Submitted:
22 May 2026
Posted:
25 May 2026
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Abstract
Keywords:
1. Introduction
2. Materials and Methods
2.1. Study Area
2.2. Study Design
2.3. Field Data Collection
2.4. Chemical Analysis of the Samples and Data Management
2.5. Data Analysis
2.5.1. Water Quality Analysis
- SAWQG Volume 1: Domestic Water Use (DWAF, 1996a).
- SAWQG Volume 4: Agricultural Water Use – Irrigation (DWAF, 1996b).
- SAWQG Volume 5: Agricultural Water Use – Livestock Watering (DWAF, 1996c).
- SAWQG Volume 7: Aquatic ecosystem (DWAF, 1996d).
2.5.2. Water Quality Indices
2.5.2.1. The Weighted Arithmetic Water Quality Index
2.5.2.2. Canadian Council of Ministers of the Environment Water Quality Index
2.5.3. Water Quality Suitability for Irrigation
2.5.4. Gibbs Diagram Analysis
- Precipitation dominance – characterised by low TDS value against minimal SO4 and Ca concentrations.
- Rock dominance – associated with moderate TDS and water chemistry influenced by the dissolution of silicate and carbonate rocks.
- Evaporation-crystallisation dominance – defined by high TDS and elevated ion concentrations due to evaporation or poor drainage.
2.5.5. Statistical Analysis
3. Results and Discussion
3.1. Water Chemistry
3.2. Water Quality Indices
3.3. Water Quality Suitability for Irrigation
3.4. Spatial and Temporal Trends
3.5. Principal Component Analysis
3.6. Correlation Analysis
4. Conclusions and Recommendations
- Targeted management of key contaminants: Priority intervention should focus on the dominant contaminants identified in the study, including salinity related parameters (TDS, EC, SO4, Ca and Mg) and trace metals (Fe, Mn, and Al) associated with AMD processes. Appropriate treatment and mitigation measures should aim to limit metal mobilisation and reduce salinity enrichment in the Leeuwfonteinspruit.
- Control of sources and pathways of contamination: Pollution prevention measures must address the confirmed sources and pathways, including mine effluent discharges, seepage from discard dumps and pollution control dams, surface runoff from disturbed mining areas, and AMD generation. This includes the improved lining of the pollution control dams, seepage interception system, controlled discharge protocols, and rehabilitation of contaminated flow paths.
- Stormwater and mine water management: Clean and dirty water systems must be strictly separated. Clean stormwater should be diverted away from disturbed areas (such as active mining zones, coal stockpiles, carbonaceous material storage areas, discard dumps, haul roads, wash bays, workshops, and loading/ offloading zones), while contaminated water should be contained in lined pollution control dams for treatment, reuse, or compliant discharges. This is critical during high-risk temporal periods, particularly wet seasons and high-runoff events.
- Temporal risk management and adaptive monitoring: Monitoring and management strategies should explicitly account for periods of elevated risk, particularly during intensified mining phases and hydrologically sensitive periods. Adaptive monitoring programmes should be implemented to increase sampling frequency during high-risk periods to allow early detection and rapid management response to episodic contamination events.
- Protection of vulnerable downstream users: Management interventions must prioritise downstream user vulnerabilities, including domestic water users, agricultural users (irrigation and livestock), and aquatic ecosystems. This includes improving water treatment for community use, and ensuring ecological flow and quality requirements are maintained to protect aquatic biodiversity.
- Regulatory enforcement: Relevant authorities (DWS) should strengthen regulatory enforcement measures to ensure that the coal mining operations are held accountable for the degradation of water resources. This includes conducting regular inspections, ensuring compliance with water use licenses and environmental management plans, and imposing penalties or remediation requirements on mines found to be contributing to water pollution.
- Progressive rehabilitation: Active and disturbed mining areas should undergo concurrent rehabilitation to restore ecosystem functions, reduce long-term pollution risks, limit contaminant mobilisation and ensure post-mining land use sustainability.
