Submitted:
27 April 2023
Posted:
27 April 2023
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Abstract
Keywords:
1. Introduction
2. Literature review
3. Research design
3.1. Modeling of hybrid electrochemical-nuclear battery
3.1.1. Modeling of the Li-ion battery
3.1.2. Modeling of MMRTG
- Steady-state radioisotope thermoelectric module (the temperature distribution of the air gap is the same as the thermoelectric elements; hence heat transfer of the thermoelectric device can be treated as approximately one-dimensional heat transfer)
- Identical configurations of the p-type and n-type thermoelectric element (equal lengths, widths, thicknesses)
- Materials with a similar thermal coefficient of expansion must be chosen for the thermoelectric elements because different materials will bring about a thermal expansion mismatch of the materials, which will lead to severe stress, leading to the degradation and breaking of the contacts between the thermoelectric elements (p-type and n-type semiconductors) and the ceramic substrate. When using similar materials is impossible, the thermoelectric module must be designed to minimize thermal stresses.
- Thermoelectric elements are connected electrically in series and thermally in parallel.
- The thermoelectric elements' material properties (Seebeck coefficient, thermal conductivity, and electrical conductivity) are temperature dependent.
- Uniform heat from the heat source
- Radioisotope thermoelectric module is thermal insulation packaged; hence the heat leakage through the lateral surface is negligible.
3.1.3. Modeling of auxiliary components
4. Results and Discussion
5. Assessment of the effect of temperature
6. Conclusions
Author Contributions
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Fakham, H.; Lu, D.; Francois, B. Power Control Design of a Battery Charger in a Hybrid Active PV Generator for Load-Following Applications. IEEE Trans. Ind. Electron. 2011, 58, 85–94. [Google Scholar] [CrossRef]
- Becherif, M. Passivity-Based Control of Hybrid Sources: Fuel Cell and Battery; IFAC, 2006; Vol. 11, ISBN 9783902661135. [Google Scholar]
- Ambrosi, R.M.; Williams, H.; Watkinson, E.J.; Barco, A.; Mesalam, R.; Crawford, T.; Bicknell, C.; Samara-Ratna, P.; Vernon, D.; Bannister, N.; et al. European Radioisotope Thermoelectric Generators (RTGs) and Radioisotope Heater Units (RHUs) for Space Science and Exploration. Space Sci. Rev. 2019, 215. [Google Scholar] [CrossRef]
- Obodovskiy, I. Atomic Energy Sources. In Radiation: Fundamentals, Applications, Risks, and Safety; Elsevier, 2019; pp. 361–365. ISBN 9780444639790. [Google Scholar]
- Zoui, M.A.; Bentouba, S.; Stocholm, J.G.; Bourouis, M. A Review on Thermoelectric Generators: Progress and Applications. Energies 2020, 13. [Google Scholar] [CrossRef]
- NASA Radioisotope Thermoelectric Generator. Space Radioisotope Power Systems. Available online: https://science.nasa.gov/about-us/smd-programs/radioisotope-power-systems#:~:text=The Radioisotope Power Systems (RPS,enable future space exploration missions (accessed on 16 June 2015).
- Chou, S.K.; Yang, W.M.; Chua, K.J.; Li, J.; Zhang, K.L. Development of Micro Power Generators - A Review. Appl. Energy 2011, 88, 1–16. [Google Scholar] [CrossRef]
- Ghamaty, S.; Bass, J.C.; Elsner, N.B. Quantum Well Thermoelectric Devices and Applications. In Proceedings of the 22nd International Conference on Thermoelectrics, ICT; IEEE: La Grande Motte, 2003; pp. 563–566. [Google Scholar]
- Gulian, A.; Wood, K.; Fritz, G.; Gyulamiryan, A.; Nikogosyan, V.; Giordano, N.; Jacobs, T.; Van Vechten, D. X-Ray/UV Single Photon Detectors with Isotropic Seebeck Sensors. Nucl. Instruments Methods Phys. Res. Sect. A Accel. Spectrometers, Detect. Assoc. Equip. 2000, 444, 232–236. [Google Scholar] [CrossRef]
- NASA General Purpose Heat Source | Thermal Systems – NASA RPS: Radioisotope Power Systems. Available online: https://rps.nasa.gov/power-and-thermal-systems/thermal-systems/general-purpose-heat-source/ (accessed on 15 April 2023).
- NASA Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). Natl. Aeronaut. Sp. Adm. 2013, 2950–2957.
