A Life Cycle Analysis Applied to Municipal Effluents in Africa Has the Potential to Make a Significant Contribution to the Field

1. Introduction

The literature suggests various waste management strategies, including conventional treatments, with outcomes varying depending on farm type [1,2,3,4]. Natural treatment systems for wastewater (NTSW) have emerged as viable options for both urban and rural settings due to their low energy requirements, effective contaminant removal capabilities, and potential for effluent reuse [5,6,7,8,9,10,11,12]. NTSW, as defined in the essay, are treatment systems where effluent storage involves high residence times, allowing organic matter degradation by bacterial activity. These systems are referred to in scientific literature as unconventional technologies, low-cost systems, soft technologies, green systems, and others. The key differences between NTSW and conventional systems include zero energy consumption for removal and a larger treatment surface area. NTSW harness the synergy of physical, chemical, and biological processes found in nature. They have demonstrated suitability across various applications, including urban and rural contexts, with high pollutant removal capacities and opportunities for effluent reuse. On Gran Canaria Island, NTSW solutions have been trialed in remote rural areas [13,14,15], yielding promising results with removal efficiencies exceeding 75% for chemical oxygen demand (COD) and 90% for total suspended solids (TSS).

The UNE-EN-ISO 14040 (Spain) provides a definition of Life Cycle Assessment (LCA) as a methodology for evaluating the environmental impacts of a product system throughout its life cycle. This life cycle encompasses all consecutive and interrelated stages, from the acquisition of raw materials to final disposal. LCA involves collecting and assessing data regarding inputs, outputs, and potential environmental impacts associated with each stage of the product system's life cycle. Depending on the specific objectives of the assessment, LCA can be conducted at different levels of detail, resulting in three main types: The first type is a qualitative study that identifies the most significant impacts in a generic way. The second type is a more comprehensive LCA that focuses on the most important steps and analyzes the most important data. The final type is the most intricate, as it involves a comprehensive analysis of the impacts, stages, and inventory at both qualitative and quantitative levels [16,17,18,19]. The LCA covers all stages of the system's life cycle, from the extraction and processing of raw materials for construction to its operation and maintenance. By conducting a comprehensive LCA, it aims to provide an estimate of the environmental impacts associated with each stage of the system's life cycle. Furthermore, the results of this LCA can serve as a valuable tool for decision-making in the planning of wastewater treatment and reuse models in similar areas. It can provide insights into the environmental implications of different treatment options, helping stakeholders make informed choices that prioritize sustainability and minimize environmental harm. Ultimately, this LCA contributes to the development of a decision-making guide for sustainable wastewater management in regions with characteristics like those studied [20,21,22,23,24].

The aim of this study is to evaluate the environmental impact of a natural wastewater treatment system throughout its entire life cycle, using Life Cycle Assessment (LCA). The system is designed to treat wastewater discharges from the municipality of Santa Catarina, with a focus on the Achada Galego locality on the island of Santiago, Cape Verde. Currently, the system operates at a flow rate of 140 m³ per day, although it was designed for a maximum capacity of 200 m³ per day [25,26,27,28].

The novelty of this study considers the data used was collected from the operational NDS located in Santa Catarina. In contrast, the majority of other studies are conducted in pilot plants. However, this study considers the impact of real-world factors such as rainfall, droughts, population density, and wastewater generation. Furthermore, the subsequent application of treated water, either for irrigation or direct discharge, is a further innovation. This is due to the properties of the treated water. It was not possible to consider the use of water for irrigation in this study due to a lack of information and knowledge regarding its application in the program, necessitating further study.

2. Materials and Methods

NTSW is located on the island of Santiago (Cape Verde), in the locality of Achada Galego (N: 15 05' 49.99, W: 234101.75). This pilot project is financed by the Spanish Cooperation and aims to provide Cape Verde with a system for the storage and treatment and distribution of treated wastewater for agricultural purposes. The planned infrastructure takes as a reference a small experimental part of the reuse of treated wastewater carried out in the framework of the ADAPTaRES project at the Santa Catarina NTSW, co-financed in this case by the European MAC Programme 2014-2020 and Canary Islands Technological Institute (ITC). The facility is designed for a population equivalent of 1,600 inhabitants.

2.1. Description Plant

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Preliminary treatment consisting of roughing screens, this stage will guarantee the proper functioning of the subsequent equipment, avoiding possible obstructions. There are two lines of 0.4 meters wide and 3 meters long.

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Primary treatment (anaerobic lagoons), this process consists of reproducing the self-purification phenomena that occur naturally in rivers and lakes. In this type of lagoons, there are high organic loads that produce oxygen-free conditions and anaerobic bacteria proliferate. This slows down the velocity and causes the heavier suspended particles to settle to the bottom, thus reducing the suspended solids content. These accumulate at the bottom and r e s u l t in the formation of a sludge layer which is usually removed every 5-10 years of operation due to anaerobic stabilization at room temperature, which reduces its volume. There are three lines 3.6 meters deep, 21.8 meters long and 8.8 meters wide. This is followed by a batch discharge system.

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Secondary treatment (Constructed Wetland with Vertical flow): The water coming from the anaerobic lagoon flows vertically through a media is collected in a drainage network at the bottom of the wetland, which is connected to aeration chimneys. The feed is discontinuous. In this case there are 6 vertical flow wetlands 13 meters wide and 26.8 meters long. This is made up of different layers of gravel and sand and has an impermeable membrane at the bottom of the basin.

