2. Methods
According to the results obtained within the framework of the DLFO theory and adapted to the conditions of the pressure flow of the WCF, the destruction of the suspension structure, accompanied by an uneven distribution of solid phase particles throughout the suspension volume, occurs when the following condition is met [
2,
11,
16,
20,
21]:
where
is the total energy of interaction between two spherical particles in a liquid;
is the external energy of the flow directed at destroying the bond between the two particles.
Regarding the formula for determining the total interaction energy of two spherical particles in a liquid, most researchers propose the classical dependence of the DLFO theory [
2,
11,
16,
20,
21]:
where
– reverse Debye radius, in most cases 1·108 m-1;
– parameter of energy interaction of solid phase particles SS;
– absolute dielectric permeability of liquid phase SS, 7.26·10–10 F/m;
– radius of solid phase particles SS, m;
– potential of a diffuse particle of a double electric layer on the surface of solid phase particles SS, V;
– distance between solid phase particles SS, m;
– constant equal to 3.14;
– dimensionless distance between particles of the solid phase of SS, m;
– Hamaker constant, J.
While calculating the external energy of a flow aimed at destroying the connection between two particles, different researchers propose different approaches [
2,
3,
7,
10,
11,
12,
14,
16,
21].
There is a well-known hypothesis that this energy is proportional to the difference in the velocities of the flows impinging on two adjacent particles [
2,
3]
where
is the Coriolis coefficient;
is the density of the liquid phase;
is the difference in the velocities of the flows impinging on two adjacent particles in the coagulation structure, m/s;
S is the cross-sectional area of the flow impinging on a single particle, m
2;
is the duration of the flow, s.
The authors of dependence (3) do not explain why the energy of the flow is considered rather than the energy of the particles obtained from the flow. There is also no explanation of how to calculate the values of S and t. In general, the duration of the flow is characteristic of turbulent flows, where there are corresponding velocity pulsations along and across the flow. However, the destruction of the suspension structure occurs before the development of turbulence. The presence of the Coriolis coefficient in formula (3), which reflects the uneven distribution of the kinetic energy of the flow across the cross-sectional area, also requires additional justification.
Other authors believe that the external energy of the flow directed at destroying the connection between two particles is the kinetic energy of these particles, and propose the following dependence [
5,
7]
where
is the difference in the velocities of the particles under consideration relative to each other, m/s;
is the density of the solid phase.
Dependence (4) is very close to the difference in kinetic energies of interacting particles, provided that their sizes and densities are the same. However, in this case, instead of the square of the difference in the velocities of the particles under consideration relative to each other, it is necessary to use the difference in the squares of the velocities of these particles.
Within the hypothesis on which formula (4) is based, different results can be obtained for estimating the relative radius that defines the flow region where SS will not be destroyed, if different patterns of velocity distribution along the pipe radius are assumed [
10,
11,
12,
14,
16,
21]. There are known cases of using the logarithmic law [
20,
21], which does not correspond to the conditions in the layer between the inner surface of the pipeline and the undeformed flow core. A number of specialists who have studied the peculiarities of non-Newtonian fluid flow in a pipeline note that if we consider the destruction of the suspension structure during SS flow in a pipeline, the velocity distribution in the layer near the pipeline surface will correspond to the following dependence [
10,
11,
16]
where
U – local flow velocity SS;
– pipe radius, m;
– current radius value, m;
– relative current radius;
– tangential stress of hydraulic friction on the inner surface of the pipe, Pa;
– dynamic viscosity coefficient of the liquid phase of the fluid, kg/m/s;
– relative radius of the undeformed flow core;
– initial tangential stress of the fluid flow, Pa;
– pressure difference at the beginning and end of the pipeline, Pa;
– pipeline length, m.
Using dependence (5), the difference in the velocities of two particles of the solid phase SS, after neglecting the square of the relative distance between the particles of the solid phase SS, can be calculated using the following formula [
16]
which made it possible to obtain a condition under which the structure of the suspension is destroyed when the SS flows in the pipeline [
16]:
where
is the maximum value of the relative radius at which the suspension structure is still preserved during the flow of SS in the pipeline;
is the relative distance between the particles of the solid phase of SS.
Note that the double sign in the second formula (7) appeared after taking the square root, i.e., it reflects a mathematical pattern, not a physical one. In addition, note that under the first root on the right side of the second formula (7) is the relative value of the total interaction energy of two spherical particles in a liquid, the first formula (2). This value is zero at equilibrium points, but becomes positive or negative in other cases. At the same time, if we consider the second formula (7) at equilibrium points, its second term is zero, and it coincides with the dependence for determining the relative radius at which the structure of the suspension is still preserved during SS flow in the pipeline, exclusively according to rheological and hydraulic characteristics, the second formula from (5).