- Integrated catchment management: An integrated catchment management approach should be implemented to effectively address cumulative impacts from mining, agriculture, domestic activities, and other land uses.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| Al | Aluminium |
| AMD | Acid Mine Drainage |
| AWARD | Association for Water and Rural Development |
| Ca | Calcium |
| CCME-WQI | Canadian Council of Ministers of the Environment Water Quality Index |
| Cl | Chloride |
| DWAF | Department of Water Affairs and Forestry |
| DWS | Department of Water and Sanitation |
| EC | Electrical Conductivity |
| ESP | Exchangeable Sodium Percentage |
| F | Fluoride |
| Fe | Iron |
| K | Potassium |
| Mg | Magnesium |
| Mn | Manganese |
| N | Nitrate and nitrite |
| PCA | Principal Component Analysis |
| PO4 | Phosphate |
| SAR | Sodium Adsorption Ratio |
| SAWQG | South African Water Quality Guidelines |
| SMK | Sequential Mann-Kendall |
| SO4 | Sulphate |
| TDS | Total Dissolved Solids |
| TWQR | Target Water Quality Range |
| WA-WQI | Weighted Arithmetic Water Quality Index |
| WQI | Water Quality Index |
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| Site | Co-ordinates | Description | |
|---|---|---|---|
| Latitude | Longitude | ||
| Site 1 | 26° 08' 26.03" S | 29° 29' 46.85" E | Located upstream of the mining area in Leeuwfonteinspruit. |
| Site 2 | 26° 08' 16.00" S | 29° 29' 16.69" E | Located upstream of the mining area (north-east) in a non-perennial stream of the Leeuwfonteinspruit. |
| Site 3 | 26° 08' 54.67" S | 29° 29' 18.78" E | Located upstream of the mining area (southeast) in a non-perennial stream of the Leeuwfonteinspruit. |
| Site 4 | 26° 08' 21.39" S | 29° 28' 24.83" E | Located upstream of the mining area (northern site) in a non-perennial stream of the Leeuwfonteinspruit. |
| Site 5 | 26° 09' 6.64" S | 29° 28' 11.68" E | Located downstream of the mining area in the Leeuwfonteinspruit. |
| Water Quality Index Level | Water quality rank |
|---|---|
| 0 – 44 | Poor |
| 45 – 64 | Marginal |
| 65 – 79 | Fair |
| 80 – 94 | Good |
| 95 - 100 | Excellent |
| Chemical Variables | TDS (mg/l) | SO4 (mg/l) |
Ca (mg/l) |
Mg (mg/l) |
Na (mg/l) |
Fe (mg/l) |
Mn (mg/l) |
EC (mS/m) |
pH | Al (mg/l) |
|
|---|---|---|---|---|---|---|---|---|---|---|---|
| TWQR | Domestic use | 450 | 200 | 32 | 30 | 100 | 0,10 | 0,05 | 70 | 6.0-9.0 | 0,15 |
| Aquatic ecosystem | NA | NA | NA | NA | NA | NA | 0,18 | NA | NA | 0,01 | |
| Agricultural: Irrigation | 40 | NA | NA | NA | 70 | 5 | 0,02 | 40 | 6.5-8.4 | 5 | |
| Agricultural: Livestock | 1000 | 1000 | 1000 | 500 | 2000 | 10 | 10 | 150 | NA | 5 | |
| 2018 | Site 1 | 296,00 | 40,30 | 23,18 | 16,36 | 49,16 | 0,45 | 0,02 | 49,54 | 8,16 | 0,08 |