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The reserve lagoon is covered with a shading mesh made up of two grids of 5 mm Bayco type black polyamide monofilament yarn, arranged in 0.5x0.5 grids, with dynamometer-controlled tensioning tied to the perimeter anchoring structure and a double layer of black polyethylene shading fabric with a minimum 85% shade, located between the two grids of yarns. The dimensions of this water are 31.6 meters long, 20.60 meters wide and 0.5 meters deep, giving a volume of about 325 m³. This lagoon will act as an initial reservoir, where the water treated in the treatment plant will be stored and can be pumped to feed the tertiary treatment.

The wastewater reclamation processes installed at the plant will be described below.

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Underground treated water tank: The storage volume is 10 m³ . It has two impulsion pumps at the outlet that will propel the water to the filtration system.

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Filtration: In this stage, the aim is to eliminate dissolved solids practically in their entirety, in addition to reducing the microbiological activity of the water. This filtration system consists of a vertical filter with AFM (Activated Filter Media) as the filter medium. These must have a backwashing system with clean water. Two lines are arranged in parallel and at the inlet of this system there is a flow meter to control the flow of water entering the system.

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Refining: Once the water has been filtered, it will be passed through a manual cleaning ring filter with a 50 mm pitch, which will improve the quality of suspended solids and turbidity. In this process there are also two lines, consecutive to the previously mentioned filters.

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Main disinfection: The selected disinfection system is a compact ultraviolet disinfection equipment. This system can interact with the DNA and RNA of bacteria, viruses... preventing their reproduction.

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Final tank: The treated water will be deposited in a 50 m³ closed reinforced concrete tank. This is equipped with a water disinfection system based on the addition of trichlorine tablets.

In Figure 1 is shown the stages of Santa Catarina NTSW.

The stages/aspects that are considered in the LCA are the following:

• Materials for the construction of the facilities and their transport.
• Construction of the installation considering the required energy/fuel consumption.
• Maintenance and operation.
• The impact of the treatment and disposal of waste to be landfilled or treated as by-products.

The stage excluded from the analysis is the dismantling. Likewise, charges relating to the manufacture of the machinery and infrastructure necessary for the extraction and transport of any raw materials or materials used in the construction of the plant or the materials, waste or by-products resulting from the maintenance of the plant are also disregarded. Figure 2 shows the stages that are included in the study (red box) and those that have not been considered for this study.

2.2. Inventory

In this section, the inventory analysis of each of the selected wastewater treatment plants must be carried out. To do this, it is necessary to describe the facilities in such a way that all the processes that make them up are known. The inventory will consist of two parts; one associated with the construction phase, where all the materials and processes necessary for the construction of the treatment plant will be collected, and the other with the maintenance and operation phase. The latter will include the reagents necessary for the correct development of the plant and the maintenance stages and the waste/by-products obtained from this maintenance. In turn, the emissions associated with each of the processes in this operation phase will be obtained.

2.2.1. Construction Phase

Materials used.

This section defines the quantities of the main components of each of the stages that make up the Santa Lucía waste-water treatment plant, namely the intake works, the roughing works, the septic tank, the siphon and flow meter boxes, the vertical wetlands, the horizontal wetlands, the storage tank, the interconnection elements and the passageways. For the calculation of the quantities required and the materials used for the construction of the treatment plant, reference was made to the construction reports for both the Santa Lucía treatment plant and the Calheta treatment plant (Maio Island in Cape Verde), which has similar characteristics to the Santa Lucía NTSW. The latter is required for the calculation of elements such as the septic tank and the interconnection chambers, which were not included in the Santa Lucia report.

Arrival and roughing works

It is considered that the pit is built with a medium-hard concrete base, like cleaning concrete. Elements such as plastering the inside of the pit or compacting the soil, or the removal of surplus material, are not considered. For the roughing gratings, it is considered that they are manufactured with low alloy steel as this steel is the most used for the manufacture of stainless steels as in this case. The following are also not considered. The quantities of steel required for the manufacture of the grating are simply considered in the manufacturing process of the grating. The excavation of the ground is considered as the sum of the amount of ground to be excavated from the roughing pit.

Roughing.

First, the amount of concrete necessary for the construction of the pit containing the roughing gratings is obtained per inhabitants, m³ concrete = 2.6x10^-4 m³ /ℎ. e. Secondly, the amount of steel required for the construction of the roughing grate is obtained. kg steel = 0,18 kg/ ℎ.e.

Excavation. To obtain the impact associated with the excavation process, it is considered that the entire impact will be determined by the fuel use of the backhoe loader carrying out the excavation. The total excavation area is determined as the land occupied by the backhoe loader 1,995 m³. Knowing that the efficiency of the backhoe loader is 0.12 h/m³, we can calculate the number of hours needed to excavate the land. Furthermore, it is known that the power of the backhoe loader is 70 kW, so if we multiply the time needed to obtain kWh needed. The efficiency of the backhoe loader is 90%. As the fuel used by this machinery is diesel, the number of liters per inhabitant equivalent used is obtained by means of the LCV of this fuel. Fuel used was 0.011 L / h.e.

Land occupation: One of the most important aspects of this type of treatment system is the amount of land it occupies, so it is considered very necessary to quantify the amount of land that each of the processes that make up the NTSW will occupy. Land occupation was 0,0018 m²/h.e.

Discontinuous discharge system.

