Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Heteronuclear Dual Metal Atom Electrocatalysts for Water-Splitting Reactions

Version 1 : Received: 28 February 2024 / Approved: 28 February 2024 / Online: 29 February 2024 (08:13:04 CET)

A peer-reviewed article of this Preprint also exists.

Lu, L.; Wu, X. Heteronuclear Dual Metal Atom Electrocatalysts for Water-Splitting Reactions. Molecules 2024, 29, 1812. Lu, L.; Wu, X. Heteronuclear Dual Metal Atom Electrocatalysts for Water-Splitting Reactions. Molecules 2024, 29, 1812.

Abstract

Hydrogen is considered as an ideal substitute to the traditional fossil fuels because of its widespread sources, high calorific value of combustion, and zero carbon emissions. The electrocatalytic water-splitting to produce hydrogen is also deemed to be the best approach, however, it is a challenge to make high-efficient and low-cost electrocatalysts. Single-atom catalysts (SACs) are considered the most promising candidate to replace the traditional noble-metal catalysts. Compared with SACs, the dual-atom catalysts (DACs) are of greater attraction including higher metal loading, more versatile active sites, and excellent catalytic activity. In the review, several general synthetic strategies and structural characterization methods of DACs are introduced, and the mechanisms of hydrogen evolution reaction (HER) and oxygen evolution reactions (OER) are discussed. The authors hope that the review has given some insights and inspiration to the researchers about DACs in electrocatalytic water-splitting.

Keywords

Heteronuclear dual metal atoms; electrocatalysts; water-splitting; electrocatalytic mechanism

Subject

Chemistry and Materials Science, Electrochemistry

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