According to research, we have learned that Mg and TiO2 are new types material of marine protective coatings. We found that the addition of Mg can improve the performance of Zn-Al coating passivation film, and TiO2 has excellent photocatalytic self-cleaning performance. In this paper Zn-Al pseudo alloy coating was prepared by cold spray technique, and Zn-Al-Mg-TiO2 pseudo alloy composite coating was prepared by adding Mg and nano-TiO2. The effects of Mg and TiO2 to the marine protective properties of Zn-Al coatings were studied by friction and wear test, dynamic salt water corrosion test, electrochemical test, scanning electron microscope(SEM), energy dispersive spectrometer(EDS) and super deep scene 3D microscope. The results show that the addition of Mg and nano-TiO2 not only fills the gap of the coating and improves the density of the coating, but also generates grid-like flocculent corrosion products on the surface of the coating which can gather other corrosion products to improve the density of corrosion products, reduce the friction coefficient and corrosion rate of the coating surface, effectively prevent the invasion of Cl- in solution, and improve the wear and corrosion resistance of the coating.

Electrodeposition of cadmium telluride (CdTe) on fluorine doped tin oxide (FTO) using two electrode configuration was successfully achieved with the main focus on the growth temperature. The electroplating temperatures explored ranges between (55 and 85)℃ for aqueous electrolytes containing 1.5 M cadmium nitrate tetrahydrate (Cd(NO3)2 •4H2O) and 0.002 M tellurium oxide (TeO2). The ensuing CdTe thin-films were characterised using X-ray diffraction (XRD), UV-Vis spectrophotometry, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and photoelectrochemical (PEC) cell measurements. The electroplated CdTe thin-films exhibit a dominant (111) CdTe cubic structure, while the crystallite size increases with the increase in the electroplating temperature. The internal strain, dislocation density and the number of crystallites per unit area decrease with increasing growth temperature. The optical characterization depicts that the CdTe samples show comparable absorbance and a resulting bandgap of 1.51±0.03 eV for as-deposited CdTe layers. A marginal increase in the bandgap and reduction in the absorption edge slope towards lower deposition temperatures were also revealed. The annealed CdTe thin-films showed improvement in energy bandgap as it tends towards 1.45 eV while retaining the aforementioned absorption edge slope trend. Scanning electron microscopy shows that the underlying FTO layers are well covered with increasing grain size observable relative to the increase in the deposition temperature. The energy dispersive X-ray analyses show an alteration in the Te/Cd relative to the deposition temperature. Higher Te ratio with respect to Cd was revealed at deposition temperature lower than 85℃. The photoelectrochemical cell study shows that both p- and n-type CdTe can be electroplated and that deposition temperatures below 85℃ at 1400 mV results in p-type CdTe layers.

Coating of suitable materials having thickness of few atoms to several microns on a substrate is of great interest to the scientific community. Hard coatings develop under the significant composition of suitable-natured atoms where their force-energy behaviors when in certain transition state favour binding. In the binding mechanism of suitable atoms, electron belonging to outer ring filled state of gas-atom undertakes another clamp of energy knot belonging to outer ring unfilled state of solid-atom. Set process conditions develop the binding of different-natured atoms when processing their suitable composition in a system. Atoms of different nature develop structure in the form of hard coating by locating their ground points between the original ones. Here, gas-natured atoms increase the potential energy under decreasing levitational force of electrons, whereas, solid-natured atoms decrease the potential energy under decreasing gravitational force of electrons. In TiN coating, Ti–Ti atoms bind under the difference of expansion of their lattices, called nets of energy knots, where one atom just lands on the already landed atom. An adhered N-atom to a Ti-atom forms its position among four Ti-atoms where N-atom occupies the interstitial site of Ti-atoms. Two oppositely working force-energy behavior atoms deposit in the form of coating at substrate surface as per set conditions of the process. The rate of ejecting (or dissociating) solid-natured atoms depend on the nature of their source (target), process parameters and processing technique. In random arc-based vapor deposition system, depositing differently natured atoms at substrate surface depends on the input power. In addition to intrinsic nature of atoms, different properties and characteristics of coatings emerge as per engaged forces under their involved energy. The present study sets new trends in the field of coatings involving the diversified class of materials and their counterparts.

Ga doped ZnO thin films were formed by the Ultrasonic Chemical Spray Pyrolysis method onto substrates using zinc acetate and gallium (III) nitrate hydrate as precursors. The structural, optical, surface and electrical properties were studied as a function of increasing Ga doping concentration from 0 to 6 at %. Structural studies were shown polycrystalline with a hexagonal crystal structure. The transparency in the visible range was around 85% for thin film deposited using 6 at % Ga doping. With the aim of determining surface images and surface roughness of the films atomic force microscope images were taken. Ga doping of ZnO thin films could markedly decrease surface roughness. Electrical resistivity was determined by four point method. The resistivity 2.0% Ga doped ZnO film was the lowest resistivity of 1.7 cm. In the photoluminescence measurements of the films, existence of UV and defect emission band was observed. As a result, Ga doped ZnO films have advanced properties and promising materials for solar cells.

The process of preparing anti-glare thin films by spray-coating silica sol-gel to soda-lime glass was exclusively and statistically studied in this paper. The effects of sol-gel deliver pressure, air transport pressure, and spray gun displacement speed on the gloss, haze, arithmetic mean surface roughness, and total transmittance light were analyzed. The experimental results indicate that the factors of sol-gel deliver pressure, air transport pressure, and displacement speed exhibit significant effect on the haze, gloss, and Ra. In contrast, the variation of total transmittance light with these three factors are insignificant. Because the anti-glare property is predominantly determined by low gloss and high haze, therefore, we aim to minimize gloss and maximize haze to achieve high anti-glare. Central composite design and response rurface methodology are employed to analyze the main and interaction effects of the three factors through quadratic polynomial equations, which are confirmed by the analysis of variance and R². The response surface methodology predict the lowest gloss and highest haze are 9.2 GU and 57.0%, corresponding to the sol-gel deliver pressure, air-transport pressure, and displacement speed of 250 kPa, 560 kPa, and 140 mm/s, and 340 kPa, 620 kPa, and 20 mm/s, respectively. Comparing the predicted optimal data with the real experimental results validates the applicability of the mathematical model. This study provides an important basis for the subsequent production of anti-glare glass with different specifications to satisfy the market demand.

An effort was made to find a relationship between the ratio of average asperities height and lubricant thickness at the point of contact of rolling element ball bearings, and empirical equations to predict the life for bearings under constant motion. Two independent failure mechanisms were considered, fatigue failure and lubricant failure resulting in seizing of the roller bearing. A theoretical formula for both of these methods was established for the combined probability of failure using both of these failure mechanisms. Fatigue failure was modeled with the empirical equations of Lundberg and Palmgren and standardized in DIN/ISO281. The seizure failure, which this effort sought to investigate, was predicted using Greenwood and Williamson's theories on surface roughness and asperities during lubricated contact. These two mechanisms were combined, and compared to predicted cycle lives of commercial roller bearing, and a clear correlation was demonstrated. This effort demonstrated that the Greenwood-Williams theories on the relative height of asperities versus lubricant film thickness can be used to predict the probability of a lubricant failure resulting in a roller bearing seizing during use.

Many strategies have been developed for the synthesis of silicon carbide (SiC) thin films on silicon (Si) substrates by plasma-based deposition techniques, especially plasma enhanced chemical vapor deposition (PECVD) and magnetron sputtering, due to importance of these materials for microelectronics and related fields. A drawback is the large lattice mismatch between SiC and Si. The insertion of a thin aluminum nitride (AlN) buffer layer between them has been shown useful to overcome this problem. Herein, the high-power impulse magnetron sputtering (HiPIMS) technique was used to grow SiC thin films on AlN/Si substrates. Furthermore, the SiC films were also grown on Si substrates. Comparisons of the structural and chemical properties of SiC thin films grown on the two types of substrates allowed us to evaluate the influence of AlN buffer layer on such properties. The chemical composition and stoichiometry of the samples were investigated by Rutherford backscattering spectrometry (RBS) and Raman spectroscopy, while the crystallinity was characterized by grazing incidence X-ray diffraction (GIXRD). Our set of results evidenced the versatility of HiPIMS technique to produce polycrystalline SiC thin films at near room temperature only varying the discharge power. In addition, this study opens up a feasible route for the deposition of crystalline SiC films with a good structural quality using AlN buffer layer.

Titanium dioxide (TiO2) and aluminum oxide (Al2O3) coatings have been investigated in a wide range of bio-applications due to their biodegradation and biocompatibility properties, that are key parameters for their use in the food packaging and biomedical devices fields. The present study evaluates and compares the electrochemical behavior of the non-coated, commercial resin-coated, TiO2-coated and Al2O3-coated aluminum in commercial beer electrolyte. For this, TiO2 and Al2O3 thin films were deposited on aluminum (Al) substrates using atomic layer deposition (ALD). The evaluation of the corrosion barrier layer properties was performed by linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). In addition, profilometry, grazing incidence X-ray diffractometry (GIXRD), scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FT-IR) analyses were performed to investigate the physical and chemical properties of the pristine and / or corroded samples. TiO2 and Al2O3 films presented an amorphous structure, a morphology that follows Al substrate surface, and a thickness of around 100 nm. Analysis of LSV data showed that ALD coatings promoted a considerable increase in corrosion barrier efficiency being 86.3% for TiO2-coated Al and 80% for Al2O3-coated Al in comparison with 7.1% of commercial resin-coated Al. This is mainly due to the lower electrochemical porosity, 11.4% for TiO2-coated Al and 20.4% for Al2O3-coated Al in comparison with 96% of the resin-coated Al, i.e. an increase of up to twofold in the protection of Al when coated with TiO2 compared to Al2O3 coated. The EIS results allow us to complement the discussions about the reduced corrosion barrier efficiency of the Al2O3 film for beer electrolyte once SEM and FT-IR analyzes did not show drastic changes in both investigated ALD films after the corrosion assays. The above results indicate that ALD TiO2 and Al2O3 films may be a viable alternative to replace the synthetic resin coatings frequently used in aluminum cans of use in the food industry.

Stabilized un-doped Zinc Telluride (ZnTe) thin films were grown on glass substrates under vacuum using closed space sublimation (CSS) technique. A dilute copper nitrate solution (0.1/100 ml) was prepared for copper doping known as ion exchange process in the matrix of ZnTe thin film. The reproducible polycrystalline cubic structure of undoped and Cu doped ZnTe thin films with preferred orientation (111) was confirmed by X-rays diffraction (XRD) technique. Lattice parameter analyses verified the expansion of unit cell volume after incorporation of Cu species into ZnTe thin films samples. The micrographs of scanning electron microscopy (SEM) were used to measure the variation in crystal sizes of samples. The energy dispersive X-rays was used to validate the elemental composition of undoped and Cu-doped ZnTe thin films.  The bandgap energy 2.24 eV of ZnTe thin film decreased after doping Cu to 2.20 eV may be due to the introduction of acceptors states near to valance band.  Optical studies showed that refractive index was measured from 2.18 to 3.24 whereas thicknesses varied between 220 nm to 320 nm for un-doped and Cu doped ZnTe thin film respectively using Swanepoel model. The oxidation states of Zn⁺², Te⁺² and Cu⁺¹ through high resolution X-ray photoelectron spectroscopy (XPS) analyses was observed. The resistivity of thin films changed from ~10⁷ Ω-cm for undoped ZnTe to ~1 Ω-cm for Cu-doped ZnTe thin film, whereas p-type carrier concentration increased from to  respectively. These results predicted that Cu-doped ZnTe thin film can be used as an ideal, efficient and stable intermediate layer between metallic and absorber back contact for the heterojunction thin film solar cell technology.