In our opinion, if we consider that the external energy of the flow directed at destroying the connection between two particles is the kinetic energy of these particles, then it must be equal to the difference in the kinetic energies of the adjacent particles. That is, with the same sizes and densities of these particles, this difference in kinetic energies will be proportional to the difference in the squares of the velocities at which each of the compatible particles will move under the action of the flow:
where
is the velocity of the particle with the smaller current radius, m/s;
is the velocity of the particle with the larger current radius, m/s.
The results of fundamental research on the flow of hydro-mixtures through pipelines, carried out by domestic authors [
1,
4,
10,
11,
12,
13,
14,
16,
20,
21], indicate that the velocity of a solid particle in a hydro mixture flow is determined by the difference between the velocity of the liquid phase and the hydraulic size of this particle. Based on this experimental fact and using the first formula from (5), after the appropriate transformations, we write the following dependencies to calculate the velocities of each of the adjacent particles:
where
– hydraulic particle size of the solid phase, m/s.
Neglecting in the second formula (9) the quadratic term with the relative distance between the particles of the solid phase SS
The difference between the squares of the velocities in dependence (8) can be easily written as follows
where
– dimensionless hydraulic particle size of the solid phase, m/s.
Considering jointly the first formula of the last two, (8), the first formula of (2) and inequality (1), and taking into account that
After the appropriate transformations, we obtain a condition under which the structure of the suspension is destroyed when the SS flows in the pipeline, in the form of the following inequality
where
is the lyophobicity parameter, which takes into account the influence of gravitational and repulsive forces of an ionic-electrostatic and Van der Waals nature.
The results of the analysis of the orders of magnitude on the left side (10) indicate that the second term of this polynomial can be neglected in comparison with the others, and the dimensionless hydraulic particle size of the solid phase, in the case of WCF and most mineral processing wastes, is several orders of magnitude smaller than the square of the dimensionless thickness of the deformed part of the flow. Based on this, inequality (10) can be rewritten as follows:
If we consider condition (7) at equilibrium points, when 0
B, we obtain a restriction on the relative current radius
which coincides with the dependence for determining the relative radius at which the suspension structure is still preserved during SS flow in the pipeline, exclusively based on rheological and hydraulic characteristics, the second formula from (5).
Note that in inequality (11), the lyophobicity parameter contains the relative value of the total interaction energy of two spherical particles in a liquid, the first of the formulas (2), but not under the square root, as is the case in formula (7). That is, if we consider (11) not at equilibrium points, then the value of the lyophobicity parameter becomes either positive or negative, and the form of inequality (11) changes. However, the sign of the lyophobicity parameter does not affect the sign of the discriminant of the corresponding cubic equation, which must be solved to determine the intervals of inequality (11). The sign of this discriminant depends on the ratio of the lyophobicity parameter and the relative radius of the undeformed flow core. This discriminant will be positive if the inequality
and the cubic equation (11) has one real root, which is determined by the formula
With a positive discriminant, regardless of the sign of the lyophobicity parameter, we obtain the following formula for calculating the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline:
where
is the real root of equation (11), determined by formula (12).
The effect of the lyophobicity parameter sign is a restriction imposed by
on the value of the relative current radius. Thus, in the case of a positive lyophobicity parameter,
, the relative current radius is limited from above:
and when negative,
, from below:
It is clear that condition (14) is physically impossible, since it presupposes the existence of a destruction boundary in the middle of the flow region where there is no deformation.
With a negative discriminant, when the following inequality holds
Regardless of the sign of the lyophobicity parameter, there are three valid roots of equation (11):
and the intervals of existence of the solution of inequality (11) will be:
The influence of the lyophobicity parameter sign lies in the values of the second interval limits. Thus, in the case of a positive lyophobicity parameter,
, the values
and
are calculated as the sums of the relative radius of the undeformed flow core and the roots of equation (11):
and in the case of a negative parameter,
, – as differences:
The first constraint from (16), as well as (14), is physically impossible, i.e., with a negative discriminant of equation (11), only the second constraint from (16) needs to be considered. Formulas (17) and (18) show that in the case of a positive lyophobicity parameter, , the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline will exceed the relative radius of the undeformed flow core, which is determined by the rheological characteristics of SS. Conversely, for a negative lyophobicity parameter, , the maximum value of the relative radius at which the suspension structure is still preserved during the flow of SS in the pipeline will be less than the relative radius of the undeformed flow core, which is determined by the rheological characteristics of SS.