This article presents the design and characterization process of a lightweight Vivaldi antenna for high-voltage ultra-wideband systems. The proposed antenna consists of two radiating arms with different exponential curves on their inner and outer edges fed with an insulated-coplanar-plates transmission line. The weight reduction is achieved by implementing the antenna with sheets composed of a polyester layer between two aluminum layers, with a polylactic acid insulator inserted between the arms. The reflection coefficient of the implemented antenna demonstrates an impedance bandwidth ranging from 0.3 GHz to 4.2 GHz. High voltage operation of up to 12.4 kV is also experimentally demonstrated. The transfer function between the voltage applied to the antenna, Vs, and the radiated electric field, Er, is measured. Using this transfer function, the radiated electric field is calculated for an input voltage pulse with a rise time of 110 ps to confirm the antenna capability of producing radiated pulses with low distortion. The calculated radiated electric field pulse closely matches the results obtained with full wave simulation. To assess the similarity between the radiated and applied pulses, the pulse width stretch ratio is calculated, yielding a variation of 3.86% for the direction of maximum gain and 9.36% for 30° in the H-plane of the antenna. This feature is desirable for EMC, EMI and sensing applications. The antenna is also characterized in the frequency domain, achieving a maximum gain of 13.9 dBi at 3 GHz and a 30° 3dB beamwidth for ultra-wideband pulses.