Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

The Degradation Product Promoted Depolymerization Strategy for Chemical Recycling of Poly(bisphenol a Carbonate)

Version 1 : Received: 3 January 2024 / Approved: 4 January 2024 / Online: 5 January 2024 (01:57:40 CET)

A peer-reviewed article of this Preprint also exists.

Chai, M.; Xu, G.; Yang, R.; Sun, H.; Wang, Q. Degradation Product-Promoted Depolymerization Strategy for Chemical Recycling of Poly(Bisphenol A Carbonate). Molecules 2024, 29, 640. Chai, M.; Xu, G.; Yang, R.; Sun, H.; Wang, Q. Degradation Product-Promoted Depolymerization Strategy for Chemical Recycling of Poly(Bisphenol A Carbonate). Molecules 2024, 29, 640.

Abstract

The accumulation of waste plastics has a severe impact on the environment, and therefore, the development of efficient chemical recycling methods has become an extremely important task. In this regard, a new strategy of degradation product-promoted depolymerization process was proposed. Using N,N'-dimethyl-ethylenediamine (DMEDA) as depolymerization reagent, an efficient chemical recycling of poly(bisphenol A carbonate) (BPA-PC) material was achieved under mild conditions. The degradation product 1,3-dimethyl-2-imidazolidinone (DMI) was proven to be the critical factor in facilitating the depolymerization process. This strategy does not require catalysts or auxiliary solvents, which is truly green process. This method improves the recycling efficiency of BPA-PC and promotes the development of plastic reutilization.

Keywords

BPA-PC; bisphenol A; plastic wastes; depolymerization; chemical recycling

Subject

Chemistry and Materials Science, Polymers and Plastics

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