- Rowe, D.M. Thermoelectrics, an Environmentally-Friendly Source of Electrical Power. Renew. Energy 1999, 16, 1251–1256. [Google Scholar] [CrossRef]
- Riaz, A.; Sarker, M.R.; Saad, M.H.M.; Mohamed, R. Review on Comparison of Different Energy Storage Technologies Used in Micro-Energy Harvesting, Wsns, Low-Cost Microelectronic Devices: Challenges and Recommendations. Sensors 2021, 21. [Google Scholar] [CrossRef]
- Marsh, R.A.; Vukson, S.; Surampudi, S.; Ratnakumar, B. V.; Smart, M.C.; Manzo, M.; Dalton, P.J. Li Ion Batteries for Aerospace Applications. J. Power Sources 2001, 97–98, 25–27. [Google Scholar] [CrossRef]
- Ratnakumar, B. V.; Smart, M.C.; Ewell, R.C.; Whitcanack, L.D.; Chin, K.B.; Surampudi, S. Lithium-Ion Rechargeable Batteries on Mars Rovers. 2nd Int. Energy Convers. Eng. Conf. 2004, 3, 1763–1770. [Google Scholar]
- NASA JPL | Electrochemical Technology - Mission Support. Available online: https://electrochem.jpl.nasa.gov/?page=mission-support (accessed on 15 April 2023).
- Miao, Y.; Hynan, P.; Von Jouanne, A.; Yokochi, A. Current Li-Ion Battery Technologies in Electric Vehicles and Opportunities for Advancements. Energies 2019, 12, 1–20. [Google Scholar] [CrossRef]
- Ratnakumar, B. V.; Smart, M.C.; Kindler, A.; Frank, H.; Ewell, R.; Surampudi, S. Lithium Batteries for Aerospace Applications: 2003 Mars Exploration Rover. J. Power Sources 2003, 119–121, 906–910. [Google Scholar] [CrossRef]
- Johnson, B. Power Sources for Space Exploration. Available online: http://large.stanford.edu/courses/2012/ph240/johnson1/ (accessed on 15 April 2023).
- Radulovic, J. Why Space Might Solve the Biggest Problem with Solar Energy. Available online: https://www.inverse.com/science/solar-power-space-uk (accessed on 15 April 2023).
- Luta, D.N.; Raji, A.K. A 2 MW Grid-Tied Fuel Cell Inverter under a Single Loop Control Scheme. Proc. - 30th South. African Univ. Power Eng. Conf. SAUPEC 2022 2022, 3–8. [Google Scholar] [CrossRef]
- Luta, D.N.; Raji, A.K. Optimal Sizing of Hybrid Fuel Cell-Supercapacitor Storage System for off-Grid Renewable Applications. Energy 2018, 166, 530–540. [Google Scholar] [CrossRef]
- Mughees, N. The Pros and Cons of Hydrogen Fuel Cells vs Batteries | Electronics360. Available online: https://electronics360.globalspec.com/article/19118/the-pros-and-cons-of-hydrogen-fuel-cells-vs-batteries (accessed on 15 April 2023).
- Rayment, C.; Sherwin, S. Introduction to Fuel Cell Technology. Dep. Aerosp. Mech. Eng. Univ. Notre Dame 2003. [Google Scholar]
- Manasse, F.K.; Pinajian, J.J.; Tse, A.N. Schottky Barrier Betavoltaic Battery. IEEE Trans. Nucl. Sci. 1976, 23, 860–870. [Google Scholar] [CrossRef]
- Riffat, S.B.; Ma, X. Thermoelectrics: A Review of Present and Potential Applications. Appl. Therm. Eng. 2003, 23, 913–935. [Google Scholar] [CrossRef]
- Sethumadhavan, S.; Burger, D. Powering a Cat Warmer Using Bi2Te3 Thin-Film Thermoelectric Conversion of Microprocessor Waste Heat. In Proceedings of the ASPLOS; 2006. [Google Scholar]
- Jaziri, N.; Boughamoura, A.; Müller, J.; Mezghani, B.; Tounsi, F.; Ismail, M. A Comprehensive Review of Thermoelectric Generators: Technologies and Common Applications. Energy Reports 2020, 6, 264–287. [Google Scholar] [CrossRef]
- Streb, A.J. Radioisotope Power Systems for Manned Space Stations; ACADEMIC PRESS INC., 1966; Vol. 16. [Google Scholar]
- Cataldo, R.L.; Bennett, G.L. U.S. Space Radioisotope Power Systems and Applications: Past, Present and Future. NASA 2010. [Google Scholar]
- Shepherd, C.M. Design of Primary and Secondary Cells. J. Electrochem. Soc. 1965, 112, 657. [Google Scholar] [CrossRef]
- SATNOW LP 33450 - EaglePicher Technologies | Satellite Battery. Available online: https://www.satnow.com/products/batteries/eaglepicher-technologies/98-1276-lp-33450 (accessed on 25 April 2023).
