atomic Force Microscopy (AFM) indicated that the NMS molecules contributed to a protective layer formation by their adsorption on the steel surface. The AFM parameters such as: root-mean-square roughness (Rq); average roughness (Ra) and maximum peak to valley height (Rp-v) revealed that in the presence of NMS a smoother surface of carbon steel was obtained, compared to the steel surface corroded in sulfuric acid blank solution.
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Materials Science, Surfaces, Coatings & Films; X-ray diffraction imaging; Raman spectroscopy; indentation geometry; plastic deformation; crack generation; plastic deformation strain imaging
Online: 10 October 2017 (11:46:27 CEST)
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The crack geometry and associated strain field around Berkovich and Vickers indents on silicon have been studied by X-ray diffraction imaging and micro-Raman spectroscopy scanning. The techniques are complementary, the Raman data coming from within a few micrometers of the indentation, whereas the X-ray image probes the strain field at a distance of typically tens of micrometers. For example, Raman data provides an explanation for the central contrast feature in the X-ray images of an indent. Strain relaxation from breakout and high temperature annealing are examined and it is demonstrated that millimeter length cracks, similar to those produced by mechanical damage from misaligned handling tools, can be generated in a controlled fashion by indentation within 75 micrometers of the bevel edge of 200mm diameter wafers.
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Materials Science, Surfaces, Coatings & Films; BaxSr1-xTiO3 films; boltzmann modelling; optical band gap; deposition rate; stoichiometric content
Online: 9 October 2017 (05:20:59 CEST)
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Thin films (100-400 nm) of BaxSr1-xTiO3 (0≤x≤1) deposited in RF-magnetron co-sputtering equipment are presented in this research work. The change of deposition rate, gap energy, and resistivity as a function of temperature- applied power change in the growth parameters was studied through the ISO colour-code lines constructed with MATLAB: By analysing the trend information and take into account the influence of the calculated "x" parameter with the Boltzmann profile fitting is proposed a method to allow a controlled set up of the RF-magnetron co-sputtering system and predict the Eg and resistivity values in the BaxSr1-xTiO3 solid solution with 0≤x≤1 for amorphous and crystalline phases. Also, a versatile tool to optimise the deposition process and material properties.
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Materials Science, Surfaces, Coatings & Films; phosphate coating; nitrate; nitrite; Zn-Ni coating; porosity
Online: 27 September 2017 (03:11:33 CEST)
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The aim of this study is to investigate the effect of nitrate and nitrite on the weight, morphology and electrochemical properties of phosphated Zn-%12Ni electrodeposit coatings. In order to investigate phase structure and surface morphology of samples, X-ray diffraction and scanning electron microscopy were employed. In order to measure corrosion resistance behavior of the coats, Potentiostat/Galvanostat test was used. The results showed that nitrite accelerator reduces coating weight and surface porosity simultaneously obtaining by phosphating solution. Furthermore, coatings which were obtained by the nitrite accelerator had a higher corrosion resistance than that of the nitrate accelerator.
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Materials Science, Surfaces, Coatings & Films; CAD/CAM implant abutments; zirconia; surface roughness; soft tissue adhesion; focus variation microscopy
Online: 20 September 2017 (05:28:24 CEST)
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Objective: CAD/CAM generated ceramic implant abutments have recently attracted interest due to their superior customization possibilities and aesthetic advantages. Despite their widespread clinical use, little information is currently available on their surface topography, however. The transmucosal portion of the abutment shoulder is of particular interest, as it ideally supports soft tissue but minimizes mechanical plaque retention. The aim of this in vitro study was to topographically characterize the trans- and subgingival roughness of CAD/CAM zirconia abutments from different manufacturers and compare them with zirconia stock abutments. Material and Method: The surface topography of eight CAD/CAM zirconia implant abutments (tests) and two prefabricated zirconia stock abutments (controls) was determined using focus variation microscopy. Two points on the abutment shoulder were subjected to profilometric examination. 2D and 3D parameters of roughness were obtained and compared. Results: The surface roughness of all the test abutments exceeded the recommended threshold of Ra = 0.2 µm and therefore exhibited an increased risk of mechanical plaque retention. Obvious differences in surface structure were apparent, allowing conclusions to be drawn about the manufacturing method and subsequent reworking processes. Conclusion: Manually reworking the trans- and submucosal area of the investigated CAD/CAM zirconia abutments appears necessary to fulfil the conditions for optimal surface topography. The Sa value as arithmetic mean, taking the maximum height (Sz value) and surface excess (Sdr) into account, is an essential parameter for assessing the surface topography of implant abutments.
