Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

3D Framework Carbon for High-Performance Zinc-Ion Capacitors

Version 1 : Received: 25 June 2023 / Approved: 26 June 2023 / Online: 26 June 2023 (10:26:03 CEST)

A peer-reviewed article of this Preprint also exists.

Kiatikajornjumroen, S.; Liu, X.; Lu, Y.; Deka Boruah, B. 3D Framework Carbon for High-Performance Zinc-Ion Capacitors. Micromachines 2023, 14, 1476. Kiatikajornjumroen, S.; Liu, X.; Lu, Y.; Deka Boruah, B. 3D Framework Carbon for High-Performance Zinc-Ion Capacitors. Micromachines 2023, 14, 1476.

Abstract

With the rapid and continuous advancement and deployment of advanced energy storage de-vices, there has been significant interest in aqueous capacitors that possess non-flammable properties and high safety features. Consequently, extensive research efforts have focused on investigating zinc anodes and low-cost carbonaceous cathode materials. Despite these efforts, the development of high-performance zinc-ion capacitors (ZICs) still faces challenges such as limited cycling stability and low energy densities. In this study, we present a novel approach to address these challenges. We demonstrate the utilization of a three-dimensionally (3D) grown conductive porous carbon framework cathode coupled with zinc anode cells, which exhibit exceptional sta-bility and durability in ZICs. Our experiments reveal a remarkable cycling performance, with a capacity retention of approximately 97.3% and a coulombic efficiency of nearly 100% even after 10,000 charge-discharge cycles. These findings signify significant progress in enhancing the performance of ZICs.

Keywords

Pyrolysis; porous carbon; zinc ion capacitor

Subject

Chemistry and Materials Science, Electrochemistry

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