Lyu, X.; Kanda, R.; Tsuda, S.; Hashimoto, Y.; Fujii, T.; Kashiwagi, K. Novel Carboxylation Method for Polyetheretherketone (PEEK) Surface Modification Using Friedel–Crafts Acylation. Int. J. Mol. Sci.2023, 24, 15651.
Lyu, X.; Kanda, R.; Tsuda, S.; Hashimoto, Y.; Fujii, T.; Kashiwagi, K. Novel Carboxylation Method for Polyetheretherketone (PEEK) Surface Modification Using Friedel–Crafts Acylation. Int. J. Mol. Sci. 2023, 24, 15651.
Lyu, X.; Kanda, R.; Tsuda, S.; Hashimoto, Y.; Fujii, T.; Kashiwagi, K. Novel Carboxylation Method for Polyetheretherketone (PEEK) Surface Modification Using Friedel–Crafts Acylation. Int. J. Mol. Sci.2023, 24, 15651.
Lyu, X.; Kanda, R.; Tsuda, S.; Hashimoto, Y.; Fujii, T.; Kashiwagi, K. Novel Carboxylation Method for Polyetheretherketone (PEEK) Surface Modification Using Friedel–Crafts Acylation. Int. J. Mol. Sci. 2023, 24, 15651.
Abstract
Recently, polyetheretherketone (PEEK) has shown promising dental applications; although surface treatment is essential for dental applications owing to its poor surface energy and wettability, no consensus on an effective treatment method has been achieved. In this study, we attempt to carboxylate PEEK sample surfaces via Friedel–Crafts acylation using succinic anhydride and AlBr3. The possibility of further chemical modifications using carboxyl groups is examined. The samples are subjected to dehydration–condensation reactions with 1H,1H-pentadecafluorooctylamine and N,N'-dicyclohexylcarbodiimide. The sample surface properties at each reaction stage are evaluated. An absorption band in the 3300–3500 cm-1 wavenumber region is observed. Additionally, peak suggestive of COOH is observed in the sample spectra. Secondary modification diminished the absorption band in 3300–3500 cm-1 and a clear F1s signal is observed. Thus, Friedel–Crafts acylation with succinic anhydride produces carboxyl groups on the PEEK sample surfaces. Further chemical modification of the carboxyl groups by dehydration-condensation reactions is also possible. Thus, a series of reactions can be employed to impart desired chemical structures to PEEK surfaces.
Keywords
polyetheretherketone; Friedel–Crafts acylation; carboxy group; chemical modification
Subject
Chemistry and Materials Science, Biomaterials
Copyright:
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