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Materials Science, Surfaces, Coatings & Films; interfacial phase; interface model; displacement jump; boundary element method
Online: 15 September 2017 (11:52:35 CEST)
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Interface between matrix/coating or coating/coating in fact represents a very complicate thin interfacial layer. So interface model is necessary to avoid the difficulty on considering such a complicate thin layer in analysis. Classic interface model and cohesive model have been widely used in stress analysis of coating materials, though they cannot represent the effect of very thin interfacial layer accurately. A complete interface model has been deduced from the equivalent constitutive of interfacial layer in this paper. It is found that both classic interface model and cohesive model sometimes cannot give correct analysis results, while the complete interface model can always give a correct result. Moreover, the stress parallel to interface within the interfacial layer can also be analyzed by the new model. Besides, this model can also be used to describe the equivalent properties of interfacial layer, thereby, can provide a quantitative characterizing method for interfacial layer itself.
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Materials Science, Surfaces, Coatings & Films; amorphous oxide semiconductor (AOS); thin film transistor (TFT); nitrogen-doped amorphous InGaZnO (a-IGZO:N); nitrogen-doped amorphous InZnO (a-IZO:N); hetero-structure
Online: 8 September 2017 (09:54:19 CEST)
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The nitrogen-doped amorphous oxide semiconductor (AOS) thin film transistors (TFTs) with double-stacked channel layers (DSCL) were prepared and characterized. The DSCL structure composed of nitrogen-doped amorphous InGaZnO and InZnO films (a-IGZO:N/a-IZO:N or a-IZO:N/a-IGZO:N) made the corresponding TFT devices exhibit quite large field-effect mobility due to the existence of double conduction channels. Especially, the a-IZO:N/a-IGZO:N TFTs showed even better electrical performance (μFE = 15.0 cm2·V-1·s-1, SS = 0.5 V/dec, VTH = 1.5 V, ION/IOFF = 1.1×108) and stability (VTH shift of 1.5, -0.5, and -2.5 V for positive bias-stress, negative bias-stress and thermal stress tests, respectively) than the a-IGZO:N/a-IZO:N TFTs. Based on the X-ray photoemission spectroscopy measurements and energy band analysis, it was assumed that the optimized interface trap states, the less ambient gas adsorption, and the better suppression of oxygen vacancies in the a-IZO:N/a-IGZO:N hetero-structures might be responsible for the better behaviors of the corresponding TFTs.
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Materials Science, Surfaces, Coatings & Films; graphene oxide; porphyrin; nylon 66. coating, electrochemical techniques
Online: 5 September 2017 (05:12:26 CEST)
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Electrochemical impedance (EI) measurements were performed to evaluate the nylon 66/-tetra-(para-aminophenyl) porphyrin (H2T(p-NH2)PP)/graphene oxide (GO) film coating on stainless steel and compared to the nylon/H2T(p-NH2)PP and nylon/GO film samples using 1M H2SO4 as electrolyte. The nylon/H2T(p-NH2)PP and nylon/GO composite films showed high electrochemical impedance in the order of 109 ohm-cm2 and a system controlled by mass transfer, product of a diffusion process at low frequencies with a resistance up to 5 orders of magnitude, indicating the diffusion of protons through the coating and a decrease in the metal dissolution. Otherwise, the nylon/H2T(p-NH2)PP/GO film compound evaluated show good ionic conductivity and electrochemical stability in the acid environment, acting porphyrin as a catalyst to the passage of protons through the film, reducing its electrochemical impedance up to 7 orders of magnitude with respect to the compounds nylon/H2T(p-NH2)PP and nylon/GO. Likewise, good capacitance values are also shown by modifying the concentrations of porphyrin and GO reinforcing materials. These properties are important for technological applications, such as anticorrosion coating for bipolar plates or membrane in a fuel cell type PEM, super-capacitors, etc.
