Submitted:
09 May 2022
Posted:
10 May 2022
You are already at the latest version
Abstract
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 has been reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(μ2-I)2BiI2}{1-MeOC(=S)N(H)Ph}4] 1. Compound 1 has been characterized by IR, UV and NMR spectroscopy, the dinuclear framework has be ascertained by a single-crystal X-ray diffraction study performed at 100 K.
Keywords:
Bismuth triiodide
; thiocarbamate
; thione
; crystal structure
; Hirshfeld analysis
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