Submitted:
20 September 2025
Posted:
23 September 2025
Read the latest preprint version here
Abstract
Keywords:
1. Introduction
2. Time-Dependent Dynamics.
3. Foundational Conditions for Self-Organization FoundValid for all .
- (C1)
- Regular feedback:. Ensures differentiability of and .
- (C2)
- Positive inverse noise:. Prevents divergence and ensures a well-defined path measure.
- (C3)
- Finite partition function:, ensured by exponential decay of the path density .
- (C4)
- Strictly positive action:, , with no explicit time dependence. Ensures (in Alpha ) is finite and meaningful.
- (C5)
- Integrability: is finite because . Needed for defining (in Alpha ) and for well-posed ensemble averages.
- (C6)
- Strictly positive residual variance: and finite, due to unavoidable fluctuations (thermal, behavioral, or quantum).
4. Dynamical Action Principles in Stochastic Dissipative Self-Organization
5. Distinction from Established Formulations.
6. Average Action Efficiency as a Predictive Metric
Remark 1
| Regime | Interpretation | ||
|---|---|---|---|
| Self-organization SDDAAP |
Lyapunov ↓; ; | ||
| Steady state/attractor SDLAAP |
(NESS); constant | ||
| Disorganization SDIAAP |
Lyapunov fails; ; |
7. Connection to path entropy, MaxCal and MEPP during self-organization.
8. Time-dependent action functionals.
9. Average Action Efficiency as an Empirical Diagnostic
10. Empirical and Operational Validation
11. Computational Feasibility
12. Reaction–Diffusion Systems
13. Practical Advantages
14. Conclusions
Funding
Acknowledgments
Conflicts of Interest
References
- Seifert, U. Stochastic thermodynamics, fluctuation theorems and molecular machines. Rep. Prog. Phys. 2012, 75, 126001. [Google Scholar] [CrossRef]
- Dewar, R.C. Maximum entropy production and the fluctuation theorem. J. Phys. A: Math. Gen. 2005, 38, L371. [Google Scholar] [CrossRef]
- Endres, R.G. Entropy production selects nonequilibrium states in multistable systems. Sci. Rep. 2017, 7, 14437. [Google Scholar] [CrossRef]
- Machlup, S.; Onsager, L. Fluctuations and irreversible process. II. Systems with kinetic energy. Phys. Rev. 1953, 91, 1512. [Google Scholar] [CrossRef]
- Graham, R. Covariant formulation of non-equilibrium statistical thermodynamics. Z. Phys. B Condens. Matter 1977, 26, 397–405. [Google Scholar] [CrossRef]
- Freidlin, M.I.; Wentzell, A.D. Random perturbations. Springer 1998. [Google Scholar]
- Gay-Balmaz, F.; Yoshimura, H. A variational formulation of nonequilibrium thermodynamics for discrete open systems with mass and heat transfer. Entropy 2018, 20, 163. [Google Scholar] [CrossRef]
- Ueltzhöffer, K.; Da Costa, L.; Cialfi, D.; Friston, K. A drive towards thermodynamic efficiency for dissipative structures in chemical reaction networks. Entropy 2021, 23, 1115. [Google Scholar] [CrossRef]
- Nigmatullin, R.; Prokopenko, M. Thermodynamic efficiency of interactions in self-organizing systems. Entropy 2021, 23, 757. [Google Scholar] [CrossRef]
- Georgiev, G.; Georgiev, I. The least action and the metric of an organized system. Open Syst. Inf. Dyn. 2002, 9, 371. [Google Scholar] [CrossRef]
- Georgiev, G.; Daly, M.; Gombos, E.; Vinod, A.; Hoonjan, G. Increase of organization in complex systems. Int. J. Math. Comput. Sci. 2012, 6, 1477. [Google Scholar]
- Georgiev, G.Y. A quantitative measure, mechanism and attractor for self-organization in networked complex systems. In: Self-Organizing Systems (IWSOS 2012), Delft, The Netherlands, March 15–16, 2012. Proceedings. 2012, pp. 90–95.
