Battery Thermal Management Systems (BTMS) are critical for maintaining optimal operating temperatures (20-40°C) in lithium-ion batteries, particularly for electric vehicles (EVs) and grid-scale energy storage [1,2]. Phase Change Materials (PCMs) have emerged as a transformative solution, leveraging latent heat absorption/release during phase transitions to provide passive thermal regulation [3]. This review systematically evaluates inorganic (salt hydrates), organic (paraffins, fatty acids), and composite PCMs, analyzing their thermophysical properties, performance characteristics, and implementation challenges in BTMS applications [4,5]. Key findings reveal that advanced composite PCMs with thermal conductivity enhancers (graphene, metal foams) can achieve 3-5× improvement in heat dissipation while maintaining >90% of base latent heat capacity [6,7]. The paper concludes with actionable recommendations for next-generation PCM development and integration strategies.