We prepared poly(3,4-ethylenedioxythiophene) (PEDOT)-coated sulfonated polystyrene copolymer particles as efficient heat-shielding agents, which showed strong near-infrared (NIR) absorption, with high solid contents and good solution stability. The poly(styrene sulfonate -co-styrene) (P(SS-co-St)) copolymers were successfully synthesized via radical solution polymerization, and PEDOT-coated P(SS-co-St) (PEDOT:P(SS-co-St)) was synthesized via Fe⁺-catalyzed oxidative polymerization. PEDOT:P(SS-co-St) was characterized by nuclear magnetic resonance and Fourier transform infrared spectroscopies. The particle size and morphology of PEDOT:P(SS-co-St) were examined using transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The maximum NIR-shielding efficiency of the film was 92.0% with 40% transmittance. The high solution stability of PEDOT:P(SS-co-St) make it an ideal candidate for heat-insulating materials that find application in semi-transparent heat-insulator-coated windows.

In many instances paints interlayers delamination is attributed either to environmental or to application reasons. The composition as well as the structure, including morphology are always given for granted. Extended interlayer delamination was observed on two huge structures (>50000m2 each) causing more than $10 M damages. Overcoating time, UV exposure, Solvent retention and other possible environmental possible causes were considered. However, a careful morphological analysis showed that substantial differences existed in terms of the resin to pigment ratio, the surfactants, the quality of pigments and fillers (dimensions, shape, wettability, reactivity, homogeneity of distribution…) with respect to the sample used to certify suitability of the systems to climatic conditions C4 – C5 (ISO12944). The need to avoid any either voluntary or casual modification in both PVC and the kind and size of pigments to be used should be made evident as well as shown in some paragraph of existing Standards.

X-ray fluorescence is largely employed in the measurement of the thickness of coatings. Despite of its diffusion, the task is not straightforward because of the complex physics involved that results in high dependence on matrix effects. Thickness quantification is in practice accomplished using the Fundamental Parameters approach, adjusted with empirical measurements of standards with known composition and thickness. This approach has two major drawbacks: i) there are no standards for any possible coating and coating architecture and ii) even relying on standards, the quantification of unknown samples requires the precise knowledge of the matrix nature (e.g., in case of multilayer coatings the thickness and the composition of each underlayer). In this work, we describe a semiquantitative approach to coatings thickness measurement based on the construction of calibration curves through simulated XRF spectra built with Monte Carlo simulations.  Simulations have been performed with the freeware software XMI-MSIM.  We have assessed the accuracy of the methods by comparing the results with those obtained by i) XRF thickness determination with standards and ii) FIB-SEM cross-sectioning. Then we evaluated which parameters are critical in this kind of indirect thickness measurements.

Two novel core-shell composites [email protected], [email protected] with SiO2 as the core and terbium organic complex as the shell, were successfully synthesized. The terbium ion was coordinated with organic ligand forming terbium organic complex in the shell layer. The bi-functional organosilane ((HOOC)2C6H2(CONH(CH2)3Si(OCH2CH3)3)2 (abbreviated as PMDA-Si) was used as the first ligand and phen as the second ligand. Furthermore, the silica-modified [email protected]@SiO2, [email protected]@SiO2 core-shell-shell composites were also synthesized by sol–gel chemical route. An amorphous silica shell was coated around the [email protected] and [email protected] core-shell composites. The core-shell and core-shell-shell composites both exhibited excellent luminescence in solid state. The luminescence of core-shell-shell composites was stronger than that of core-shell composites. Meanwhile, an improved luminescence stability property for the core-shell-shell composites was found in the aqueous solution. The core-shell-shell composites exhibited bright luminescence, high stability, long lifetime, and good solubility, which may present potential applications in the field of bio-medical.

The creation of hydrophobic, antifreeze and self-cleaning coatings is currently being pursued by many industrial sectors. The potential applications include the production of liquid and gas separators and filters, new materials, optical and microelectronic devices, and textiles and clothing. These coatings will also have wide application in the construction and automobile industries, shipping, and energy and agricultural sectors. The article proposes a simple approach to the creation of superhydrophobic and antifreeze coatings, by applying powder from multi-walled carbon nanotubes (MW-CNTs) to the sample surface. This method enables combination of the necessary factors: low surface energy, micro–nano-roughness and hierarchical multi-scale. The authors investigated the dependence of the wetting angle of such a surface on the time, type and degree of functionalization. The electrophysical properties of modified MW-CNTs were studied over wide frequency and temperature ranges. This method of obtaining hydrophobic coatings differs from currently available methods in that it is simpler to prepare, is of lower cost and has less environmental impact. The proposed approach can be used to create superhydrophobic coatings that have the additional function of removing static charge and therefore reducing surface heating, and which can be used in the field of energetics for protection against the freezing of wind turbine blades and aircraft surfaces.

ZnO films with Ti atoms incorporated (TZO) in a wide range (0-18 at. %) have been grown by reactive co-sputtering on silicon and glass substrates. The influence of the titanium incorporation in the ZnO matrix on the structural and optical characteristics of the samples has been determined by Rutherford backscattering spectroscopy (RBS), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The results indicate that the samples with low Ti content (< 4 at. %) exhibit the wurtzite-like structure, with the Ti+4 ions substitutionally incorporated into the ZnO structure, forming Ti-doped ZnO films. In particular, very low concentration of Ti (<0.9 at. %) leads to a significant increase of the crystallinity of the TZO samples. Higher Ti contents give rise to a progressive amorphization of the wurtzite-like structure so samples with high Ti content (≥18at. %), displays an amorphous structure indicating the XPS analysis a predominance of Ti-O-Zn mixed oxides. The energy gap, obtained from absorption spectrophotometry, increases from 3.2 eV for pure ZnO films to 3.6 eV for those with the highest Ti content. Ti incorporation in the ZnO samples below 0.9 at. % rises both, the blue (380 nm) and green (550 nm) bands of the photoluminescence (PL) emission, thereby indicating a significant improvement of PL efficiency of the samples.

In order to design effective protective coatings against corrosion, the polyvinyl alcohol (PVA) as compound and composite with silver nanoparticles (nAg/PVA) were electrodeposited on copper surface employing electrochemical techniques such as linear potentiometry and cyclic voltammetry. A new paradigm was used to distinguish the features of coatings, i.e., a Deep Convolutional Neural Network (CNN) was implemented to automatically and hierarchically extract the discriminative characteristics from the information given by optical microscopy images. The main arguments that invoke a CNN implementation in the surface science of materials are the following: artificial intelligence techniques can be successfully applied to learn differences between surface coatings; based on their popularity for image processing, CNN can model images related to the problem of coatings; deep learning is able to extract the features that are distinguishable between material surfaces. To provide an overview of the copper surface, CNN was applied on microscope slides ([email protected]) and inherently learnt distinctive characteristics for each class of surface morphology. The material surface morphology controlled by CNN without the interference of the human factor was successfully conducted, in our study, to extract the similarities/differences between unprotected and protected surfaces to establish the PVA and nAg/PVA performance to retard the copper corrosion.

Metal nanoparticle has been reported to have a high antimicrobial activity against fungi, bacteria, and yeasts. In this study, silver nanoparticles (AgNPs) were synthesized using a chemical reduction method, at 90 oC, and used as an antifungal coating in paper packaging, to control the growth of C. gloeosporioides in cut orchid flowers during shipping. AgNPs were characterized by UV-Vis spectroscopy and atomic force microscope (AFM). The results indicated that the shape of AgNPs was spherical and homogenous with an average size of 47 nm. Twenty and 50 particles per million (ppm) concentration of AgNPs, mixed with starch, were prepared as the coating solution. The paper coated with 50 ppm AgNPs exhibited a significant antifungal activity against C. gloeosporioides compared to 20 ppm AgNPs coating. The AgNPs coated paper had a better water resistance and mechanical properties compared to paper without coating. We observed a significant reduction in the number of anthers, of orchid inflorescences, infected by C. gloeosporioides, when stored in the coated boxes. The current study demonstrates that paper boxes coated with AgNPs are a potential solution to control the infection of C. gloeosporioides in the storage of cut orchid flowers.

Functional ZnO nanostructured surfaces are important in a wide range of applications. Here we report facile fabrication of ZnO surface structures at near room temperature with morphology resembling that of sea urchins, with densely packed, μm-long, tapered nanoneedles radiating from the urchin centre. The ZnO urchin structures were successfully formed on several different substrates with high surface density and coverage, including silicon (Si), glass, polydimethylsiloxane (PDMS), and copper (Cu) sheets, as well as Si seeded with ZnO nanocrystals. Time-resolved SEM revealed growth kinetics of the ZnO nanostructures on Si, capturing the emergence of “infant” urchins at the early growth stage and subsequent progressive increase in the urchin nanoneedle length and density, whilst the spiky nanoneedle morphology was retained throughout the growth. ε-Zn(OH)₂ orthorhombic crystals were also observed alongside the urchins. The crystal structures of the nanostructures at different growth time were confirmed by synchrotron X-ray diffraction measurements. On seeded Si substrates, a two-stage growth mechanism was identified, with a primary growth step of vertically aligned ZnO nanoneedle arrays preceding the secondary growth of the urchins atop the nanoneedle array. The antibacterial, anti-reflective, and wetting functionality of the ZnO urchins—with spiky nanoneedles and at high surface density—on Si substrates was demonstrated. First, bacteria colonisation was found to be suppressed on the surface after 24 h incubation in Gram-negative E. coli culture, in contrast to control substrates (bare Si and Si sputtered with 20 nm ZnO thin film). Secondly, the ZnO urchin surface, exhibiting superhydrophilic property with a water contact angle ~0°, could be rendered superhydrophobic with a simple silanization step, characterised by a water static contact angle θ of 159° ± 1.4° and contact angle hysteresis ∆θ < 7°. The dynamic superhydrophobicity of the surface was demonstrated by bouncing-off of a falling 10 μL water droplet, with a contact time of 15.3 milliseconds (ms), captured using a high-speed camera. Thirdly, it was shown that the presence of dense spiky ZnO nanoneedles and urchins on the seeded Si substrate exhibited a reflectance R < 1% over the wavelength range λ = 200–800 nm. The ZnO urchins with unique morphology via a facile fabrication route at room temperature, readily implementable on different substrates, may be further exploited for multifunctional surfaces and product formulations.

