Skaria, S.; Berk, K.J. Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties. Polymers2021, 13, 2095.
Skaria, S.; Berk, K.J. Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties. Polymers 2021, 13, 2095.
Skaria, S.; Berk, K.J. Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties. Polymers2021, 13, 2095.
Skaria, S.; Berk, K.J. Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties. Polymers 2021, 13, 2095.
Abstract
The aim of this study was to synthesize and characterize a novel Methacrylate- functionalized Calcium Phosphate (MCP) used as a bioactive compound for innovative dental composites. The characterization was accomplished by Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR), X-Ray Diffraction Analysis (XRDA), Scanning Electron Microscopy (SEM), and EnergyDispersive Spectroscopy (EDS). The incorporation of MCP as a bioactive filler in esthetic dental composite formulations and the ability of MCP containing dental composites to promote precipitation of hydroxyapatite (HAp) on the surfaces of those dental composites was explored. The translucency parameter, depth of cure, degree of conversion, ion release profile, and other physical properties of composites were studied with respect to the amount of MCP added to the composites. Composites containing 3 Wt.%, 6 Wt.%, and 20 Wt.% MCP were evaluated at 7, 14, and 21 days. The progress of surface precipitation of hydroxyapatite on MCP-containing dental composites was studied by systematically increasing the MCP content in the composite and the time of specimen storage in Dulbecco’s phosphate-buffered solution with calcium and magnesium. It was found that there was a direct correlation between the percentage of MCP in a composite formulation, the amount of time the specimen was stored in PBS, and the deposition of hydroxyapatite on the composite’s surface
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