Version 1
: Received: 23 December 2023 / Approved: 25 December 2023 / Online: 25 December 2023 (09:24:20 CET)
How to cite:
Alotaibi, M. M.; Alharthi, A. M.; Alkayal, N. S.; Alrayyani, M. A. Synthesis and Characterization of Bromine- and Hydroxyl-Functionalized Polyaminals for CO₂ Capture. Preprints2023, 2023121792. https://doi.org/10.20944/preprints202312.1792.v1
Alotaibi, M. M.; Alharthi, A. M.; Alkayal, N. S.; Alrayyani, M. A. Synthesis and Characterization of Bromine- and Hydroxyl-Functionalized Polyaminals for CO₂ Capture. Preprints 2023, 2023121792. https://doi.org/10.20944/preprints202312.1792.v1
Alotaibi, M. M.; Alharthi, A. M.; Alkayal, N. S.; Alrayyani, M. A. Synthesis and Characterization of Bromine- and Hydroxyl-Functionalized Polyaminals for CO₂ Capture. Preprints2023, 2023121792. https://doi.org/10.20944/preprints202312.1792.v1
APA Style
Alotaibi, M. M., Alharthi, A. M., Alkayal, N. S., & Alrayyani, M. A. (2023). Synthesis and Characterization of Bromine- and Hydroxyl-Functionalized Polyaminals for CO₂ Capture. Preprints. https://doi.org/10.20944/preprints202312.1792.v1
Chicago/Turabian Style
Alotaibi, M. M., Nazeeha S. Alkayal and Maymounah A. Alrayyani. 2023 "Synthesis and Characterization of Bromine- and Hydroxyl-Functionalized Polyaminals for CO₂ Capture" Preprints. https://doi.org/10.20944/preprints202312.1792.v1
Abstract
Increased CO2 emissions and air pollution impact the environment and human health. In this manner, new functionalized polyaminal-based polymers are synthesized via a one-pot polycondensation reaction of melamine with aldehyde monomers 2-bromo-1-naphthaldehyde and 2-hydroxy-1-naphthaldehyde to yield bromine- hydroxyl- functionalized polymer networks PAN-BrNA and PAN-HNA, respectively. The polyaminals porosity parameters were investigated and applied as an adsorbent for CO2 capture. FTIR, solid-state 13C NMR, and X-ray diffraction verified the PANs structure development. A scanning electron microscope and N2 adsorption-desorption methods were utilized to identify the porous properties of the polymers at 77 K. The Brunauer-Emmett-Teller (BET) surface area of PAN-BrNA and PAN-HNA is (16.6990 m2/g) and (716.7568 m2/g), respectively. At 273 K, PAN-BrNA and PAN-HNA can take CO2 gas up to (4.42786 cm3/g) and (47.55 cm3/g), respectively. The findings show that inserting functional groups has a significant impact on surface area and porosity parameters, as well as CO2 uptake.
Keywords
porous organic polymer, polyaminal-linked polymers, melamine, surface area, CO2 capture
Subject
Chemistry and Materials Science, Polymers and Plastics
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