An investigation was made to determine the effects of tungsten surface coating on the coefficient of friction of sliding contact between lubricated steel surfaces. The four-ball test was modified, using a tungsten carbide ball bearing in the spindle to cause sliding contact onto three hard steel ball bearings coated with tungsten disulfide lamellar dry lubricant coating, with a coating of grease lubrication applied to the ball bearings. The coatings, loads, speed, and grease level was varied to best understand the impact of different conditions to the friction coefficient.

Recent advances and demands in clinical applications drive a large amount of research to hydroxyapatite (HA) composite coatings fabricated by plasma spray. However, lower degree of HA crystallinity related to high temperature exposure in plasma spray usually leads to rapid weakening and disintegration of HA coatings and often promotes inflammatory responses in the surrounding tissue. In this research, graphene nanosheet (GNS) reinforced HA coatings were fabricated using plasma spray and followed by heat and hydrothermal treatment (hereafter referred to as thermal treatment). The addition of GNSs resulted in competing phenomenon to influence HA crystallinity viz. increased portion of the partially melted/unmelted zones and higher cooling rate during splat formation, leading to slight increase in HA crystallinity (~46.0-51.3%) in the as-sprayed coating. XRD and FTIR results showed that thermal treatment was capable of inducing significant transformation of amorphous HA to the crystalline form and removing other foreign non-HA compounds through regaining OH- ion, and therefore HA coatings displayed ~45.5-47.1% improvements in HA crystallinity regardless of addition or not of the GNS nanofillers. Microstructure observations revealed that thermal treatment enabled microcrack propagation due to stresses caused by crystallisation and phase transformations, and the residual partially melted/unmelted zone of the thermally treated GNS/HA coating was significantly decreased in size. More importantly, the added GNSs contributed greatly to the significant increase in surface nanoroughness of the thermally treated HA coatings owing to the fact that much more structural defects along with the GNSs mainly induced by thermal treatment might act as nucleation sites to accelerate HA nanoparticle precipitation, which would be beneficial for the improved adhesion strength of the osteoblast cells on the coating surface.

Palm fatty acid distillate (PFAD) is a by-product from the refining of crude palm oil. It comprises mainly of free fatty acids, having around 45% of palmitic and 33% oleic acids as the major components. Ultra-violet (UV) curable urethane acrylate (UA) oligomers could be synthesized from PFAD by the following procedure. A hydroxyl terminated macromer was first prepared by reacting PFAD with a mixture of isophthalic acid, phthalic anhydride, neopentagylcol (NPG) and pentaerythritol. The macromer is then reacted with 2-hydroxylethylacrylate (2HEA) and toluene diisocynate (TDI) to generate a resin containing acrylate side chains for UV curable application. A series of UA resins were prepared by using 15, 25, 45, 55 and 70% of PFAD respectively. The UA resin has Mw in the range of 3200 to 27,000. They could be cured by UV irradiation at intensity of 225mW/cm². Glass transition temperature (T_g) of the cured film was measured by differential scanning calorimeter (DSC), and hardness of the film was determined by pendulum hardness tester according to ASTM4366. The resins were used in wood coating application. All of the cured films showed good adhesion, hardness and chemical resistant for resins using up to 55% PFAD; however the resin at 70% did not cure properly.

Even if silicon alkoxides (especially ethylsilicates) have long been used as consolidants of weathered stone monuments, their physical properties are not ideal. In this study, an innovative procedure for the consolidation of sedimentary rocks was developed that combines the use of organometallic and alkylamine catalysts with the addition of well-defined nanoparticles exhibiting a narrow size distribution centered at ca 10 nm. As a suitable test material, the Pietra di Lecce limestone was selected because of its color and problematic physico-chemical properties, such as rather low hardness. Using the developed procedure, the mechanical and surface properties of the limestone were improved without the unwanted over-consolidation of the surface layers of the stone, and any significant deterioration in the pore size distribution, water vapor permeability or the stone’s appearance. The developed modified ethylsilicates penetrated deeper into the pore structure of the stone than the unmodified ones and increased the hardness of the treated material. The formed xerogels within the stone pores did not crack. Importantly, they did not significantly alter the natural characteristics of the stone.

Heating films were prepared by using poly(methyl methacrylate) and polybutadiene composites containing graphite. The heating film was prepared by casting the as-made polymer composite on PET film. Copper electrodes were attached to both ends of the as-prepared film, and the heating characteristics of the film was analyzed while applying DC voltage. The electrical conductivity and the heating temperature of the heating films depended on the size, the structure, the content and the dispersion characteristics of the graphite in the composite. The electrical resistance of the heating film was controlled to adjust the heating temperature of the film. The relationship between the physical/chemical structure and the heating characteristics of the composite film was studied by measuring the heating temperature as functions of film thickness and resistance by using an infrared thermal imaging camera. The lower the film resistance, the higher the heating temperature of the film. The surface temperature was uniform throughout the film.

A great improvement in food safety and quality controls worldwide has been achieved through the development of biosensing platforms. Foodborne pathogens continue to cause serious outbreaks due to the ingestion of contaminated food. The development of new, sensitive, portable, high-throughput, and automated platforms is a primary objective to allow detection of pathogens and their toxins in foods. Listeria monocytogenes is one common foodborne pathogen. Major outbreaks of listeriosis have been caused by a variety of foods, including milk, soft cheeses, meat, fermented sausages, poultry, seafood and vegetable products. Due to its high sensitivity and easy setup, electrochemical impedance spectroscopy (EIS) has been extensively applied for biosensor fabrication and in particular in the field of microbiology as a mean to detect and quantify foodborne bacteria. Here we describe a miniaturized, portable EIS platform consisting of a microfluidic device with EIS sensors for the detection of L. monocytogenes in milk samples, connected to a portable impedance analyzer for on-field application in clinical and food diagnostics but also for biosecurity purposes. To achieve this goal microelectrodes were functionalized with antibodies specific for L. monocytogenes. The binding and detection of L. monocytogenes was achieved in the range 2.2 x 103 cfu/ml to 1 x 102 with a Limit of Detection (LoD) of 5.5 cfu/ml.

The aim of this work was to prepare bioplastics from renewable and biodegradable molecules. In particular, the bioplastics were produced by using as biopolymer source the grass pea (Lathyrus sativus L.) flour, the proteins of which were structurally modified by means of microbial transglutaminase, an enzyme able to catalyze isopeptide bonds between glutamines and lysines. We analyzed, by means of Zeta-potential, the flour suspension with the aim to choose which pH is more stable for the production of film-forming solutions. The bioplastics were produced by casting and they were characterized according to several technological properties. Optical analysis demonstrated that films cast in the presence of the microbial enzyme are more transparent compared to the untreated ones. Moreover, the visualization by Scanning Electron Microscopy demonstrated that the enzyme-modified films possessed a more compact and homogeneous structure. Furthermore, the presence of microbial transglutaminase allowed to obtain film more mechanically resistant. Finally, digestion experiments under physiological conditions performed in order to obtain information useful for applying these novel biomaterials as carriers in the industrial field, indicated that the enzyme-treated coatings might allow the delivery of bioactive molecules in the gastro-intestinal tract.

In this study, TiO2 nanostructured coatings on Ti-6A-4V alloys were fabricated by two methods: H2O2 oxidation and RF sputtering. In the annealing temperature range of 25 C - 500 C, there were the peaks at 35, 37, 40 and 52 corresponding to {100}, {002}, {101} and {102} crystal planes of hcp structure of α-Ti. At the annealing temperature of 600 C, there was the presence of peaks corresponding to crystal planes of anatase and rutile TiO2. The relative intensities of anatase and rutile phases of the sample fabricated by RF sputtering were 3.62 and 10.25 %, respectively; while those of the sample fabricated by H2O2 oxidation were 21.27 and 3.20 %, respectively (The relative intensity of α-Ti phase was 100 %). The results investigated the peak shift of α-Ti phase in TiO2/Ti-6Al-4V nanostructured coatings fabricated by the two methods which was reasonably explained from the difference in the thermal expansion coefficients of Ti alloy and TiO2 components, as well as the difference in the ratio of anatase to rutile phases.

Oriental lacquer, a natural and renewable polymeric coating, comes from the sap produced by lacquer trees. For practical application, oriental lacquer must be refined to reduce excess water and enhance its quality. In this study, drying oils were blended with oriental lacquer during the refining process to prepare an oil-modified refined lacquer (OMRL). The type and adding amount (0, 10, and 20% by wt.) of drying oils for wood coatings utilization were evaluated. Rhus succedanea oriental lacquer is composed of 54.1% urushiols, 34.3% water, 7.2% plant gum, and 4.4% nitrogenous compounds, and drying oils, including tung oil (TO), linseed oil (LO), and dehydrated castor oil (DCO) were used as materials in this study. The results show that the drying oil acts as a diluent, which reduces the viscosity and enhances the workability and could shorten the touch-free drying time and speed up the hardened drying of the OMRL. The results also indicate that the hardness, mass retention, Tg, tensile strength, abrasion resistance, and lightfastness of OMRL films decrease as more drying oils are blended. Conversely, the bending resistance, elongation at break, impact resistance increase, and particularly, the gloss, is greatly improved through the blending of more drying oils. In conclusion, the LO-modified refined lacquer (RL) has the highest film gloss and the DCO-modified RL has the shortest drying time for coating; otherwise, the film properties are similar among the three types of drying oil.

Carburizing of stainless steels at low temperatures (below 500°C) develops a high content carbon layer, known for its high hardness. X-ray Diffraction investigation indicates that carburization treatment does not impact the structure of substrate; however, introduced carbon causes expansion in the carburized layer through the increase in d-spacing. Characterization of carbon concentration and hardness profiles indicate that carbon content gradually decreases while moving further into the substrate; and the origin of the increased hardness of the expanded layer arises from the super-saturated carbon content, following the solid solution strengthening theory. An area that is not well understood is in regard to the carburized layer’s relation to the substrate and the significance in their differences. Using two grades of stainless steel, AISI 316L and PH 17-4, it was observed that the carburized layer is not a separate layer, but a higher carbon content version of the substrate,

This paper presents computational study of non-stoichiometric nickel oxide in a 32-cell NiO system to model and validate localized heating effects due to nanosecond laser irradiation. Variation in Bandgap of NiO is studied as a function of varying concentrations of native defects ranging from 0 to 25%. It is observed that there is a slight increase in the bandgap from 3.8 eV for stiochiometric NiO to 3.86 eV for Ni-rich NiO and to 3.95 eV for O-rich NiO. It is hence deduced that the experimental laser irradiation leads to simultaneous reduction of Ni²⁺ ions and oxidation of NiO as the number of laser pulses increase. As well, a detailed study on the effects of doping nickel family elements, i.e. palladium (Pd) and platinum (Pt) in stoichiometric NiO is presented. A bandgap decrease from 3.8 eV for pure NiO to 2.5 eV for Pd-doping and 2 eV for Pt-doping for varying doping concentrations ranging from 0–25% Pd, Pt respectively is observed.

