Noting that the specifications of the configuration shell quantum numbers
l in both
generator and atomic
-energy level orbital state spectra are precisely consistent, we harmonize the specifications of the
symmetric-antisymmetric generator pair and the atomic magnetic quantum numbers,
m, by considering that in the atomic orbital state spectrum, the single
,
state
takes a symmetrically neutral unit value obtained as
while the remaining
orbital states
,
, specified by
can be reinterpreted as
l conjugate pairs (
), now specified by
l values of the magnetic quantum number
according to the standard relation [16 , 17]
Taking the single symmetrically neutral orbital state
in Equation (
24) and the
l conjugate pairs
related according to Equation (
25) together, we now redefine the atomic magnetic quantum number
m as a conjugate orbital state pair quantum number taking
values
including the unit state
, which is now precisely consistent with the specification of the
symmetric-antisymmetric generator pair quantum number
m also taking
values
including the identity generator
.
We now redefine the
generators and introduce an appropriate notation specified by the quantum numbers
l ,
m corresponding directly to the specification and notation of the atomic orbital angular momentum states
,
. Such a redefinition of
generators is easily achieved in the spin angular momentum basis, where we follow the formulae for enumerating and determining
generators in symmetric-antisymmetric pairs in equations (3) , (4) to introduce hermitian conjugate spin angular momentum state raising and lowering operators
defined by
Using the
symmetry group basis state vector orthonormality relation given in Equation (
2), noting
we obtain the algebraic relations
The
generators in the Gell-Mann basis
are now interpreted as hermitian spin angular momentum operators specified by quantum numbers
l ,
m. In particular, the off-diagonal symmetric-antisymmetric generator pair (
) enumerated and determined according to the formula in Equation (3) is now interpreted as the off-diagonal symmetric-antisymmetric hermitian spin operator pair (
) determined in the form
while the diagonal symmetric-antisymmetric generator pair (
) enumerated and determined according to the formula in Equation (
4) is now interpreted as the diagonal symmetric-antisymmetric generator hermitian spin operator pair (
) determined according to Equation (
4) in the form
It follows from the definitions in equations (28) , (29) , (30) , (31) that the off-diagonal generators
,
and the diagonal generators are expressed in terms of the spin state raising and lowering operators
in the form
We interpret the
traceless off-diagonal generators
,
(enumerated by
) and the single traceless diagonal generator
(enumerated by
) as components of a
-component
-shell spin angular momentum vector
defined by
We then introduce an
-shell quadratic spin angular momentum operator
obtained as
Using
,
from Equation (
32) gives
which we substitute into Equation (
34) to obtain the form
To introduce some higher order spin operators, we use the algebraic relations in equations (28) , (29) , (30) , (31) to obtain the following algebraic relations
We can now use these general algebraic properties of the
generators in the spin angular momentum basis to introduce generalizations of the
-shell quadratic spin angular momentum
to higher order spin operators. Noting that
as defined in Equation (
34) is an even-power spin operator, we introduce generalizations to
-shell
even-power spin operator and
odd-power spin operator of
-order,
defined by
Using equations (37) , (38), we obtain
which we substitute into Equation (
39) as appropriate to express the even-power and odd-power spin operators in the form
Setting
in Equation (
41) gives 0
th-order even and odd power spin operators
,
in the
-shell in the form
where
I is the full
identity generator. We observe that the
-shell odd-power spin operator of 0
th-order,
, obtained here in Equation (
42) takes a form precisely similar to the form of a semiclassical spin Hamiltonian operator, which we define here as a spin state superposition operator. In general, we may now identify the
-shell odd-power spin operator
in Equation (
41) as the
-shell spin state superposition operator of
-order. On the other hand, the property that the full
identity
I commutes with all the
generators, the sub-identity
commutes with all the corresponding generators within the
-shell means that the 0
th-order even-power spin operator
commutes with all the
generators within the
-shell, meaning that
may be interpreted as a Casimir operator within the
-shell. In addition, it is important to note that setting
in
in Equation (
41) gives the 1
st-order even-power spin operator
in the form
which we identify as the
-shell quadratic spin angular momentum operator
obtained in Equation (
36). We may then interpret the general
-shell even-power spin operator
in Equation (
41) as the
-shell quadratic spin angular momentum operator of
-order.
