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Article
Physical Sciences
Thermodynamics

Muhamad Fouad

Abstract: This paper introduces a Thermodynamic Unified Field Theory (UFT) where prime-enforced symmetry constraints emerge from helical recoils in photrino dynamics, unifying phase behaviors and transport phenomena through a covariant fugacity-Hessian equation. By deriving the viscous stress tensor from entropy maximization without pa-rameters, the framework resolves Navier-Stokes limitations (e.g., infinite speeds, non-Fourier transport) and reproduces empirical phase diagrams for substances like he-lium, water, and neon via prime-locked gears. We demonstrate how primes arise from triad indivisibility, leading to rational direction cosines that enforce shell uniformity and curvature floors. Applications to catalysis, superfluidity, and non-equilibrium systems highlight UFT's potential as a parameter-free TOE candidate, with time and gravity as emergent distortions in the flux sea.
Article
Physical Sciences
Thermodynamics

Yong Gang Zheng

Abstract:

This study investigates the dynamic shielding model during the Curie phase transition through simulations. It reveals that the intermittent magnetic shielding effect during the Curie phase transition enables a moving ferromagnetic body to gain mechanical work along a closed motion path, suspected to originate from phase transition heat conversion. Further research demonstrates that altering the shape of the Curie-phase-transition ferromagnetic body can cause the moving ferromagnetic body to perform either positive or negative work. Theoretical analyses based on Curie phase transition theory, magnetic medium thermodynamics, and classical electromagnetism indicate that this shielding mechanism creates a temporally non-conservative field. Consequently, the moving ferromagnetic body does not exchange energy with the phase transition system while acquiring mechanical work. This discovery holds significant implications for deepening our understanding of the spatiotemporal characteristics of magnetic fields.

Article
Physical Sciences
Thermodynamics

Xiaolin Li

Abstract: Using the concept of quantum wave probability, combined with the identity principle, we can derive the Boltzmann distribution, Fermi distribution, and Bose distribution. Different distributions correspond to different conditions. The Boltzmann condition corresponds to the Boltzmann distribution. The Fermi condition corresponds to the Fermi distribution. The Bose condition corresponds to the Bose distribution. This demonstrates that the foundation of these three statistical distributions is quantum wave probability, all originating from quantum mechanics. The Boltzmann distribution is also an independent quantum distribution and is not simply a sparse limit of the Fermi or Bose distributions. The essence of the Boltzmann distribution is a uniform distribution. The Fermi and Bose distributions are deviations from the uniform distribution. Particles that follow the Boltzmann distribution can be called Boltzmannons. Boltzmann entropy based on the quantum wave probability can resolve the Gibbs paradox. We need to rethink the fundamentals of statistical mechanics.
Article
Physical Sciences
Thermodynamics

Yonggang Zheng

Abstract: This paper comprehensively analyzes the magnetization work exerted on objects during phase transitions and their heat absorption/release characteristics in superconducting and Curie phase transition cycles. By comparing and analyzing the thermodynamic processes of two adiabatic phase transitions in a varying magnetic field, it reveals that the energy conversion in both phase transitions is fundamentally similar. Specifically, after a complete adiabatic phase transition cycle, both superconductors and ferromagnets return to their initial states without accumulated magnetization work, the net heat exchange is zero, internal energy is conserved, and there is no net thermal energy exchange with the external environment, indicating no energy consumption in the phase transition cycle.
Article
Physical Sciences
Thermodynamics

Evgenii Rudnyi

Abstract: The problem of coordination for thermodynamic entropy as a physical quantity is expressed in two related questions: 1) What counts as a measurement of entropy? 2) What is entropy? These issues are considered in this paper for thermodynamic properties of pure substances in classical thermodynamics. The conceptual model to define entropy in the second law of thermodynamics cannot be used directly to produce an ideal experiment related to real measurements. Thus, the solution of the problem of coordination for entropy is based on the tight integration of entropy with other thermodynamic properties in the formalism of classical thermodynamics. Therefore, the solution of the problem of coordination for entropy is related to the simultaneous solution of the problem of coordination for other thermodynamic quantities, such as heat capacity, internal energy, enthalpy, and the Gibbs energy.
Article
Physical Sciences
Thermodynamics

Evgenii Rudnyi

Abstract: In his paper 'The Impossible Process: Thermodynamic Reversibility', John Norton criticized the concept of reversible processes in classical thermodynamics and suggested that they should be considered approximations. In mathematics, however, the term approximation is related to the approximately equal sign, which is inappropriate for the mathematical formalism of thermodynamics. This paper examines the relationship between the formalism of thermodynamics, conceptual models and the world, and then discusses Norton's proposal from this point of view. In conclusion, a proposal by mathematician Zorich for the reversible process of heat transfer between two bodies with different temperatures is described.
Concept Paper
Physical Sciences
Thermodynamics