The chemical synthesis of silver nanoparticles (Ag-NPs) by using an environmentally friendly methodology for their preparation is presented. Thus, considering that plants possess components that can act as reducing agents and stabilizers in the nanoparticles production, in this work, the synthesis of Ag-NPs by using a solution of grape waste extract as reducing and capping agent is studied. First, the total polyphenols content and reducing sugars in extracts produced at different conditions are characterized. After that, Ag-NPs are synthesized regarding the interaction of Ag ions (from silver nitrate) and the grape waste extract. The effect of temperature, contact time, extract/metal solution volume ratio and pH solution in the synthesis of metal nanoparticles are studied too. Different sets of nanoparticle samples are fully characterized by means of Electron Microscopy coupled with Energy Dispersive X-Ray for qualitative chemical identification. Ag-NPs with an average diameter of 27.7 ± 0.6 nm are selected to proof their suitability for sensing purposes. Thus, screen-printed electrodes modified with Ag-NPs are tested for the simultaneous voltammetric stripping determination of Pb(II) and Cd(II). Results indicate good reproducibility, sensitivity and limits of detection around 2.7 µg L⁻¹ for both metal ions.

Compressive residual stresses in thin films can inhibit crack propagation under normal or sliding contact loading, with associated enhancement of the coating apparent toughness, load bearing capacity and wear resistance. This study investigates the influence of residual stress distributions on the thin film/substrate adhesion using a nanoindenter coupled with scanning electron microscope (SEM) investigations of indentation induced failure modes. Reactive and un-reactive magnetron sputtering with ion plating was used to coat a (100) silicon substrate with aluminum nitride (AlN) with and without an aluminum (Al) adhesion layer. The presence of an Al bond layer gives additional interfacial tensile stress because of the difference in thermal expansion coefficient. Additionally, a different magnitude of residual stresses in the AlN coating was achieved by changing the applied bias voltage onto the substrate. Wafer curvature method and incremental focused ion beam (FIB) milling, combined with high-resolution in situ scanning electron microscopy (SEM) imaging and full field strain analysis by digital image correlation (DIC), were used to measure the average and in-depth stress residual stress distribution in the produced coatings. The adhesion energy was then quantified by using a nanoindentation based model. Results demonstrate that the additional tensile residual stress in the aluminum adhesion layer decrease significantly the coating adhesion, even in presence of a higher compressive stress state in the AlN top-layer. Therefore, the coatings without Al-layer showed better adhesion because of a more homogeneous compressive residual stress in comparison with the coating having Al layer, even though both groups of coatings are produced under same bias voltage. Results are discussed, and some general suggestions are made on the correlation between coating/substrate property combination and the adhesion energy of multilayer stacks. The results suggested that Al bond-layer and inhomogeneous residual stresses affected the adhesion of AlN negatively to a substrate like silicon.

Zirconium based bulk metallic glasses are industrially valuable materials which commercial market grows rapidly. Surface modification of these metallic glasses by high-intensity lasers is relatively new and costly treatment promising great advantages over classical surface processing methods. In this work we perform the case study of surface modification of Zr$_{46}$Cu$_{36.8}$Ag$_{9.2}$Al$_8$ metallic glass by high-intensity millisecond laser beam. Our results suggest chemical deposition of atmospheric oxygen and nitrogen in the laser-melted surface area and its surroundings. Zirconium nitride layer was detected in the middle of laser-irradiated area. Nanocrystals embedded in the amorphous matrix were also formed on the surface. Overall, our findings suggest possibilities for improvement of mechanical characteristics of the studied metallic glass.

We report on the effects of the film morphology on the fluorescence spectra for a thin film including a quinoxaline-based co-polymer (TQ1) and a fullerene derivative (PC₇₀BM). The ratio between the polymer and the fullerene derivative, as well as the processing solvent were varied. Beside the main emission peak at 700 nm in the fluorescence spectra of thin films of this phase-separated blend, a broad emission band is observed with a maximum at 520 - 550 nm. The intensity of this emission band decreases with an increasing degree of mixing in the film and becomes most prominent in thicker films, films with high PC₇₀BM content, and films that were spin-coated from solvents with lower PC₇₀BM solubility. We assign this emission band to aggregated PC₇₀BM.

Within the task of replacing bronze journal bearings with aluminum the processes taking part on friction surface of high-alloyed aluminum alloys working with steel are investigated. The surface and subsurface layer of experimental aluminum bearings were studied before and after tribological tests by scanning electron microscopy including energy-dispersive analysis. Both structural and composition changes in surface layer are shown. It has been revealed that secondary structures are formed on the surface during friction process and include all the chemical elements of the tribosystem which is a consequence of its self-organization. The interaction behavior of some chemical elements of tribological system is discussed.

An effort was made to find a relationship between the predicted tribological conditions at the point of contact of ball bearings, and empirical equations to predict the life for bearings under constant motion. The model was modified to predict the temperature dependence, and compare rapid accelerations and decelerations with empirical extrapolations.

Ecological and environmental damage caused by oil spillage has attracted great attention. Used cigarette filter (CF) has also caused negative environmental consequences. Converting CF to economical materials is a feasible way to address these problems. In this study, we demonstrate a simple method for production of a highly hydrophobic absorbent from CF. CF was modified by using different volume ratios of octadecyltrichlorosilane and methyltrimethoxysilane. When the volume ratio was 3:2, the modified CF had the high water contact angle of 155°. It could selectively and completely absorb silicone oil from an oil-water mixture and showed a good absorption capacity of 38.3 g/g. The absorbed oil was readily and rapidly recovered by simple mechanical squeezing, and it could be reused immediately without any additional treatments. The as-obtained superhydrophobic modified CF retained an absorption capacity of 80% for pump oil and 82% for silicone oil after 10 cycles. The modified CF showed good elasticity in the test of repeated use. The present study provides novel design of a functional material for development of hydrophobic absorbents from used CF via a facile method toward oil spillage cleanup as well as a new recycling method of CF to alleviate the environmental impact.

This research investigated high-temperature corrosion (500 °C) of Cr-Mo steel processed using water jet peening or multifunction cavitation (MFC), and the suitability of such steel for high-temperature boilers and reaction vessels. High-temperature corrosion was induced using an embedment test and a coating test using sulfide-type K2SO4-Na2SO4 powder. To measure the relaxation of the residual stress due to the decrease in work hardening caused by an increase in specimen temperature and the difference in thermal shrinkage between the surface and interior of the specimen, a thermal cycling test was conducted. For the MFC-processed specimen, the oxide film that formed on the surface suppressed mass loss, prevented crack formation, and reduced the compressive residual stress caused by high-temperature corrosion. MFC-processed Cr-Mo steel is thus suitable for a high-temperature corrosion environment.

Protective coatings, in recent years also from nanocomposite formulations, are commonly applied onto architectural stone and stone artefacts, mainly to prevent absorption into the porous stone structure of condensed water and dissolved atmospheric pollutants. While standard protocols are available to assess a coating’s performance, understanding the response of the coating-stone system is a complex task, due to the interplay of various factors determining the overall behaviour. Characterization techniques allowing to correlate the extent and nature of surface modification upon treatment with the most relevant physical properties (i.e water absorption and surface wettability) are thus of great interest. Electrokinetic analysis based on streaming current measurements, thanks to its sensitivity towards even minor changes in the surface chemical composition, may fulfil such requirement. Indeed, by involving the interaction with a testing aqueous electrolyte solution, this technique allows to probe not only the outer surface but also the outermost layer of the pore network, which plays a crucial role in the interaction of the stone with condensed atmospheric water. In this work a correlation was found between the extent of surface modification, as determined by streaming current measurements, surface wettability and capillary water absorption of 6 coating-lithotype combinations (3 lithotypes and 2 nanocomposites).

Cold gas-dynamic spray (cold spray) is an evolving coating deposition and restoration technology in which particles are deposited above the sonic speed. This paper presents the non-destructive three-dimensional characterization of cold sprayed stainless steel coating. The visualization of coating morphology and volumetric porosity, and the analyses of porosity size and spatial distributions confirmed that dense stainless steel coating with non-connected, micron-sized gradient porosity is successfully produced by cold spray. The suitability of X-ray tomography for characterizing cold sprayed coatings is assessed.

Wearable sensors for human physiological monitoring have attracted tremendous interest from researchers in recent years. However, most of the research was only done in simple trials without any significant analytical algorithms. This study provides a way of recognizing human motion by combining textile stretch sensors based on single-walled carbon nanotubes (SWCNTs) and spandex fabric (PET/SP) and machine learning algorithms in a realistic applications. In the study, the performance of the system will be evaluated by identification rate and accuracy of the motion standardized. This research aims to provide a realistic motion sensing wearable products without unnecessary heavy and uncomfortable electronic devices.

A good optical quality crystal of 2-aminopyridine (2AP) metal complex crystals was grown by slow evaporation technique at room temperature. The transparent and defect less bulk size of 2-aminopyridine potassium dihydrogen orthophosphate metal complex crystals have been grown by solution growth method. The molecular structure and morphology of grown crystals was drawn and planes are indexed using WINXMORPH software. A optical absorption spectrum, the UV cut-off wavelength, Band gap (Eg), Reflectance (R), Refractive Index (n), Extinction coefficient (K) and Electrical susceptibility (χc) are calculated for 2AP metal complex crystals.

Regenerated silk (RS) is a protein-based “biopolymer” that enables the design of new materials; here, we called “bionic” the process of regenerated silk production by a fermentation-assisted method. Based on yeast’s fermentation, here we produced a living hybrid composite made of regenerated silk nanofibrils and a single-cell fungi, the Saccharomyces cerevisiae yeast extract, by fermentation of such microorganisms at room temperature in a dissolution bath of silkworm silk fibers. The fermentation-based processing enhances the beta-sheet content of the RS, corresponding to a reduction in water permeability and CO₂ diffusion through RS/yeast thin films enabling the fabrication of a mechanically robust film that enhances food storage durability. Finally, a transfer print method, which consists of transferring RS and RS/yeast film layers onto a self-adherent paraffin substrate, was used for the realization of heat-responsive wrinkles by exploiting the high thermal expansion of the paraffin substrate that regulates the applied strain, resulting in a switchable coating morphology from the wrinkle-free state to a wrinkled state if the food temperature overcomes a designed threshold. We envision that such efficient and smart coatings can be applied for the realization of smart packaging that, through such a temperature-sensing mechanism, can be used to control food storage conditions.

The ANFC/ABPE-10 composite film was prepared by ABPE-10 impregnating into ANFC films under negative pressure. And the composite film had meted high performance FOLED substrate requirement even when ANFC dosage was high for approximately 70%, which was consistent with for low cost efficiency, recyclability, and environmentally friendly. The enhanced properties of ANFC films were mainly because of the nature of ABPE-10 itself and the IPN structure formed between ABPE-10 and ANFC film. The transparency of composite films with different ANFC dosage was significantly increased from 67% to 88% by UV-Vis analysis. The composite film inherited the properties of AFNC, obtaining low CTE characteristics and ductile compact structure. The contact angles of ANFC films increased by 102% from 49.2° to 102.9°after dipping ABPE-10. Additionally, the composite films had outstanding mechanical properties such as tensile strength 173.72 MPa, Young’s modulus 4.06 GPa, and elongation at break 5.81%.

