Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Modeling of Sulfur and Iron Dynamics in Enclosed Bay Sediments and Evaluation of the Suppression Effect on Sulfides Release by Iron

Version 1 : Received: 12 May 2023 / Approved: 12 May 2023 / Online: 12 May 2023 (08:11:39 CEST)

A peer-reviewed article of this Preprint also exists.

Mochida, F.; Miyatsuji, T.; Nakamura, Y.; Inoue, T. Modeling of Sulfur and Iron Dynamics in Enclosed Bay Sediments and Evaluation of the Suppression Effect on Sulfide Release by Iron. Water 2023, 15, 2366. Mochida, F.; Miyatsuji, T.; Nakamura, Y.; Inoue, T. Modeling of Sulfur and Iron Dynamics in Enclosed Bay Sediments and Evaluation of the Suppression Effect on Sulfide Release by Iron. Water 2023, 15, 2366.

Abstract

In eutrophic waters, such as Mikawa Bay, Japan, anoxic bottom water develops in summer. This causes sulfide release into seawater by sulfate reduction in the sediment, leading to environmental problems. The addition of iron to sediments is a method used to improve the sediment environment, which was devised from a natural phenomenon. However, this method has not yet been quantitatively evaluated. In this study, we aim to quantitatively evaluate the suppressive effect of iron on sulfide release. First, we develop a sediment model that focuses on S and Fe. We then attempted to reproduce the observations and experiments on sulfide dynamics using the model. Consequently, the proposed model was able to reproduce field sulfur and Fe dynamics in sediments. Additionally, the model described the characteristics of sulfide release considering the effects of additive iron materials. Finally, we conducted predictive calculations and quantitatively evaluated the effects of adding iron materials to the sediments in terms of sulfur and iron cycles.

Keywords

sediment model; sulfur and iron cycles; semi-enclosed bay

Subject

Engineering, Civil Engineering

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