Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

Methane to Methanol Conversion Using PEM Fuel Cell and PdAu/ATO Nanomaterials

Version 1 : Received: 20 April 2023 / Approved: 21 April 2023 / Online: 21 April 2023 (05:33:46 CEST)

A peer-reviewed article of this Preprint also exists.

Maia, V.A.; Nandenha, J.; Gonçalves, M.H.; de Souza, R.F.B.; Neto, A.O. Methane to Methanol Conversion Using Proton-Exchange Membrane Fuel Cells and PdAu/Antimony-Doped Tin Oxide Nanomaterials. Methane 2023, 2, 252-264. Maia, V.A.; Nandenha, J.; Gonçalves, M.H.; de Souza, R.F.B.; Neto, A.O. Methane to Methanol Conversion Using Proton-Exchange Membrane Fuel Cells and PdAu/Antimony-Doped Tin Oxide Nanomaterials. Methane 2023, 2, 252-264.

Abstract

This study investigates the use of Au-doped Pd anodic electrocatalysts on ATO support for the conversion of methane to methanol. The study involves cyclic voltammetry, in-situ Raman spectra, polarization curves, and FTIR analysis to determine the optimal composition of gold and palladium for enhancing the conversion process. The results demonstrate the potential for utilizing methane as a feedstock for producing sustainable energy sources. Pd75Au25/ATO electrode exhibited the highest OCP value, and Pd50Au50/ATO had the highest methanol production value at a potential of 0.05 V. Therefore, it can be concluded that an optimal composition of gold and palladium exists to enhance the conversion of methane to methanol. The findings contribute to the development of efficient and sustainable energy sources, highlighting the importance of exploring alternative ways to produce methanol.

Keywords

Methane conversion; Fuel cell; methanol; PEM; PdAu/ATO

Subject

Chemistry and Materials Science, Electrochemistry

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