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First Physicochemical and Heavy Metal Characterization of Qurayyat Salt, a Traditional Saudi Salt

Submitted:

26 May 2026

Posted:

28 May 2026

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Abstract
Al Qurayyat salt is a traditional salt product that has been historically used in northern Saudi Arabia for food preservation, seasoning, and domestic uses. The city of Al Qurayyat is famous for its salt and is known as the city of salt in Saudi Arabia due to the abundance of salt deposits in areas such as Etra and Kaf. Despite its daily use by locals, there is no scientific information available regarding its chemical composition, heavy metals and safety. In this preliminary study, we aimed to analyze the physicochemical properties and metal contents of Al Qurayyat salt (ETR) and compare it to a commercially known salt (SAS). ETR chemical analysis showed a purity of 98.179%, moisture content of 0.68%, insoluble matter of 0.25%, and sulphate concentration of 7400 mg/kg. As expected, Iodine was not detected in the ETR sample, suggesting that the salt is non-iodized. Mineral analysis showed the presence of calcium (27 mg/kg), magnesium (32 mg/kg), potassium (10 mg/kg), copper (0.21 mg/kg), mercury (0.03 mg/kg), lead (0.13 mg/kg), and arsenic (0.01 mg/kg), while cadmium and iron were not detected or below the limit of detection. Heavy metal concentrations was below commonly accepted safety limits for edible salts. These findings provide the first reported physicochemical characterization of Al Qurayyat salt and establish baseline data for future investigations regarding its mineral composition, potential health uses, safety, nutritional significance, and potential industrial or culinary applications.
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Introduction

Salt is one of the most essential dietary and preservation substances used by human populations worldwide [1,2]. In Saudi Arabia, several traditional salt products have been used for hundreds of years in food preparation, meat preservation, and cultural culinary practices [3]. Among these products is Al Qurayyat salt, which is found in Al Qurayyat region in northern Saudi Arabia near the Jordanian border [4,5]. Traditionally, Al Qurayyat salt has been used in seasoning, preservation of meat and dairy products, and household food processing . Al Qurayyat city is historically recognized for trade routes and desert resources, including naturally occurring salt deposits in many places including Etra, Kaf, Menwa, Al-Qarqar and Ageeq [5,6]. Despite the cultural and commercial importance of this salt, there is currently no published data regarding its chemical composition, purity, mineral content, or heavy metal safety and potential health uses. The quality and safety of edible salts are influenced by several factors such as geological origin, processing methods, environmental contamination, and storage conditions. Evaluation of physicochemical parameters such as purity, moisture, insoluble matter, and mineral composition is therefore important for determining product quality and compliance with food safety standards. Also, monitoring heavy metals such as arsenic, mercury, lead, and cadmium is necessary due to their potential toxicological effects on the health [7]. The present study aimed to provide a preliminary physicochemical and trace metal characterization of Al Qurayyat salt (ETR) and compare its values with commonly accepted commercial salt standards.

Materials and Methods

Sample Collection

Al Qurayyat salt (ETR) sample was obtained from Etra (Ithra), area located near Al-Qurrayat in northern Saudi Arabia, and submitted for laboratory analysis [5]. Approximately 500 g of the salt sample was collected and stored under dry conditions until laboratory analysis.

Physicochemical Analysis

Physicochemical parameters including purity, moisture content, insoluble matter, sulphate concentration, and iodine content were analyzed according to standardized analytical procedures. Purity and moisture analyses were performed using AOAC methods, while insoluble matter was determined according to ASTM E534 [8,9]. Sulphate concentration was measured using APHA 4500-SO₄ methodology, and iodine content was evaluated according to ISO 3961:2024 [10,11].

Trace Metal and Mineral Analysis

The concentrations of calcium (Ca), magnesium (Mg), potassium (K), copper (Cu), iron (Fe), arsenic (As), mercury (Hg), cadmium (Cd), and lead (Pb) were determined using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) following acid digestion of the salt samples. Analytical procedures were performed according to AOAC 2015.01 guidelines [12]. Briefly, salt samples were dissolved and digested using analytical-grade acids prior to ICP-MS analysis for elemental quantification. Element concentrations were reported as mg/kg of salt sample.

Quality and Safety Evaluation

Measured values were compared with commonly accepted commercial salt standards and permissible heavy metal limits to assess the quality and safety profile of the analyzed Al Qurayyat salt sample.

Results

Physicochemical Characteristics

According to data in Table 1, Al Qurayyat salt showed a purity of 98.179%, indicating high sodium chloride content. Moisture content was measured at 0.68%, while insoluble matter was 0.25%, both within acceptable commercial ranges. Sulphate concentration reached 7400 mg/kg. Iodine was not detected in the analyzed sample, suggesting the product is non-iodized. The pH was around 6.5–7.5 similar to commercially known salt.

