Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Study on Corrosion Behavior of Porous Pure Copper Based Onelectrochemistry and Scanning Kelvin Probe

Version 1 : Received: 11 October 2023 / Approved: 12 October 2023 / Online: 12 October 2023 (08:56:27 CEST)

A peer-reviewed article of this Preprint also exists.

Chen, X.; Liao, Q.; Zuo, H.; Fu, Q. Study on Corrosion Behavior of Porous Pure Copper Based on Electrochemistry and Scanning Kelvin Probe. Materials 2023, 16, 7370. Chen, X.; Liao, Q.; Zuo, H.; Fu, Q. Study on Corrosion Behavior of Porous Pure Copper Based on Electrochemistry and Scanning Kelvin Probe. Materials 2023, 16, 7370.

Abstract

Porous metals possess low bulk density, large specific strength, high stiffness and special thermal, electromagnetic and acoustic conductivity, so that porous metals are widely used in filtration and separation, flame retardant explosion-proof, biomedical application, etc. Compared with its corresponding dense metal, the presence of porous structures also leads to different corrosive performances of porous metal. So, some researches have utilized weight loss method, electrochemical impedance to evaluate porous metals’ corrosion behavior; however, the influence of pore structure on metal corrosion is still controversial, and present methods used for analyses of porous metals’ corrosion are statistical averages of the corrosion behavior of the entire porous material, which cannot accurately reflect the corrosion behavior inside the pore structure. Herein, we prepare porous copper samples with 0, 24, 72, 96 pores using mechanical process, and employ scanning kelvin probe combined with electrochemical polarization curve and impedance spectroscopy to test the corrosion performance of the porous copper in static and dynamic NaCl solution. The relevant results indicate that in static solution, the corrosion resistance of samples gradually increases with the rise of the number of pores. By contrast, the sample with 24 pores exhibits more susceptible to corrosion than the sample without pore.

Keywords

porous copper; scanning kelvin prope; electrochemical impedance; dynamic electrolye

Subject

Chemistry and Materials Science, Electrochemistry

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