We have now defined the full content of the
-shell of the orbital spectrum of an
symmetry group in spin angular momentum interpretation. Having
traceless generators expressed as spin angular momentum operators
,
,
, together with the corresponding
-order quadratic spin angular momentum operator
and spin state superposition operator
, the
-shell of an
symmetry group orbital spectrum of generators now takes the form presented in Equation (
43) below.
In the spin angular momentum basis, the
traceless generators within the
-shell are correlated by an algebra obtained in the general form
corresponding to the
-shell algebra in the Gell-Mann basis in Equation (
6).
As examples, we present the standard orbital spectra of generators of
,
,
,
symmetry groups in the spin angular momentum basis, including the respective
-shell quadratic spin angular momentum and spin state superposition operators of
-order in equations (45)-(48) below.
The generators are determined in explicit forms using the definitions of the spin state raising and lowering operators
in Equation (
27) for
,
, with the respective group basis vectors defined in equations (7) , (9) , (11) , (12). The resulting matrix forms are exactly the same as the corresponding Gell-Mann matrices obtained in the respective orbital spectra of
,
,
,
in equations (8) , (10) , (11) , (12), enumerated according to the relations in equations (30) , (31).
4.1. Symmetry Group Algebra in the Cartan-Weyl Basis
Let us now determine the basic algebraic properties of the
traceless generators distributed among the
configuration shells in the standard orbital spectrum of an
symmetry group. We use the property that in the spin angular momentum basis, the
-shell contains 1 traceless diagonal generator
, which we identify as a Cartain generator
, and
traceless off-diagonal generators
,
, composed of two hermitian conjugate spin angular momentum operators
,
according to Equation (
30). We identify the set
,
,
as the Cartan-Weyl basis in the
-shell [18 , 19]. The algebra generated by the Cartan-Weyl basis constitutes the Cartan subalgebra of the
traceless generators within the
-shell. The
-shell and therefore, each of the
(
) configuration shells in the orbital spectrum of an
symmetry group, may be interpreted as a Cartan-Weyl subspace. The complete algebraic properties of the
symmetry group is then determined by the algebra of the Cartan-Weyl basis in each of the
shells (subspaces) and the algebra of correlations across the shells, which we have determined in the general forms as presented below.
The
Cartan generators
in the orbital spectrum of generators mutually commute, satisfying
where the two different quantum numbers
specify two different shells. ,
The Cartan-Weyl subalgebra of the basis
,
,
within the
-shell is obtained in the general form governing correlations among all the
traceless generators as
where two different pair quantum numbers
specify two different generators within the
-shell.
Across the configuration shells, the Cartan generators
in
higher shells specified by
commute with all operators
in the
lower shells specified by
according to the algebraic relations
while Cartan generators
in lower shells specified by
have mixed algebraic relations with the operators
in the upper shells specified by
;
according to
Finally, the commutation brackets across shells between operators
in lower shells (
) and operators
in higher shells (
)
vanish, except for the case
, giving the general forms:
The full set of algebraic properties in equations (49)-(53) captures the complete quantum structure of an
symmetry group with generators systematically distributed among
configuration shells (Cartan-Weyl subspaces) in an orbital spectrum specified by quantum numbers
,
. Note that in the familiar Gell-Mann basis, the generators in the Cartan-Weyl basis within the
-shell (or
-subspace) are defined by
,
. It is straightforward to check that in the respective Cartan-Weyl basis, the
,
,
,
generators determined explicitly in equations (8) , (10) , (11) , (12) satisfy the algebraic properties in equations (49)-(53).