The available conventional corrosive fatigue model for assessing the corrosion fatigue failures on magnesium mount structural casting is not quite accurate as the formation of corrosion pit is random nature and the empirical equations that are derived out from specimen samples are majorly in linear format. Generally, casting shrinkage and porosity in as cast magnesium alloys can specially act as stress concentration sites for fatigue crack initiation additional to the oxide inclusions that are prompted under corrosive environmental conditions. These preferential sites for fatigue crack initiation will be related to formation of pits on the surface and at particular to tensile fiber stress locations. When magnesium mount structural casting is exposed to corrosive environment, both anodic and cathodic reactions are happening with a result of releasing hydrogen gas that plays major role in environmental assisted cracking [1-3].
Magnesium dissolution in aqueous solution is an anodic reaction whilst the hydrogen evolution is a cathodic reaction. Hydrogen could diffuse into magnesium matrix through corrosion pits formation and then cause the hydrogen embrittlement that could significantly reduce the mechanical strength of magnesium alloys. Thus, although the size of the pits is smaller than that of oxide inclusions on fracture surfaces fatigue cracks can still preferentially nucleate at pits even at lower stress amplitude in NaCl solution than at air.
2.2. Stochastic Process and Random Variables- Formulation
In order to explain quantitatively and investigate the regularities of the random phenomenon, it is a common practice to introduce a mathematical formulation that brings the randomness together with an appropriate measure of the possibilities of occurrences of various uncertain outcome of an experiment. Such a model forms a basic system for probability model in which main notions are defined as:
Sample space: This is defined as the collection of all possible outcomes from the experiments.
Random event: Event that can happen at unpredictable way.
Probability: Probability of the event.
A sample space will be denoted as Ω which contains all the possible or elementary outcomes of an observation denoted as γ, which satisfies, γ∈Ω. Let ξ be denoted as the family of subsets of Ω, described as the family of random events with which a probability of event P is defined. The probability of event P is described here as the probability of reaching required fatigue life at critical porosity fraction. The probability of event P is a function whose arguments are random events which is element of ξ so that it follows the following three axioms of modern probability [
2],
0≤ P(A) ≤ 1, for each A∈ ξ,
P(Ω) = 1
For any countable collection of mutually disjoint events, A1, A2, …An in ξ:
P{ ∪ An} = Σ P(An)
It is clear that in experiments on random phenomena, various outcomes or elementary events can occur. In many situations, they are represented by the real number X (γ). It is also possible that a real number can be assigned to each elementary event, γ∈Ω. X(γ) is called as a random variable which is defined as a real-valued function X = X(γ), γ∈Ω, defined on the sample space Ω, such that for every real number ‘x’ then the probability is defined as,
P{Ω: X(γ) ≤ x }
The existence of the probability of event {γ: X (γ) ≤ x} ensures that the probability of any finite or countable infinite combination of such events is well defined as P {x1 < X (γ) ≤ x2}.
The probabilistic behaviour of a random variable X (γ) is completely and uniquely specified by cumulative distribution function F
X (x) which is defined as,
By definition, the distribution function always exists and is a non-negative and non-decreasing function of the real variable ‘x’.
Property 1:
From the properties cumulative distribution function, it follows that,
FX (-∞)
= 0 ; and FX (+∞) = 1
(2)
Property 2 For any two real numbers a, b such that a < b, the probability is computed as,
Property 3 The function fX (x) is non-negative. Since integrating the density function on an event gives us the probability of the event. This property can be proved easily since the probability density function is the derivative of the cumulative distribution function. This cumulative function being a non-decreasing function, its derivative can never be negative.
2.2.1. Single Random Variables –Formulations.
The basic probability model for a single random variable is defined in this section.
By assuming, a random variable X (γ) is termed as a continuous random variable if its probability distribution function F
X (x) has a density function, such that,
Where ‘U’ is defined as any dummy variable. The function f
X (x) is called the probability density function of the random variable X (γ). Hence,
Further properties of probability density function are,
Physically when the random samples are drawn from the sample spaceΩ, it is essential to compute the mean and standard deviation of these random samples so that the probability density function could be derived out based on the type of distribution function it follows. When the random samples are repeated ‘N’ times, by having the X as random variables, x as real set numbers, among N experiments, the real value x
i can be repeated as n
i times, the average or mean is calculated as
Intuitively, the quantity of
is none other than measuring the probability of obtaining the result x
i over N experiments. Then the equation 9 can be re-written as,
When N as random samples which are infinitely growing, and X is the random variable which sometimes equal to the real number x
i, the ratio
goes to an infinitesimally small quantity which represents f
x(x
i). dx at point x
i. The mean or average value of a random variable is defined as an operator called expectation operator, E(X).