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Materials Science, Surfaces, Coatings & Films; 3-((2-chlorobenzylidene)amino)coumarin; corrosion inhibitor; damage reduction
Online: 7 August 2017 (10:51:42 CEST)
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New corrosion inhibitor derived from coumarin-3-amine namely 3-((2-chlorobenzylidene)amino)coumarin was synthesized and characterized by CHN elemental analysis in addition to Fourier transform infrared and nuclear magnetic resonance techniques. The anti-corrosion ability of 3-((2-chlorobenzylidene)amino)coumarin to inhibit the impacts of corrosion has been demonstrated and damage reduction of the mild steel also. 3-((2-chlorobenzylidene)amino)coumarin, has been employed as a good corrosion inhibitor for mild steel in HCL solution. The efficiency of the inhibition was figured according to weight loss method and it was 74.6%.
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Materials Science, Surfaces, Coatings & Films; corrosion inhibitor; coumarin; resonance
Online: 31 July 2017 (16:37:19 CEST)
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Corrosion inhibitors are the natural or synthetic compounds that have the ability to inhibit the average of corrosion and reduce the damage of the mild steel. Enormous organic inhibitors nowadays employed in the corrosion domain but excluded due to costly. Comparatively cheap, and stable organic compound, namely 3-((4-nitrobenzylidene)amino)coumarin, have been utilized as an excellent corrosion inhibitor in hydrochloric acid for mild steel. The inhibition efficiency has been figured regarding to weight loss method. The corrosion inhibitor was identified according to spectroscopic techniques namely Fourier transform infrared and nuclear magnetic resonance in addition to micro-elemental analysis. Inhibition efficiency for the studied inhibitor was 71.4% that, at the highest studied concentration.
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Materials Science, Surfaces, Coatings & Films; Ionic liquids; dicationic; imidazolium; poly(ethylene glycol); tribochemistry; mechanically stimulated gas emission mass-spectrometry
Online: 19 July 2017 (22:59:19 CEST)
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Dynamic tribochemical processes for dicationic ionic liquid containing a germinal imidazolium cation head groups bridged by a poly(ethylene glycol) and bis(trifluoromethylsulfonyl)imide anion were studied using time-resolved Mechanically Stimulated Gas Emission Mass-Spectrometry (MSGE-MS). In comparison with similar monocationic imidazolium ionic liquids with short alkylic or long polyether side chains the dicationic ionic liquid had lower coefficient of friction on Ti6Al4V alloy and smoother behaviour. The analysis of volatile decomposition products suggested multiple tribochemical reactions in which both anionic and cationic moieties are involved. Tribochemical degradation of cations was mainly through detachment of the side and bridging chains from the imidazolium head groups. Absence of volatile products containing nitrogen implies that imidazole group remained unchanged. Hydrogen and water desorption were attributed to the reactions of hydrogen fluoride being a product of anion degradation with titanium and titanium oxide.
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Materials Science, Surfaces, Coatings & Films; membranes; polymer solution; breath-figures; ordering; capillary cluster
Online: 30 June 2017 (11:05:45 CEST)
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The review is devoted to the physical, chemical and technological aspects of the breath-figures self-assembly process. Main stages of the process and the impact of the polymer architecture and physical parameters of the breath-figures self-assembly on the eventual pattern are covered. The review is focused on the hierarchy of spatial and temporal scales inherent for the breath-figures self-assembly. Multi-scale patterns arising from the process are addressed. The characteristic spatial lateral scales of patterns vary from nanometers to dozens of micrometers. The temporal scales of the process span from micro-seconds to seconds. The qualitative analysis performed in the paper demonstrates that the process is mainly governed by the interfacial phenomena, whereas the impact of inertia and gravity is negligible. Characterization and applications of polymer films manufactured with breath-figures self-assembly are discussed.
