Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Electroreduction of Bi(III) Ions in the Aspect of Expanding the ”Cap – Pair” Effect

Version 1 : Received: 19 October 2020 / Approved: 20 October 2020 / Online: 20 October 2020 (08:36:05 CEST)

How to cite: Nosal Wiercińska, A.; Skrzypek, S. Electroreduction of Bi(III) Ions in the Aspect of Expanding the ”Cap – Pair” Effect. Preprints 2020, 2020100405 (doi: 10.20944/preprints202010.0405.v1). Nosal Wiercińska, A.; Skrzypek, S. Electroreduction of Bi(III) Ions in the Aspect of Expanding the ”Cap – Pair” Effect. Preprints 2020, 2020100405 (doi: 10.20944/preprints202010.0405.v1).

Abstract

The paper discusses the electroreduction of Bi(III) ions in the aspect of expanding the ”cap – pair” effect. The ”cap – pair” rule is associated with the acceleration of the electrode’s processes by organic substances. The interpretation of the ”cap – pair” effect mechanism was expanded to include the effect of supporting electrolyte concentration on the acceleration process and the type of electrochemical active as well as used protonated organic substances. It has also been shown that the phenomena occurring at the electrode/solution interface can influence a change in the dynamics of the electrode’s process according to the ”cap – pair” rule.

Subject Areas

cap - pair effect; electrochemistry; electroreduction of Bi(III); active complexes; catalytic activity

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