This study examines how the Internet of Things (IoT) acts as a key enabler of sustainability in industrial production systems within the Industry 4.0 paradigm, addressing the fragmented understanding of the mechanisms linking digital technologies to environmental, operational, and emerging human-centric outcomes. A systematic literature review was conducted following PRISMA 2020 guidelines using the Web of Science Core Collection. After applying explicit inclusion and exclusion criteria, 69 peer-reviewed studies published between 2016 and 2026 were analyzed through qualitative thematic synthesis and comparative analysis. The findings reveal that IoT functions as a foundational digital infrastructure enabling real-time monitoring, operational transparency, and data-driven decision-making in production environments. Four dominant application domains are identified: (i) energy and resource efficiency, (ii) production monitoring and control, (iii) predictive maintenance and asset management, and (iv) emerging human-centric production systems aligned with Industry 5.0. While IoT consistently improves operational reliability and resource efficiency, its contribution to the social dimension of sustainability remains comparatively underdeveloped. This study advances existing literature by providing a mechanism-oriented synthesis that explains how IoT-enabled infrastructures generate sustainability outcomes across production systems. Furthermore, it establishes a conceptual bridge between Industry 4.0 digitalization and the transition toward human-centric and resilient manufacturing models associated with Industry 5.0. From a practical perspective, the results highlight that IoT adoption contributes to reducing energy consumption, optimizing resource utilization, and enhancing operational performance, while also supporting safer and more adaptive working environments. However, challenges related to data integration, workforce adaptation, and digital capability gaps persist, underscoring the need for inclusive and strategically aligned digital transformation processes.