Enhancement of mechanical properties by using TiN/TiCN/TiC multilayer thin films deposited on commercially pure cast Titanium (CP-Ti), Ti6Al4V and silicon (Si) substrates via magnetron sputtering technique was investigated in this study. The structural, chemical and mechanical properties of the coatings were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), nanoindentation and scratch test. Results of the XRD analysis showed reflections corresponded to FCC (1 1 1) cubic and polycrystalline structure for TiN/TiCN/TiC films. XPS analysis revealed formation of titanium nitride, titanium carbonitride and titanium carbide in the coatings. According to SEM images, the coatings demonstrated dense cross-sectional morphology and columnar structure as well as good adhesion to the substrate with a thickness of 1.77 μm deposited on silicon (1 0 0). Scratch and nanoindentation test results showed the best mechanical behavior for the coated Ti6Al4V substrate material with the 19.96 GPa hardness and 25 N critical load values, because of its higher hardness and toughness of substrate in compared to Cp-Ti substrate.

Membrane distillation techniques appear as one of the most promise alternative to guarantee the availability of potable water in time of scarce of this essential resource. For membrane preparation, polyvinylidene fluoride (PVDF) is preferred due to the easier synthesis procedures with respect to other fluorine based polymers. In this work, copper oxide nanoparticles (CuONPs) at different weight percent (wt.%), embedded in PVDF membranes supported on non-woven polyester fabric (NWPET) were prepared by the phase-inversion method, and characterized by spectroscopy (ATR-FTIR, Raman) and electron microscopy techniques (SEM). The PVDF deposited onto the NWPET was highly composed by its polar -phase (F()= 53 %) which was determined from the ATR-FTIR spectrum. The F() value was kept constant, in the whole range of CuONPs studied (2-10 wt.%) as was determined from the ATR-FTIR spectrum. The absence of signals corresponding to CuONPs in the ATR-FTIR spectra and the appearance of peaks at 297, 360 and 630 cm-1 in the Raman spectra of the membranes suggested that the CuONPs are preferably located in the inner of the membrane but not on its surface. The membrane morphologies were characterized by SEM. From the obtained SEM micrographs, a decrease and increase in the amount of micropores and nanopores, respectively, near to the surface and intercalated in the finger-like layer were observed. As result of the CuONPs addition, the nanopores in the sponge-like layer decrease in size. The values of water contact angle (WCA) measurements showed a trend to decrease from 94° to 80° upon the addition of CuONPs (2-10 wt.%) indicating a diminish in the hydrophobicity degree of the membranes. Apparently, the increase in the amount of nanopores near to the surface decreased the membrane roughness becoming less hydrophobic.

The aim of this work is evaluation of corrosion behavior of SS 304 coated through TIG process. In this work, Ti tube cored with graphite powder was applied. Experimental processes were shown that the optimum parameters for coating procedure are voltage of 15V, current density of 120A and the speed of 2.1mm/s. Investigations on corrosion resistance of coating are shown that not only this composite coating can improve the tribological behavior of this type of stainless steel, but also there is an improvement in its deteriorative property. Moreover, it is observed that mass reduction in coating is 5 times lower than the base metal.

The attributes of electroplating as a low-cost, simple, scalable and manufacturable semiconductor deposition technique for the fabrication of large-area and nanotechnology-based device applications are discussed. These strengths of electrodeposition are buttressed experimentally using techniques such as X-ray diffraction, Ultraviolet-visible spectroscopy, Scanning electron microscopy, Atomic force microscopy, Energy-dispersive X-ray spectroscopy and photoelectrochemical cell studies. Based on the structural, morphological, compositional optical, and electronic properties evaluated results, it is evident that electroplating possesses the capabilities of producing high-quality semiconductors usable in producing excellent devices. In this paper, we will describe the progress of electroplating technique mainly for the deposition of semiconductor thin film materials, their treatment processes and fabrication of solar cells.

Laser Cladding is one of the leading processes within Additive Manufacturing technologies, a fact which has concentrated an important amount of effort on its development. In regard to the latter, the current study aims to summarize the influence of the most relevant process parameters in the laser cladding processing of single and compound volumes (solid forms) made from AISI 316L stainless steel powders and using a coaxial nozzle for deposition. Process speed, applied laser power and powder flow are considered to be the main variables affecting laser cladding in single clads, meanwhile overlap percentage and overlapping strategy become also relevant when dealing with multiple clads. By means of setting appropriate values of each process parameter, the main goal of this paper is to develop a processing window in which a good metallurgical bond between the delivered powder and substrate is obtained, trying simultaneously to maintain processing times in their lowest value possible. Conventional metallography techniques were performed on the cross sections of the laser tracks to measure the effective dimensions of clads for dilution analysis, height and width for the values of overlap between contiguous clads and layers, and also to analyze them for physical defects such as porosity and cracks. The resulting solid piece was 8 mm high at 800 mm/min.

The surface planarity and asperity removal behaviors of atomic scale under the ultrathin water environment was studied for the nanoscale process by molecular dynamics simulation. The monolayer atomic removal was achieved under the noncontact and monoatomic layer contact conditions with different water film thickness, and the newly formed surface is relatively smooth and no deformed layer and plastic defects exist. The nanoscale processing is governed by the interatomic adhering action during which the water film transmits the loading forces to Cu surface and thereby result in the migration and removal of surface atoms. With scratching depth ≥ 0.5 nm, the abrasive particle squeezed out the water film from scratching region and scratched Cu surface directly, leading to the surface quality deterioration mainly governed by the plowing action. This study brings the goals of “0 nm planarity, 0 residual defects and 0 polishing pressure” closer to us in the nanoscale process for the development of ultra-precision manufacture technology.

Grazing incidence X-Ray Diffraction spectroscopy was employed to characterize crystallinity of Iron, Nickel, Copper and Tungsten, prepared by sparking discharge process in presence of 0.4 T magnetic field at ambient temperature 25 °C. Iron thin film preserved crystallinity even after one year of ageing. Nickel exhibit higher crystallinity when sparked in nitrogen gas flow from the one sparked in oxygen. Tungsten was successfully crystalized after just 40 minutes of sparking inside of magnetic field.

This manuscript deals with the cavitation erosion resistance of low-velocity oxy-flame (LVOF) sprayed Al2O3–40%TiO2/NiMoAl cermet coatings, a new functional application of cermet coatings. The aim of the study was to investigate the cavitation erosion mechanism and determine the effect of feedstock powder ratio (Al2O3–TiO2/NiMoAl) of LOVF cermet coatings on their cavitation erosion resistance. As-sprayed coatings were investigated for roughness, porosity, hardness, Young’s modulus. Microstructural characteristics of the cross-section and the surface of as-sprayed coatings were examined by light optical microscopy (LOM) and scanning electron microscopy (SEM) equipped with the EDS and XRD methods. Coatings cavitation tests were conducted in accordance with the ASTM G32 standard with usage of reference samples made from steel, copper and aluminum alloys. Cavitation erosion resistance was measured by weight and volume loss, and normalised cavitation erosion resistance was calculated. Surface eroded due to cavitation was examined in successive time intervals by LOM and SEM-EDS. On the basis of coating properties and cavitation investigations, a phenomenological model of the cavitation erosion of Al2O3–40%TiO2/NiMoAl cermet coatings was elaborated. General relationships between their properties, microstructure and cavitation wear resistance were established. The Al2O3–40%TiO2/NiAlMo composite coating containing 80% of ceramic powder has a higher cavitation erosion resistance than the reference aluminium alloy.

Three-dimensional nanocomposite networks consisting of percolated Si nanowires in a SiO₂ matrix, Si:SiO₂, were studied. The structures were obtained by reactive ion beam sputter deposition of SiO_x (x ≈ 0.6) thin films at 450 °C and subsequent crystallization using conventional oven as well as millisecond line focus laser annealing. Rutherford backscattering spectrometry, Raman spectroscopy, X-ray diffraction, cross-sectional and energy-filtered transmission electron microscopy were applied for sample characterization. While oven annealing resulted in a mean Si wire diameter of 10 nm and a crystallinity of 72 % within the Si volume, almost single-domain Si structures with 30 nm in diameter and almost free of amorphous Si were obtained by millisecond laser application. The structural differences are attributed to the different crystallization processes: Conventional oven tempering proceeds via solid state, millisecond laser application via liquid phase crystallization of Si. The 5 orders of magnitude larger diffusion constant in the liquid phase is responsible for the three times larger Si nanostructure diameter. In conclusion, laser annealing offers not only significantly shorter process times but moreover a superior structural order of nano-Si compared to conventional heating.

Friction and wear take place on two solid surfaces in sliding contact as a result of the mechanical, thermal and chemical interactions with the participation of environmental species. Electron microscopy and the associated spectroscopic analyses are powerful in probing these mechanisms in spatial resolutions from micro to atomic scale. This article provides a review of the author’s work in the wear and friction mechanisms of PVD hard coatings in which various SEM- and TEM-based microscopic and spectroscopic techniques were employed. Understanding on the failure mechanisms and the origin of self-adaptive friction has been improved to nano-scale. Other related issues are also discussed, such as sample preparation techniques for cross-sectional electron microscopy, energy dispersive X-ray spectroscopy and electron energy loss spectroscopy.

This article reports a novel and efficient method to synthesize graphene by thermal decomposition process. In this method, silicon carbide (SiC) thin films grown on Si(100) wafers with an AlN buffer layer were used as substrates. A CO₂ laser beam heating without vacuum or controlled atmosphere was applied for SiC thermal decomposition. The physical, chemical, morphological, and electrical properties of the laser-produced graphene were investigated for different laser energy densities. The results demonstrate that graphene was produced in form of small islands with quality, density and properties depending on the applied laser energy density. Furthermore, the produced graphene exhibits a sheet resistance characteristic similar to graphene grown on mono-crystalline SiC wafer, which indicates its potential for electronic device applications.

The effect of the acetylene and hydrogen gases mixture ratios in direct low-temperature vacuum carburization was investigated. The gas ratio is an important parameter for producing the free radicals in the carburization. The free radicals can remove the natural oxide film by the strong reaction of the hydrocarbons, and then thermodynamically activity can be increased. When the gas ratio was below 1, the supersaturation expanded austenite layers were formed on the surface of the AISI 316L stainless steel, which had the maximum carbon solubility up to 11.5 at.% at 743 K, were formed. On the other hand, when the gas ratio was above 1, the carbon concentration of them remained low even if the process time was enough increased to reach the maximum carbon solubility. As a result, the carbon concentration underneath the surface was determined to be highly dependent on the gas mixture ratio of acetylene and hydrogen. In conclusion, it is necessary to restrict the ratio of acetylene and hydrogen gases to total mixture gases to form the expanded austenite layer with the high carbon concentration in the direct low-temperature vacuum carburization.