The notation E (.) stands for the average value operator, commonly called s mathematical expectation. The equation 11 is a similitude of centre of gravity equation which is defined as a summation of the product of each area strip to the length of the strips divided by total area of the body. The denominator of the equation 11 is representing the total area of the probability density function which is unity. Hence the equation 11 becomes,
Equation 12 is also called as average or mean value of the random variables X (γ) which is denoted as μX.
The variance of random variables X(γ) is defined as,
The square root of the equation 13 is called as the standard deviation of the random variables.
The ratio of variance to mean provides a coefficient of variation which normalizes the spread of occurrence of real numbers from the random variables X(γ).
Ideally, the equation 15 represents the standard deviation of random variables which is containing difference of mean square value to the square of the mean of random variables. Physically, σX measures the dispersion of the experiments results around its average value. When σX is small, the probability density function of X is a curve concentrated around its mean. When σX is large, this curve flattens and gets wider.
By the same means, it can be introduced the moments of any order n:
and the order ‘n’ centered moments is formulated by,
The characteristic function is an important analytical tool which enables to analyse the sum of independent random variables. Moreover, this function contains all the necessary information specific to the random variables X.
3.2.2. Bivariate and Multivariate Random Variables –Formulations.
The basic probability model when there are two or more random variables is defined in this section by above description which is based on a single random variable. This means it is also possible to generalize the above equations for the multi-dimensional case. It is focused now instead of random variables, to random vectors.
Let be X a two dimensional random vector X = (X
1, X
2). The joint cumulative distribution function of the random variables X
1 and X
2 are also called the cumulative distribution function of the random vector X which is defined as similar to equations 1 and 4.
Directly from the probability of axioms defined for single random variables alternatively changed as:
0≤ P {x1 ≤ X (γ) ≤ x2} ≤ 1, for each A∈ ξ,
P(Ω) = 1, or FX1, X2 (+∞, +∞) = 1,
FX1, X2 (x1, -∞) = 0 and FX1, X2 ( -∞, x2) =0,
For any countable collection of mutually disjoint events, A1, A2, …An in ξ:
P{ ∪ An} = Σ P(An)
As with the case of a single random variable, in the vector case, it is necessary to build a function called the joint probability density function of the variables X1 and X2 such that, the integration of these two events in the sample space, the conditional probability is obtained as:
It is now essential to bring the basic fundamental properties of conditional probability of events, that gives,
The condition for the equation 22 is at X1 and X2 is independent random variables, and then the joint probability density function of two independent random variables is given by the product of their respective marginal densities.
Similarly, the mean, variance, moments and centered order of moments are also defined for bi-variate random variables.
Joints moments of order n and m for X
1 and X
2 random variables,
The centered ordered n, m moments,
Among the centered moments the most important parameter, is called covariance between the two random variables X1 and X2.
The equation 27 is called variance-covariance matrix of (X1, X2) vector. If these two random variables are independent to each other, then their covariance is zero. If their correlation value is zero, then these variables said to be at orthogonal.
The correlation coefficient between the two random variables X
1, and X
2 is calculated as,
For transformation of n-dimensional random vectors, Jacobian of coordinates mapping is used. The stochastic equation which may be used to describe the time dependent corrosion process should consist of two main parameters that describe fluctuation in environmental conditions, and microscopical structural behavior of the material. A correlation of microscopic mechanisms of corrosion with its macroscopic statistical nature is needed for this development of stochastic corrosion fatigue equation. The macroscopic mechanisms of corrosion of material can be derived as referencing empirical equation from experiments. Microscopical structural behavior of material can be contributed with two factors: consideration of fluctuation in environmental, and average background of structure superimposed by inhomogeneous fluctuations due to variety of inherent defects.
The stochastic equation which may be used to describe the process of corrosion as presented above stochastic process with random variable as pit formation with respect to time, fatigue life and stress (loading). Because fluctuations of the environment or of the microscopic structure led to stochastic fluctuations of the corrosion rate, the corrosion rate should obey the above-mentioned stochastic corrosion fatigue model in along with experimentally obtained empirical equations (as presented in next section).