The discontinuous discharge system consists of a "decolloideurs" and a "chasses", both composed of 3 compartments of equal magnitude. The first of these has dimensions of 4.5 meters by 5 meters each with a depth of 2 meters, making a total of 4.5 meters wide by 15 meters long. The second of these is 7 meters wide by 4.5 meters long each with a depth of 1 meter, making a total of 13.5 meters long. Both structures will be made of medium-hard concrete with a thickness of 0.1 meter. m³ concrete was 0,02 m³ /ℎ. e

Excavation: To obtain the impact associated with the excavation process, it is considered that the entire impact will be determined using fuel by the backhoe loader carrying out the excavation. For this purpose, the total excavation surface is determined as the land occupied by both systems: 94.5 m³ (chasses) and 135 m³ (decolloideurs), and was 0.13 L / h.e.

Land occupation: 0.101m² /ℎ. e

Anaerobic Lagoon.

The anaerobic lagoons in the treatment plant are open-air. The purpose of these lagoons is to reduce the content of suspended solids, which are incorporated into the layer of sludge accumulated at the bottom. The water is introduced at the bottom of the lagoon, causing an absence of oxygen in the inlet water. The output water is obtained from the upper part. The considerations made in the manufacturing process of the anaerobic ^lagoons are as follows: There are three parallel lagoons operating at the same time whose dimensions are 8.24 meters wide (each) and 23.26 meters long. The depth of the three lagoons is 4 meters each. The construction process is based on excavating the area where the lagoons are installed, covering the ground with a layer of geotextile and a layer of EPDM on top of the geotextile. This will allow the surface to be waterproof and the EPDM covering with geotextile will prevent cracks in the geotextile. On the other hand, pipes are required for the drainage of the incoming and outgoing water and a manhole at the inlet to allow the correct distribution of the water.

Anaerobic lagoon pit.

The water inlet to the lagoons is regulated by a chamber located at the beginning of the lagoons. The dimensions of the chamber are: 1 meter wide, 1 meter long and 1 meter high. Considering a thickness of 0.05 meters of concrete, the result is as follows: m³ concrete = was 1.6x10^-4 m³/ℎ. e. The steel used in the manhole closure plate is calculated according to the dimensions of the manhole and the thickness of the door, which are: 1 meter long, 1 meter wide and 0.02 meter thick. kg steel used 0.098kg/ℎ. e

Anaerobic lagoon manufacture.

The lagoons are waterproofed with a 1.52 mm thick EPDM sheet and a 300 g/m² geotextile sheet underneath the EPDM sheet. The geotextile sheet is made of polypropylene. In this case, more EPDM and geotextile is required because in addition to covering the ground, the sides (4 meters high) must be covered and there is material left over at the top of the wetland (0.5 meters will be considered). Therefore, the following will be needed: Geotextile 0,27 kg/ℎ.e. and EPDM 0.185kg/ℎ. e

Pipelines.

Approximately 15 meters of piping is required in each of the lagoons, with three lagoons totaling 45 meters. PE pipes with a diameter of 160 mm and a thickness of 3.0 mm are used 0.033 kg/ℎ.e.

Obtaining the required volume of PE: Calculation of the perimeter of the cylinder with a diameter of 160 mm and calculation of the perimeter of the cylinder with a diameter of 154 mm. Subtract and multiply by the length to obtain the amount of PE required. Multiply by the density of the cylinder and obtain the kg of PE required.

Excavation:

The excavated land corresponds to the sum of the dimensions of the three anaerobic lagoons and the inlet chamber, being in total: 2300 m³. The liters of diesel are calculated in the same way as in the previous sections, and it was 1.31 L / h.e.

Land occupation: The anaerobic lagoons occupy a total of 574.99 m² so they will have a much more relevant weight than the rest of the processes. The total surface area occupied was 0.36 m² /ℎ. e

Vertical Flow Constructed Wetlands

There are six vertical flow constructed wetlands. It should be noted that for the purposes of the inventory of wetlands, a single wetland is considered, the dimensions of which are the sum of the two wetlands separately, thus having a wetland of 3,335 m². The aggregates used are 15-25 mm and 5-12 mm gravel, but due to the lack of data on particle sizes, all gravel is 30-32 mm. In addition, a sheet of ethylene-propylene-diene rubber (EPDM) will be used to waterproof the system. In addition, there is a collection chamber at the inlet of the vertical flow system. No account will be taken of the stones protecting the sheeting or other materials other than gravel, EPDM, polyethylene (PE) pipes and concrete.

Vertical wetland pit: The dimensions of both manholes, and was considered 3,1x10^-4 m³ /ℎ.e. The steel used in the manhole closure plate is calculated in the same way as the closure plate of the roughing manhole, and it was 0.314 kg/ℎ.e.

Manufacture of vertical flow wetland: The dimensions of each wetland are as follows (note that there are 6 wetlands in total): 13 meters wide, 26.8 meters long and 1.2 meters deep. In this case the flattening of the terrain is not considered. The wetland is waterproofed with a 1.52 mm thick EPDM sheet and 2 sheets of 300 gr/m² geotextile between the EPDM sheets. The geotextile sheet is made of polypropylene. In this case, a larger quantity of EPDM and geotextile is required because in addition to covering the ground, the sides must be covered (1.2 meters of height) and surplus material at the top of the wetland (0.5 meters shall be considered). Therefore, the following will be needed of 1.039 m²-/h.e and EPDM 0.36 kg/ℎ.e. For the calculation of the amount of gravel required, the same gravel is considered for the entire surface. Therefore, it was required to 1,698 kg/ℎ.e.

