Submitted:
15 June 2026
Posted:
17 June 2026
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Abstract
Keywords:
1. Introduction
2. Materials and Methods
2.1. Ship, Engine and operating conditions
2.2. Emission Measurements
3. Results
3.1. Stabilized point CH4 emission factors
3.2. Black Carbon (BC) Emission Factors under Stabilized Conditions
4. Discussion
4.1. BC emission factors, comparison with related studies.
4.2. Analysis of the relative contributions of methane slip and (BC) to GHG emissions.
4.3. Evolution of WtW CO2,equivalent emissions between 46DF and 46TS-DF.
4.4. Engine Load monitoring (ELM) based evaluation of methane slip.




5. Conclusion
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| BC | Black Carbon |
| LNG | Liquefied natural gas |
| IMO | International Maritime Organization |
| NDIR | Non-dispersive infrared |
| GHG | Greenhouse gas |
| GWP | Global Warming Potential |
| MGO | Marine gas oil |
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| MGO Mode | Mg.kWh-1 | LNG Mode | Mg.kWh-1 | ||
|---|---|---|---|---|---|
| Engine load (E2 wt.) | BC | Engine load (E2 wt.) | BC | ||
| 12.3% | (-) | 32.1 | 12.8% | (-) | 0.77 |
| 27.1%* | (0.15) | 12.5 | 26.4%* | (0.15) | 0.04 |
| 50.2%* | (0.15) | 8.3 | 50.2%* | (0.15) | 0.18 |
| 74.7%* | (0.5) | 5.8 | 73.7%* | (0.5) | 0.36 |
| 85.4% | (-) | 5.1 | 85.4% | (-) | 0.24 |
| 90% | (-) | 4.7 | 89.8% | (-) | 0.53 |
| 100%** | (0.2) | 3.9 | 100%** | (0.2) | 0.63 |
| E2 cycle | 5.9 | E2 cycle | 0.40 | ||
| MGO Mode | gCO2/kWh TtW | TtW | WtT | WtT | WtW | ||||
| Engine load (E2 wt.) | CO2 | CH4 as CO2,equ. | N2O as CO2,equ. | BC as CO2,equ. | Total CO2,equ. | LNG as CO2,equ. | MGO as CO2,equ. | Total CO2,equ. | Total CO2,equ. |
| (a) | (b) | (c) | (a) | (f) | |||||
| 12.3% (-) | 815.3 | 0.4 | 14.0 | 28.9 | 859 | 0 | 160 | 160 | 1019 |
| 27.1%* (0.15) | 675.8 | 0.3 | 11.6 | 11.2 | 699 | 0 | 133 | 133 | 832 |
| 50.2%* (0.15) | 616.9 | 0.3 | 10.6 | 7.4 | 635 | 0 | 121 | 121 | 757 |
| 74.7%* (0.5) | 594.6 | 0.3 | 10.2 | 5.2 | 610 | 0 | 117 | 117 | 727 |
| 85.4% (-) | 588.7 | 0.3 | 10.1 | 4.6 | 604 | 0 | 116 | 116 | 720 |
| 90% (-) | 586.6 | 0.3 | 10.1 | 4.2 | 601 | 0 | 115 | 115 | 717 |
| 100%** (0.2) | 581.3 | 0.3 | 10.0 | 3.5 | 595 | 0 | 114 | 114 | 709 |
| E2 cycle | 598 | 0.3 | 10.3 | 5.3 | 614 | 0.0 | 117.7 | 118 | 732 |
| LNG Mode | gCO2/kWh TtW | TtW | WtT | WtT | WtW | ||||
| Engine load (E2 wt.) | CO2 | CH4 as CO2,equ. | N2O as CO2,equ. | BC as CO2,equ. | Total CO2,equ. | LNG as CO2,equ. | MGO as CO2,equ. | Total CO2,equ. | Total CO2,equ. |
| (a) | (a) | (c)(d) | (a) | (e) | (f) | ||||
| 12.8% (-) | 585.1 | 749.9 | 8.0 | 0.70 | 1344 | 205 | 7.0 | 212 | 1556 |
| 26.4%* (0.15) | 507.3 | 167.8 | 6.3 | 0.04 | 681 | 167 | 3.4 | 170 | 851 |
| 50.2%* (0.15) | 455.4 | 64.0 | 5.5 | 0.16 | 525 | 149 | 1.7 | 151 | 676 |
| 73.7%* (0.5) | 435.2 | 51.4 | 5.3 | 0.33 | 492 | 143 | 1.1 | 144 | 636 |
| 85.4% (-) | 428.6 | 60.4 | 5.2 | 0.21 | 494 | 142 | 1.0 | 143 | 637 |
| 89.8% (-) | 426.8 | 59.9 | 5.2 | 0.47 | 492 | 141 | 0.9 | 142 | 634 |
| 100%** (0.2) | 421.4 | 65.3 | 5.1 | 0.56 | 492 | 140 | 0.8 | 141 | 633 |
| E2 cycle | 438 | 63.6 | 5.3 | 0.36 | 507 | 144.2 | 1.2 | 145 | 652 |
| Rel. difference LNG/MGO | -21% | 19% | -12% | ||||||
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