This study aimed to characterize the antioxidant, mechanical and physical properties of chicken skin gelatin/CMC/Centella asiatica blended film. The influence of Centella asiatica at 0.3% and 0.7% on antioxidant activities; mechanical properties and physical properties of chicken skin gelatin/CMC/Centella asiatica film were investigated. Characterization of the blended films with 0.7% Centella asiatica extract shows higher antioxidant activities with a total phenolic content of 0.36 mg/g of GAE, DPPH of 89.26%, and reducing power of 0.80 nm compared to 0.3% Centella asiatica extract. The addition of 0.3% of Centella extract provide higher value in tensile strength (5.0 × 10⁻² MPa), elongation at break (281%), melting point (131.31 °C), transparency (0.86) but lower UV-light penetration. While the addition of 0.7% Centella extract contribute to higher value in WVP (1.13 × 10⁻⁴ g m⁻¹s⁻¹Pa⁻¹) and puncture test (0.06 N). There are no significant differences between functional groups obtained from this blended film as evaluated by FTIR analysis (p > 0.05). Furthermore, XRD analysis showed the addition of extract decrease the crystallinity of film. In conclusion, the incorporation of Centella asiatica extracts on film greatly increased antioxidant levels and improved some of the mechanical and physical properties of the film blends.

An oxidation resistant coating on cemented tungsten carbides is characterised in this work. Cemented tungsten carbides (cWCs) are routinely used in mining and manufacturing but are also candidate materials for compact radiation shielding in fusion power generation. In both environments, cWCs will suffer significant degradation due to oxidation at relatively low temperatures. In a recent study, a Si-deposition coating method was demonstrated to improve the oxidation resistance of cWCs by up to a factor of 1,000. This work focusses on the growth kinetics, phase composition, and mechanical properties of these coatings. By combining quantitative X-ray diffraction, electron microscopy and nanoindentation, we show that the coating layer has a 20 % higher hardness than the substrate, which was explained on the basis of a previously-unknown presence of a fine distribution of very hard SiC laths. To interpret the coating stability, a coating growth map is developed. The map shows the structure is stable under a broad range of processing temperatures and composite compositions, demonstrating the potential application of these coatings in a variety of nuclear shielding cWCs.

Synthesis of activated carbon from waste biomass is of current interest towards sustainability. The properties of biomass derived activated carbon largely depends on the carbonization process. This study reports preparing extremel high surface area mesoporous activated carbon from hemp bast fibre using hydrothermal processing. Processing in hot water (390-500^oC), then activation using KOH and NaOH was investigated at different loading ratios. The described approach was found to enhance the mesoporosity (centered at 3.0 to 4.5 nm) of the hemp derived activated carbon (HAC) from activation (confirmed by BJH pore size distribution and TEM imaging). BET results showed that the product has an extremely high surface area (2425 m²/g) while the surface functional groups (-OH, COOH, C=C/C-C) were confirmed and quantified by XPS and FTIR results. Increasing KOH concentration was found to enhance the surface area with an optimum biochar to KOH ratio of 1:3. The crystallite domain size of HAC was determined using Raman spectroscopy of different wavelengths. The procedure described in this study is an environmentally friendly scalable route for the mass production of activated carbon using hemp fiber.

In order to understand the hot deformation behavior of novel Cu/Al laminated composites, isothermal hot compression tests were conducted by Gleeble-1500D thermo-mechanical simulator. And the effect of bonding interface, deformation temperature and strain rate on the deformation behavior was analyzed. Results show that under the interface constraint effect, soft Al layer trends to flow synchronously with hard Cu layer. And further microstructure examinations indicate the cooperative deformation capability of Cu/Al composites increases with increasing stain rate and decreasing deformation temperature. Strain hardening exponent, calculated based on the true stress-true strain data, also proves the effect of deformation temperature and strain rate on the cooperative deformation behavior. Meanwhile, unique composites structure allows the Al matrix to exhibit the characteristic of dynamic recrystallization during the hot deformation process. Lastly, strain compensated Arrhenius-type constitutive equation was employed to describe the coupling effect of temperature, strain rate and strain on the flow stress.

The persistent issue of bacterial and fungal colonization of artificial implantable materials and decreasing efficacy of conventional systemic antibiotics used to treat implant-associated infections has led to the development of a wide range of antifouling and antibacterial strategies. This article reviews one such strategy where inherently biologically active renewable resources, i.e. secondary plant metabolites (SPMs) and their naturally occurring combinations (i.e. essential oils) are used for surface functionalization and synthesis of polymer thin films. With a distinct mode of antibacterial activity, broad spectrum of action and diversity of available chemistries, secondary plant metabolites present an attractive alternative to conventional antibiotics. However, their conversion from liquid to solid phase without significant loss of activity is not trivial. Using select examples, this article shows how plasma techniques provide a sufficiently flexible and chemically reactive environment to enable the synthesis of biologically-active polymer-coatings from volatile renewable resources.

We performed for the first time to our knowledge fully ab initio molecular dynamics simulations of additive tribochemistry in boundary lubrication conditions. We consider an organophosphourus additive that has been experimentally shown to reduce friction in steel-on-steel sliding contacts thanks to the tribologically-induced formation of an iron phosphide tribofilm. The simulations allow us to observe in real time the molecular dissociation at the sliding iron interface under pressure and to understand the mechanism of iron phosphide formation. We discuss the role played by the mechanical stress by comparing the activation times for molecular dissociation observed in the tribological simulations at different applied loads with that expected on the basis of the dissociation barrier.

Oriented strand board (OSB) panels are widely marketed for several applications, from building to packaging. The manufacturing of poplar OSB started recently in Northern Italy representing a relevant innovation in the sector since this product is usually made of coniferous wood. The thermal treatment is widely used for reducing the hygroscopicity of wood-based products, nonetheless it influences the mechanical behavior and degrades the main components of wood, which can affect their finishing. Therefore, it is important to know the properties of the treated surfaces. To this purpose, in this study a lot of OSB panels, made of poplar wood, 15 mm thick and with a density of 590 kg/m³, were thermally treated under vacuum conditions at 190 °C for 2 h and then subjected to accelerated weathering. The changes in color and in wettability due to treatment and accelerated weathering were studied. The thermal treatment determined a significant darkening of the color; the accelerated weathering darkened the untreated surfaces and, on the opposite, lightened the thermo-treated surfaces. The wettability decreased after thermal treatment and increased after weathering, more evidently in treated panels. Overall, this study improves the knowledge about the behavior of the surface of thermo-treated poplar OSB, which is relevant for the industrial coating of this product.

In the paper, the effect of voltage increasing (from 500 VDC up to 650 VDC) on the structure and chemical composition of porous coating on titanium made by Plasma Electrolytic Oxidation, is presented. In the present paper, phosphates based coatings enriched with calcium, magnesium, zinc and copper in electrolyte based on 1 L of 85% concentrated H3PO4 with additions of Ca(NO3)2·4H2O, and Mg(NO3)2∙6H2O, and Zn(NO3)2∙6H2O, and Cu(NO3)2∙3H2O, are described. The morphology, chemical and phase composition, are evaluated using SEM, EDS, XRD, XPS, GDOES. Based on all the analyses, it was found out that the PEO coatings are porous and enriched with calcium, magnesium, zinc and copper. They consist mainly of the amorphous phase, which is more visible for higher voltages, and it is correlated with the increasing of the total PEO coating thickness (the higher the voltage, the thicker the PEO coating). However, for 650 VDC an amorphous phase and titanium substrate was also recorded with a signal from Ti2P2O7 crystalline, that was not observed for lower voltages. It was also found out that all the obtained coatings may be divided in three sub-layers, i.e. porous, semiporous, and transition one.

Ti64 alloy plays a significant role in the biomedical applications such as bioimplants for its excellent biocompatibility. Its usage can be further extended by improving the surface hardness and wear resistance. In this respect, laser surface glazing (LSG), an advanced surface modification technique, is very useful which can produce thin hardened surface layer and strong metallurgical bonding. Investigation of temporal and spatial temperature distributions of laser glazed surface of materials are essential because temperature plays significant role in achieving required surface properties. Therefore, in this study, a 3D Finite element analysis has been developed to perform transient thermal analysis of LSG for Ti64 alloy. The model investigated temperature distribution, depth of modified zone and heating and cooling. The results show that the peak temperature is attained 2095 K for 300 W laser power, 0.2 mm beam width and 0.15 ms residence time. Since this temperature is above the melting point (1933 K) of Ti64 alloy, the melt depth is calculated 22.5 μm. Furthermore, from the simulation results, the average heating and cooling rates are estimated 1.19×10⁷ Ks^-1 and 2.71×10⁶ Ks^-1 respectively which indicate the presence of hard phases in the modified zone.

MCrAlX (M: Ni or Co or both, X: minor elements) coatings have been widely used to protect hot components in gas turbines against oxidation and hot corrosion at high temperatures. Understanding the influence of the X-elements on oxidation behaviour is important in the design of durable MCrAlX coatings. In this study, NiCoCrAlX coatings doped with Y+Ru and Ce, respectively, were deposited on Inconel-792 substrate by HVOF. The samples were subjected to isothermal oxidation test in laboratory air at 9000, 1000, 1100 ºC and cyclic oxidation test between 100 ºC and 1100 ºC with 1 hour dwell time at 1100 ºC. It was observed that the coating with Ce shows a much higher oxidation rate than the coating with Y+Ru under both isothermal and cyclic oxidation tests. Besides, β-depletion due to interdiffusion between coating and substrate was significantly lower with Ru addition. Simulations results using both a moving phase boundary model and an established oxidation-diffusion model show that Ru stabilize β grains which reduces β-depletion of coating due to substrate interdiffusion. This paper presents a comprehensive study of the influence of Ce and Ru on oxidation behaviour including investigation of the microstructure evolution influenced by oxidation time at coating surface and coating-substrate interface combining experiment and simulation results.

Stess in laser cladding coating is an important factor affecting the safe operation of remanufacturing components. Ultrasonic testing has become a hot direction in nondestructive evaluation of stress, because it has the advantages of safety, non-destructive and on-line detection. This paper provides a review of ultrasonic testing for stress in remanufacturing laser cladding coating. It summarizes the recent research outcomes on ultrasonic testing for stress, analyzes mechanism of ultrasonic testing for stress. Remanufacturing laser cladding coating shows typical anisotropic behaviors, the ultrasonic testing signal in laser cladding coating is influenced by many complex factors, such as microstructure, defect, temperature and surface roughness, etc. At present, ultrasonic testing for stress in laser cladding coating can only be done roughly. The paper discusses active mechanism of micro / macro factors to the reliability of stress measurement and the impact of stress measurement to the quality and safety of remanufacturing components. Base on the discussion, the paper proposes strategies for acquisition of nondestructive, rapid and accurate measurement of stress in remanufacturing laser cladding coating.

Plasma treatment of soft polymers is the promising technique to improve biomedical properties. The response to the deformation of such materials is not yet clear. Soft elastic polyurethane treated with plasma immersion ion implantation is subjected to fatigue uniaxial loading (50000 cycles, frequency – 1 Hz, strain amplitude – 10, 20, 40%). The influence of the strain amplitude and the plasma treatment regime on damage character is discussed. Surface defects are studied in unloaded and stretched states of the material. As a result of fatigue loading, transverse cracks (with closed overlapping edges as well as with open edges deeply propagating into the polymer) and longitudinal folds which are break and bend inward, appear on the surface. Hard edges of cracks cut the soft polymer which is squeezed from the bulk to the surface.

