Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch

Version 1 : Received: 13 June 2023 / Approved: 13 June 2023 / Online: 13 June 2023 (12:34:32 CEST)

A peer-reviewed article of this Preprint also exists.

Marta, H.; Rismawati, A.; Soeherman, G.P.; Cahyana, Y.; Djali, M.; Yuliana, T.; Sondari, D. The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch. Polymers 2023, 15, 3215. Marta, H.; Rismawati, A.; Soeherman, G.P.; Cahyana, Y.; Djali, M.; Yuliana, T.; Sondari, D. The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch. Polymers 2023, 15, 3215.

Abstract

Starch is widely applied in various industrial sectors, including the food industry. Starch is used as a thickener, stabilizer, or emulsifier. However, arrowroot starch generally has weaknesses, such as unstable under heating and acidic conditions, which are generally applied to processing in the food industry. Modifications were applied to improve the characteristics of native arrowroot starch. In this study, arrowroot starch was modified by heat-moisture treatment (HMT), octenylsuccinylation (OSA), and dual modification between OSA and HMT in a different sequence, namely HMT followed by OSA, and OSA followed by HMT. This study aims to determine the effect of different modification methods on the physicochemical and functional properties of native arrowroot starch. The result shows that both single HMT and dual modification caused damage to native starch granules, such as the formation of cracks and roughness. Especially for single OSA treatment, there is no significant change in granule morphology after modification. All modification treatments did not change the crystalline type of starch but reduced the RC of native starch. Both single HMT and dual modifications (HMT-OSA, OSA-HMT) increased pasting temperature and setback, conversely decreasing the peak and breakdown viscosity of native starch. Whereas, single OSA has the opposite trend compared with the other modifications. HMT played a greater role in increasing the thermal stability and retrogradation ability of arrowroot starch. Both single modifications (HMT and OSA) increase the hardness and gumminess of native starch, conversely for dual modifications. HMT has a greater effect on color characteristics, where decreased the lightness and whiteness index of native arrowroot starch. Single OSA modification increased swelling volume higher than dual modification. Both single HMT and dual modifications increase water absorption capacity and decrease the oil absorption capacity of native arrowroot starch.

Keywords

arrowroot starch; heat-moisture treatment; octenylsuccinilation; dual-modification; physicochemical properties; functional properties

Subject

Chemistry and Materials Science, Materials Science and Technology

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