Pipelines: 1,245 meters of pipes are needed for the conduits corresponding to the vertical wetlands. PE pipes with a diameter of 160 mm and a thickness of 3.0 mm are used. It was required to 0.922 kg/h.e. Obtaining the required volume of PE: Calculation of the perimeter of the cylinder with a diameter of 110 mm and calculation of the perimeter of the cylinder with 106.8 mm. Subtract, multiply by the length and obtain the amount of PE required. Multiply by the density of the PE and obtain the kilograms required.

Excavation: The excavated land corresponds to the sum of the dimensions of the two vertical wetlands and the manholes of each of them, being in total: 2,509 m³. The liters of diesel are calculated in the same way as in the previous sections. It was required to 1.42 L /h.e.

Land occupation:

The vertical flow wetlands occupy a total of 2,090 m² so they will have a much more relevant weight than the rest of the processes. The total surface area considered was of 1,31 m² /ℎ. e

Storage

The manufacturing process of the storage lagoon is based on the excavation of the land occupied by the lagoon, the placement of a concrete slab and its subsequent waterproofing with waterproofing paint. As in the previous cases, the removal of excess material and backfilling with excavated material is not considered. One of the main problems of the water treated in this NTSW is that it suffers a worsening of its quality conditions because it is in the open air, thus encouraging the growth of micro-algae. This factor causes a lack of oxygen. Also, the presence of birds on the surface of the lagoon can lead to an increase in microbiological indicators. It is therefore proposed to cover the lagoon as a solution to these problems. A cover consisting of a 5 mm polyamide shading mesh and a double layer of high-density polyethylene shading fabric was considered.

Manufacture of the storage lagoon:

The dimensions of the storage pond are 30.6 meters long, 19 meters wide and 1 meter deep. A thickness of 0.04 meters of concrete was considered. It was calculated of 0.15 m³ /ℎ.e. It is proposed to carry out the waterproofing with waterproofing paint. In the same way as for the septic tank, since this product was not found in the SimaPro bases, it was decided to choose a waterless acrylic varnish which can also be used as a waterproofing agent. The kilograms of acrylic varnish are obtained from the dimensions of the walls to be waterproofed and a thickness of approximately 60 microns. It was considered of 0.0052 kg/ℎ. e.

Excavation

It is therefore necessary to excavate 590 m³. Therefore, it was obtained, 0.335 L/h.e.

Land occupation

The total surface area occupied by the storage lagoon is quite similar to that of the wetlands, 0.369 m²/ℎ.e.

Lagoon cover:

In this case, it is necessary to know the quantity of polyamide yarn and shading mesh to be used.

POLYAMIDE YARN: Polyamide yarn is a synthetic fibre plastic (nylon, kevlar...) and/or natural (wool or silk). In this case a type of nylon is used. The total surface area of the storage pond is estimated and using this data, the thickness of the thread and the density of this material, the necessary kilograms was 2.10 kg/ℎ.e.

SHADING MESH: The lagoon shall be covered with double high-density polyethylene (HDPE) mesh with shading capacity. The quantity required is calculated in the same way as for the polyamide yarn. It was considered 3.50 kg/ℎ.e.

Passageways and pipelines

In this section, the materials necessary for the construction of the access and protection areas of the treatment plant and the connections to be made for the transport of water from one point to another will be obtained.

Conducts:

The connections will be made with Polyethylene pipes with a diameter of 160 mm and a thickness of 3.9 mm. The meters required was 133 meters of pipe or 0.804 kg/ℎ.e.

Excavation of the pipeline area:

Taking into account the dimensions, it is estimated that the total area to be excavated a m o u n t s t o 35 m3 . Therefore, it is obtained 0.02 L /h.e.

Occupation of land in pipelines

This section will consider the total number of meters required for pipes that serve as connections between the different processes of the WWTP:

𝑆𝑢𝑝𝑒𝑟𝑓𝑖𝑐𝑖𝑒 𝑜𝑐𝑢𝑝𝑎𝑑𝑎 = (133 ∗ 0.5)/1600 = 0.042𝑚2 /ℎ. 𝑒

Passage areas:

The areas that have had to be prepared so that the terrain is in the best possible condition for transit, if necessary, are referred to as transit areas.

For example, for sampling. In addition, the protection of the terrain by means of fences covering it shall also be considered in this section.

The total plot size is 14867 m2 . These data are approximate data obtained by means of Graf Can Visor. If we deduct from this the areas where the purification equipment is located, the plot to be developed is 10217 m2 . (The land of the drying beds is counted as having to be developed, but no inventory of the same is made).

To prepare the plot, the land will be cleared and cleaned using a wheel loader.

Knowing that the efficiency of the loader is 0.021h/m3, we can calculate the number of hours necessary to excavate the terrain. We also know that the power of the same is 120 kW, so if we multiply the time required by the power we obtain the kWh required. (Consider an efficiency of 90%).

As the fuel used by this machinery is diesel, if we obtain the PCI of this fuel, we can obtain the liters of fuel needed.

Fence used: The fence used to surround the entire plot is a grey flat electro-welded mesh with holes (50*50*4 cm) whose dimensions are 2.6 metres wide by 2 metres high.

