This study presents the development and experimental evaluation of HygroCatch, a portable hybrid fog water harvesting prototype that integrates active and passive col-lection mechanisms. The device operates by combining fog droplet ionization in a high-voltage direct-current (HV DC) electrostatic field, thermoelectric cooling based on the Peltier effect, and mechanical deposition of droplets on electrode grids. This hybrid approach enables adaptive operation across a wide range of fog liquid water content (LWC) conditions. The work establishes operating parameters for stable electrostatic ionization and evaluates the contribution of thermoelectric cooling to additional water collection. The results indicate that an operating voltage of 13–14 kV provides a stable ionization over a broad LWC range. The average fog water harvesting rate reached 3.15 kg/m²/h, with a maximum observed value of 4.44 kg/m²/h. On average, 56% of the collected water was obtained through HV DC ionization, 25% through Peltier-based thermoelectric cooling, and 19% through mechanical deposition on electrode grids under high LWC conditions. The total electrical power consumption of the device did not exceed 38.3 Wh/kg. The results demonstrate that a hybrid fog water harvesting strategy enables stable and efficient water collection under environmental conditions in which individual passive or active methods become ineffective.