Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Silica Fume Improves the Mechanical Properties of Alkali-Activated Slag/Fly Ash Pastes Subjected to Elevated Temperatures

Version 1 : Received: 14 April 2023 / Approved: 14 April 2023 / Online: 14 April 2023 (10:23:42 CEST)

How to cite: Wang, S.; Liang, Y.; Mo, D.; Zhang, C.; Xue, J.; Song, X.; Wang, Y. Silica Fume Improves the Mechanical Properties of Alkali-Activated Slag/Fly Ash Pastes Subjected to Elevated Temperatures. Preprints 2023, 2023040365. https://doi.org/10.20944/preprints202304.0365.v1 Wang, S.; Liang, Y.; Mo, D.; Zhang, C.; Xue, J.; Song, X.; Wang, Y. Silica Fume Improves the Mechanical Properties of Alkali-Activated Slag/Fly Ash Pastes Subjected to Elevated Temperatures. Preprints 2023, 2023040365. https://doi.org/10.20944/preprints202304.0365.v1

Abstract

Recycling of metallurgical solid waste has intriguing increasing attention for fabricating cementitious materials, due to its low-carbon emission, cost-effectiveness, and environmental conservation. Herein, the effects of silica fume (SF) on the microstructure and mechanical properties of alkali-activated slag/FA (fly ash) pastes subjected to elevated temperatures (150, 500, 850, and 1200℃) are investigated, to clarify the fact that whether or not the SF generates positive roles in mechanical properties of slag/FA geopolymers. The results show that the replacement with 10 wt% SF (silica fume) promotes the increasing pore volume with a diameter of 0.2~3 μm at room temperature, leading to an increase in the compressive or flexural strength, “right shifts” of endothermic peak and the initial-final temperature of mass loss, presenting a denser and compact fracture surface. Meanwhile, the mineral phase of gehlenite and labradorite emerges after exposure above 850℃ from the XRD results. Furthermore, the bloating effect of the incorporated SF occurs due to the formation of a liquid phase altogether with the amorphous silicates after exposure to 1200℃, leading to a greater deformation and enhancement of restructuring involved in the [SiO4]4− and [AlO4]5−. It explores an effective recycling approach for fabricating paste binders using metallurgical solid wastes.

Keywords

alkali-activated; silica fume; elevated temperatures; bloating effect; fly ash

Subject

Chemistry and Materials Science, Materials Science and Technology

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