Taking into account that the perimeter of the plot is 806 m, about 310 prefabricated steel fences will be needed. As each mesh weighs 18.41 kg, this makes a total of 5707 kg.

Chromium-plated steel will be used as this is the most commonly used steel in the stainless-steel industry.

Occupation of the land in transit areas:

This section considers all the land that has had to be conditioned to allow easy access to all the processes that make up the WWTP. This quantity has been calculated beforehand, as it was necessary to know the diesel used to prepare the plot. Therefore, it is obtained:

Elements of tertiary treatment1:

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Feed pump for tertiary treatment: compact, reliable, horizontal, multistage end-suction centrifugal pump.

Water pumps usually consist of the following materials:

• Hydraulic body: stainless steel
• Pump casing: AISI 304
• Impeller: Stainless steel

As can be seen, the material most commonly used for the manufacture of this type of pump is stainless steel, so for this study, the pump will be considered to be made entirely of stainless steel. The weight of the pump is 31.7 kg, according to its technical data sheet.

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Washing pump: single-stage pump with top extraction system for easy disassembly.

The main component used for the manufacture of the seal is cast iron, some small parts such as the rotary seal ring or the stationary seat are made of silicon carbide or EPDM in the case of the secondary seal.

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Filtration (AFM filter): In this case, the filter is made of laminated polyester reinforced with glass fibre almost entirely except for the cover.

It will not be introduced in the analysis as not all systems have this treatment.

The side manhole is made of plastic-coated steel and the crepinas (filtered water collectors at the bottom of the filter) are made of polypropylene. It should also be noted that the filtering material is inserted inside the filter, this being green glass.

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Ring filter: This is a physical filtration system produced by the retention of particles in the channels created by the superimposition of a set of rings. The materials used in this case are glass-fibre reinforced polyamide and synthetic rubber for the seals. It is considered to be made entirely of reinforced polyamide. The weight of these devices is approximately 6 kg.

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Main disinfection (UV disinfection): This equipment generates ultraviolet radiation at a frequency of 254 nm, capable of destroying harmful bacteria and persistent viruses in the water without generating harmful by-products. The radiation chamber is made of AISI 314 stainless steel. The weight and whether any other material is in higher proportion than steel is unknown.

The UV filter installed at the WWTP is the SAV-UV-6 with a maximum flow rate of 5 m3/h and 80 W power.

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Final secondary disinfection tank (Chlorine): After the filtration, refining and main disinfection stages, the disinfected water is sent to the new reusable water tank, with a volume of 100m3, made of concrete.

The dimensions of the tank are as follows: 7 metre wide, 4.5 metre long and 3.2 metre high. Considering a thickness of 0.05 metres of concrete, we obtain:

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Tertiary process building: It is proposed that the construction of the building containing the treatment equipment be as follows:

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Concrete floor

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Concrete block walls

Regarding the impact assessment, this one establishes a relationship between the data collected in the inventory analysis and the environmental loads generated by them. To carry out the assessment, it is advisable to have a computer program that performs the calculations quickly and reliably. There is a great variability of programs such as SimaPro, Boustead, Umberto, Open LCA, etc. Each of them has different assessment methodologies. The assessment process is conducted in five distinct stages: classification, characterization, normalization, weighting and damage assessment. The latter three stages are optional. The initial stage involves defining and selecting impact categories. An impact category is defined as a representative class of environmental variables to which the results of the inventory can be assigned. The classification is based on the grouping of the environmental loadings of the different inputs and outputs of resources and energy according to the environmental effects produced. It should be noted that certain outputs contribute to more than one category. The effect produced by the repetition of some factor will be accepted, provided that these outputs are independent. Finally, regarding the characterization, the process by which the potential contribution of each compound detected in the inventory analysis is obtained, with regard to a given environmental effect. Computer programs are available that provide characterization results directly, obviating the need for separate calculations. The processes are obtained directly as a result of the program, whereby the program itself performs the classification and characterization of the study, negating the need for manual input.

Data bases available in SimaPro are the following.

ETH-ESU Library 96(2003): Contains energy inventory data. The inventory tables include emissions from primary energy extraction, refining and distribution, extraction of mineral matter, production of raw materials, production of semi-factories and auxiliary and working materials, provision of transport and waste treatment services, construction of infrastructure and energy conversion and transmission. infrastructure and energy conversion and transmission. The system description depicts the energy distribution situation of Switzerland and Western Europe concerning the production and imports of fuels and the production and imports of fuels and electricity production and business [5].

BUWAL Bookshop 250(2001): The inventory tables include emissions from raw material production, energy production, production of semi-factories and auxiliary materials, transport and material production processes. The description of the system is based on Swiss consumption of packaging materials and imports and exports of materials. The energy systems are based on ETH data, without considering capital goods; the plastics data are based on PWMI data [5].

IDEMAT Library 2001: Developed by the Faculty of Industrial Design Engineering of the Delft University of Technology (The Netherlands). The focus of the database is more than just the production of materials. Most of the data are original (not collected from other LCA databases) and come from a wide variety of sources. The Life Cycle Inventory includes mining, concentration and processing in the case of minerals, or harvesting and processing for agricultural products. In general, the average global situation is considered. Accordingly, transport is allocated to global mining and production of resources with Rotterdam as the final destination. Recycling of secondary materials is considered according to the average Western European situation. The system boundaries cover all processes, from nature [5].