Zhi Kai Zou

Abstract: This paper introduces a novel entropy formulation — multiplicative entropy — defined as the product of energy values across all units in a quantized homogeneous invariant network. Unlike traditional statistical entropy, this approach explicitly tracks irreversible energy redistribution pathways, offering an analytic and path-dependent description of entropy growth. Logarithmic transformation recovers classical entropy forms, while preserving temporal directionality and quantum-scale resolution. The model enables precise simulation of thermodynamic processes, supporting the development of Analytic Quantum Thermodynamics as a new framework for understanding entropy-driven dynamics. Crucially, the analytical multiplicative entropy formula proposed here responds to Planck’s long-sought vision of an entropy expression in analytic form, enabling the resolution of entropy to match the high resolution of quantum processes.
Article
Physical Sciences
Thermodynamics

Vidal Aquiles de Jesus Sanchez-Sanchez

,

Pedro Quinto Diez

Abstract: Serrin’s works provided a new perspective on classical thermodynamics through his statements of the first law and the accumulation function, and of the second law and the accumulation theorem, as well as the subsequent result by Huilgol that the work done in a thermal cycle implies an inequality where the important temperatures of the thermal cycle and an integral similar to that of Clausius appear. Based on these pioneering works, explicit forms of the accumulation function have been derived for the Otto, Diesel, Stirling and Ericsson cycles. In this article, a straightforward alternative derivation is presented to obtain the inequality for the work done in a cycle, following the approaches of Serrin and Huilgol. The derivation of the accumulation function for the ideal air-standard Brayton cycle is provided, where the temperature constraints of the adiabatic compression and expansion processes under which it operates are analyzed. Finally, a practical example is presented to illustrate the application of Serrin’s accumulation function to the ideal air-standard Brayton cycle.
Article
Physical Sciences
Thermodynamics

Evgenii Rudnyi

Abstract: Jos Uffink rejected the existence of the arrow of time in classical thermodynamics, and his views turned out to be influential in the philosophy of physics. However, this position omits the connection between classical thermodynamics and continuum mechanics and is based on a simplistic view of equilibrium states. In this article, this issue is discussed with an example of a temperature field; we examine the relationship between the Fourier heat equation and classical thermodynamics in the 19th century. With this example the relationship of the Clausius inequality to time and transport equations of continuum mechanics is clarified. The question is raised whether it makes sense to carry out the axiomatization of classical thermodynamics without continuum mechanics.
Communication
Physical Sciences
Thermodynamics

Ping Wu

Abstract: The material–immaterial divide remains one of the deepest conceptual tensions in both science and philosophy. This paper introduces the Dual Entropy Uncertainty Frame-work (DEUF)—a quantitative, information-based model that unifies material structure and immaterial information under a single uncertainty law, SE × OE ≥ C. Structural Entropy (SE) and Optical Entropy (OE) represent complementary Shannon-type measures of configurational and informational uncertainty. Building upon the Hei-senberg Uncertainty Principle and Shannon Information Theory, DEUF provides a testable framework linking quantum duality, biological evolution, and Platonic ideal-ism. Empirical implications are outlined in terms of compensatory dynamics between structure and information. The framework resolves long-standing philosophical and scientific challenges and suggests that matter and information form a single, entropi-cally balanced continuum. The DEUF formulation opens a new path for studying en-tropy-driven self-organization and the informational basis of natural laws.
Review
Physical Sciences
Thermodynamics

Chris Jeynes

,

Michael Charles Parker

Abstract: Quantitative Geometrical Thermodynamics (QGT) exploits the entropic Lagrangian-Hamiltonian canonical equations of state as applied to entities obeying the holographic principle and exhibiting Shannon information, the creation of which measures the (validly defined) “entropic purpose” of the system. QGT provides a physical description for what we might consider the true ‘atoms’ of physical science, and has also recently enabled a number of significant advances: including accounting ab initio for the chirality of DNA and the stability of Buckminsterfullerene; the size of the alpha particle (and other nuclear entities) and the lifetime of the free neutron; and the shape, structure and stability of the Milky Way galaxy. All these entities, ranging in size over more than 38 orders of magnitude, can each be considered to be an ‘atom’; in particular, the size of the alpha is calculated from QGT by assuming that the alpha is a “unitary entity” (that is, than which exists no simpler). The surprising conclusion is that clearly compound entities may also be physically treated as unitary (“uncuttable”) according to a principle of scale relativity, where a characteristic size for such an entity must be specified. Since QGT is entropic, and is therefore described using a logarithmic metric (involving hyperbolic space), it is not surprising that the length scale must be specified in order to account for unitary properties and for an entity to be appropriately considered an ‘atom’. The contribution to physics made by QGT is reviewed in the context of the related work of others.
Article
Physical Sciences
Thermodynamics

