Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

A Comparison of the Effect of Cellulose Nanocrystals (CNC) and Polyethylene Glycol (PEG) As Additives in Ultrafiltration Mem-Branes (PES-UF): Characterization and Performance

Version 1 : Received: 1 May 2023 / Approved: 2 May 2023 / Online: 2 May 2023 (03:32:44 CEST)

A peer-reviewed article of this Preprint also exists.

Adeniyi, A.; Odo, G.O.; Gonzalez-Ortiz, D.; Pochat-Bohatier, C.; Mbakop, S.; Onyango, M.S. A Comparison of the Effect of Cellulose Nanocrystals (CNCs) and Polyethylene Glycol (PEG) as Additives in Ultrafiltration Membranes (PES-UF): Characterization and Performance. Polymers 2023, 15, 2636. Adeniyi, A.; Odo, G.O.; Gonzalez-Ortiz, D.; Pochat-Bohatier, C.; Mbakop, S.; Onyango, M.S. A Comparison of the Effect of Cellulose Nanocrystals (CNCs) and Polyethylene Glycol (PEG) as Additives in Ultrafiltration Membranes (PES-UF): Characterization and Performance. Polymers 2023, 15, 2636.

Abstract

This work demonstrated the potential of CNC as a substitute for PEG as an additive in ultrafiltration membrane fabrication. Two sets of modified membranes were fabricated using the phase inversion technique with polyethersulfone (PES) as the base polymer, and 1-N-methyl-2 pyrrolidone (NMP) as the solvent. The first set was fabricated with 0.075 wt% CNC, while the second set was fabricated with 2 wt% PEG. All membranes were characterized using SEM, EDX, FTIR, and contact angle measurements. The SEM images were analyzed for surface characteristics using WSxM 5.0 Develop 9.1 software. The membranes were tested, characterized, and compared for their performance in treating both synthetic turbid water and real restaurant Both membranes exhibited improved hydrophilicity, morphology, pore structure, and roughness. Both membranes also exhibited similar water flux for real and synthetic polluted water. However, the membrane prepared with CNC gave the higher turbidity removal and COD removal when raw restaurant water was treated. The membrane compared well with the UF membrane containing 2 wt% PEG in terms of morphology and performance when synthetic turbid water and raw restaurant water were treated.

Keywords

ultrafiltration; PEG; CNC; COD; turbidity; morphology

Subject

Chemistry and Materials Science, Polymers and Plastics

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