Chen, J.; Prinsloo, R.; Ni, X. A Kinetic Study of a Photo-Oxidation Reaction between α-Terpinene and Singlet Oxygen in a Novel Oscillatory Baffled Photo Reactor. Technologies2024, 12, 29.
Chen, J.; Prinsloo, R.; Ni, X. A Kinetic Study of a Photo-Oxidation Reaction between α-Terpinene and Singlet Oxygen in a Novel Oscillatory Baffled Photo Reactor. Technologies 2024, 12, 29.
Chen, J.; Prinsloo, R.; Ni, X. A Kinetic Study of a Photo-Oxidation Reaction between α-Terpinene and Singlet Oxygen in a Novel Oscillatory Baffled Photo Reactor. Technologies2024, 12, 29.
Chen, J.; Prinsloo, R.; Ni, X. A Kinetic Study of a Photo-Oxidation Reaction between α-Terpinene and Singlet Oxygen in a Novel Oscillatory Baffled Photo Reactor. Technologies 2024, 12, 29.
Abstract
By planting LEDs on the surfaces of orifice baffles, a novel batch oscillatory baffled photoreactor (OBPR) together with polymer-supported Rose Bengal (Ps-RB) beads are used to investigate reaction kinetics of a photo-oxidation reaction between α-terpinene and singlet oxygen (1O2). In the widely used NMR data analysis for this reaction, α-terpinene and ascaridole are treated as a reaction pair, assuming kinetically singlet oxygen is in excess or constant. We have, for the first time, examined the validity of the method, discovered that increasing α-terpinene initially leads to an increase of ascaridole, indicating that the supply of singlet oxygen is in excess. Applying kinetic analysis, a pseudo first order reaction kinetics is confirmed, supporting this assumption. We have subsequently initiated a methodology of estimating the 1O2 concentrations based on the proportionality of ascaridole concentrations with respect to its maximum under these conditions. With the help of the estimated singlet oxygen data, the efficiency of 1O2 utilization and the photo efficiency of converting molecular oxygen to 1O2 are further proposed and evaluated. We have also identified conditions where further increase of α-terpinene has caused decreases in ascaridole, implying kinetically that 1O2 has now become a limiting reagent, the method of treating α-terpinene and ascaridole as a reaction pair in the data analysis would no longer be valid under those conditions.
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