| Site 2 | 486,33 | 108,48 | 47,04 | 26,99 | 72,87 | 0,20 | 0,17 | 75,75 | 7,77 | 0,14 | |
| Site 3 | 445,83 | 23,89 | 46,44 | 24,03 | 74,76 | 2,65 | 2,52 | 72,98 | 7,62 | 0,46 | |
| Site 4 | 182,50 | 57,31 | 30,83 | 8,02 | 12,71 | 0,22 | 0,03 | 28,18 | 6,77 | 0,24 | |
| Site 5 | 249,00 | 65,15 | 28,91 | 13,54 | 33,03 | 0,10 | 0,01 | 40,43 | 7,45 | 0,09 | |
| 2019 | Site 1 | 294,67 | 59,18 | 27,19 | 16,94 | 41,07 | 0,40 | 0,04 | 47,28 | 8,06 | 0,49 |
| Site 2 | 355,50 | 77,52 | 42,45 | 19,69 | 48,76 | 0,43 | 0,63 | 56,47 | 7,53 | 0,30 | |
| Site 3 | 421,17 | 69,07 | 45,33 | 24,14 | 57,02 | 1,02 | 0,91 | 65,86 | 7,36 | 0,14 | |
| Site 4 | 196,00 | 89,00 | 16,60 | 6,73 | 19,35 | 4,93 | 0,67 | 24,55 | 6,76 | 2,65 | |
| Site 5 | 369,00 | 137,58 | 38,58 | 18,98 | 41,45 | 0,77 | 0,06 | 54,79 | 7,36 | 1,06 | |
| 2020 | Site 1 | 277,17 | 55,99 | 22,02 | 14,78 | 44,20 | 0,24 | 0,02 | 44,44 | 8,00 | 0,11 |
| Site 2 | 584,17 | 144,49 | 61,22 | 34,48 | 72,62 | 0,70 | 2,95 | 86,89 | 7,86 | 0,43 | |
| Site 3 | 377,50 | 52,19 | 38,89 | 21,02 | 62,20 | 0,49 | 0,32 | 60,82 | 7,62 | 0,92 | |
| Site 4 | 204,00 | 89,31 | 20,24 | 7,49 | 19,98 | 1,08 | 0,20 | 25,45 | 6,82 | 2,34 | |
| Site 5 | 477,83 | 234,58 | 46,97 | 21,83 | 60,65 | 0,22 | 0,06 | 67,98 | 7,75 | 0,29 | |
| 2021 | Site 1 | 310,67 | 64,76 | 22,23 | 16,59 | 51,89 | 0,20 | 0,01 | 50,28 | 8,31 | 0,10 |
| Site 2 | 441,83 | 104,84 | 45,01 | 26,04 | 64,88 | 0,25 | 0,06 | 71,34 | 7,83 | 0,31 | |
| Site 3 | 495,50 | 58,84 | 49,52 | 33,05 | 68,72 | 0,67 | 0,34 | 77,62 | 7,84 | 0,25 | |
| Site 4 | 222,50 | 71,90 | 25,25 | 10,31 | 12,22 | 4,53 | 1,19 | 32,38 | 6,98 | 0,48 | |
| Site 5 | 674,00 | 366,00 | 70,96 | 33,93 | 82,82 | 0,10 | 0,03 | 94,28 | 7,88 | 0,08 | |
| 2022 | Site 1 | 238,83 | 26,05 | 22,50 | 14,32 | 30,43 | 0,13 | 0,02 | 37,28 | 7,68 | 0,08 |
| Site 2 | 355,17 | 75,04 | 39,84 | 20,79 | 42,20 | 0,41 | 0,07 | 55,51 | 7,54 | 0,28 | |
| Site 3 | 285,17 | 26,61 | 29,28 | 14,01 | 39,46 | 1,30 | 0,47 | 42,67 | 7,44 | 0,38 | |
| Site 4 | 311,00 | 83,83 | 32,04 | 14,82 | 34,19 | 1,30 | 0,54 | 45,08 | 7,07 | 1,02 | |
| Site 5 | 467,17 | 188,36 | 53,25 | 28,75 | 49,53 | 0,39 | 0,19 | 66,66 | 7,27 | 0,16 | |
| 2023 | Site 1 | 285,50 | 37,23 | 26,87 | 18,82 | 38,27 | 0,17 | 1,09 | 45,98 | 7,59 | 0,06 |
| Site 2 | 412,00 | 86,86 | 42,93 | 24,59 | 55,96 | 0,34 | 0,16 | 64,91 | 7,59 | 0,39 | |
| Site 3 | 322,33 | 32,17 | 36,61 | 20,05 | 43,86 | 0,42 | 0,29 | 53,19 | 7,34 | 0,08 | |
| Site 4 | 503,27 | 159,90 | 51,57 | 25,08 | 65,88 | 0,16 | 1,74 | 73,16 | 7,20 | 0,15 | |
| Site 5 | 690,50 | 360,30 | 77,78 | 39,00 | 72,92 | 0,13 | 0,03 | 95,21 | 7,51 | 0,08 | |
| WQI Class | Range | Site 1 | Site 2 | Site 3 | Site 4 | Site 5 |