Industry Data Library (2007): This database contains detailed inventories of common materials and processes, sourced directly from industries. It includes the ecoprofiles of plastics and their associated intermediates, created by Boustead for AMPE (European Centre for Plastics in the Environment of the Association of Plastics Manufacturers in Europe). The results are the industry average, calculated as the principal value of the participating companies weighted by their production. The Inventory table includes raw materials, emissions to air, water and waste for all operations since the extraction of raw materials from the earth [5].

Ecoinvent v.3.7.1 Founded in 2000 and developed by several Swiss institutes: Swiss Centre for Life Cycle Inventories, Swiss Federal Office and EMPA (Swiss Federal Laboratories for Materials Testing and Research). Materials Testing and Research). It can be seen as an update of the BUWAL 250 and ETH databases. Data on products and services from the energy, transport, building materials, chemicals, pulp and paper and waste treatment, agricultural sector, which are valid for Swiss and Western European conditions [5].

Dutch Input/Output data base Available at SimaPro Dutch Input/Output economic database. The starting point was an overview of how the distribution of the average consumer is spread over 350 categories. A connection was made between these categories and the economic sectors. The economic input-output table was used to plot the trade flows between these sectors. There are also foreign tables for OECD and non-OECD regions. This allows to trace the impact of goods produced outside the Netherlands [5].

Finally, the impact assessment methods to be used have to be defined, so first of all the impact categories to be considered have to be determined. The following is a description of the most relevant impact categories according to the Society of Environmental Toxicology and Chemistry (SETAC):

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Global warming (kg CO2 Equivalents)

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Consumption of energy resources (MJ)

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Ozone layer depletion (kg CFC-11 Equivalents)

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Eutrophication (kg NO3 Equivalents)

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Acidification (kg. SO2 equivalents)

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Consumption of raw materials (Tn)

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Formation of photochemical oxidants (kg. C2H4 equivalents)

It should also be noted that these are not the only impact categories that exist, as it must be considered that different categories are required in each study area. Some of them are the following:

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Human toxicity

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Ecotoxicity

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Land use (area occupied in m2/year)

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Depletion of mineral and fossil resources.

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Biodiversity (number of species or density of vascular plants representative of species diversity).

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Loss of life-supporting function (data on net primary production)

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Depletion of biotic resources

3. Results.

3.1. Operation and Maintenance Phase

Emissions to soil and water environment

The emissions associated with each process are determined by the conditions under which each of the stages operate. Likewise, as the entire system is waterproofed, there are no emissions into the soil. Furthermore, since the treated water obtained at the end of the treatment process is reused for olive tree cultivation, emissions to the water environment will not be taken into account. If, on the other hand, the treated water were to be discharged into the public water domain (marine environment, watercourse or subsoil), these emissions would be considered.

It should be noted that this study does not take into account the impact generated by the water used to irrigate the olive trees due to existing limitations. Likewise, an LCA could be considered for the olive trees in which the water needed for irrigation is obtained from the storage pond. In this case, it is considered that the treated water is kept in the storage pond without taking into account what happens to it afterwards.

Therefore, the only emissions that will occur in the Santa Lucia treatment system will be emissions to the atmosphere, in the form of CO2, CH4, H2S, H2O or N2, depending on the operating conditions.

Atmospheric emissions

Emissions to air will be determined by the biodegradable organic matter removed in the different stages. For this purpose, it is necessary to determine the treatments whose digestions are anaerobic or operate under aerobic conditions in an overloaded state. In this case, anaerobic lagoons and the vertical flow system are the anaerobic processes that will generate this type of emissions. There are no treatments that operate at a higher discharge level than sized, so there will be no emissions associated with this type of system.

To calculate these emissions, the kg of _BOD5 eliminated must be known in order to be able to relate it to the amount of biogas produced. In this case, the characterisation of the water entering the plant is available, but the BOD5 parameter has not been included in the study (Table 1)_, these values will be estimated considering the theoretical yields.

For every kg of _BOD5 removed, 0.25 kg of methane is produced. That is, approximately 0.42 kg of biogas, with 60% of the biogas being methane and 40% carbon dioxide. This ratio gives the emissions generated in each stage.

In order to know the kg/year of BOD5 it is necessary to know the flow with which it operates. From the data obtained in 2018, it is estimated that the average daily flow is 198 m³.

Anaerobic lagoons:

Since there is no characterization of the water entering the plant, by means of the theoretical elimination yields of the anaerobic lagoons, taking into account the characteristics of the water leaving the lagoons, it is possible to obtain an estimate of the values of the input parameters. With this, the amount of BOD5 removed in this process can be obtained. The _BOD5 removal efficiency in an anaerobic lagooning system is around 40-50% (Manual for the implementation of purification systems in small towns). If an average efficiency is used, i.e., 45% removal, it is obtained that the inlet water to this system has the following characteristics in Table 2 and 3.

