Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Thymol@activated Carbon Nanohybrid for Low-Density Polyeth-Ylene Based Active Packaging Films for Pork Fillets Shelf-Life Extension

Version 1 : Received: 7 June 2023 / Approved: 7 June 2023 / Online: 7 June 2023 (07:09:07 CEST)

A peer-reviewed article of this Preprint also exists.

Giannakas, A.E.; Karabagias, V.K.; Moschovas, D.; Leontiou, A.; Karabagias, I.K.; Georgopoulos, S.; Karydis-Messinis, A.; Zaharioudakis, K.; Andritsos, N.; Kehayias, G.; Avgeropoulos, A.; Proestos, C.; Salmas, C.E. Thymol@activated Carbon Nanohybrid for Low-Density Polyethylene-Based Active Packaging Films for Pork Fillets’ Shelf-Life Extension. Foods 2023, 12, 2590. Giannakas, A.E.; Karabagias, V.K.; Moschovas, D.; Leontiou, A.; Karabagias, I.K.; Georgopoulos, S.; Karydis-Messinis, A.; Zaharioudakis, K.; Andritsos, N.; Kehayias, G.; Avgeropoulos, A.; Proestos, C.; Salmas, C.E. Thymol@activated Carbon Nanohybrid for Low-Density Polyethylene-Based Active Packaging Films for Pork Fillets’ Shelf-Life Extension. Foods 2023, 12, 2590.

Abstract

Nowadays, bioeconomy and nanotechnology trends push food packaging sector in the re-placement of food additives by biobased antioxidant/antibacterial compounds and their inclusion in nanocarriers to control their release. Herein by following this trend, a rich in thymol-(TO) activated carbon (AC) nanostructure (TO@AC) was prepared and physiochemically characterized with various technics. This TO@AC nanostructure as well as pure AC were extruded with low density polyethylene (LDPE) to develop novel active packaging LDPE/TO@AC and LDPE/AC films. X-ray diffractometry, Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy measuraments shown high dispersity and capability of both AC and TO@AC in LDPE matrix which was resulted in enhanced tensile and water/oxygen barrier properties of obtained LDPE/AC and LDPE/TO@AC films. LDPE/TO@AC films shown higher elongation at break values and water/oxygen barrier than LDPE/AC films and significant antioxidant activity. TO release kinetics studies shown that by increasing TO@AC content the total TO amount released increased and the constant release rate decreased. Pork fillets wrapped with the optimum active film containing 15 wt.% TO@AC and succeed to prevent lipid oxidation and heme iron loss during storage. Estimation of microbial population of pork fillets shown that this active film could ex-tend the microbiological shelf-life of pork fillets by 2 days

Keywords

activated carbon; thymol; low-density polyethylene; active packaging; control release; kinetics; pork fillets; heme iron; shelf life

Subject

Chemistry and Materials Science, Nanotechnology

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