|---|---|---|---|---|---|---|
| Excellent | WQI ≤ 25 | 6 | 7 | 2 | 2 | 5 |
| Good | 26 ≤ WQI ≤ 50 | 27 | 14 | 20 | 9 | 14 |
| Poor | 51 ≤ WQI ≤ 75 | 18 | 18 | 9 | 6 | 19 |
| Very Poor | 76 ≤ WQI ≤ 100 | 3 | 5 | 5 | 2 | 14 |
| Unsuitable for Use | WQI > 100 | 18 | 28 | 36 | 22 | 20 |
| Year | Sampling Site | F1 | F2 | F3 | CCME WQI | WQI Ranking |
|---|---|---|---|---|---|---|
| 2018 | Site 1 | 42,86 | 10,71 | 21,43 | 71,92 | Fair |
| Site 2 | 78,57 | 30,36 | 29,55 | 49,23 | Marginal | |
| Site 3 | 71,43 | 30,36 | 84,98 | 34,07 | Poor | |
| Site 4 | 28,57 | 21,43 | 16,99 | 79,83 | Good | |
| Site 5 | 28,57 | 38,69 | 4,74 | 82,69 | Good | |
| 2019 | Site 1 | 50,00 | 17,26 | 30,34 | 64,79 | Fair |
| Site 2 | 64,29 | 24,40 | 55,15 | 49,11 | Marginal | |
| Site 3 | 71,43 | 25,00 | 67,06 | 41,62 | Poor | |
| Site 4 | 21,43 | 21,43 | 84,65 | 48,09 | Marginal | |
| Site 5 | 71,43 | 25,60 | 51,79 | 46,96 | Marginal | |
| 2020 | Site 1 | 42,86 | 8,93 | 10,80 | 73,97 | Fair |
| Site 2 | 78,57 | 35,12 | 83,09 | 30,93 | Poor | |
| Site 3 | 64,29 | 20,24 | 53,92 | 50,17 | Marginal | |
| Site 4 | 21,43 | 14,29 | 66,67 | 58,74 | Marginal | |
| Site 5 | 71,43 | 26,79 | 27,62 | 53,16 | Marginal | |
| 2021 | Site 1 | 57,14 | 10,71 | 8,33 | 66,09 | Fair |
| Site 2 | 78,57 | 30,36 | 23,61 | 49,49 | Marginal | |
| Site 3 | 78,57 | 30,36 | 51,76 | 42,92 | Poor | |
| Site 4 | 28,57 | 21,43 | 83,25 | 47,70 | Marginal | |
| Site 5 | 64,29 | 38,69 | 19,66 | 55,22 | Marginal | |
| 2022 | Site 1 | 21,43 | 4,76 | 4,44 | 87,07 | Good |
| Site 2 | 42,86 | 20,24 | 28,01 | 68,22 | Fair | |
| Site 3 | 35,71 | 13,69 | 60,88 | 58,49 | Marginal | |
| Site 4 | 57,14 | 21,43 | 67,01 | 47,67 | Marginal | |
| Site 5 | 64,29 | 30,95 | 36,81 | 53,65 | Marginal | |
| 2023 | Site 1 | 50,00 | 11,90 | 61,04 | 53,93 | Marginal |
| Site 2 | 71,43 | 24,40 | 35,95 | 51,73 | Marginal | |
| Site 3 | 50,00 | 17,26 | 38,54 | 62,21 | Marginal | |
| Site 4 | 78,57 | 31,82 | 72,62 | 35,55 | Poor | |
| Site 5 | 57,14 | 31,55 | 25,07 | 59,63 | Marginal |
| Sampling Sites | Component | Initial Eigenvalues | Rotation sums of squared loadings | ||||
|---|---|---|---|---|---|---|---|
| Total | % of variance | Cumulative % | Total | % of variance | Cumulative % | ||
| Site 1 | 1 | 6,77 | 35,64 | 35,64 | 5,83 | 30,68 | 30,68 |
| 2 | 2,53 | 13,32 | 48,95 | 2,32 | 12,23 | 42,91 | |
| 3 | 2,14 | 11,25 | 60,85 | 2,18 | 11,47 | 54,38 | |
| 4 | 1,83 | 9,65 | 69,85 | 2,13 | 11,21 | 65,59 | |
| 5 | 1,15 | 6,05 | 75,90 | 1,94 | 10,19 | 75,78 | |
| 6 | 1,00 | 5,28 | 81,18 | 1,03 | 5,40 | 81,18 | |
| Site 2 | 1 | 9,27 | 48,81 | 48,81 | 8,77 | 46,16 | 46,16 |
| 2 | 3,10 | 16,29 | 65,10 | 3,06 | 16,09 | 62,24 | |
