Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

On-the-Go Vis-NIR Spectroscopy for Field-Scale Spatial-Temporal Monitoring of Soil Organic Carbon

Version 1 : Received: 29 June 2023 / Approved: 12 July 2023 / Online: 12 July 2023 (04:58:36 CEST)

A peer-reviewed article of this Preprint also exists.

Reyes, J.; Ließ, M. On-the-Go Vis-NIR Spectroscopy for Field-Scale Spatial-Temporal Monitoring of Soil Organic Carbon. Agriculture 2023, 13, 1611. Reyes, J.; Ließ, M. On-the-Go Vis-NIR Spectroscopy for Field-Scale Spatial-Temporal Monitoring of Soil Organic Carbon. Agriculture 2023, 13, 1611.

Abstract

Agricultural soils serve as crucial storage sites for soil organic carbon (SOC). Their appropriate management is pivotal for mitigating climate change. To evaluate spatial and temporal changes in SOC within agricultural fields, continuous monitoring is imperative. In-field data sets of Vis-NIR soil spectra were collected on a long-term experimental site using an on-the-go spectrophotometer. Data processing for continuous SOC prediction involves a two-steps modelling approach. In Step 1, a Partial Least Square (PLSR) regression model is trained to establish a relationship between the SOC content and the spectral information also including spectral preprocesisng. In Step 2, the predicted SOC content obtained from the PLSR models is interpolated using ordinary kriging. Among the tested spectral preprocessing techniques and semivariogram models, SG and gapDer preprocessing along with a Gaussian semivariogram model, yielded the best performance resulting in a root mean square error of of 1.24 and 1.26 g kg-1. A striping effect due to the transect-based data collection was addressed by testing the effectiveness of extending the spatial separation distance, employing data aggregation, and defining the distribution based on treatment plots using block kriging. Overall, the results highlight the immense potential of on-the-go spectral Vis-NIR data for field-scale spatial-temporal monitoring of SOC.

Keywords

soil organic carbon; Vis-NIR spectroscopy; monitoring; pedometrics

Subject

Biology and Life Sciences, Agricultural Science and Agronomy

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