The inhibition impacts of 1,10-Phenanthroline-5,6-diamine (PTDA) on mild steel in 1 M HCl solution were investigated through weight loss method. The inhibition efficiencies of PTDA increase with increase in PTDA concentration at the temperature 303. Weight loss method indicate that PTDA is an excellent inhibitor the inhibition efficiency of 81.5% at the maximum PTDA concentration of 0.5 g/L at the temperature 303K.

We describe our investigations of the surface physicochemical and biological properties of polylactic acid modified by silver, argon and carbon ion implantation to doses of 1 × 10¹⁴, 1 × 10¹⁵ and 1 × 10¹⁶ ion/cm² at energies of 20 keV (for C and Ar) and 40 keV (for Ag). X-ray analysis shows enhancement of coherent scattering regions and lattice constant increase after ion implantation. Secondary electron mass-spectrometry indicates that Ag concentration in the subsurface layer is less than 80%, but at a depth of 500 nm does not exceed 1–2%. The silver forms metal particles in the subsurface layer rather than making additional chemical bonds with polymer atoms. Atomic force microscopy reveals that the higher the irradiation dose the larger the surface roughness of the samples. Ag-irradiated samples implanted to a dose of 1 × 10¹⁶ ions/cm² have the highest roughness, 190 nm. Our investigation of the cytotoxicity of two individual donor macrophages shows that Ag-implanted polylactic acid has no negative impact on immune system cells and could be a promising material for biomedical application.

The global polyvinyldene flouride market is estimated to reach $937,278.5 thousand by 2019, therefore to develop new membranes and gain pioneering ideas, which could create innovative business opportunities, a fundamental knowledge about membrane properties fabricated from recent commercially available PVDF polymers is highly mandatory. In this study, we successfully prepared nine non-woven supported PVDF membranes using a phase inversion precipitation method starting from a 15 wt% PVDF solution in N-methyl-2-pyrrolidone. Various membrane morphologies were obtained by using (1) PVDF polymers with diverse molecular weight in a range from 300.000 Da to 700.000 Da and (2) different temperatures of the coagulation bath (20, 40, and 60 ±2°C) used for the films precipitation. Environmental Scanning Electron Microscope (ESEM) was used for surface and cross-section morphologies characterization.  Atomic Force Microscope (AFM) was employed to investigate surface roughness, while Contact Angle (CA) instrument was used for membranes wettability studies. Fourier Transform Infrared Spectroscopy (FTIR) results show that the fabricated membranes are formed by a mixture of TGTG’ chains in α phase crystalline domains and all-TTTT trans planar zigzag chains characteristic to β phase. Moreover, generated results indicate that the phases content and membrane morphologies depend on the polymer molecular weight and conditions used for the membranes preparation. The diversity of fabricated membranes could be applied by the End User Industries for different applications.

Our study aims to implement a strategy to reduce the carbon steel corrosion rate in sulfuric acid solution, using an expired drug with adsorption affinity on the metal surface. To investigate the corrosion protection efficiency of an environmental friendly inhibitor, namely neomycin sulfate (NMS), the electrochemical measurements were applied on carbon steel immersed in 1.0 M H₂SO₄ solution with and without NMS. The protective layer formed on the steel surface was studied by atomic force microscopy (AFM). The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) showed that the presence of the neomycin sulfate in acid solution leads to the decrease in corrosion current density (i_corr) and the increase of polarization resistance (R_p). The mixed mechanism between physical and chemical adsorption of NMS molecules on the steel surface was proposed according to the Langmuir adsorption isotherm. The Atomic Force Microscopy (AFM) indicated that the NMS molecules contributed to a protective layer formation by their adsorption on the steel surface. The AFM parameters such as: root-mean-square roughness (R_q); average roughness (R_a) and maximum peak to valley height (R_p-v) revealed that in the presence of NMS a smoother surface of carbon steel was obtained, compared to the steel surface corroded in sulfuric acid blank solution.

The crack geometry and associated strain field around Berkovich and Vickers indents on silicon have been studied by X-ray diffraction imaging and micro-Raman spectroscopy scanning. The techniques are complementary, the Raman data coming from within a few micrometers of the indentation, whereas the X-ray image probes the strain field at a distance of typically tens of micrometers. For example, Raman data provides an explanation for the central contrast feature in the X-ray images of an indent. Strain relaxation from breakout and high temperature annealing are examined and it is demonstrated that millimeter length cracks, similar to those produced by mechanical damage from misaligned handling tools, can be generated in a controlled fashion by indentation within 75 micrometers of the bevel edge of 200mm diameter wafers.

Thin films (100-400 nm) of Ba_xSr_1-xTiO₃ (0≤x≤1) deposited in RF-magnetron co-sputtering equipment are presented in this research work. The change of deposition rate, gap energy, and resistivity as a function of temperature- applied power change in the growth parameters was studied through the ISO colour-code lines constructed with MATLAB: By analysing the trend information and take into account the influence of the calculated "x" parameter with the Boltzmann profile fitting is proposed a method to allow a controlled set up of the RF-magnetron co-sputtering system and predict the E_g and resistivity values in the Ba_xSr_1-xTiO₃ solid solution with 0≤x≤1 for amorphous and crystalline phases. Also, a versatile tool to optimise the deposition process and material properties.

Objective: CAD/CAM generated ceramic implant abutments have recently attracted interest due to their superior customization possibilities and aesthetic advantages. Despite their widespread clinical use, little information is currently available on their surface topography, however. The transmucosal portion of the abutment shoulder is of particular interest, as it ideally supports soft tissue but minimizes mechanical plaque retention. The aim of this in vitro study was to topographically characterize the trans- and subgingival roughness of CAD/CAM zirconia abutments from different manufacturers and compare them with zirconia stock abutments. Material and Method: The surface topography of eight CAD/CAM zirconia implant abutments (tests) and two prefabricated zirconia stock abutments (controls) was determined using focus variation microscopy. Two points on the abutment shoulder were subjected to profilometric examination. 2D and 3D parameters of roughness were obtained and compared. Results: The surface roughness of all the test abutments exceeded the recommended threshold of Ra = 0.2 µm and therefore exhibited an increased risk of mechanical plaque retention. Obvious differences in surface structure were apparent, allowing conclusions to be drawn about the manufacturing method and subsequent reworking processes. Conclusion: Manually reworking the trans- and submucosal area of the investigated CAD/CAM zirconia abutments appears necessary to fulfil the conditions for optimal surface topography. The Sa value as arithmetic mean, taking the maximum height (Sz value) and surface excess (Sdr) into account, is an essential parameter for assessing the surface topography of implant abutments.

Interface between matrix/coating or coating/coating in fact represents a very complicate thin interfacial layer. So interface model is necessary to avoid the difficulty on considering such a complicate thin layer in analysis. Classic interface model and cohesive model have been widely used in stress analysis of coating materials, though they cannot represent the effect of very thin interfacial layer accurately. A complete interface model has been deduced from the equivalent constitutive of interfacial layer in this paper. It is found that both classic interface model and cohesive model sometimes cannot give correct analysis results, while the complete interface model can always give a correct result. Moreover, the stress parallel to interface within the interfacial layer can also be analyzed by the new model. Besides, this model can also be used to describe the equivalent properties of interfacial layer, thereby, can provide a quantitative characterizing method for interfacial layer itself.

The nitrogen-doped amorphous oxide semiconductor (AOS) thin film transistors (TFTs) with double-stacked channel layers (DSCL) were prepared and characterized. The DSCL structure composed of nitrogen-doped amorphous InGaZnO and InZnO films (a-IGZO:N/a-IZO:N or a-IZO:N/a-IGZO:N) made the corresponding TFT devices exhibit quite large field-effect mobility due to the existence of double conduction channels. Especially, the a-IZO:N/a-IGZO:N TFTs showed even better electrical performance (μ_FE = 15.0 cm²·V^-1·s^-1, SS = 0.5 V/dec, V_TH = 1.5 V, I_ON/I_OFF = 1.1×10⁸) and stability (V_TH shift of 1.5, -0.5, and -2.5 V for positive bias-stress, negative bias-stress and thermal stress tests, respectively) than the a-IGZO:N/a-IZO:N TFTs. Based on the X-ray photoemission spectroscopy measurements and energy band analysis, it was assumed that the optimized interface trap states, the less ambient gas adsorption, and the better suppression of oxygen vacancies in the a-IZO:N/a-IGZO:N hetero-structures might be responsible for the better behaviors of the corresponding TFTs.

Electrochemical impedance (EI) measurements were performed to evaluate the nylon 66/-tetra-(para-aminophenyl) porphyrin (H₂T(p-NH₂)PP)/graphene oxide (GO) film coating on stainless steel and compared to the nylon/H₂T(p-NH₂)PP and nylon/GO film samples using 1M H₂SO₄ as electrolyte. The nylon/H₂T(p-NH₂)PP and nylon/GO composite films showed high electrochemical impedance in the order of 109 ohm-cm² and a system controlled by mass transfer, product of a diffusion process at low frequencies with a resistance up to 5 orders of magnitude, indicating the diffusion of protons through the coating and a decrease in the metal dissolution. Otherwise, the nylon/H₂T(p-NH₂)PP/GO film compound evaluated show good ionic conductivity and electrochemical stability in the acid environment, acting porphyrin as a catalyst to the passage of protons through the film, reducing its electrochemical impedance up to 7 orders of magnitude with respect to the compounds nylon/H₂T(p-NH₂)PP and nylon/GO. Likewise, good capacitance values are also shown by modifying the concentrations of porphyrin and GO reinforcing materials. These properties are important for technological applications, such as anticorrosion coating for bipolar plates or membrane in a fuel cell type PEM, super-capacitors, etc.

New corrosion inhibitor derived from coumarin-3-amine namely 3-((2-chlorobenzylidene)amino)coumarin was synthesized and characterized by CHN elemental analysis in addition to Fourier transform infrared and nuclear magnetic resonance techniques. The anti-corrosion ability of 3-((2-chlorobenzylidene)amino)coumarin to inhibit the impacts of corrosion has been demonstrated and damage reduction of the mild steel also. 3-((2-chlorobenzylidene)amino)coumarin, has been employed as a good corrosion inhibitor for mild steel in HCL solution. The efficiency of the inhibition was figured according to weight loss method and it was 74.6%.

Corrosion inhibitors are the natural or synthetic compounds that have the ability to inhibit the average of corrosion and reduce the damage of the mild steel. Enormous organic inhibitors nowadays employed in the corrosion domain but excluded due to costly. Comparatively cheap, and stable organic compound, namely 3-((4-nitrobenzylidene)amino)coumarin, have been utilized as an excellent corrosion inhibitor in hydrochloric acid for mild steel. The inhibition efficiency has been figured regarding to weight loss method. The corrosion inhibitor was identified according to spectroscopic techniques namely Fourier transform infrared and nuclear magnetic resonance in addition to micro-elemental analysis. Inhibition efficiency for the studied inhibitor was 71.4% that, at the highest studied concentration.