| 3 | 1,85 | 9,73 | 74,83 | 2,38 | 12,55 | 74,79 | |
| 4 | 1,13 | 5,96 | 80,79 | 1,14 | 6,00 | 80,79 | |
| Site 3 | 1 | 8,07 | 42,46 | 42,46 | 7,30 | 38,41 | 38,41 |
| 2 | 2,35 | 12,37 | 54,83 | 2,36 | 12,39 | 50,80 | |
| 3 | 1,77 | 9,33 | 64,17 | 2,09 | 10,98 | 61,78 | |
| 4 | 1,20 | 6,31 | 70,48 | 1,44 | 7,60 | 69,37 | |
| 5 | 1,14 | 6,00 | 76,47 | 1,27 | 6,69 | 76,06 | |
| 6 | 1,10 | 5,79 | 82,26 | 1,18 | 6,20 | 82,26 | |
| Site 4 | 1 | 7,63 | 40,16 | 40,16 | 5,89 | 30,99 | 30,99 |
| 2 | 3,10 | 16,29 | 56,45 | 3,97 | 20,89 | 51,87 | |
| 3 | 1,78 | 9,35 | 65,80 | 2,51 | 13,23 | 65,10 | |
| 4 | 1,39 | 7,33 | 73,12 | 1,43 | 7,51 | 72,61 | |
| 5 | 1,03 | 5,40 | 78,52 | 1,10 | 5,77 | 78,38 | |
| 6 | 1,01 | 5,29 | 83,81 | 1,03 | 5,43 | 83,81 | |
| Site 5 | 1 | 7,44 | 39,18 | 39,18 | 7,15 | 37,65 | 37,65 |
| 2 | 3,53 | 18,59 | 57,76 | 3,13 | 16,45 | 54,10 | |
| 3 | 1,93 | 10,16 | 67,92 | 2,16 | 11,39 | 65,49 | |
| 4 | 1,85 | 9,73 | 77,65 | 2,05 | 10,78 | 76,27 | |
| 5 | 1,06 | 5,57 | 83,22 | 1,32 | 6,95 | 83,22 | |
| Sites | Component | Variables | ||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Turbidity | Na | EC | TDS | K | SO4 | Mg | pH | N | Ca | SS | Al | Fe | Cl | F | Alk | Mn | PO4 | Hardness | ||
| Site 1 | 1 | 0,94 | 0,89 | 0,88 | 0,79 | 0,69 | 0,67 | 0,61 | 0,95 | 0,52 | ||||||||||
| 2 | 0,44 | 0,73 | 0,65 | 0,61 | 0,53 | |||||||||||||||
| 3 | 0,66 | 0,87 | 0,76 | |||||||||||||||||
| 4 | 0,42 | 0,87 | 0,82 | |||||||||||||||||
| 5 | 0,47 | 0,57 | 0,78 | 0,57 | ||||||||||||||||
| 6 | 0.96 | |||||||||||||||||||
| Site 2 | 1 | 0,86 | 0,94 | 0,97 | 0,60 | 0,85 | 0,97 | 0,92 | 0,64 | 0,92 | 0,60 | 0,84 | 0,98 | |||||||
| 2 | 0,94 | 0,51 | 0,90 | 0,74 | 0,49 | 0,41 | ||||||||||||||
| 3 | 0,72 | 0,74 | 0,60 | |||||||||||||||||
| 4 | 0,96 | |||||||||||||||||||
| Site 3 | 1 | 0,87 | 0,96 | 0,96 | 0,80 | 0,55 | 0,92 | 0,77 | 0,87 | 0,62 | 0,26 | 0,89 | ||||||||
| 2 | 0,54 | 0,54 | 0,64 | 0,83 | ||||||||||||||||
| 3 | 0,78 | 0,46 | 0,74 | 0,58 | ||||||||||||||||
| 4 | 0,87 | 0,48 | ||||||||||||||||||
| 5 | 0,74 | 0,59 | ||||||||||||||||||
| 6 | 0,90 | |||||||||||||||||||
| Site 4 | 1 | 0,48 | 0,75 | 0,88 | 0,94 | 0,82 | 0,93 | 0,81 | 0,91 | |||||||||||
| 2 | 0,83 | 0,63 | 0,63 | 0,88 | 0,86 | |||||||||||||||
| 3 | 0,76 | 0,84 | 0,55 | 0,83 | ||||||||||||||||
| 4 | 0,69 | 0,91 | ||||||||||||||||||
| 5 | 0,97 | |||||||||||||||||||
| 6 | 0,98 | |||||||||||||||||||
| Site 5 | 1 | 0.93 | 0.98 | 0.98 | 0.97 | 0.96 | 0.53 | 0.97 | 0.98 | |||||||||||
| 2 | 0.52 | 0.93 | 0.93 | 0.90 | ||||||||||||||||
| 3 | 0.85 | 0.56 | 0.88 | |||||||||||||||||
| 4 | 0.96 | 0.92 | ||||||||||||||||||
| 5 | 0.62 | 0.77 | 0.49 | |||||||||||||||||
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