Submitted:
15 December 2025
Posted:
17 December 2025
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Abstract
Keywords:
1. Introduction
2. Materials and Methods
2.1. Site Description and Soil
2.2. Lysimeter Design, and Arrangement
2.3. Experimental Design, Planting, and N Fertiliser Treatments
2.4. Total Nitrogen Uptake Determination
2.5. Measurement and Modelling of Nitrate Leaching Losses from the Lysimeters
2.5.1. Overview of Overseer Model
2.5.2. Input data requirements of the model for lysimeter simulations
2.5.3. Nitrate Leaching Simulations
2.6. Error Analysis of Overseer
2.6.1. Mean Difference (Md)
2.6.2. Root Mean Square Error (RMSE)
2.6.3. Percent of Relative Error (Er %)
2.6.4. Regression Equation
2.7. Sensitivity Analysis
2.8. Data Analysis
3. Results
3.1. Simulated Annual Water Fluxes
3.2. Cumulative Nitrate Leaching Losses During Beetroot Cropping
3.3. Cumulative Nitrate Leaching Losses During Pak Choi Cropping
3.4. Crop N Uptake
3.5. Sensitivity Analysis
3.5.1. Length of Fallow Period
3.5.2. Impeded Layer Depth
3.5.3. Soil Group and Texture
3.5.4. Saturated Hydraulic Conductivity
3.5.5. Amount of Incorporated Material
3.6. Evaluation of the Precision of Overseer
4. Discussion
4.1. Nitrate Leaching Predictions
4.2. Sensitivity of the Model
4.3. Evaluation of the Precision of Overseer Under Different Fertiliser Regimes
4.4. Overall Simulation Performance of Overseer
4.5. Uncertainties Associated with the Simulation Scenarios
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| N | Nitrogen |
| NO3- | Nitrate |
| Md | Mean difference |
| RMSE | Root Mean Square Error |
| Er | Error |
| CAN | Calcium Ammonium Nitrate |
| CRF | Controlled Release Fertiliser |
| EXC | Excess |
| STD | Standard |
| SCRUM-APSIM | Simple Crop Resource Uptake Model-Agricultural Production Systems sIMulator |
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| Treatments | Measured leaching losses (kg N/ha) | predicted leaching losses (kg N/ha) |
| CTRL | 73.4 | 120 |
| CRF 1 | 76.4 | 101 |
| CRF 2 | 111.2 | 97 |
| STD 1 | 96.7 | 130 |
| STD 2 | 78.3 | 131 |
| EXC 1 | 93.4 | 112 |
| EXC 2 | 95.5 | 71 |
| Treatments | Measured leaching losses (kg N/ha) | Overseer predicted leaching losses (kg N/ha) |
| CTRL | 260.9 | 266 |
| CRF 1 | 299.2 | 326 |
| CRF 2 | 404.2 | 273 |
| STD 1 | 299.6 | 344 |
| STD 2 | 302.1 | 392 |
| EXC 1 | 277.0 | 313 |
| EXC 2 | 286.9 | 356 |
| Year | Simulation scenario | Cumulative water drainage (mm) | |
| Measured (mean ± 95% C.I) | Overseer simulated | ||
| Year 1 | CTRL | 440 ± 183 | 621 |
| CRF1 | 425 ± 221 | 621 | |
| CRF2 | 641 ± 162 | 621 | |
| STD 1 | 490 ± 230 | 621 | |
| STD 2 | 439 ± 140 | 621† | |
| EXC 1 | 466 ± 109 | 621† | |
| EXC 2 | 410 ± 255 | 621 | |
| Year 2 | CTRL | 422 ± 368 | 556 |
| CRF1 | 383 ± 220 | 529 | |
| CRF2 | 559 ± 147 | 529 | |
| STD 1 | 482 ± 380 | 556 | |
| STD 2 | 522 ± 288 | 556 | |
| EXC 1 | 431 ± 265 | 529 | |
| EXC 2 | 439 ± 290 | 529 | |
|
No. |
Input variables |
Simulation scenarios | |||||||
| Ctrl | CRF 1 | CRF 2 | STD 1 | STD 2 | EXC 1 | EXC 2 | |||
| Beetroot (year 1) | |||||||||
| 1. | Soil residual N (kg N/ha) | 32 | 32 | 32 | 32 | 32 | 32 | 32 | |
| 2. | Fresh yield (t/ha) | 64 | 70 | 69 | 65 | 73 | 70 | 65 | |
| 3. | Month and amount of fertiliser application (kg N/ha) (including Nitrophoska) | 0 | Jan, 115.2 | Jan, Mar 115.2 | Jan, 117.0 | Jan, Feb 117.0 | Jan, 198.0 | Jan, 198.0 | |
| 4. | Amount of incorporated harvest material, dry matter (DM) and N concentration | ||||||||
| (a) Beetroots | Amount (kg) | 63632 18 3.3 |
70208 14 3.5 |
68560 14 2.7 |
65112 16 3.0 |
72620 17 3.4 |
69888 16 2.7 |
65024 15 3.5 |
|
| DM% | |||||||||
| N % | |||||||||
| (b) Beetroot leaves | Amount (kg) | 33696 11 2.5 |