Dynamic tribochemical processes for dicationic ionic liquid containing a germinal imidazolium cation head groups bridged by a poly(ethylene glycol) and bis(trifluoromethylsulfonyl)imide anion were studied using time-resolved Mechanically Stimulated Gas Emission Mass-Spectrometry (MSGE-MS). In comparison with similar monocationic imidazolium ionic liquids with short alkylic or long polyether side chains the dicationic ionic liquid had lower coefficient of friction on Ti6Al4V alloy and smoother behaviour. The analysis of volatile decomposition products suggested multiple tribochemical reactions in which both anionic and cationic moieties are involved. Tribochemical degradation of cations was mainly through detachment of the side and bridging chains from the imidazolium head groups. Absence of volatile products containing nitrogen implies that imidazole group remained unchanged. Hydrogen and water desorption were attributed to the reactions of hydrogen fluoride being a product of anion degradation with titanium and titanium oxide.

The review is devoted to the physical, chemical and technological aspects of the breath-figures self-assembly process. Main stages of the process and the impact of the polymer architecture and physical parameters of the breath-figures self-assembly on the eventual pattern are covered. The review is focused on the hierarchy of spatial and temporal scales inherent for the breath-figures self-assembly. Multi-scale patterns arising from the process are addressed. The characteristic spatial lateral scales of patterns vary from nanometers to dozens of micrometers. The temporal scales of the process span from micro-seconds to seconds. The qualitative analysis performed in the paper demonstrates that the process is mainly governed by the interfacial phenomena, whereas the impact of inertia and gravity is negligible. Characterization and applications of polymer films manufactured with breath-figures self-assembly are discussed.

Rare earth rich magnesium alloys are used in aerospace and automotive fields because of their high specific strength and good castability. However, due to their low corrosion resistance, protective surface treatments, such as conversion coating or electroless plating are necessary, when they have to be used in humid or corrosive environments. The present study was aimed to evaluate the effect of Plasma Electrolytic Oxidation (PEO) and different surface roughness  (Ra≈0.8 μm and Ra≈0.3 μm) on the rotating bending fatigue of an innovative Mg alloy, with a high content of Nd (up to 3.1 wt%) and Gd (up to 1.7 wt %). Fatigue tests revealed a 15% decrease in the fatigue strength of the PEO treated alloy (fatigue strength = 88 MPa) with respect to the bare alloy (fatigue strength = 103 MPa). The reduction of fatigue strength was mainly due to the residual tensile stresses induced by the PEO treatment. The effect of surface roughness on the bare alloy was, instead, negligible. The mechanisms of crack initiation were similar in the untreated and PEO treated alloy, with crack nucleation sites located in correspondence of large facets of the cleavage planes.

A simple and effective surface modification of polyester fabrics with sulfuric acid to improve the interfacial deposition of polypyrrole was presented in our work. A range of sulfuric acid concentrations were analyzed by studying water contact angle. Effect of sulfuric acid modification on the deposition of polypyrrole was investigated by sheet resistance and color depth of fabric samples. Polyester fabrics coated with polypyrrole layer were confirmed by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-Ray diffraction spectra (XRD), Fourier transform infrared spectroscopy (FTIR). XPS showed that sulphur containing functional groups were obviously appeared on the polyester fiber surface after modification, which were advantageous to promote the deposition of polypyrrole onto polyester fabrics. The improved deposition increased electrical conductivity of fabric samples.

There is a growing interest in fibers supporting optoelectrical properties for textile and wearable display applications. Solution-processed electroluminescent (EL) material systems can be continuously deposited onto fiber or yarn substrates in a roll-to-roll process, making it easy to scale manufacturing. It is important to have precise control over layer deposition to achieve uniform and reliable light emission from these EL fibers. Slot-die coating offers this control and increases the rate of EL fiber production. Here, we report a highly adaptable, cost-effective 3D printing model for developing slot dies used in automatic coating systems. The resulting slot-die coating system enables rapid, reliable production of alternating current powder-based EL (ACPEL) fibers and can be adapted for many material systems. The benefits of this system over dip-coating for roll-to-roll production of EL fibers are demonstrated in this work.

A time-sequential working, spatially multiplexed autostereoscopic 3D display design consisting of a fast switchable RGB-color filter array is presented. The wavelength-selective filter barrier emits the light from a display over a larger active area than common autostereoscopic barrier displays. An optical modelling of wavelength-selective barriers has been used for instance to calculate the light ray distribution properties of that arrangement. To find well working display designs, automated searches by simulation and computational evaluation has been proceeded. Wavelength-selective filter barrier arrangements exhibit characteristics different from common barrier displays with similar barrier pitch and ascent. In particular, these constructions show strong angular luminance dependency under barrier inclination specified by correspondent slant angle. In time-sequential implementation it is important to avoid that quick eye or eyelid movement lead to visible color artifacts. In the millisecond regime tunable liquid crystal Fabry-Pérot color filters for the colors red, green and blue are presented. They consist of a sub-micrometer thick nematic layer sandwiched between dielectric mirrors and ITO-electrodes. These cells shall switch narrow-banding light of red, green or blue. An array for a glasses-free 3D display has to be equipped with several thousand switchable filter elements having different color apertures. The newly introduced design is usable as a multi user display as well as a single user system with user adaptive control.

Development of the self-cleaning and anti-fogging superhydrophobic coating for aluminum surfaces which is durable in the aggressive conditions has raised tremendous interest in materials science. In this work, by employing chemical etching technique with mixture of hydrochloric and nitric acid, followed by passivation with lauric acid, superhydrophobic aluminum surface was synthesized. The surface morphology analysis reveals the presence of rough microstructures on coated aluminium surface. Superhydrophobicity with water contact angle of 170 ± 3.9° and sliding angle of 4 ± 0.5° is achieved. Surface bounces off the high speed water jet, indicating excellent water-repellent nature of coating. It is also continuously floated on water surface for several weeks, showing excellent buoyancy nature. Additionally, coating maintains its superhydrophobicity after undergoing 100 cycles of adhesive tape peeling test. Its superhydrophobic nature withstands 90° and 180° bending, and repeated folding and de-folding. Coating exhibits the excellent self-cleaning property. In low temperature condensation test, almost no accumulation of water drops on the surface, showing the excellent anti-fogging property of coating. This approach can be applied to any size and shape of aluminium surface and hence has great industrial applications.

The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

The local electrical response in alkaline-doped CuInSe₂ films prepared by single step electrodeposition onto Cu substrates was studied by current sensing atomic force microscopy. The CIS films were prepared from single baths containing the dopant ions (Li, Na, K or Cs) and were studied by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and photocurrent response. Increased crystallinity and surface texturing as the ion size increases was observed as well as enhanced photocurrent response in Cs doped CIS. Li and Na doped films have larger conductivity than the undoped film while the K and Cs doped samples display shorter currents and the current images indicate strong charge accumulation in the K and Cs doped films forming surface capacitors. Corrected CAFM IV curves were adjusted with Shockley equation.

This study explored the effects of cryogenic treatment on the microstructure, hardness, and wear-resistance of diamond-like carbon (DLC) by cryogenically treating NAK 80 mold steel coated with DLC. Raman spectroscopy analyzed the structure of the DLC film. Nanoindenter analyzed the hardness and Young’s modulus of the film, and their relationship determined the wear resistance. Wear test assessed the wear rate and friction coefficient of the DLC film. The results showed that cryogenic treatment increased the rate of carbide precipitation and refined the grain structure. Raman spectroscopy indicated that the Raman intensity rate (I_D/I_G) of treated DLC films was smaller than those without cryogenic treatment. When the sp3 bond increased, the hardness and wear-resistance of the DLC film also increased.

Special preparation of SBA-15 materials has been carried out for creating adsorbents exhibiting an enhanced and selective adsorption toward CO2. This creation starts from an adequate conditioning of the silica surface, via a thermo-alkaline treatment to increase the population of silanol species on it. CO2 adsorption is only reasonably achieved when the SiO2 surface becomes aminated after put in contact with a solution of an amino alkoxide compound in the right solvent. Unfunctionalized and amine-functionalized substrates were characterized through X-ray diffraction, N2 sorption, Raman spectroscopy, electron microscopy, 29Si solid-state NMR, and NH3 thermal programmed desorption. These analyses proved that the thermo-alkaline procedure desilicates the substrate and eliminates the micropores (without affecting the SBA-15 capillaries), present in the original solid. NMR analysis confirms that the hydroxylated solid anchors more amino functionalizing molecules than the unhydroxylated material. The SBA-15 sample subjected to hydroxylation and amino- functionalization displays a high enthalpy of interaction, a reason why this solid is suitable for a strong deposition of CO2 but with the possibility of observing a low-pressure hysteresis phenomenon. Contrastingly, CH4 adsorption on amino-functionalized, hydroxylated SBA-15 substrates becomes almost 5 times lesser than the CO2 one, thus giving proof of their selectivity toward CO2.

The carbonyl iron particles were dispersed in a polychloroprene rubber (CR) matrix under an external magnetic field for practical application as microwave absorption composites film. The film prepared under external magnetic field with a thickness of only 0.54 mm showed least reflection loss of -15.98 dB and the reflection loss value less than -10.0 dB over the frequency range of 11.4~14.8 GHz. In comparison with the microwave absorption properties of calculation by transmission line theory based on the tested relative complex permittivity and permeability and film prepared by general route without external magnetic field, the film made with external magnetic field exhibited more excellent microwave absorption properties, strongly depending on the increment of anisotropy and rearrangement of magnetic particles. The results indicated the composite film made under external magnetic field have excellent microwave absorption properties, which suggest that the composites thin film could be used as a thinner and lighter microwave absorber.

In this study, a new type of temperature sensor device was developed. The circular electrode of the thermal sensitive sensor was modified with TMT and O₂ plasma to enhance the conductivity by forming a thin SnOxCy layer on the electrode surface. The Nano-Au particles were subjected to O₂ plasma pretreatment to form peroxide groups on the surface. The thermally sensitive sensor was made by mixing the above-treated Nano-Au particles with N-isopropylacrylamide (NIPAAm) to form solution and then UV-induced grafting polymerization of the NIPAAm-containing solution onto the electrode substrate. The composite hydrogels on the electrode introduce thermo-sensitive polymeric surface films for temperature sensing. Using ambient environment resistance test to measure the resistance, the LCST (lower critical solution temperature) of Nano-Au (MUA) mixed with NIPAAm hydrogel was found to be 32 °C. At ambient temperatures higher than LCST, the electrode resistance decreases linearly.

A series of waterborne polyurethane (WBPU)/modified lignin amine (MLA) adhesives was prepared using modified lignin amine (MLA) as a chain extender by a prepolymer mixing process. A successful Mannich reaction was achieved during the synthesis of MLA by reacting lignin with bis(3-aminopropyl)amine. Higher tensile strength, Young’s modulus and thermal stability were recorded for WBPU/MLA adhesives with higher MLA contents. The WBPU/MLA adhesive materials were used to coat PVC substrates. The adhesive strength increased with increasing MLA content. More importantly, the MLA also enhanced the WBPU/MLA coating in terms of adhesive strength at moderately high temperatures as well as under natural weather exposed conditions. The adhesive strength was essentially unaffected with 6.48 mole% MLA in the WBPU/MLA coating after exposure to natural weather conditions for 180 days.