Submitted:
19 March 2024
Posted:
22 March 2024
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Abstract
Keywords:
1. Introduction
2. Control Strategy
2.1. Optimization Control Strategy to Minimize Aging Cost in a Single Operational Period
2.2. Rolling Optimization Process for Long-Time Operational Scenarios
3. Extraction and Prediction of Multi-Dimensional HFs
3.1. Aging Experiment
- Actual capacity test: Discharge the batteries at a constant current of 1/3C to the lower cut-off voltage of 2.75 V. Charge them at a constant current of 1/3C to 4.2 V, and subsequently charge at a constant voltage until the current drops below C/20. Next, discharge them at a constant current of 1/3C to the lower cut-off voltage of 2.75V. Repeat this charge and discharge procedure two times. Refer to view a of Figure 8.
- Low-current discharge curve: Charge the batteries at a current of 1/3C to the cut-off voltage, and discharge them at a current of C/20 to 2.75V after standing, as shown in view b of Figure 8.
- HPPC: Perform tests at varying SOC levels[23]. After the batteries are fully charged, gradually discharge them to 80%, 60%, 50%, 40% and 20% SOC for evaluations. Specifically, discharge them at a current of 2C for 18s, after setting them aside to stand for 40s, charge them at 1C for 10s, and then set them aside again to stand for 40s. Then charge the batteries with a current of 2C for 18s, after setting them aside to stand for 40s, discharge them at a current of 1C for 10s, and finally set them aside to stand for 40s. Refer to view e of Figure 8.
3.2. Extraction of HFs
- 2.
- 3.
- Incremental capacity analysis (ICA). Figure 16(a) shows the original IC curve of a single test, subjected to smoothing. Figure 16(b) shows the IC curves of multiple tests, indicating decreasing peak values, rightward shifting peak positions, and narrowed peak areas with aging progression. Figure 17 shows the variation curves of peak values and peak areas, respectively.
- 4.
- Relaxation. Relaxation refers to the process in which voltage slowly returns to a specific stationary stage upon the conclusion of excitation. The recovery to 3.91 V upon the conclusion of excitation was considered for current calculations. Figure 18 illustrates the recovery process following the removal of excitation during multiple HPPC tests. As shown, the recovery process is prolonged with aging progression. Figure 19 shows the variation curves of relaxation time and slope.
3.3. Prediction of HFs
4. Prediction Method of Aging Cost for Energy Storage System
is expressed as follows:5. Case Study
5.1. Description of Application Scenario
5.2. Simulation Model of Energy Storage System
5.3. Comparative Analysis of Results
6. Conclusions
- The optimization control strategy presented, along with its solving process, helps in reducing aging costs and extending the service life of energy storage systems. Furthermore, it improves module consistency, offering advantages for cascade utilization following module recombination.
- The periodic rolling optimization mode proposed for integrating this strategy into engineering operation benefits not only from reducing the computational power needed for each optimization control but also from enabling iterative adjustments based on the actual operational status.
- The aging cost evaluation introduced incorporates multi-dimensional features, rather than solely considering capacity SOH.
- Due to time and equipment limitations, the comparative experiments were not sufficient. Variable intervals may be refined in the future, to establish a more accurate aging prediction model. Additionally, data collected during long-term operation revealed that batteries with high SOC and low operating frequency exhibited noticeable storage aging. In the subsequent strategy optimization, it may be beneficial to optimize SOC points after charging instead of performing a full charge each time.
- Utilizing the universality of the proposed approach, models can be developed with a small amount of experimental data in scenarios involving other types of batteries. These models can then be used for simulations of aging under multiple variables to provide a reference. This approach can help in reducing the cost associated with long-term aging experiments.
- Shortening the time span of each period allows for more refined optimization control in engineering applications.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
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| S | D | E | |
| D1 | D2 | D3 | |
| C1 | C2 | C3 |
| C | 1 | 1.2 | 1.5 | 2 |
| DOD | ||||
| 30 | 1,2 | 9,10 | 17,18 | 25,26 |
| 50 | 3,4 | 11,12 | 19,20 | 27,28 |
| 70 | 5,6 | 13,14 | 21,22 | 29,30 |
| 100 | 7,8 | 15,16 | 23,24 | 31,32 |
| Extraction method | HFs | Description |
|---|---|---|
| Measured data※[24] (applicable for cells, modules, and systems) | Self-discharge rate | To identify serious energy loss. |
| Temperature rise rate | To identify temperature-related performance, such as serious self-heating and poor heat dissipation. | |
| Available charge/discharge capacity | To diagnose failures such as energy response absence, excessive attenuation rate, and capacity diving. | |
| Relaxation-related features, such as recovery time, and recovery slope | To diagnose reduced energy efficiency, insufficient power, etc. if failure to quickly return to normal after excitation. | |
| Hysteresis voltage | To analyze whether the power performance degrades. | |
| Difference curves and associated features, such as ICA[25], DTV[26] | To analyze performance details as a function of Voltage, Temperature, or Pressure, such as power, energy, and heat production. | |
| Resistance, such as ohmic resistance, polarization resistance | To analyze energy performance degradation and power performance degradation. | |
| Coulombic efficiency[27] | ||
| Description of the change in the charging curve, such as capacity variance (VAR) ※[1,28] | ||
| A series of features based on the CCCV curve[29] | ||
| Equivalent circuit model (applicable for cells and modules) | R[30], C[31] and CPE[32] of equivalent resistance | To evaluate attenuation by comparing with relevant values of normal batteries of the same specification |
| Experimental data | HPPC Resistance[33] (applicable for cells and clusters) | To analyze power performance degradation |
| EIS parameters[34](applicable for cells) | To reflect the physicochemical properties of internal materials and detect underlying failures from the perspective of impedances. | |
| Algorithm-based state estimation (applicable for cells, modules, and systems) | SOC※[35], SOH※[14], [25,36], SOE[37], SOP※[38], SOT※[39], etc. | To comprehensively analyze energy performance degradation and power performance degradation as a mature technique based on numerous studies. |
| Statistics on stacking relationship ※[1,19,29], (applicable for modules and systems) | Statistical analysis of extreme values and variances of voltage/temperature in modules | To screen abnormal cells or evaluate module consistency. |
| Statistical analysis of extreme values and variances of inter-cluster current | Screen abnormal clusters or evaluate cabin consistency. | |
| Various types of measurable data or HFs may be used to statistically analyze battery systems at different layers. Specific examples are omitted in this paper. | ||
| Electrochemical model※[40,41] (applicable for cells) | Physical and chemical parameters, such as maximum available lithium-ion concentration, SEI film resistance, overpotential, resistance of components, lithium-ion concentration distribution, and particle sizes of active materials | To analyze energy and power attenuation and identify root causes based on electrochemical mechanisms[42]. |
| Round 1 | Round 2 | Round 3 | ||||
| Proposed method | Equalized method | Proposed method | Equalized method | Proposed method | Equalized method | |
| Service life (quarterly) | 58 | 50 | 54 | 49 | 60 | 51 |
| Average aging cost per kilowatt-hour ($/kWh) | 0.0759 | 0.0819 | 0.0785 | 0.0824 | 0.0749 | 0.812 |
| Inconsistency (expressed as the sum of variances) | 2.1821e-04 | 2.8150e-04 | 2.2413e-04 | 2.7615e-04 | 2.0047e-04 | 2.6590e-04 |
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