Zhang, M.; Li, L.; Yang, F.; Zhang, S.; Zhang, H.; Zhu, Y.; An, J. Thermal Activation of High-Alumina Coal Gangue Auxiliary Cementitious Admixture: Thermal Transformation, Calcining Product Formation and Mechanical Properties. Materials2024, 17, 415.
Zhang, M.; Li, L.; Yang, F.; Zhang, S.; Zhang, H.; Zhu, Y.; An, J. Thermal Activation of High-Alumina Coal Gangue Auxiliary Cementitious Admixture: Thermal Transformation, Calcining Product Formation and Mechanical Properties. Materials 2024, 17, 415.
Zhang, M.; Li, L.; Yang, F.; Zhang, S.; Zhang, H.; Zhu, Y.; An, J. Thermal Activation of High-Alumina Coal Gangue Auxiliary Cementitious Admixture: Thermal Transformation, Calcining Product Formation and Mechanical Properties. Materials2024, 17, 415.
Zhang, M.; Li, L.; Yang, F.; Zhang, S.; Zhang, H.; Zhu, Y.; An, J. Thermal Activation of High-Alumina Coal Gangue Auxiliary Cementitious Admixture: Thermal Transformation, Calcining Product Formation and Mechanical Properties. Materials 2024, 17, 415.
Abstract
In order to utilize high-alumina coal gangue (HACG) as auxiliary cementitious admixture, it is of fundamental significance to thermally activating Al2O3 effectively in HACG and promoting formation of hydratable products containing Al2O3. In this paper, a new preparation technology is developed to make HACG auxiliary cementitious admixture by thermal activation of HACG-Ca(OH)2 (CH) mixture. HACG powders mixed with 20wt.% CH were calcined within a temperature range of 600-900oC, the thermal transformation and mineral phase formation were analyzed by thermogavimetric analyzer (TGA), X-ray diffractometer (XRD), scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDS). The hydration reaction between activated HACG-CH mixture and cement was also investigated. HACG experienced a conventional transformation from kaolinite to metakaolin at 600oC and finally to mullite at 900oC. However, CH underwent an unexpected transformation process from CH to CaO, then to CaCO3, and finally to CaO again with increasing calcining temperature. These substances states were associated with dehydroxylation of CH, chemical reaction between CaO and CO2 generating from combustion of carbon in HACG, and decomposition of CaCO3, respectively. It is the formation of a large amount of CaO above 800oC that favors the formation of hydratable products containing Al2O3 in the calcining process and C-A-H gel in hydration process. The mechanical properties of HACG-cement mortar specimens were measured, from which the optimal calcination temperature for preparing HACG auxiliary cementitious admixture was determined to be 850oC. As compared with pure cement mortar specimens, the maximum 28-d flexural and compressive strength of HACG-cement mortar specimens increased by 5.4% and 38.2%, respectively.
Engineering, Architecture, Building and Construction
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