Submitted:
16 October 2024
Posted:
17 October 2024
You are already at the latest version
Abstract

Keywords:
1. Introduction
- Easy integration into real-time applications by reducing computational resources, computational burden, and the complexity of its start-up.
- Adaptability of the SOH estimator to changes in battery behavior according to different applications.
- Utilization of generally available battery datasheet parameters and low-cost instrumentation for parametric estimation and validation of online SOH estimation (as well as state-of-charge (SOC) estimation).
- Versatility in modeling different battery technologies, considering implementation cost and applicability to battery management and optimization systems in engineering and research.
2. Proposed Real-Time SOH Estimator Based on a Partial Discharge Method
2.1. SOH Energy
2.2. Partial Discharge Method
2.3. SOH Model Deduction
- A battery voltage level that indicates when the battery is fully charged and it is also used to indicate the battery voltage at the beginning of the discharge ; this value is defined as the float voltage and will be used as a constant because it is obtained from battery datasheet, and
- A battery voltage level that indicates when the battery is fully discharged (the battery voltage value at the end of the backup period ), which is known as the final voltage , and this voltage level changes for every constant current profile.
2.4. Algorithm for Real-Time SOH Estimation
3. Test Results of the Proposed Method for Estimating SOH and SOC in Real-Time
- 1.
- An offline Simulink-MATLAB simulation is conducted to validate the SOH estimator, using the models of the three different battery technologies.
- 2.
- A real-time simulation of an EV-BMS into the MIL environment on OPAL-RT is performed to validate the SOH estimation proposal by using the Lithium-ion battery model.
3.1. Simulation 1
3.2. Simulation 2
4. Conclusion
Author Contributions
Funding
Conflicts of Interest
Abbreviations
| ANN | Artificial Neural Networks |
| BMS | Battery Management Systems |
| CCM | Coulomb Counting Method |
| Com | Complex |
| DDM | Data-Driven Methods |
| DVA | Differential Voltage Analysis |
| EIS | Electrochemical Impedance Spectroscopy |
| ECM | Electrical circuit model |
| EVs | Electric Vehicles |
| EV-BMS | Electric Vehicles-Battery Management Systems |
| FL | Fuzzy Logic |
| GA | Genetic Algorithms |
| ICA | Incremental Capacity Analysis |
| IRM | Internal Resistance Measurement |
| KF | Kalman Filter |
| Lim | Limited |
| Li-ion | Lithium-ion |
| Med | Medium |
| MIL | Model in loop |
| Mod | Moderately |
| NiMH | Nickel-methal hydride |
| OCV | Open-Circuit Voltage |
| Off | Offline |
| OM | Observer Methods |
| On | Online |
| Pb-acid | Lead-acid |
| PDM | Partial Discharge Method |
| PE | Peukert Equation |
| RMSE | Root Mean Square Error |
| SM | Shepherd’s Model |
| SOC | State of Charge |
| SOH | State of Health |
| UM | Ultrasonic Method |
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| Attributes / Methods | Desired | CCM | ICA, DVA |
PE, SM |
KF | OM | DDM | UM | EIS | OCV | IRM |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Online/Off-line | On | On | On | On | On | On | On | On | On | Off | Off |
| For embedded systems | Easy | Easy | Mod | Lim | Mod | Mod | Com | Com | Com | Easy | Easy |
| Computational resources/burden | Low | Low | Med | Low | High | Med | High | High | High | Low | Low |
| Calibration for start-up | Easy | Easy | Easy | Easy | Mod | Mod | Com | Com | Com | Easy | Mod |
| Charge/discharge description | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | |||
| For fault detection/diagnosis | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ||||
| Design and implementation cost | Low | Low | Med | Low | Med | Low | High | High | High | Low | Low |