1º The kg/year of _BOD5 eliminated is calculated, using the values shown in Table 2:

96𝑚𝑔/𝐿 = 0,096𝑘𝑔/𝑚³ ∗ 198𝑚³ /𝑑ay ∗ 365𝑑ays/year = 6938 𝑘𝑔/year𝐷𝐵𝑂₅ 𝑒𝑙𝑖𝑚𝑖𝑛𝑎ted

[1]

2º The kg of biogas emitted are obtained:

6938𝑘𝑔𝐷𝐵𝑂5/year 𝐷𝐵𝑂𝑒𝑙𝑖𝑚𝑖𝑛𝑎𝑑𝑎 ∗ 0,42𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/𝑘𝑔𝐷𝐵𝑂₅ = 2914 𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/year

[2]

3º Knowing that the biogas mixture is composed of 60% methane and 40% CO2, these emissions are calculated:

2914kgbiogas/year * 60kgCH₄ /100kgbiogas = 1748 kgCH kgCH₄ /year= 1,1𝑘𝑔𝐶𝐻₄ /year - ℎ. 𝑒

[3]

2914𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/year ∗ 40𝑘𝑔𝐶𝑂₂ /100𝑘𝑔𝑏𝑖𝑜𝑔a𝑠 = 1165𝑘𝑔𝐶𝑂 /year

[4]

= 0.73 𝑘𝑔𝐶𝑂₂ /year - ℎ. 𝑒

Vertical flow system:

1º The kg/year of _BOD5 eliminated is calculated, using the values shown in Table 2, Figure 4 and Figure 5:

167𝑚𝑔/𝐿 = 0,167 𝑘𝑔/𝑚³ ∗ 198𝑚³ /𝑑𝑎y ∗ 365 𝑑𝑎ys/year = 12069 𝑘𝑔/year 𝐷𝐵𝑂₅ 𝑒𝑙𝑖𝑚𝑖𝑛𝑎ted

[5]

2º The kg of biogas emitted are obtained:

12069 𝑘𝑔𝐷𝐵𝑂5/year 𝐷𝐵𝑂 eliminated ∗ 0,42 𝑘𝑔 𝑏𝑖𝑜𝑔a𝑠/𝑘𝑔𝐷𝐵𝑂₅ = 5069 𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/year

[6]

3º Knowing that the biogas mixture is composed of 60% methane and 40% CO2, these emissions are calculated:

5069𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/year ∗ 60𝑘𝑔𝐶𝐻₄ /100𝑘𝑔𝑏𝑖𝑜𝑔a𝑠 = 6041 𝑘𝑔𝐶𝐻 𝑘𝑔𝐶𝐻₄ /year = 3.78 𝑘𝑔𝐶𝐻₄ /year - ℎ. 𝑒

[7]

5069𝑘𝑔𝑏𝑖𝑜𝑔a𝑠/year ∗ 40𝑘𝑔𝐶𝑂₂ /100𝑘𝑔𝑏𝑖𝑜𝑔a𝑠 = 2028 𝑘𝑔𝐶𝑂 𝑘𝑔𝐶𝑂₂ /year = 1.27 𝑘𝑔𝐶𝑂₂ /year - ℎ. 𝑒

[8]

In Figure 3 and Figure 4 it is shown the primary and secundary efluent parameters of ETAR Santa Catarina. Moreover, in Table 4 is shown the generation of waste and/or by-products.

None of the activities described in the maintenance manuals are carried out, but waste is generated, so the quantities generated in the different cases will be estimated (Table 4).

Roughing grid

The roughing system installed is located in the pumping station outside the treatment plant, i.e., the management of this waste does not belong to the plant, but it will be taken into account as it is waste generated as a result of wastewater treatment. The data will be obtained by estimating the production of Santa Lucia. If the waste generated in Santa Lucía is 10.

kg per week, taking into account that the water of 1600 equivalent inhabitants is treated in this system, 32 kg of waste will be generated per week, therefore:

32𝑘𝑔/𝑠𝑒𝑚𝑎𝑛𝑎 ∗ 52𝑠𝑒𝑚𝑎𝑛𝑎𝑠/1𝑎ñ𝑜 ∗ 1/1600ℎ. 𝑒 = 1.04 𝑘𝑔/(𝑎ñ𝑜 - ℎ. 𝑒)

Anaerobic lagoon

In these systems, the flotsam that appears on the surface of the lagoons must be removed, using a pool leaf catcher and taking advantage of the moments when the prevailing winds accumulate the flotsam. This quantity of waste is not considerable and will therefore not be taken into account in the analysis. However, every 5-10 years, the sludge that has accumulated at the bottom of the lagoons in operation will be purged. It is estimated that the sludge production is 30-40 litres/h.3 and year (manual for the implementation of wastewater treatment systems in small settlements). As a result, it can be estimated that the amount of waste in this case will be about 35 L/h.e- year of sludge on a wet basis.

Vertical flow wetlands

From similar cases such as the purification system in St. Lucia, the following is considered;

In these wetlands, the sludge that has accumulated on the surface of the gravel during the operating period is left to dehydrate. Once they have dried, the surface is raked to remove them and prepare the system for the new period of operation. This operation is carried out once a month, taking into account the two operating wetlands. This mainly produces solids in the form of dewatered primary sludge and leaf debris. It will be considered as waste to be sent to landfill. The amount of waste obtained monthly from the vertical wetlands is 15 kilograms.

15𝑘𝑔/𝑚𝑒𝑠 ∗ 12 𝑚𝑒𝑠𝑒𝑠/1 𝑎ñ𝑜 ∗ 1/1600ℎ. 𝑒 = 0.11 𝑘𝑔/(𝑎ñ𝑜 - ℎ. 𝑒)

LCV IMPACT ASSESSMENT OF THE STUDIED SYSTEMS

For the correct development of the LCA methodology, it is necessary to use a software tool to save time and achieve reliable results. The basic function of these is to perform the material and energy balances on the specific process and to allocate emissions, energy uses, etc., normalised on a common basis. In this case, the tool SimaPro version 9.1.1 is used.

