Oliveira, A.E.F.; Pereira, A.C.; Resende, M.A.C.; Ferreira, L.F. Gold Nanoparticles: A Didactic Step-by-Step of the Synthesis Using the Turkevich Method, Mechanisms, and Characterizations. Analytica2023, 4, 250-263.
Oliveira, A.E.F.; Pereira, A.C.; Resende, M.A.C.; Ferreira, L.F. Gold Nanoparticles: A Didactic Step-by-Step of the Synthesis Using the Turkevich Method, Mechanisms, and Characterizations. Analytica 2023, 4, 250-263.
Oliveira, A.E.F.; Pereira, A.C.; Resende, M.A.C.; Ferreira, L.F. Gold Nanoparticles: A Didactic Step-by-Step of the Synthesis Using the Turkevich Method, Mechanisms, and Characterizations. Analytica2023, 4, 250-263.
Oliveira, A.E.F.; Pereira, A.C.; Resende, M.A.C.; Ferreira, L.F. Gold Nanoparticles: A Didactic Step-by-Step of the Synthesis Using the Turkevich Method, Mechanisms, and Characterizations. Analytica 2023, 4, 250-263.
Abstract
The gold nanoparticle (AuNP) was synthesized using the well-known Turkevich method. This article explains didactic step-by-step of the synthesis, showing pictures of the entire process, including a well-explained mechanism and characterization study. The synthesis includes the reduction of NaAuCl4 using sodium citrate in high temperature (around 90 ⁰C). The two main mechanisms used to explain the AuNP synthesis via Turkevich method were explained. The first mechanism considerate that a nanowire intermediary and the other proposed that aggregate intermediates are not formed at any time during the synthesis. The materials (NaAuCl4 and AuNP) were characterized by UV-Vis, SEM, AFM, XRD and DLS. The UV-Vis exhibit an absorption maximum in 521 nm because the surface plasmon resonance (SPR) absorption band of AuNP. The SEM images of NaAuCl4 presents crystals with cubic shapes, while the AuNP presents average particle size of about 16-25 nm and particles that appear mainly spherical. To confirm the particles shapes, the AFM was conducted and it was possible to observe clearly the individual spherical nanoparticles. The XRD of AuNP showed the four main characteristic peaks for silver corresponding to (111), (200), (220) and (311) planes, confirming the cubic (FCC) silver. The DLS presented the average particle size of 3.3 ± 0.9 nm and the polydispersity index (PDI) of 0.574. In summary, the AuNP was synthesized using a simple and fast method. The result was a spherical and ultrasmall particle, that can be used is several applications.
Chemistry and Materials Science, Analytical Chemistry
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