- Jaguemont, J.; Boulon, L.; Dubé, Y. A Comprehensive Review of Lithium-Ion Batteries Used in Hybrid and Electric Vehicles at Cold Temperatures. Appl. Energy 2016, 164, 99–114. [Google Scholar] [CrossRef]
- Gao, F.; Tang, Z. Kinetic Behavior of LiFePO4/C Cathode Material for Lithium-Ion Batteries. Electrochim. Acta 2008, 53, 5071–5075. [Google Scholar] [CrossRef]
- Petzl, M.; Kasper, M.; Danzer, M.A. Lithium Plating in a Commercial Lithium-Ion Battery - A Low-Temperature Aging Study. J. Power Sources 2015, 275, 799–807. [Google Scholar] [CrossRef]
- Gunawardhana, N.; Dimov, N.; Sasidharan, M.; Park, G.J.; Nakamura, H.; Yoshio, M. Suppression of Lithium Deposition at Sub-Zero Temperatures on Graphite by Surface Modification. Electrochem. commun. 2011, 13, 1116–1118. [Google Scholar] [CrossRef]
- Masih-Tehrani, M.; Yahyaei, R. Study of Lithium Battery Thermal Effect on Battery and Hybrid Battery/Ultra-Capacitor Sizing for an Electric Vehicle. J. Eng. Technol. 2017, 6, 85–99. [Google Scholar]
- Tsai, H.L.; Lin, J.M. Model Building and Simulation of Thermoelectric Module Using Matlab/Simulink. J. Electron. Mater. 2010, 39, 2105–2111. [Google Scholar] [CrossRef]
- Holgate, T.C.; Bennett, R.; Hammel, T.; Caillat, T.; Keyser, S.; Sievers, B. Increasing the Efficiency of the Multi-Mission Radioisotope Thermoelectric Generator. J. Electron. Mater. 2015, 44, 1814–1821. [Google Scholar] [CrossRef]
- Kushwah, M.; Patra, A. PID Controller Tuning Using Ziegler-Nichols Method for Speed Control of DC Motor. Int. J. Sci. Eng. Technol. Res. 2014, 3, 2924–2929. [Google Scholar]






| Isotope | Isotope fuel from | Watts cm3 | Half-life | Melting point oC | Weight density g/cm3 | Specific activity W/Kc | Decay particle |
|---|---|---|---|---|---|---|---|
| Po-210 | Metal | 1210 | 138 days | 254 | 9.3 | 31.7 | Alpha |
| Pm-147 | Pm2O3 | 1.5 | 2.6 years | 2300 | 5.55 | 0.37 | Beta |
| Sr-90 | SrO2 | 0.93 | 28 years | 2430 | 2.65 | 6.5 | Beta |
| Pu-238 | PuO2 | 5.0 | 89.6 years | 2250 | 11.46 | 34.5 | Alpha |
| Ce-144 | CeO2 | 13.8 | 285 days | 2680 | 7 | 7.9 | Beta |
| Specifications | |
|---|---|
| Part Number | LP33450 |
| Nominal Cell Weight | 1.27 kg |
| Voltage Range | 3.0 to 4.1V |
| Nominal Voltage | 3.6V |
| Nominal Capacity | 43Ah at C/5 at 20oC (68oF) |
| Energy Density | 378 Wh/L |
| Specific Energy | 153 Wh/kg |
| Discharge Rates | Max constant current 200A |
| Max pulse current (<1 sec) 400A | |
| Nominal Cell Impedance | 2mΩ at 20oC (68oF) |
| Cycle Life (80% capacity measured at 0.5C discharge current at 20oC (68oF)) | >2000 at 100% DOD |
| Standard Charging Method | Constant current 21.5A (0.5C) to 4.1V |
| Constant voltage 4.1V to 0.86A (C/50) | |
| Operating Temperature | -20 to 60oC (-4 to 140oF) |
| Storage Temperature | -40 to 60oC (-40 to 140oF) |
| Design parameters | MMRTG |
| No. of GPHS bricks TE materials No. of couples Design-point QHS TE hot-side temp TE cold-side temp BOL power (WE) Est. EOL (14 years) power BOL system efficiency Specific power (WE kg-1) Containment system Mission usage Addressed program |
8 PbTe(TAGS 85, PbSnTe) 768 1984 WTh @ BOL 525oC 100-200oC ̴120 60 6.0% 2.8 Argon overpressure Multi-mission MSL and Mars 2020 |
| Parameter | Value |
| Efficiency (Thermal to Electrical conversion) Thermal Power Electrical Power Specific power Output voltage Hot-side temperature Cold-side temperature Figure of merit, Z Seebeck coefficient, S Thermal Conductivity, Kth Resistance, R |
6.3 % 2000 W 110 W 2.8 We/Kg 28-32 V dc 525oC (798.15oK) 100-200oC 0.001032 Z-1 0.1818 V/K 4.271 W/K 7.5 Ω |
| Description | Value |
| Armature Resistance Ra (Ω) | 1 |
| Armature Inductance La (H) | 0.5 |
| Torque Constant Kt | 0.01 |
| Moment of Inertia J (Kgm2S-2) | 0.01 |
| EMF constant | 0.01 |
| Friction Coefficient B | 0.1 |
| Boost converter | |
| Description | Value |
| MMRTE voltage (V) | 34.25 |
| Motor voltage (V) | 60 |
| Switching frequency (kHz) | 25 |
| Voltage ripple | 1% |
| Minimum inductance () | 7 |
| Minimum capacitor (mF) | 1.72 |
| Duty cycle | 43% |
| Half-bridge converter | |
| Battery voltage (V) | 30 |
| Duty cycle | 57% |
| Minimum inductance () | 15 |
| Load capacitor (mF) | 5 |
| Minimum battery capacitor (mF) | 2.3 |
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