For this LCA, we work with the most appropriate database Ecoinvent v3.7.1 as it is an improvement of the BUWAL 250 and ETH databases, with more than 4000 processes belonging to different sectors.

The methodology used in the study is the ILCD 2011 as it will be the reference methodology for the EU Environmental Footprints, with the impact categories shown below:

Climate change.

Depletion of the ozone layer.

Ecotoxicity to freshwater ecosystems.

Human toxicity (carcinogenic effects).

Inorganic particles with respiratory effects.

Ionising radiation, effects on human health.

Photochemical ozone formation.

Acidification.

Terrestrial eutrophication.

Aquatic eutrophication.

Freshwater ecotoxicity.

Depletion of resources (water, minerals, fossils).

Land transformation.

It should also be noted that the IPCC 2013 methodology is used to calculate the carbon footprint.

Assessment and interpretation of the impacts of the construction phase.

According to the results obtained in the impact assessment of the construction phase (Figure 3), it can be seen that the passage and pipeline area generates greater effects on the environment. It is believed that this is due to the fact that more impact- generating materials are used in this stage than in other stages. It should also be noted that the greatest occupation of the land is at this stage. When compared to the rest of the processes, the other stages generate very low impacts.

A comparison of the most significant impact categories shows (Table 5) that the "freshwater ecotoxicity" category is the highest. The cause of the high values for this impact is unknown. Table 5 gives a more general overview o f t h e impacts generated in each of the stages.

In it (Table 5), the storage and the passage areas and pipelines are always the processes that generate the greatest impact. The large size of these two stages compared to the rest may be the reason for the greater generation of impact. It is also worth noting the negative values of "water resource depletion" associated with these passage areas. This may be associated with the treatment of the steel in the factory itself. Assessment and interpretation of the impacts of the operation and maintenance phase.

There is a contribution to impact generation of the operation and maintenance phase. It can be seen that maintenance of the vertical flow wetland is the process that generates the greatest impact. It should also be noted that the roughing grate does not generate any type of impact despite the generation of waste produced there and that, despite the amount of sludge extracted in the anaerobic lagoon, it generates a lower impact than the rest of the stages.

Of particular interest is the presence of only two impact categories in the assessment. When entering the data into the programme, the only two impact categories that occur are "climate change" and "photochemical ozone formation", while the rest have a value of zero, i.e., they do not occur.

This chapter compares the impacts generated in the construction phase with the impacts generated in the operation and maintenance phase. Figure 8 shows that there are only two impact categories in common, i.e., in the rest of the categories there is no impact in the operation and maintenance phase. Likewise, the operation and maintenance phase generate a greater impact in the "climate change" category, this is due to the elimination of organic matter in each of the stages taken into account. However, in the category "photochemical ozone formation" the operation and maintenance phase generate a much lower impact than the contraction phase. It should be noted that as this is a biological purification system in which the energy input is zero, the operation phase is only affected by the emissions generated in the different stages and the waste and/or by-products obtained in each of these stages. However, in the construction phase, much larger quantities of materials are used, the distances travelled by the means of transport are greater...

Table 6 gives a more generic overview of the impacts generated in each phase.

6. Discussions and Conclusions

During the construction phase, the highest values of environmental impact are obtained. Therefore, it is possible to improve the environmental performance of the construction process by using less environmentally harmful materials. For instance, the utilization of natural cements, which consume less energy due to their lower firing temperatures, or the substitution of steel with other metals in the fabrication of grating components, could be considered. The substitution of thermoplastic polyolefin for EDPM is a potential avenue for improvement. An additional potential enhancement would be the implementation of automated and regular maintenance systems, which could be powered by solar energy.

As in previous studies, in the construction stage, the materials that contribute most to the generation of impact are the steel and concrete used. In the impact of this type of steel and concrete, chosen from the database of the computer program, it can be seen how the impacts of the production of these materials in the factories at source are accounted for, which is why they have such a negative impact in this analysis. It should also be noted that the impact category "human toxicity, carcinogenic effects" is the highest. This is due to the use of steel and concrete. However, the impact category "land use" compared to the above mentioned is much lower.

Despite the fact that the consumption of materials is lower in the operation and maintenance phase and that it is a plant that operates at zero energy cost, two relevant impact categories are obtained in the study. The "climate change" category is the highest in this case, significantly outweighing the other categories. A total of 124 kg CO2 equivalent were generated during the operation and maintenance phase of the plant.

When comparing the impacts generated in both phases, it can be seen that the maintenance and operation phase generates a greater impact than the construction phase in the "climate change" impact category. Despite the fact that the installations operate at zero energy cost, the maintenance phase is higher than the construction phase. The highest impact category in both cases is "climate change", which produces 227 kg CO2 equivalent. Of this, 103 kg of CO2 correspond to the construction phase, i.e., 45% of the total emissions, so once again it can be seen that this first phase contributes less to the generation of impact.

If a comparison is made of the impacts generated at the Santa Catarina WWTP located on the island of Cape Verde, made up of the previously described stages, with other treatment plants that operate in a similar way, the data obtained in this case are similar to those obtained in the other studies. In conclusion, the overall impact of the installation is not excessively high when compared with wastewater treatment plants that have stages with high energy costs such as activated sludge, MBR, etc. Even so, it should be noted that the impact of this installation would be lower if the program did not use materials from the database that take into account the manufacturing part of the same.