Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Simulation of Ultrafast Polarization Switching in BaTiO3

Version 1 : Received: 10 May 2023 / Approved: 11 May 2023 / Online: 11 May 2023 (13:43:36 CEST)

How to cite: Zhilyaev, P.; Brekhov, K.; Tantardini, C.; Mishina, E. Simulation of Ultrafast Polarization Switching in BaTiO3. Preprints 2023, 2023050863. https://doi.org/10.20944/preprints202305.0863.v1 Zhilyaev, P.; Brekhov, K.; Tantardini, C.; Mishina, E. Simulation of Ultrafast Polarization Switching in BaTiO3. Preprints 2023, 2023050863. https://doi.org/10.20944/preprints202305.0863.v1

Abstract

The challenge of achieving ultrafast switching of electric polarization in ferroelectric materials remains unsolved, as there is no experimental evidence of such switching to date. In this study, we have developed an enhanced model that describes switching within a two-dimensional space of generalized coordinates. Our findings indicate that stable switching in barium titanate cannot be achieved through a single linearly polarized pulse. When the intensity of the linearly polarized pulse reaches a certain threshold, the sample experiences depolarization, but not stable switching. Our study also reveals that phonon friction plays a minor role in the switching dynamics and provides an estimate of the optimal parameters of the perturbing pulse with the lowest intensity that results in depolarization of an initially depolarized sample.

Keywords

ultrafast switching; ferroelectric materials; stable switching; phonon friction; optimal parameters

Subject

Chemistry and Materials Science, Ceramics and Composites

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