Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

The Dynamic Constants of Unidirectional Fibrous Composites at the Glass Transition Region as Obtained from the Interphase Concept

Version 1 : Received: 6 December 2018 / Approved: 7 December 2018 / Online: 7 December 2018 (17:07:22 CET)

How to cite: Sideridis, E.; Venetis, J. The Dynamic Constants of Unidirectional Fibrous Composites at the Glass Transition Region as Obtained from the Interphase Concept. Preprints 2018, 2018120093. https://doi.org/10.20944/preprints201812.0093.v1 Sideridis, E.; Venetis, J. The Dynamic Constants of Unidirectional Fibrous Composites at the Glass Transition Region as Obtained from the Interphase Concept. Preprints 2018, 2018120093. https://doi.org/10.20944/preprints201812.0093.v1

Abstract

Dynamic mechanical analysis (DMA) is a versatile technique that complements the information given by the more traditional thermal analysis techniques such as differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermal mechanical analysis (TMA). Dynamic constants such as storage modulus, loss modulus, and loss factor are temperature dependent and provide information about interfacial bonding between reinforced fibre and polymer matrix of composite material. To study the above mentioned properties at the glass transition region, for unidirectional fibrous composites reinforced with continuous fibers a reliable model was applied. In particular, the composite material was considered as composed of three phases with the intermediate phase between matrix and fibres, the interphase, to have variable properties depending on those of main phases and the mode of preparation of the overall material. The glass transition temperature is defined as the point at which the specific volume versus temperature curve changes abruptly slope marking the region between rubbery polymer and glassy polymer nature. Hence, the behaviour of unidirectional fibrous composites was investigated at this region. Examination of the glass transition temperature, which constitutes an upper limit for the structurally important glassy region through the loss factor, was performed by its consideration as a combination of glass transition temperature of matrix and interphase.

Keywords

unidirectional fibrous composites, interphase, storage/loss modulus, loss factor, frequency, glass transition.

Subject

Chemistry and Materials Science, Polymers and Plastics

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