Xuefeng Xu

,

Liran Ma

Abstract: The equilibrium between a sessile liquid droplet and its environment under gravity hold both theoretical significance and practical implications. However, debates regarding the existence of such equilibrium have persisted for decades. Here, the effects of gravity on liquid-gas systems are first analyzed, and the results show that the gravitational influence need not be included in the Kelvin equation. Then, by considering the changes in both the atmospheric pressure and the liquid surface curvature, a generalized Kelvin equation is derived. Using this generalized Kelvin equation rather than the simplified classical form, we show that sessile liquid droplets resting on a flat, horizontal solid surface can indeed achieve full equilibrium with their atmosphere even in the presence of gravity.
Article
Physical Sciences
Thermodynamics

Sergey Amelkin

Abstract: The article considers the description of a macrosystem in terms that do not depend on the nature of the macrosystem. The results obtained can be used to describe macrosystem models of thermodynamic processes, and to create interdisciplinary models that take into account interactions of various nature. The macrosystem model is based on its representation in the form of a self-similar coloured oriented multigraph, for each node of which the equation of state is fulfilled, which connects extensive variables. One of the extensive variables is entropy, the maximum of which corresponds to the state of equilibrium. For processes in which fluxes are linearly dependent on driving forces, Onsager's relations are shown to be true, which makes it possible to prove that in the space of stationary processes, entropy production in a closed macrosystem is a metric similar to the Mahalanobis metric, which determines the distance between processes. Zero in such a space are reversible processes, thus the production of entropy shows the degree of irreversibility, as the distance from a researched process to a reversible one.
Article
Physical Sciences
Thermodynamics

Georgi Yordanov Georgiev

Abstract: Self-organizing systems convert noisy motion into efficient structure, yet a universal, dimensionless measure of this transformation is lacking. We derive the Average Action Efficiency (AAE)—events per total action—from a stochastic path-integral least-action principle. A Lyapunov identity links its monotonic rise to the action variance and the rate of noise reduction, defining growth, saturation, and decay regimes. AAE’s rise reflects path-entropy reduction under maximum-caliber principles. Agent-based ant foraging and single-molecule ATP-synthase data confirm the predicted sigmoidal rise and plateau. Because AAE needs only an event count and an integrated action, it offers a lightweight metric and design rule for feedback-controlled self-organization across physics, chemistry, biology, and active matter.
Article
Physical Sciences
Thermodynamics

Evgenii Rudnyi

Abstract:

The emergence of the entropy-as-disorder metaphor in the 19th century is considered. The logic behind the emergence of the metaphor of negative entropy in Schrödinger’s book is presented. After that the irrelevance of the entropy-as-disorder metaphor as well as the negative entropy metaphor is discussed. An alternative metaphor based on the concept of free energy is proposed.

Article
Physical Sciences
Thermodynamics

Muhamad Fouad

Abstract: In this work, we present a novel unified equation of state (UEOS) that integrates thermodynamic variables across all phases of matter, challenging longstanding paradigms in quantum mechanics and statistical physics. By deriving the UEOS from first principles combining relativistic invariance and nonlocal field interactions, we demonstrate that particle-wave duality emerges as an artifact of incomplete classical approximations rather than a fundamental property of quantum systems. Our analysis reveals those apparent dual behaviors in phenomena such as the double-slit experiment stem from emergent statistical fluctuations in the UEOS, effectively debunking the need for intrinsic duality and reconciling quantum observations with a purely field-theoretic framework. Furthermore, entropy is reinterpreted not as a measure of disorder but as a pseudo-thermodynamic quantity arising from incomplete knowledge of the UEOS parameters, resolving paradoxes in information theory and black hole thermodynamics. Finally, the UEOS elucidates the mystery of phase transitions by providing a continuous analytic function that predicts critical points without invoking symmetry breaking or renormalization group flows, offering exact solutions for van der Waals-like behaviors in real gases and superconductors. This unified approach not only simplifies the theoretical landscape but also suggests experimental tests via high-precision calorimetry and interferometry, paving the way for a paradigm shift in foundational physics.
Brief Report
Physical Sciences
Thermodynamics