| Used in reliable engineering | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ||
| Used in research & development | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | |||
| For management & optimization | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | |||||
| Estimation with interval data | ✔ | ✔ |
| Parameters and equations | Method and description |
|---|---|
|
Available capacitance: . |
Integral of the battery current method (in a full-discharge test): is in Farads [29], and are cycle number and temperature-dependent correction factors (dimension-less), respectively (they are ideally “1” because and temperature are considered constants each cycle), and is a constant equal to 3600 seconds per volt-hours. |
|
Internal resistance: . |
Current and voltage step (at in Figure 2): is in Ohms [18]. j represents the rest period number. is estimated by averaging the J resistance values obtained by the ratio between and (at the transition of to 0 A), at the begin of each j-th . |
|
Open-circuit voltage: . |
Linear function of the open-circuit voltage versus SOC voltage: (in Volts) is estimated by linear regression of J values of OCV obtained at the end of each j-th (at ). M and K are constants. |
|
RC parameters: . |
Linearized exponential regression (every and after a pulse): and are in Ohms, and are in Faradas [18]. The measured voltage data of each (between and ) is conditioned as a two-term exponential function. is the voltage value at the end of every (at ). The value of is obtained by the integral of the current at the j-th discharge segment. Coefficients a, b, c, and d are calculated by the Curve Fitting Toolbox in MATLAB [18]. RC parameters are estimated by the average of the J values of the j-th coefficients a, b, c, and d obtained at every j-th . |
| Battery data (math. symbol, and unit) | NiMH | Pb-acid | Li-ion |
|---|---|---|---|
| Nominal Voltage (, V) | 1.2 a | 2.0 b | 3.6 c |
| Float voltage (, V) | 1.4 a | 2.35 b | 4.2 c |
| Nominal Capacity (, Ah) | 2.3 a | 6.0 b | 2.7 c |
| Available Capacity (, Ah) | 1.448 | 6.592 | 1.339 |
| Equivalent available capacitance (, F) | 5212.8 | 23731.2 | 4820.4 |
| Internal resistance (, ) | 0.05744 | 0.02165 | 0.02430 |
| Transient resistance one (, ) | 0.02173 | 0.01380 | 0.05577 |
| Transient resistance two (, ) | 0.02175 | 0.03470 | 0.09786 |
| Transient capacitance one (, F) | 5.7635 | 38734.5258 | 1045.6885 |
| Transient capacitance two (, F) | 112.2328 | 1519282.831 | 379918.1737 |
| Slope of the linear OCV function (M, dimensionless) | 0.1133 | 0.2555 | 0.9755 |
| Constant of the linear OCV function (K, V) | 1.1886 | 1.9372 | 3.215 |
| Coefficient | NiMH | Pb-acid | Li-ion |
|---|---|---|---|
| 41.9330 | 1.8965 | 2.6896 | |
| -39.5367 | 3.5968 | 7.2341 | |
| -93.7191 | 1.8965 | 2.6896 | |
| -3.0812 | 1.1941 | 1.0664 |
| Coefficients | NiMH | Pb-acid | Li-ion |
|---|---|---|---|
| (V) | 1.14 | 1.83 | 3.27 |
| (V) | -0.142 | -0.161 | -1.79 |
| (1/s) | -0.183 | -0.0914 | 5.25 |
| (V) | -0.102 | -0.384 | -0.630 |
| (1/s) | -2.07 | -1.31 | -0.500 |
| Coefficients | NiMH | Pb-acid | Li-ion |
|---|---|---|---|
| (·) | 1.04 | 1.14 | 1.16 |
| (·) | -0.00471 | -0.142 | 0.0148 |
| (1/A) | 0.748 | -0.183 | -0.345 |
| (·) | -0.0440 | -0.102 | 0.0418 |
| (1/A) | -0.376 | -2.07 | -2.30 |
| (A) | 2.30 | 3.60 | 2.7 |
| (h) | 1 | 1 | 1 |
| Data description | NiMH | Pb-acid | Li-ion |
|---|---|---|---|
| Observed battery voltage’s RMSE | 0.037747 | 0.01621 | 0.007452 |
| Expected SOH voltage (given by: ) | 0.629 (∼62.9 %) | 1.000 (∼100 %) | 0.495 (∼49.5 %) |
| used to estimate | 0.02 (∼2 %) | 0.07 (∼7 %) | 0.05 (∼5 %) |
| Data description | Li-ion |
|---|---|
| Observed battery voltage’s RMSE | 0.001671 |
| Expected SOH voltage (by: ) | 0.495 (∼49.5 %) |
| used to estimate | 0.01 (∼1 %) |
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