Arar, W.; Khatyr, A.; Knorr, M.; Strohmann, C.; Schmidt, A. Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth. Molbank2022, 2022, M1381.
Arar, W.; Khatyr, A.; Knorr, M.; Strohmann, C.; Schmidt, A. Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth. Molbank 2022, 2022, M1381.
Arar, W.; Khatyr, A.; Knorr, M.; Strohmann, C.; Schmidt, A. Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth. Molbank2022, 2022, M1381.
Arar, W.; Khatyr, A.; Knorr, M.; Strohmann, C.; Schmidt, A. Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth. Molbank 2022, 2022, M1381.
Abstract
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 has been reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(μ2-I)2BiI2}{1-MeOC(=S)N(H)Ph}4] 1. Compound 1 has been characterized by IR, UV and NMR spectroscopy, the dinuclear framework has be ascertained by a single-crystal X-ray diffraction study performed at 100 K.
Chemistry and Materials Science, Inorganic and Nuclear Chemistry
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