- Georgiev, G.Y.; Henry, K.; Bates, T.; Gombos, E.; Casey, A.; Daly, M.; Vinod, A.; Lee, H. Mechanism of organization increase in complex systems. Complexity 2015, 21, 18–28. [Google Scholar] [CrossRef]
- Georgiev, G.Y.; Chatterjee, A.; Iannacchione, G. Exponential Self-Organization and Moore’s Law: Measures and Mechanisms. Complexity 2017, 2017. [Google Scholar] [CrossRef]
- Butler, T.H.; Georgiev, G.Y. Self-Organization in Stellar Evolution: Size-Complexity Rule. In: Efficiency in Complex Systems: Self-Organization Towards Increased Efficiency. 2021, pp. 53–80.
- Brouillet, M.; Georgiev, G.Y. Modeling and Predicting Self-Organization in Dynamic Systems out of Thermodynamic Equilibrium: Part 1: Attractor, Mechanism and Power Law Scaling. Processes 2024, 12, 2937. [Google Scholar] [CrossRef]
- Jarzynski, C. Nonequilibrium equality for free energy differences. Phys. Rev. Lett. 1997, 78, 2690. [Google Scholar] [CrossRef]
- Hatano, T.; Sasa, S.-i. Steady-state thermodynamics of Langevin systems. Phys. Rev. Lett. 2001, 86, 3463. [Google Scholar] [CrossRef]
- Dewar, R.C. Maximum entropy production as an inference algorithm that translates physical assumptions into macroscopic predictions: Don’t shoot the messenger. Entropy 2009, 11, 931–944. [Google Scholar] [CrossRef]
- Virgo, N. From maximum entropy to maximum entropy production: a new approach. Entropy 2010, 12, 107–126. [Google Scholar] [CrossRef]
- Davis, S.; González, D.; Gutiérrez, G. Probabilistic inference for dynamical systems. Entropy 2018, 20, 696. [Google Scholar] [CrossRef]
- González Diaz, D.; Davis, S.; Curilef, S. Solving equations of motion by using Monte Carlo Metropolis: novel method via random paths sampling and the maximum caliber principle. Entropy 2020, 22, 916. [Google Scholar] [CrossRef]
- Jülicher, F.; Ajdari, A.; Prost, J. Modeling molecular motors. Rev. Mod. Phys. 1997, 69, 1269. [Google Scholar] [CrossRef]
- Sagawa, T.; Ueda, M. Generalized Jarzynski equality under nonequilibrium feedback control. Phys. Rev. Lett. 2010, 104, 090602. [Google Scholar] [CrossRef]
- Horowitz, J.M.; Vaikuntanathan, S. Nonequilibrium detailed fluctuation theorem for repeated discrete feedback. Phys. Rev. E 2010, 82, 061120. [Google Scholar] [CrossRef]
- Nath, S. Novel molecular insights into ATP synthesis in oxidative phosphorylation based on the principle of least action. Chem. Phys. Lett. 2022, 796, 139561. [Google Scholar] [CrossRef]
- Tuckerman, M.E. Path integration via molecular dynamics. In: Quantum Simulations of Complex Many-Body Systems: From Theory to Algorithms 2002, 10, 269. [Google Scholar]
- Wang, B.; Jackson, S.; Nakano, A.; Nomura, K.-i.; Vashishta, P.; Kalia, R.; Stevens, M. Neural Network for Principle of Least Action. J. Chem. Inf. Model. 2022, 62, 3346–3351. [Google Scholar] [CrossRef]
- Stavek, J.; Sipek, M.; Sestak, J. The application of the principle of least action to some self-organized chemical reactions. Thermochim. Acta 2002, 388, 441–450. [Google Scholar] [CrossRef]


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