Richard L Summers

Abstract: The second law of thermodynamics is grounded in our empirical experiences in which the total entropy of a physical system must always either increase or remain constant during any spontaneous process. This notion of entropy is classically described as a measure of the randomness or uncertainty concerning a system’s state and represents the degree to which the details of the system are unknowable and therefore unavailable to be converted into an identifiable activity or useful work. This uncertainty is a result of an observer’s inability to exactly discern, know, and predict the state of the system as a condition of indeterminacy. Recently, the concepts of entropy have been reconstituted as observational entropy corresponding to the observer’s lack of knowledge about the system. If the observer is to hold a central place in our modern understanding of en-tropy, then it is important to incorporate the biological principles for the processing of information as knowledge acquisition into the determination of these measures.
Article
Physical Sciences
Thermodynamics

Andreas Warkentin

Abstract: A multiscale thermodynamic model is considered, in which cosmological dynamics maintain non-equilibrium conditions by means of energy exchange among hierarchically ordered subsystems. The internal energy of each subsystem is recursively determined by energetic interactions with its subcomponents, forming a nested hierarchy extending up to cosmological scales. The total energy of the universe is assumed constant, imposing global consistency conditions on local dynamics. On the quantum scale, subsystems remain thermodynamically constrained in their accessible state space due to the unresolved energetic embedding imposed by higher-order couplings. As a result, quantum behavior is interpreted as an effective projection of unresolved thermodynamic interactions. In this view, the wave function serves as a statistical representation of a subsystem’s thermodynamic embedding, summarizing the unresolved energetic couplings with its environment, as shaped by recursive interactions across cosmological and microscopic scales. Phenomena such as zero-point energy and vacuum fluctuations are thereby understood as residual effects of structural energy constraints, rather than as signatures of fundamental quantum randomness. Classical mechanics arises as a limiting case under full energetic resolution, while the quantum formalism reflects thermodynamic incompleteness. This formulation bridges statistical mechanics and quantum theory without metaphysical assumptions. It remains fully compatible with standard formalism, offering a thermodynamic interpretation based solely on energy conservation and hierarchical organization. All effects arise from scale-dependent resolution, not from violations of established physics.
Article
Physical Sciences
Thermodynamics

Joel Almeida

Abstract: We propose the Dead Universe Theory (DUT), an alternative cosmological framework that redefines cosmic thermal evolution without relying on metric expansion, focusing on entropic dynamics within a collapsing vacuum. Contrary to classical thermodynamics, which posits absolute zero (0 K) as the lower limit, DUT introduces an entropic formulation of gravitational collapse and vacuum degeneracy capable of producing effective temperatures far below 0 K—reaching values on the order of 10⁻⁵⁷ K. Through high-precision computational simulations, we identify several falsifiable predictions, including the natural emergence of sub-0 K thermodynamic states in degenerate vacua; the existence of DUT-Ice, an ultra-dense crystalline phase with frozen entropy and selective transparency; entropic freezing, whereby cooling rates slow despite decreasing background temperatures; a sharp degeneracy threshold near E ≈ 10⁻³⁰ J marking the onset of extreme entropy collapse; a modified Stefan–Boltzmann law incorporating entropic resistance, altering late-stage cosmic thermodynamics; potential observational signatures in fossil planets orbiting dead stellar cores; and extreme gravitational degeneracy effects leading to weak repulsive interactions in ultra-low-energy regimes. Our results establish a computable, falsifiable model for post-CMB thermodynamics, with profound implications for vacuum energy extraction, black hole entropy theory, and a radically new perspective on the universe’s thermal future.
Short Note
Physical Sciences
Thermodynamics

Jordan Barton

Abstract: Classical thermodynamics describes energy and entropy in physical systems but lacks a framework for information-processing systems where meaning, coherence, and contradiction resolution play fundamental roles. We develop Coherence Thermodynamics, a rigorous extension of thermodynamic principles to semantic systems, by redefining temperature as semantic agitation energy, entropy as semantic disorder intensity, and heat as contradiction transfer across coherence boundaries. We establish four fundamental laws: a zeroth law defining semantic thermal equilibrium through temperature equality, a first law incorporating coherence work terms into energy conservation, a second law permitting local entropy reduction via contradiction metabolism while preserving global entropy increase, and a fourth law governing semantic force dynamics via a generalized Navier-Stokes equation driven by coherence gradients and information-theoretic inertia. All formulations maintain strict dimensional consistency and provide operational definitions through measurable field quantities defined on classical spacetime. Coherence Thermodynamics offers a mathematically rigorous foundation for the quantitative analysis of information processing, artificial intelligence, and biological cognition, establishing thermodynamic principles as universal laws governing both physical energy and semantic meaning across all scales of organization.

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