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Materials Science, Surfaces, Coatings & Films; Rare earth rich magnesium alloy, Plasma Electrolytic Oxidation, PEO, Microstructure, Fatigue
Online: 25 May 2017 (18:24:45 CEST)
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Rare earth rich magnesium alloys are used in aerospace and automotive fields because of their high specific strength and good castability. However, due to their low corrosion resistance, protective surface treatments, such as conversion coating or electroless plating are necessary, when they have to be used in humid or corrosive environments. The present study was aimed to evaluate the effect of Plasma Electrolytic Oxidation (PEO) and different surface roughness (Ra≈0.8 μm and Ra≈0.3 μm) on the rotating bending fatigue of an innovative Mg alloy, with a high content of Nd (up to 3.1 wt%) and Gd (up to 1.7 wt %). Fatigue tests revealed a 15% decrease in the fatigue strength of the PEO treated alloy (fatigue strength = 88 MPa) with respect to the bare alloy (fatigue strength = 103 MPa). The reduction of fatigue strength was mainly due to the residual tensile stresses induced by the PEO treatment. The effect of surface roughness on the bare alloy was, instead, negligible. The mechanisms of crack initiation were similar in the untreated and PEO treated alloy, with crack nucleation sites located in correspondence of large facets of the cleavage planes.
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Materials Science, Surfaces, Coatings & Films; polyester fabrics; surface modification; sulfuric acid; polypyrrole; deposition; conductivity
Online: 1 May 2017 (08:48:17 CEST)
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A simple and effective surface modification of polyester fabrics with sulfuric acid to improve the interfacial deposition of polypyrrole was presented in our work. A range of sulfuric acid concentrations were analyzed by studying water contact angle. Effect of sulfuric acid modification on the deposition of polypyrrole was investigated by sheet resistance and color depth of fabric samples. Polyester fabrics coated with polypyrrole layer were confirmed by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-Ray diffraction spectra (XRD), Fourier transform infrared spectroscopy (FTIR). XPS showed that sulphur containing functional groups were obviously appeared on the polyester fiber surface after modification, which were advantageous to promote the deposition of polypyrrole onto polyester fabrics. The improved deposition increased electrical conductivity of fabric samples.
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Materials Science, Surfaces, Coatings & Films; electroluminescent; 3D-printing; rapid prototyping; light-emitting fibers; roll-to-roll process
Online: 1 May 2017 (07:25:50 CEST)
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There is a growing interest in fibers supporting optoelectrical properties for textile and wearable display applications. Solution-processed electroluminescent (EL) material systems can be continuously deposited onto fiber or yarn substrates in a roll-to-roll process, making it easy to scale manufacturing. It is important to have precise control over layer deposition to achieve uniform and reliable light emission from these EL fibers. Slot-die coating offers this control and increases the rate of EL fiber production. Here, we report a highly adaptable, cost-effective 3D printing model for developing slot dies used in automatic coating systems. The resulting slot-die coating system enables rapid, reliable production of alternating current powder-based EL (ACPEL) fibers and can be adapted for many material systems. The benefits of this system over dip-coating for roll-to-roll production of EL fibers are demonstrated in this work.
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René De La Barré,
Roland Bartmann,
Silvio Jurk,
Mathias Kuhlmey,
Bernd Duckstein,
Arno Seeboth,
Detlef Lötzsch,
Christian Rabe,
Peter Frach,
Hagen Bartsch,
Matthias Gittner,
Stefan Bruns,
Gerhard Schottner,
Johanna Fischer
Materials Science, Surfaces, Coatings & Films; fast switchable wavelength-selective elements, autostereoscopic image splitter, color filter barrier array, Fabry-Pérot color filter, on-off filter mode
Online: 1 February 2017 (16:52:44 CET)
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A time-sequential working, spatially multiplexed autostereoscopic 3D display design consisting of a fast switchable RGB-color filter array is presented. The wavelength-selective filter barrier emits the light from a display over a larger active area than common autostereoscopic barrier displays. An optical modelling of wavelength-selective barriers has been used for instance to calculate the light ray distribution properties of that arrangement. To find well working display designs, automated searches by simulation and computational evaluation has been proceeded. Wavelength-selective filter barrier arrangements exhibit characteristics different from common barrier displays with similar barrier pitch and ascent. In particular, these constructions show strong angular luminance dependency under barrier inclination specified by correspondent slant angle. In time-sequential implementation it is important to avoid that quick eye or eyelid movement lead to visible color artifacts. In the millisecond regime tunable liquid crystal Fabry-Pérot color filters for the colors red, green and blue are presented. They consist of a sub-micrometer thick nematic layer sandwiched between dielectric mirrors and ITO-electrodes. These cells shall switch narrow-banding light of red, green or blue. An array for a glasses-free 3D display has to be equipped with several thousand switchable filter elements having different color apertures. The newly introduced design is usable as a multi user display as well as a single user system with user adaptive control.
