Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Multi-Layer Ceramic Capacitors in Lighting Equipment: Presence and Characterisation of Rare Earth Elements and Precious Metals

Version 1 : Received: 4 October 2023 / Approved: 6 October 2023 / Online: 9 October 2023 (04:16:54 CEST)

A peer-reviewed article of this Preprint also exists.

Sideris, K.M.; Fragoulis, D.; Stathopoulos, V.N.; Sinioros, P. Multi-Layer Ceramic Capacitors in Lighting Equipment: Presence and Characterisation of Rare Earth Elements and Precious Metals. Recycling 2023, 8, 97. Sideris, K.M.; Fragoulis, D.; Stathopoulos, V.N.; Sinioros, P. Multi-Layer Ceramic Capacitors in Lighting Equipment: Presence and Characterisation of Rare Earth Elements and Precious Metals. Recycling 2023, 8, 97.

Abstract

In this study, multi-layer ceramic capacitors (MLCCs) detached from lighting sector's waste electrical-electronic equipment (WEEE) are characterised for the presence of rare earth elements (REEs) and precious metals (PMs). Their digestion was carried out with HNO3 & aqua regia on a heating plate and characterised with the use of inductively coupled plasma optical emission spectroscopy (ICP-OES) & scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The contents of REEs and PMs are 0.84 wt% and 0.60 wt%, respectively, and create an economic stored value in MLCCs that is essentially defined by PMs of 98.67% and by Pd 78.37%. The content of the main elements is: Nd 0.366 wt%, Y 0.220 wt%, Dy 0.131 wt%, Ag 0.467 wt%, and Pd 0.105 wt%. The results confirm the need of selective removal and separate recycling process of MLCCs from WEEE drivers.

Keywords

Measurements and characterization; lighting equipment; multi-layer ceramic capacitors; rare earth elements; precious metals; ICP-OES analysis

Subject

Engineering, Electrical and Electronic Engineering

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