Mineral and Heavy Metal Profile

Mineral analysis identified calcium (27 mg/kg), magnesium (32 mg/kg), and potassium (10 mg/kg). Trace heavy metals including arsenic (0.01 mg/kg), mercury (0.03 mg/kg), and lead (0.13 mg/kg) were detected at concentrations below commonly accepted safety thresholds. Cadmium was below the limit of quantification, while iron was not detected.

Discussion

The current study provides the first preliminary chemical characterization of Al Qurayyat salt. The measured purity level suggests that the product possesses acceptable sodium chloride concentration comparable to several commercial salts available in regional markets. The relatively insoluble matter values further indicate reasonable product quality and processing. The absence of detectable iodine suggests that Al Qurayyat salt is naturally obtained without iodination processing. Since iodine fortification is commonly employed to reduce iodine deficiency disorders, consumers relying exclusively on non-iodized salt may require alternative dietary iodine sources [13].
Trace mineral concentrations observed in the present study were relatively low, which is expected for refined or semi-refined edible salts. Importantly, the detected heavy metal concentrations remained below commonly accepted safety limits, suggesting no immediate evidence of significant contamination in the analyzed sample.
The study is limited by analysis of a single sample and absence of microbiological or further elemental profiling. Future studies will include microbiological assessment, antimicrobial activity, analysis of multiple batches, seasonal sampling, and broader mineral characterization of Al Qurayyat salt.

Conclusions

This study presents the first reported physicochemical and heavy metal characterization of Al Qurayyat salt (ETR), a traditional salt product used in northern Saudi Arabia. The analyzed sample demonstrated high purity and heavy metal concentrations below common safety thresholds. However, iodine was not detected since it is naturally obtained. These findings establish baseline scientific data for future investigations into the nutritional, safety and potential health applications of Al Qurayyat salt.

References

  1. Kaushik S, Kumar R, Kain P. Salt an Essential Nutrient: Advances in Understanding Salt Taste Detection Using Drosophila as a Model System. J Exp Neurosci. 2018;12:1179069518806894.
  2. Lartey S. The Role of Salt in Human Health and Its Importance in Nutritional Requirements. 2024.
  3. Saudi Salt Company. Saudi Salt. Available online: Saudi Salt.
  4. Saudi Press Agency. Al-Qurayyat Salt Production and Economic Importance. Available online: Saudi Press Agency.
  5. SaudiPedia. Al-Qurayyat Governorate. Available online: SaudiPedia.
  6. Kupi. Qurayyat, Saudi Arabia. Available online: Kupi.
  7. Wróblewski M, Miłek J, Godlewski A, Wróblewska J. The Impact of Arsenic, Cadmium, Lead, Mercury, and Thallium Exposure on the Cardiovascular System and Oxidative Mechanisms in Children. Curr Issues Mol Biol. 2025;47(7).
  8. AOAC International. Official Methods of Analysis of AOAC International; AOAC International: Rockville, MD, USA, 2023.
  9. ASTM International. ASTM E534-18, Standard Test Methods for Chemical Analysis of Sodium Chloride. Available online: ASTM International.
  10. American Public Health Association (APHA). Method 4500-SO₄²⁻: Sulfate. Available online: APHA Method 4500-SO₄²⁻ PDF.
  11. International Organization for Standardization (ISO). ISO FDIS 3961: Determination of Iodine Value. Available online: ISO FDIS 3961 PDF.
  12. Xing L. Determination of toxic elements in food by ICP-MS using AOAC method 2015.01. Spectroscopy. 2022;37(10):7-12.
  13. Rigutto-Farebrother J, Zimmermann MB. Salt Reduction and Iodine Fortification Policies Are Compatible: Perspectives for Public Health Advocacy. Nutrients. 2024;16(15).
Table 1. Chemical Composition and Trace Metal Profile of ETR and SAS Salt Samples Compared with Typical Commercial Salt Standards.
Table 1. Chemical Composition and Trace Metal Profile of ETR and SAS Salt Samples Compared with Typical Commercial Salt Standards.
Parameter Salt (ETR) Commercially Known Salt (SAS) Normal Range
Purity (%) 98.179 98.6 97–99.9%
Insoluble matter (%) 0.25 0.49 <0.5%
Sulphate (SO₄²⁻) (mg/kg) 7400 4500 <10,000 mg/kg
Iodine (mg/kg) ND (Not Detected) 17.766 ~15–40 mg/kg for iodized salt
Moisture (%) 0.68 0.196 <1%
Calcium (Ca) (mg/kg) 27 ND <500 mg/kg
Arsenic (As) (mg/kg) 0.01 0.02 <0.5 mg/kg
Magnesium (Mg) (mg/kg) 32 14 <500 mg/kg
Potassium (K) (mg/kg) 10 ND <50 mg/kg
Cadmium (Cd) (mg/kg) <LOQ ND <0.5 mg/kg
Mercury (Hg) (mg/kg) 0.03 0.04 <0.1 mg/kg
Lead (Pb) (mg/kg) 0.13 0.19 <1 mg/kg
Copper (Cu) (mg/kg) 0.21 0.13 <2 mg/kg
Iron (Fe) (mg/kg) ND 0.19 <10 mg/kg
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