Zhang, S.; Ye, Y.; Chen, Z.; Lai, Q.; Liu, T.; Wang, Q.; Yuan, S. Improved Electrochemical Performance of Li-Rich Cathode Materials via Spinel Li2MoO4 Coating. Materials2023, 16, 5655.
Zhang, S.; Ye, Y.; Chen, Z.; Lai, Q.; Liu, T.; Wang, Q.; Yuan, S. Improved Electrochemical Performance of Li-Rich Cathode Materials via Spinel Li2MoO4 Coating. Materials 2023, 16, 5655.
Zhang, S.; Ye, Y.; Chen, Z.; Lai, Q.; Liu, T.; Wang, Q.; Yuan, S. Improved Electrochemical Performance of Li-Rich Cathode Materials via Spinel Li2MoO4 Coating. Materials2023, 16, 5655.
Zhang, S.; Ye, Y.; Chen, Z.; Lai, Q.; Liu, T.; Wang, Q.; Yuan, S. Improved Electrochemical Performance of Li-Rich Cathode Materials via Spinel Li2MoO4 Coating. Materials 2023, 16, 5655.
Abstract
Li-rich manganese-based cathode materials (LRMs) are considered one of the most promising cathode materials for the next generation lithium-ion batteries (LIBs) because of their high energy density. However, there are problems such as capacity decay, poor rate performance, and continuous voltage drop, which seriously limit their large-scale commercial applications. In this work, Li1.2Mn0.54Co0.13Ni0.13O2 coated with Li2MoO4 with unique spinel structure was prepared by wet chemistry method and the subsequent calcination process. The Li2MoO4 coating layer with spinel structure can provide a 3D Li+ transport channel, which is beneficial for improving rate performance, while protecting LRMs from electrolyte corrosion, suppressing interface side reactions, and improving cycling stability. The capacity retention rate of LRMs coated with 3wt% Li2MoO4 increased from 69.25% to 81.85% after 100 cycles at 1C, and the voltage attenuation decreased from 7.06 to 4.98 mV per cycle. The lower Rct also exhibits improved magnification performance. The results indicate that the Li2MoO4 coating effectively improves the cyclic stability and electrochemical performance of LRMs.
Chemistry and Materials Science, Surfaces, Coatings and Films
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