Electroreduction of Bi(III) Ions in the Aspect of Expanding the ”Cap – Pair” Effect

Agnieszka Nosal Wiercińska; Sławomira Skrzypek

doi:10.20944/preprints202010.0405.v1

Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Version 1 : Received: 19 October 2020 / Approved: 20 October 2020 / Online: 20 October 2020 (08:36:05 CEST)

The paper discusses the electroreduction of Bi(III) ions in the aspect of expanding the ”cap – pair” effect. The ”cap – pair” rule is associated with the acceleration of the electrode’s processes by organic substances. The interpretation of the ”cap – pair” effect mechanism was expanded to include the effect of supporting electrolyte concentration on the acceleration process and the type of electrochemical active as well as used protonated organic substances. It has also been shown that the phenomena occurring at the electrode/solution interface can influence a change in the dynamics of the electrode’s process according to the ”cap – pair” rule.

cap - pair effect; electrochemistry; electroreduction of Bi(III); active complexes; catalytic activity

Chemistry and Materials Science, Analytical Chemistry

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Electroreduction of Bi(III) Ions in the Aspect of Expanding the ”Cap – Pair” Effect

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