Submitted:
30 October 2025
Posted:
31 October 2025
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Abstract
Keywords:
1. Introduction
2. Materials and Methods
2.1. Site Selection
2.2. Data Collection
2.3. Sampling Procedure
2.4. Exposure Limits
4. Results and Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| ACGIH | American Conference of Governmental Industrial Hygienists |
| CIPP | Cured-In-Place Pipe |
| CUIRE | Center for Underground Infrastructure Research and Education |
| GC-MS | gas chromatography-mass spectrometry |
| MH | Manhole |
| NIOSH | National Institute for Occupational Safety and Health |
| OSHA | Occupational Safety and Health Administration |
| PEL | permissible exposure limit |
| PID | Photoionization Detector |
| Ppm | Parts per Million |
| TWA | time-weighted average |
| USEPA | United States Environmental Protection Agency |
| VOCs | Volatile Organic Compounds |
| AEGLs | Acute Exposure Limits Guideline Levels |
References
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| Installations Sites |
Length (feet) |
Diameter (inches) |
Year | Curing Method | Type or Resin | Location |
|---|---|---|---|---|---|---|
| Installation 1 (Site 1) |
327 | 10 | 2024 | UV-Light | Non-styrene-based Resins | Washington, D.C. |
| Installation 2 (Site 2) |
250 | 10 | 2024 | UV-Light | Non-styrene-based Resins | Washington, D.C. |
| Installation 3 (Site 3) |
241 | 10 | 2024 | Hot Water | Non-styrene-based Resins | Washington, D.C. |
| Installation 4 (Site 4) |
261 | 10 | 2024 | Hot Water | Non-styrene-based Resins | Washington, D.C. |
| Installation 5(Site 5) |
674 | 8 | 2024 | Steam | styrene-based Resins | Texas |
| Installation 6 (Site 6) |
1,029 | 48 | 2023 | Hot water | styrene-based Resins | Texas |
| No | Analytes | No | Analytes |
|---|---|---|---|
| 1 | Acetone | 32 | Ethyl acetate |
| 2 | Benzene | 33 | Ethylbenzene |
| 3 | Benzyl chloride | 34 | 4-Ethyltoluene |
| 4 | Bromodichloromethane | 35 | Heptane |
| 5 | Bromoform | 36 | Hexachlorobutadiene |
| 6 | Bromomethane (Methyl Bromide) | 37 | Hexane |
| 7 | 1,3-Butadiene | 38 | Isopropanol |
| 8 | Carbon disulfide | 39 | Methyl t-butyl ether (MTBE) |
| 9 | Carbon tetrachloride | 40 | Methyl butyl ketone (2-Hexanone) |
| 10 | Chlorobenzene | 41 | Methyl ethyl ketone (2-Butanone) |
| 11 | Chloroethane (Ethyl Chloride) | 42 | Methyl isobutyl ketone (MIBK) |
| 12 | Chloroform | 43 | Propene |
| 13 | Chloromethane (Methyl Chloride) | 44 | Styrene |
| 14 | 3-Chloro-1-Propene (Allyl Chloride) | 45 | 1,1,2,2-Tetrachloroethane |
| 15 | Cyclohexane | 46 | Tetrachloroethene (PCE) |
| 16 | Dibromochloromethane | 47 | Tetrahydrofuran (THF) |
| 17 | 1,2-Dibromoethane (EDB) | 48 | Toluene |
| 18 | 1,2-Dichlorobenzene | 49 | 1,1,1-Trichloroethane (TCA) |
| 19 | 1,3-Dichlorobenzene | 50 | 1,1,2-Trichloroethane |
| 20 | 1,4-Dichlorobenzene | 51 | 1,3,5-Trimethylbenzene |
| 21 | 1,1-Dichloroethane | 52 | 1,2,4-Trimethylbenzene |
| 22 | 1,1-Dichlorethene | 53 | 2,2,4-Trimethylpentane |
| 23 | Dichlorodifluoromethane (F12) | 54 | 1,2,4-Trichlorobenzene |
| 24 | Dichlorotetrafluoroethane (F114) | 55 | Trichloroethene (TCE) |
| 25 | 1,2-Dichloroethane (EDC) | 56 | Trichlorofluoromethane (F-11) |
| 26 | cis-1,2-Dichloroethene | 57 | Trichloritrifluoroethane (F-113) |
| 27 | trans-1,2-Dichloroethene | 58 | Vinyl acetate |
| 28 | Dichloromethane (Methylene chloride) | 59 | Vinyl Bromide (Bromomethane) |
| 29 | 1,2-Dichloropropane | 60 | Vinyl chloride |
| 30 | cis-1,3-Dichloropropene | 61 | m&p-Xylenes |
| 31 | trans-1,3-Dichloropropene | 62 | o-Xylene |
| Environment | Installations (Sites) |
Styrene (ppm) |
Hexane (ppm) |
Toluene (ppm) |
Ethanol (ppm) |
m&p-Xylenes (ppm) |
|---|---|---|---|---|---|---|
| Residential | Site 1 | 0 | 0.0070935 | 0.0053077 | 0.0265357 | 0.0025332 |
| Residential | Site 2 | 0 | 0.0022132 | 0.0148616 | 0.0424571 | 0.0025332 |
| Residential | Site 3 | 0 | 0 | 0 | 0.0169829 | 0 |
| Residential | Site 4 | 0.0032869 | 0.0007094 | 0.0009289 | 0.0419264 | 0.0089814 |
| Residential | Site 5 | 8.22 | 0.0061003 | 0 | 0.1326785 | 0 |
| Residential | Site 6 | 13.85 | 0.0029281 | 0.0006635 | 0 | 0.0009442 |
| Installations | Styrene (ppm) |
Cumene (ppm) |
Acetophenone (ppm) |
|---|---|---|---|
| Threshold (20) | Threshold (50) | Threshold (10) | |
| Installation 1 | 0.006 | 0.0038 | 0.004 |
| Installation 2 | 0.002 | 0.008 | 0.005 |
| Installation 3 | 0.354 | 0.02 | 0.03 |
| Installation 4 | 0.0159 | 0.0155 | 0.0296 |
| Installation 5 | 6.12 | 0.0028 | 0.0031 |
| Installation 6 | 25.5 | 0.007 | 0.004 |
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