Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Apple-Like Shape of Freezing Paraffin Wax Droplets and its Origin

Version 1 : Received: 12 July 2023 / Approved: 14 July 2023 / Online: 17 July 2023 (09:27:24 CEST)

A peer-reviewed article of this Preprint also exists.

Roy, P.K.; Shoval, S.; Shvalb, N.; Dombrovsky, L.A.; Gendelman, O.; Bormashenko, E. Apple-like Shape of Freezing Paraffin Wax Droplets and Its Origin. Materials 2023, 16, 5514. Roy, P.K.; Shoval, S.; Shvalb, N.; Dombrovsky, L.A.; Gendelman, O.; Bormashenko, E. Apple-like Shape of Freezing Paraffin Wax Droplets and Its Origin. Materials 2023, 16, 5514.

Abstract

Paraffin wax stores energy in the form of latent heat at a nearly constant temperature during melting and releases this energy during solidification. This effect is used in industrial energy storage. An unusual change in the shape of a melted droplet of paraffin wax placed on a relatively cold glass plate is studied. As the droplet solidifies, its upper surface becomes nearly flat and a dimple is formed in the center of this surface, making the droplet look like a fruit (pumpkins are more commonly shaped like this, but the authors prefer apples). A series of experiments, as well as physical and numerical modeling of the droplet's thermal state, taking into account the formation of a mushy zone between liquidus and solidus, made it possible to understand the role of gravity and gradual increase in viscosity and density of paraffin wax on changing the droplet shape and, in particular, to clarify the mechanism of formation of the dimple on its upper.

Keywords

droplet; dimple; shape; freezing; paraffin wax; phase change material.

Subject

Physical Sciences, Applied Physics

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