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Materials Science, Surfaces, Coatings & Films; Superhydrophobic; Water-repellent; Chemical etching; Self-cleaning; Anti-fogging
Online: 2 January 2017 (17:27:05 CET)
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Development of the self-cleaning and anti-fogging superhydrophobic coating for aluminum surfaces which is durable in the aggressive conditions has raised tremendous interest in materials science. In this work, by employing chemical etching technique with mixture of hydrochloric and nitric acid, followed by passivation with lauric acid, superhydrophobic aluminum surface was synthesized. The surface morphology analysis reveals the presence of rough microstructures on coated aluminium surface. Superhydrophobicity with water contact angle of 170 ± 3.9° and sliding angle of 4 ± 0.5° is achieved. Surface bounces off the high speed water jet, indicating excellent water-repellent nature of coating. It is also continuously floated on water surface for several weeks, showing excellent buoyancy nature. Additionally, coating maintains its superhydrophobicity after undergoing 100 cycles of adhesive tape peeling test. Its superhydrophobic nature withstands 90° and 180° bending, and repeated folding and de-folding. Coating exhibits the excellent self-cleaning property. In low temperature condensation test, almost no accumulation of water drops on the surface, showing the excellent anti-fogging property of coating. This approach can be applied to any size and shape of aluminium surface and hence has great industrial applications.
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Materials Science, Surfaces, Coatings & Films; chemical phosphate coating; EIS; nano TiO2; TAFEL
Online: 23 December 2016 (10:23:24 CET)
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The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).
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Materials Science, Surfaces, Coatings & Films; CuInSe2 electrodeposition; alkaline doping; current sensing atomic force microscopy
Online: 18 December 2016 (09:48:30 CET)
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The local electrical response in alkaline-doped CuInSe2 films prepared by single step electrodeposition onto Cu substrates was studied by current sensing atomic force microscopy. The CIS films were prepared from single baths containing the dopant ions (Li, Na, K or Cs) and were studied by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and photocurrent response. Increased crystallinity and surface texturing as the ion size increases was observed as well as enhanced photocurrent response in Cs doped CIS. Li and Na doped films have larger conductivity than the undoped film while the K and Cs doped samples display shorter currents and the current images indicate strong charge accumulation in the K and Cs doped films forming surface capacitors. Corrected CAFM IV curves were adjusted with Shockley equation.
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Materials Science, Surfaces, Coatings & Films; Cryogenic treatment; wear resistance; Raman intensity rate
Online: 7 December 2016 (11:13:10 CET)
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This study explored the effects of cryogenic treatment on the microstructure, hardness, and wear-resistance of diamond-like carbon (DLC) by cryogenically treating NAK 80 mold steel coated with DLC. Raman spectroscopy analyzed the structure of the DLC film. Nanoindenter analyzed the hardness and Young’s modulus of the film, and their relationship determined the wear resistance. Wear test assessed the wear rate and friction coefficient of the DLC film. The results showed that cryogenic treatment increased the rate of carbide precipitation and refined the grain structure. Raman spectroscopy indicated that the Raman intensity rate (ID/IG) of treated DLC films was smaller than those without cryogenic treatment. When the sp3 bond increased, the hardness and wear-resistance of the DLC film also increased.
