Version 1
: Received: 15 October 2017 / Approved: 16 October 2017 / Online: 16 October 2017 (06:19:27 CEST)
Version 2
: Received: 16 November 2017 / Approved: 16 November 2017 / Online: 16 November 2017 (07:51:47 CET)
Hu, K.; Jeong, S.; Wakisaka, M.; Fujita, J.-I.; Ito, Y. Bottom-up Synthesis of Porous NiMo Alloy for Hydrogen Evolution Reaction. Metals2018, 8, 83.
Hu, K.; Jeong, S.; Wakisaka, M.; Fujita, J.-I.; Ito, Y. Bottom-up Synthesis of Porous NiMo Alloy for Hydrogen Evolution Reaction. Metals 2018, 8, 83.
Hu, K.; Jeong, S.; Wakisaka, M.; Fujita, J.-I.; Ito, Y. Bottom-up Synthesis of Porous NiMo Alloy for Hydrogen Evolution Reaction. Metals2018, 8, 83.
Hu, K.; Jeong, S.; Wakisaka, M.; Fujita, J.-I.; Ito, Y. Bottom-up Synthesis of Porous NiMo Alloy for Hydrogen Evolution Reaction. Metals 2018, 8, 83.
Abstract
Bottom-up synthesis of porous NiMo alloy reduced by NiMoO4 nanofibers was systematically investigated to fabricate non-noble metal porous electrodes for hydrogen production. The different annealing temperatures of NiMoO4 nanofibers under hydrogen atmosphere reveal that the 950 °C annealing temperature is a key to produce bicontinuous and monorhinic porous NiMo alloy without oxide phases. The porous NiMo alloy as cathodes in electrical water splitting demonstrates not only almost identical catalytic activity with commercial Pt/C, but also superb stability for 12 days.
Keywords
nanoporous; NiMo; non-noble metal catalyst; hydrogen evolution
Subject
Chemistry and Materials Science, Nanotechnology
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.