34544 11 2.8 |
34080 11 2.6 |
35776 11 2.7 |
38928 11 2.7 |
32496 12 2.5 |
36736 11 2.9 |
|
| DM% | |||||||||
| N % | |||||||||
| Pak choi (year 2) | |||||||||
| 1. | Soil residual N (kg N/ha) | 92.2 | 110.4 | 97.4 | 80.9 | 120 | 84.2 | 94.4 | |
| 2. | Fresh yield (t/ha) | 102 | 117 | 112 | 111 | 114 | 130 | 124 | |
| 3. | Amount of harvest material incorporated | 0 | 0 | 0 | 0 | 0 | 0 | 0 | |
| 4. | Month and amount of fertiliser application (kg N/ha) | 0 | Jan, 48 | Jan, Mar 48 | Jan, 49 | Jan, Mar 48 | Jan, 97 | Jan, Mar 98 | |







|
No. |
Input variables |
Simulation scenarios | |||||||
| Ctrl | CRF 1 | CRF 2 | STD 1 | STD 2 | EXC 1 | EXC 2 | |||
| Beetroot (year 1) | |||||||||
| 1. | Soil residual N (kg N/ha) | 32 | 32 | 32 | 32 | 32 | 32 | 32 | |
| 2. | Fresh yield (t/ha) | 64 | 70 | 69 | 65 | 73 | 70 | 65 | |
| 3. | Month and amount of fertiliser application (kg N/ha) (including Nitrophoska) | 0 | Jan, 115.2 | Jan, Mar 115.2 | Jan, 117.0 | Jan, Feb 117.0 | Jan, 198.0 | Jan, 198.0 | |
| 4. | Amount of incorporated harvest material, dry matter (DM) and N concentration | ||||||||
| (a) Beetroots | Amount (kg) | 63632 18 3.3 |
70208 14 3.5 |
68560 14 2.7 |
65112 16 3.0 |
72620 17 3.4 |
69888 16 2.7 |
65024 15 3.5 |
|
| DM% | |||||||||
| N % | |||||||||
| (b) Beetroot leaves | Amount (kg) | 33696 11 2.5 |
34544 11 2.8 |
34080 11 2.6 |
35776 11 2.7 |
38928 11 2.7 |
32496 12 2.5 |
36736 11 2.9 |
|
| DM% | |||||||||
| N % | |||||||||
| Pak choi (year 2) | |||||||||
| 1. | Soil residual N (kg N/ha) | 92.2 | 110.4 | 97.4 | 80.9 | 120 | 84.2 | 94.4 | |
| 2. | Fresh yield (t/ha) | 102 | 117 | 112 | 111 | 114 | 130 | 124 | |
| 3. | Amount of harvest material incorporated | 0 | 0 | 0 | 0 | 0 | 0 | 0 | |
| 4. | Month and amount of fertiliser application (kg N/ha) | 0 | Jan, 48 | Jan, Mar 48 | Jan, 49 | Jan, Mar 48 | Jan, 97 | Jan, Mar 98 | |
| Year | Simulation scenario | Cumulative water drainage (mm) | |
| Measured (mean ± 95% C.I) | Overseer simulated | ||
| Year 1 | CTRL | 440 ± 183 | 621 |
| CRF1 | 425 ± 221 | 621 | |
| CRF2 | 641 ± 162 | 621 | |
| STD 1 | 490 ± 230 | 621 | |
| STD 2 | 439 ± 140 | 621† | |
| EXC 1 | 466 ± 109 | 621† | |
| EXC 2 | 410 ± 255 | 621 | |
| Year 2 | CTRL | 422 ± 368 | 556 |
| CRF1 | 383 ± 220 | 529 | |
| CRF2 | 559 ± 147 | 529 | |
| STD 1 | 482 ± 380 | 556 | |
| STD 2 | 522 ± 288 | 556 | |
| EXC 1 | 431 ± 265 | 529 | |
| EXC 2 | 439 ± 290 | 529 | |
| Treatments | Measured leaching losses (kg N/ha) | Overseer predicted leaching losses (kg N/ha) |
| CTRL | 260.9 | 266 |
| CRF 1 | 299.2 | 326 |
| CRF 2 | 404.2 | 273 |
| STD 1 | 299.6 | 344 |
| STD 2 | 302.1 | 392 |
| EXC 1 | 277.0 | 313 |
| EXC 2 | 286.9 | 356 |
| Treatments | Measured leaching losses (kg N/ha) | predicted leaching losses (kg N/ha) |
| CTRL | 73.4 | 120 |
| CRF 1 | 76.4 | 101 |
| CRF 2 | 111.2 | 97 |
| STD 1 | 96.7 | 130 |
| STD 2 | 78.3 | 131 |
| EXC 1 | 93.4 | 112 |
| EXC 2 | 95.5 | 71 |
| Year | Simulations | Md | RMSE | Er% |
| Year 1 | CTRL | -5.0 ns | 157.0 | - 0.4 |
| CRF 1 | - 26.8 ns | 113.7 | -1.8 | |
| CRF 2 | 131.1* | 151.0 | 6.5 | |
| STD 1 | - 13.3 ns | 135.3 | - 0.9 | |
| STD 2 | -53.8 ns | 114.0 | -3.5 | |
| EXC 1 | - 66.9 ns | 124.1 | -4.8 | |
| EXC 2 | - 105 ns | 180.3 | - 7.3 | |
| Year 2 | CTRL | - 46.6 ns | 59.4 | - 12.7 |
| CRF 1 | 24.6 ns | 39.8 | -6.4 | |
| CRF 2 | 14.2 ns | 47.8 | 2.5 | |
| STD 1 | - 33.2 ns | 67.6 | - 6.8 | |
| STD 2 | - 52.7* | 62.6 | - 13.4 | |
| EXC 1 | - 18.5 ns | 48.0 | - 3.9 | |
| EXC 2 | 24.5ns | 51.5 | 5.1 |
| Statistical parameter | NO3-leaching loss (kgN /ha) |
P value |
| Correlation coefficient (r) | 0.89 | < 0.0001 |
| Slope (b) | 0.89 | < 0.0001 |
| Intercept (a) | 39.4 | 0.21 |
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