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Materials Science, Surfaces, Coatings & Films; CO2 enhanced capture; SBA-15 habilitation for CO2 sorption; desilication; silanol functionalization; covalent coordinated CO2 deposition
Online: 29 September 2016 (12:38:24 CEST)
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Special preparation of SBA-15 materials has been carried out for creating adsorbents exhibiting an enhanced and selective adsorption toward CO2. This creation starts from an adequate conditioning of the silica surface, via a thermo-alkaline treatment to increase the population of silanol species on it. CO2 adsorption is only reasonably achieved when the SiO2 surface becomes aminated after put in contact with a solution of an amino alkoxide compound in the right solvent. Unfunctionalized and amine-functionalized substrates were characterized through X-ray diffraction, N2 sorption, Raman spectroscopy, electron microscopy, 29Si solid-state NMR, and NH3 thermal programmed desorption. These analyses proved that the thermo-alkaline procedure desilicates the substrate and eliminates the micropores (without affecting the SBA-15 capillaries), present in the original solid. NMR analysis confirms that the hydroxylated solid anchors more amino functionalizing molecules than the unhydroxylated material. The SBA-15 sample subjected to hydroxylation and amino- functionalization displays a high enthalpy of interaction, a reason why this solid is suitable for a strong deposition of CO2 but with the possibility of observing a low-pressure hysteresis phenomenon. Contrastingly, CH4 adsorption on amino-functionalized, hydroxylated SBA-15 substrates becomes almost 5 times lesser than the CO2 one, thus giving proof of their selectivity toward CO2.
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Materials Science, Surfaces, Coatings & Films; carbonyl iron; composites film; external magnetic field; microwave absorption properties
Online: 28 September 2016 (10:32:52 CEST)
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The carbonyl iron particles were dispersed in a polychloroprene rubber (CR) matrix under an external magnetic field for practical application as microwave absorption composites film. The film prepared under external magnetic field with a thickness of only 0.54 mm showed least reflection loss of -15.98 dB and the reflection loss value less than -10.0 dB over the frequency range of 11.4~14.8 GHz. In comparison with the microwave absorption properties of calculation by transmission line theory based on the tested relative complex permittivity and permeability and film prepared by general route without external magnetic field, the film made with external magnetic field exhibited more excellent microwave absorption properties, strongly depending on the increment of anisotropy and rearrangement of magnetic particles. The results indicated the composite film made under external magnetic field have excellent microwave absorption properties, which suggest that the composites thin film could be used as a thinner and lighter microwave absorber.
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Materials Science, Surfaces, Coatings & Films; nano-Au particles; NIPAAm hydrogel; plasma treatment; UV grafting
Online: 28 September 2016 (09:49:23 CEST)
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In this study, a new type of temperature sensor device was developed. The circular electrode of the thermal sensitive sensor was modified with TMT and O2 plasma to enhance the conductivity by forming a thin SnOxCy layer on the electrode surface. The Nano-Au particles were subjected to O2 plasma pretreatment to form peroxide groups on the surface. The thermally sensitive sensor was made by mixing the above-treated Nano-Au particles with N-isopropylacrylamide (NIPAAm) to form solution and then UV-induced grafting polymerization of the NIPAAm-containing solution onto the electrode substrate. The composite hydrogels on the electrode introduce thermo-sensitive polymeric surface films for temperature sensing. Using ambient environment resistance test to measure the resistance, the LCST (lower critical solution temperature) of Nano-Au (MUA) mixed with NIPAAm hydrogel was found to be 32 °C. At ambient temperatures higher than LCST, the electrode resistance decreases linearly.
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Materials Science, Surfaces, Coatings & Films; waterborne polyurethane; adhesive; lignin
Online: 9 August 2016 (14:53:10 CEST)
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A series of waterborne polyurethane (WBPU)/modified lignin amine (MLA) adhesives was prepared using modified lignin amine (MLA) as a chain extender by a prepolymer mixing process. A successful Mannich reaction was achieved during the synthesis of MLA by reacting lignin with bis(3-aminopropyl)amine. Higher tensile strength, Young’s modulus and thermal stability were recorded for WBPU/MLA adhesives with higher MLA contents. The WBPU/MLA adhesive materials were used to coat PVC substrates. The adhesive strength increased with increasing MLA content. More importantly, the MLA also enhanced the WBPU/MLA coating in terms of adhesive strength at moderately high temperatures as well as under natural weather exposed conditions. The adhesive strength was essentially unaffected with 6.48 mole% MLA in the WBPU/MLA coating after exposure to natural weather conditions for 180 days.